CN104788628A - 无氟拨水剂、其制备方法及其应用 - Google Patents
无氟拨水剂、其制备方法及其应用 Download PDFInfo
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- CN104788628A CN104788628A CN201410095237.2A CN201410095237A CN104788628A CN 104788628 A CN104788628 A CN 104788628A CN 201410095237 A CN201410095237 A CN 201410095237A CN 104788628 A CN104788628 A CN 104788628A
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/285—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
- D06M15/29—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides containing a N-methylol group or an etherified N-methylol group; containing a N-aminomethylene group; containing a N-sulfidomethylene group
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3568—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Paper (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Claims (11)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
TW103101937 | 2014-01-20 | ||
TW103101937A TWI491721B (zh) | 2014-01-20 | 2014-01-20 | 無氟撥水劑,其製備方法,及其應用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104788628A true CN104788628A (zh) | 2015-07-22 |
CN104788628B CN104788628B (zh) | 2017-10-03 |
Family
ID=53544297
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410095237.2A Active CN104788628B (zh) | 2014-01-20 | 2014-03-14 | 无氟拨水剂、其制备方法及其应用 |
Country Status (4)
Country | Link |
---|---|
US (1) | US9234311B2 (zh) |
JP (1) | JP6016882B2 (zh) |
CN (1) | CN104788628B (zh) |
TW (1) | TWI491721B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108893985A (zh) * | 2018-06-12 | 2018-11-27 | 苏州联胜化学有限公司 | 一种无氟型防水剂及其制备方法 |
CN109423887A (zh) * | 2017-09-05 | 2019-03-05 | 立得光电科技股份有限公司 | 无氟拨水组成、无氟拨水组件及无氟拨水纱 |
TWI682084B (zh) * | 2019-01-04 | 2020-01-11 | 遠東新世紀股份有限公司 | 無氟撥水劑的製造方法與撥水織物 |
TWI694093B (zh) * | 2019-01-18 | 2020-05-21 | 福盈科技化學股份有限公司 | 聚氨酯壓克力複合型無氟撥水劑的製備方法及其應用 |
CN111454430A (zh) * | 2019-01-18 | 2020-07-28 | 福盈科技化学股份有限公司 | 聚氨酯压克力复合型无氟拨水剂的制备方法及其应用 |
CN115651609A (zh) * | 2022-11-14 | 2023-01-31 | 天津天女化工集团股份有限公司 | 一种含氟聚合物的拨水剂 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5922706B2 (ja) * | 2014-05-23 | 2016-05-24 | 明成化学工業株式会社 | フッ素を含まないはっ水剤組成物及びはっ水加工方法 |
JP6949354B2 (ja) * | 2016-06-08 | 2021-10-13 | 明成化学工業株式会社 | フッ素を含まないはっ水剤及びはっ水加工方法、はっ水性繊維製品 |
JP6319419B1 (ja) * | 2016-12-28 | 2018-05-09 | ダイキン工業株式会社 | 表面処理剤 |
AU2019338447A1 (en) * | 2018-09-12 | 2021-05-13 | Chemstone, Inc. | Biobased barrier coatings |
CN112300334B (zh) * | 2020-12-02 | 2022-11-11 | 陕西科技大学 | Poss/有机硅改性聚丙烯酸酯无氟防水剂及制备方法 |
CN114808455B (zh) * | 2022-05-19 | 2023-05-05 | 广州大学 | 一种环境友好型无氟织物防水透湿剂、制备方法与应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003049398A (ja) * | 2001-03-27 | 2003-02-21 | Dainippon Ink & Chem Inc | 防湿加工用合成樹脂エマルジョン、防湿加工用樹脂組成物および防湿材 |
CN100582132C (zh) * | 2004-03-11 | 2010-01-20 | 瓦克化学有限公司 | 含硅氧烷的共聚物的制备方法 |
CN102333915A (zh) * | 2009-03-28 | 2012-01-25 | 亨茨曼纺织货品(德国)有限责任公司 | 用于处理织物的不含氟的水性分散体 |
CN102851410A (zh) * | 2012-08-30 | 2013-01-02 | 昆山承宇机电科技有限公司 | 一种皮革用防水抗菌剂 |
CN103266482A (zh) * | 2013-03-23 | 2013-08-28 | 广东德美精细化工股份有限公司 | 一种含蜡防水防油剂及制备方法、纺织品 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3281318A (en) * | 1962-09-06 | 1966-10-25 | Chapman Chem Co | Wood treatment composition and method of formulating same |
US3486911A (en) * | 1967-08-21 | 1969-12-30 | Sun Chemical Corp | Textile treating compositions and textiles treated therewith |
US6437070B1 (en) * | 1998-09-22 | 2002-08-20 | Rohm And Haas Company | Acrylic polymer compositions with crystalline side chains and processes for their preparation |
US6656653B2 (en) * | 1999-12-15 | 2003-12-02 | Mitsubishi Chemical Corporation | Toner for the development of electrostatic image and method for producing the same |
US7388044B2 (en) * | 2002-07-15 | 2008-06-17 | Henkel Kommanditgesellschaft Auf Aktien | Coatings with enhanced water-barrier and anti-corrosive properties |
JP4752197B2 (ja) * | 2004-06-04 | 2011-08-17 | ユニマテック株式会社 | 撥水撥油剤の製造法 |
JP5716676B2 (ja) * | 2009-12-25 | 2015-05-13 | 旭硝子株式会社 | 撥水撥油剤組成物、その製造方法および物品の処理方法 |
CN103572603A (zh) * | 2013-10-24 | 2014-02-12 | 广东德美精细化工股份有限公司 | 纺织品无氟防水剂及其制备方法、纺织品 |
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2014
- 2014-01-20 TW TW103101937A patent/TWI491721B/zh active
- 2014-03-14 CN CN201410095237.2A patent/CN104788628B/zh active Active
- 2014-08-14 US US14/459,679 patent/US9234311B2/en active Active
- 2014-12-26 JP JP2014264787A patent/JP6016882B2/ja active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003049398A (ja) * | 2001-03-27 | 2003-02-21 | Dainippon Ink & Chem Inc | 防湿加工用合成樹脂エマルジョン、防湿加工用樹脂組成物および防湿材 |
CN100582132C (zh) * | 2004-03-11 | 2010-01-20 | 瓦克化学有限公司 | 含硅氧烷的共聚物的制备方法 |
CN102333915A (zh) * | 2009-03-28 | 2012-01-25 | 亨茨曼纺织货品(德国)有限责任公司 | 用于处理织物的不含氟的水性分散体 |
CN102851410A (zh) * | 2012-08-30 | 2013-01-02 | 昆山承宇机电科技有限公司 | 一种皮革用防水抗菌剂 |
CN103266482A (zh) * | 2013-03-23 | 2013-08-28 | 广东德美精细化工股份有限公司 | 一种含蜡防水防油剂及制备方法、纺织品 |
Non-Patent Citations (1)
Title |
---|
许胜: "《有机化学》", 30 September 2012 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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CN108893985A (zh) * | 2018-06-12 | 2018-11-27 | 苏州联胜化学有限公司 | 一种无氟型防水剂及其制备方法 |
TWI682084B (zh) * | 2019-01-04 | 2020-01-11 | 遠東新世紀股份有限公司 | 無氟撥水劑的製造方法與撥水織物 |
CN111411515A (zh) * | 2019-01-04 | 2020-07-14 | 远东新世纪股份有限公司 | 无氟拨水剂及其制造方法与拨水织物 |
TWI694093B (zh) * | 2019-01-18 | 2020-05-21 | 福盈科技化學股份有限公司 | 聚氨酯壓克力複合型無氟撥水劑的製備方法及其應用 |
CN111454430A (zh) * | 2019-01-18 | 2020-07-28 | 福盈科技化学股份有限公司 | 聚氨酯压克力复合型无氟拨水剂的制备方法及其应用 |
CN115651609A (zh) * | 2022-11-14 | 2023-01-31 | 天津天女化工集团股份有限公司 | 一种含氟聚合物的拨水剂 |
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US20150204010A1 (en) | 2015-07-23 |
CN104788628B (zh) | 2017-10-03 |
US9234311B2 (en) | 2016-01-12 |
JP2015137363A (ja) | 2015-07-30 |
JP6016882B2 (ja) | 2016-10-26 |
TW201529822A (zh) | 2015-08-01 |
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