CN104810544A - Rechargeable aluminum ion battery and preparation method thereof - Google Patents
Rechargeable aluminum ion battery and preparation method thereof Download PDFInfo
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- CN104810544A CN104810544A CN201510188866.4A CN201510188866A CN104810544A CN 104810544 A CN104810544 A CN 104810544A CN 201510188866 A CN201510188866 A CN 201510188866A CN 104810544 A CN104810544 A CN 104810544A
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- ion battery
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- battery
- aluminium ion
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
- H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention discloses a rechargeable aluminum ion battery and a preparation method thereof, and belongs to the technical field of batteries. The rechargeable aluminum ion battery can be widely used in the electronics industry and communications industry, and can also be used as a power battery for an electric vehicle. The invention provides a novel aluminum ion battery device, especially a soft bagged battery. The aluminum ion battery device adopts a membrane to separate the positive and negative electrodes of the aluminum ion battery, and uses an insulating soft bag to wrap the positive and negative electrodes of the aluminum ion battery; the enclosed battery is assembled in a shielding gas atmosphere, and only the positive and negative electrode leads which are conductive are exposed for being connected with an external circuit; according to different electrode making technologies, the battery can be assembled into square or round or other shapes. The soft bagged aluminum ion storage battery provided by the invention has the benefits that the capacity is high, the charge and discharge efficiency is high, the cycling stability is good, and the charge and discharge features are excellent; in addition, the electrode materials are extensive in source, and the battery is easy to prepare, low in cost, green and environment-friendly, and low in price.
Description
Art
The present invention relates to a kind of rechargeable aluminium ion battery and preparation method thereof, especially Soft Roll aluminium ion battery, can be used as new green power battery applications in fields such as electronic industry, communications industry and power battery of electric vehicle.
Background technology
Current, the non-renewable fossil fuel such as coal, oil and natural gas is day by day exhausted, and environmental pollution and greenhouse effect increasingly sharpen, and energy crisis and environmental protection become two hang-ups that the world faces.Therefore, development of new green energy resource and energy storage device more and more attract much attention.Since Japanese Sony Corporation successfully releases lithium ion battery, lithium ion battery is just rapid to be widely used in many-sides such as electronic product, power source, military fields, develops to the electrokinetic cell industrial aspect of electric automobile at present.But the limitation due to lithium resource causes cost intensive and larger potential safety hazard to limit further developing of lithium ion battery.Thus, in recent years, as aiming at high capacity, the ionic conductor of lithium ion can being replaced, adopt the research of the class rechargeable battery of polycation to become increasingly active.
The content of aluminium element in the earth's crust is only second to oxygen and silicon, and occupying the 3rd, be the metallic element that in the earth's crust, content is the abundantest, and cost of winning is low, low price.Relative to traditional lithium ion, aluminium ion can shift three electronics, and therefore its specific capacity has very large potentiality to be exploited.In addition aluminium ion radius is also less than lithium ion radius, is conducive to the deintercalation of ion on electrode material, thus is conducive to the structure of holding electrode material in theory, improves circulating battery stability, extends battery.At present, about the report of aluminium ion battery is also fewer, this is not mainly because correlative study is also very general, and the parameters such as battery specific capacity mentioned in the report simultaneously rarely had are not also very desirable, therefore fails to cause the extensive attention of business.And this just makes exploitation specific capacity high, it is urgent and important that the aluminium ion battery of stable cycle performance becomes very.
Aluminium ion chargeable battery is a kind of novel battery, in patent: (the patent number of accepting: mention a kind of with the method for graphite and aluminium flake assembled battery 201410115329.2), the present invention has made development to it and improved a kind of aluminium ion battery and preparation method thereof.
Summary of the invention
In order to advance the practical of aluminium ion battery, the present invention proposes a kind of novel aluminum ion battery device, especially Soft Roll and packed battery.
A kind of rechargeable aluminium ion battery, is characterized in that comprising insulation soft bag, positive electrode, barrier film, negative material; Positive electrode, barrier film, negative material combine successively, are all sealed in insulation soft bag, only expose positive and negative lug; Positive electrode is graphite-structure material with carbon element, and negative material is aluminium foil or aluminium flake.
Positive electrode is graphite-structure material with carbon element, comprise graphite, carbon paper, carbon fiber paper, carbon nano-tube, Graphene, expanded graphite and carbon black etc., contact with anode ear and wrapped up by barrier film, negative metal aluminium contacts with negative electrode lug, have aluminium ion electrolyte in cell apparatus, sealing means is heat-sealing or rubber seal.
Diaphragm material be there is ion permeability and not with the one in the polypropylene micropore diaphragm material of positive pole and negative reaction, polyethylene micropore diaphragm material and glass fiber material.
Positive and negative lug the selection of material is electric conducting material, and insulated from each other between both positive and negative polarity, and anode ear is tantalum, niobium, platinum, molybdenum, glass carbon etc., and negative electrode lug is aluminium or molybdenum etc.
Aluminium ion electrolyte is formed by anhydrous Aluminum chloride and 3-methylimidazole compound, in aluminium ion electrolyte, the mol ratio of anhydrous Aluminum chloride and 3-methylimidazole compounds is 1.1:1 to 1.6:1, and described 3-methylimidazole compounds comprises 1-butyl-3-methylimidazolium chloride, 1-propyl group-3-methylimidazole villaumite, 1-ethyl-3-methylimidazole chloride, 1-butyl-3-methyl imidazolium tetrafluoroborate, 1-butyl-3-methylimidazole hexafluorophosphate.
Rechargeable aluminium ion battery shape is square, circular or triangle.
Concrete preparation process is as follows:
1). as aluminium ion cell positive material be sheet as carbon paper time, use alcohol swab scrub, dry, and itself and anode ear to be fixed; As for time Powdered, itself and binding agent are mixed, bake pureed and be coated on plus plate current-collecting body or briquetting being connected with anode ear.
2). with diaphragm material positive electrode wrapped up completely or keep apart;
3). using after metallic aluminium cleaning, drying as negative pole, and to be connected with negative electrode lug;
4). both positive and negative polarity is put into soft bag successively, and guarantees that positive and negative lug does not contact;
5). using graphite-structure material with carbon element as positive pole, metallic aluminium as negative pole, mix containing the Al that can move freely
3+the ionic liquid of ion as electrolyte, assembled battery in the glove box being full of argon gas (oxygen content in glove box and water content are all less than 0.1ppm); Finally carry out sealing or rubber seal with heat sealing machine.
The invention has the beneficial effects as follows, the battery of gained can work alone, and also can carry out connection in series-parallel composition battery pack, to reach practical object by multiple battery.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the present invention is further described.
Fig. 1 is soft-package battery structural representation of the present invention.
1 positive electrode, 2. barrier film, 3. negative material, 4. anode ear, 5. negative electrode lug in figure, 6. insulate soft bag.
Embodiment
In FIG, positive electrode (1) is connected with anode ear (4), negative material (3) is aluminium foil or aluminium flake, is connected with negative electrode lug (5), barrier film (2) for there is ion permeability and not with the one in the polypropylene micropore diaphragm material of positive pole and negative reaction, polyethylene micropore diaphragm material and glass fiber material, with positive electrode (1), itself and negative material (3) are insulated, insulation soft bag (6) is polybag or plastic-aluminum packaging film, with soft bag (6) the parcel cell apparatus that insulate, expose outside anode ear (4) and negative electrode lug (5), inject electrolyte, then closing battery, wherein electrolyte is formed by anhydrous Aluminum chloride and 3-methylimidazole compound, in liquid aluminium ion electrolyte, the mol ratio of anhydrous Aluminum chloride and 3-methylimidazole compounds is 1.1:1 to 1.6:1, described 3-methylimidazole compounds comprises 1-butyl-3-methylimidazolium chloride, 1-propyl group-3-methylimidazole villaumite, 1-ethyl-3-methylimidazole chloride, 1-butyl-3-methyl imidazolium tetrafluoroborate, 1-butyl-3-methylimidazole hexafluorophosphate, enclosure method is heat-sealing or rubber seal.
In actual experiment operation, positive electrode (1) is graphite-structure material with carbon element (graphite, carbon paper, carbon fiber paper, carbon nano-tube, Graphene, expanded graphite and carbon black etc.), negative material (3) is aluminium flake or aluminium foil, anode ear (4) is metal tantalum, niobium, platinum, molybdenum, glass carbon etc., negative electrode lug (5) is metallic aluminium or molybdenum, barrier film (2) is GF/D glass fiber filter paper, electrolyte is the chlorination one ethyl-trimethyl imidazole solution of anhydrous Aluminum chloride, and mode of closing is for heat-sealing or rubber seal.
Claims (8)
1. a rechargeable aluminium ion battery, is characterized in that comprising insulation soft bag, positive electrode, diaphragm material, negative material, liquid aluminium ion electrolyte; The soft bag that wherein insulate is aluminum plastic film bag or plastics bag, positive electrode is graphite-structure material with carbon element, negative material is metallic aluminium, liquid aluminium ion electrolyte is formed by anhydrous Aluminum chloride and 3-methylimidazole compound, and in liquid aluminium ion electrolyte, the mol ratio of anhydrous Aluminum chloride and 3-methylimidazole compounds is 1.1:1 to 1.6:1.
2. rechargeable aluminium ion battery according to claim 1, it is characterized in that graphite-structure material with carbon element contacts with anode ear and wrapped up by barrier film, aluminium flake contacts with negative electrode lug, has aluminium ion electrolyte in cell apparatus, and sealing means is heat-sealing or rubber seal.
3. according to claim 1 rechargeable aluminium ion battery, it is characterized in that diaphragm material be there is ion permeability and not with the one in the polypropylene micropore diaphragm material of positive pole and negative reaction, polyethylene micropore diaphragm material and glass fiber material.
4. rechargeable aluminium ion battery according to claim 1, is characterized in that, graphite-structure material with carbon element is graphite, carbon paper, carbon fiber paper, carbon nano-tube, Graphene, expanded graphite and carbon black.
5. rechargeable aluminium ion battery according to claim 1, is characterized in that positive and negative lug the selection of material is electric conducting material, and insulated from each other between both positive and negative polarity, and anode ear is tantalum, niobium, platinum, molybdenum or glass carbon, and negative electrode lug is aluminium flake or molybdenum sheet.
6. rechargeable aluminium ion battery according to claim 2, is characterized in that described 3-methylimidazole compounds comprises 1-butyl-3-methylimidazolium chloride, 1-propyl group-3-methylimidazole villaumite, 1-ethyl-3-methylimidazole chloride, 1-butyl-3-methyl imidazolium tetrafluoroborate, 1-butyl-3-methylimidazole hexafluorophosphate.
7. rechargeable aluminium ion battery according to claim 1, is characterized in that rechargeable aluminium ion battery shape is square, circular or triangle.
8. the preparation method of rechargeable aluminium ion battery according to claim 1, it is characterized in that, preparation process is as follows:
1). be sheet as aluminium ion cell positive material, when positive electrode is carbon paper, use alcohol swab scrub, dry, and itself and anode ear are fixed; When positive electrode is Powdered, itself and binding agent are mixed, bake pureed and be coated on plus plate current-collecting body or briquetting being connected with anode ear;
2). with diaphragm material positive electrode wrapped up completely or keep apart;
3). using after metallic aluminium cleaning, drying as negative pole, and to be connected with negative electrode lug;
4). both positive and negative polarity is put into soft bag successively, and guarantees that positive and negative lug does not contact;
5). using graphite-structure material with carbon element as positive pole, metallic aluminium as negative pole, the ionic liquid that mixes as electrolyte, assembled battery in the glove box being full of argon gas, the oxygen content in glove box and water content are all less than 0.1ppm; Finally carry out sealing or rubber seal with heat sealing machine.
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| CN201510188866.4A CN104810544A (en) | 2015-04-20 | 2015-04-20 | Rechargeable aluminum ion battery and preparation method thereof |
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| CN201510188866.4A CN104810544A (en) | 2015-04-20 | 2015-04-20 | Rechargeable aluminum ion battery and preparation method thereof |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105406112A (en) * | 2015-12-09 | 2016-03-16 | 江苏科技大学 | Aluminium battery and preparation method |
| CN105406111A (en) * | 2015-12-09 | 2016-03-16 | 江苏科技大学 | Secondary aluminium ion battery having high discharge voltage and preparation method |
| CN105810898A (en) * | 2016-03-10 | 2016-07-27 | 中国科学院金属研究所 | Preparation method of amorphous carbon/carbon composite electrode material for aluminum secondary battery |
| CN106252531A (en) * | 2015-12-08 | 2016-12-21 | 浙江科技学院 | A kind of aluminium ion battery and graphite electrode material preparation method thereof |
| CN106450309A (en) * | 2016-09-23 | 2017-02-22 | 浙江大学 | Preparation method for flexible and bendable aluminum ion battery |
| CN106558693A (en) * | 2016-11-04 | 2017-04-05 | 浙江大学 | It is a kind of based on the aluminium ion battery and preparation method thereof containing iodine positive pole |
| CN106887637A (en) * | 2015-12-15 | 2017-06-23 | 中国科学院苏州纳米技术与纳米仿生研究所 | Self-supporting aluminium ion battery and preparation method thereof |
| CN107464932A (en) * | 2017-08-11 | 2017-12-12 | 杭州高烯科技有限公司 | A kind of low-cost aluminum ion battery |
| CN107482219A (en) * | 2017-08-11 | 2017-12-15 | 杭州高烯科技有限公司 | A kind of high-performance aluminum ion battery |
| CN107492631A (en) * | 2017-08-11 | 2017-12-19 | 杭州高烯科技有限公司 | A kind of aluminum cell of no collector positive pole |
| CN107546390A (en) * | 2017-08-11 | 2018-01-05 | 杭州高烯科技有限公司 | A kind of aluminium ion battery of high graphitization degree positive pole |
| CN108321394A (en) * | 2018-01-15 | 2018-07-24 | 山东科技大学 | A kind of Dual-ion cell and preparation method thereof |
| CN108365257A (en) * | 2018-02-23 | 2018-08-03 | 山东科技大学 | A kind of aluminium ion battery and preparation method thereof based on carbon nanotube anode |
| CN109037789A (en) * | 2018-07-27 | 2018-12-18 | 江西迪比科股份有限公司 | A kind of lithium aluminium double ion rechargeable battery |
| WO2019029192A1 (en) * | 2017-08-11 | 2019-02-14 | 杭州高烯科技有限公司 | Aluminum battery |
| CN109378444A (en) * | 2018-10-15 | 2019-02-22 | 杭州高烯科技有限公司 | A kind of aluminium ion battery and its positive preparation method |
| CN109411712A (en) * | 2018-09-10 | 2019-03-01 | 天津理工大学 | A kind of novel aluminium chlorine hybrid ionic battery |
| US10418663B2 (en) | 2016-05-17 | 2019-09-17 | Industrial Technology Research Institute | Metal-ion battery |
| JP2020522113A (en) * | 2017-04-10 | 2020-07-27 | エービー システムス，インコーポレーテッド（ユーエス） | Secondary battery with long cycle life |
| US11296329B2 (en) | 2016-12-16 | 2022-04-05 | Industrial Technology Research Institute | Metal-ion battery |
| CN114784344A (en) * | 2022-03-15 | 2022-07-22 | 辽宁师范大学 | Hydrothermal battery and preparation method thereof |
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Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106252531A (en) * | 2015-12-08 | 2016-12-21 | 浙江科技学院 | A kind of aluminium ion battery and graphite electrode material preparation method thereof |
| CN105406112A (en) * | 2015-12-09 | 2016-03-16 | 江苏科技大学 | Aluminium battery and preparation method |
| CN105406111A (en) * | 2015-12-09 | 2016-03-16 | 江苏科技大学 | Secondary aluminium ion battery having high discharge voltage and preparation method |
| CN105406111B (en) * | 2015-12-09 | 2018-10-23 | 江苏科技大学 | A kind of secondary aluminium ion battery and preparation method of high discharge voltage |
| CN106887637A (en) * | 2015-12-15 | 2017-06-23 | 中国科学院苏州纳米技术与纳米仿生研究所 | Self-supporting aluminium ion battery and preparation method thereof |
| CN105810898A (en) * | 2016-03-10 | 2016-07-27 | 中国科学院金属研究所 | Preparation method of amorphous carbon/carbon composite electrode material for aluminum secondary battery |
| US10418663B2 (en) | 2016-05-17 | 2019-09-17 | Industrial Technology Research Institute | Metal-ion battery |
| CN106450309A (en) * | 2016-09-23 | 2017-02-22 | 浙江大学 | Preparation method for flexible and bendable aluminum ion battery |
| CN106450309B (en) * | 2016-09-23 | 2019-01-29 | 浙江大学 | A kind of preparation method of the aluminium ion battery of flexible |
| CN106558693A (en) * | 2016-11-04 | 2017-04-05 | 浙江大学 | It is a kind of based on the aluminium ion battery and preparation method thereof containing iodine positive pole |
| CN106558693B (en) * | 2016-11-04 | 2019-08-13 | 浙江大学 | A kind of aluminium ion battery and preparation method thereof based on the anode containing iodine |
| US11296329B2 (en) | 2016-12-16 | 2022-04-05 | Industrial Technology Research Institute | Metal-ion battery |
| JP2020522113A (en) * | 2017-04-10 | 2020-07-27 | エービー システムス，インコーポレーテッド（ユーエス） | Secondary battery with long cycle life |
| CN107482219A (en) * | 2017-08-11 | 2017-12-15 | 杭州高烯科技有限公司 | A kind of high-performance aluminum ion battery |
| CN107492631A (en) * | 2017-08-11 | 2017-12-19 | 杭州高烯科技有限公司 | A kind of aluminum cell of no collector positive pole |
| CN107546390A (en) * | 2017-08-11 | 2018-01-05 | 杭州高烯科技有限公司 | A kind of aluminium ion battery of high graphitization degree positive pole |
| CN107464932A (en) * | 2017-08-11 | 2017-12-12 | 杭州高烯科技有限公司 | A kind of low-cost aluminum ion battery |
| WO2019029192A1 (en) * | 2017-08-11 | 2019-02-14 | 杭州高烯科技有限公司 | Aluminum battery |
| CN108321394A (en) * | 2018-01-15 | 2018-07-24 | 山东科技大学 | A kind of Dual-ion cell and preparation method thereof |
| CN108365257A (en) * | 2018-02-23 | 2018-08-03 | 山东科技大学 | A kind of aluminium ion battery and preparation method thereof based on carbon nanotube anode |
| CN109037789B (en) * | 2018-07-27 | 2021-04-13 | 江西迪比科股份有限公司 | Lithium-aluminum double-ion rechargeable battery |
| CN109037789A (en) * | 2018-07-27 | 2018-12-18 | 江西迪比科股份有限公司 | A kind of lithium aluminium double ion rechargeable battery |
| CN109411712A (en) * | 2018-09-10 | 2019-03-01 | 天津理工大学 | A kind of novel aluminium chlorine hybrid ionic battery |
| CN109411712B (en) * | 2018-09-10 | 2021-09-03 | 天津理工大学 | Aluminum-chlorine mixed ion battery |
| CN109378444A (en) * | 2018-10-15 | 2019-02-22 | 杭州高烯科技有限公司 | A kind of aluminium ion battery and its positive preparation method |
| CN114784344A (en) * | 2022-03-15 | 2022-07-22 | 辽宁师范大学 | Hydrothermal battery and preparation method thereof |
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