CN104788505B - 一种金属‑有机框架单晶外延生长的DMCoF/DMMnF异质结材料及其制备方法 - Google Patents
一种金属‑有机框架单晶外延生长的DMCoF/DMMnF异质结材料及其制备方法 Download PDFInfo
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- CN104788505B CN104788505B CN201510101659.0A CN201510101659A CN104788505B CN 104788505 B CN104788505 B CN 104788505B CN 201510101659 A CN201510101659 A CN 201510101659A CN 104788505 B CN104788505 B CN 104788505B
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- 239000013078 crystal Substances 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002184 metal Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000000407 epitaxy Methods 0.000 claims abstract description 7
- 239000000758 substrate Substances 0.000 claims abstract description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 25
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 22
- 235000002867 manganese chloride Nutrition 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229910021380 Manganese Chloride Inorganic materials 0.000 claims description 16
- 239000011565 manganese chloride Substances 0.000 claims description 16
- 229940099607 manganese chloride Drugs 0.000 claims description 16
- 239000011572 manganese Substances 0.000 claims description 15
- 239000012621 metal-organic framework Substances 0.000 claims description 15
- 239000012153 distilled water Substances 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910017052 cobalt Inorganic materials 0.000 claims description 10
- 239000010941 cobalt Substances 0.000 claims description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 10
- 229910052748 manganese Inorganic materials 0.000 claims description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical group [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 8
- 238000007789 sealing Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- 239000005416 organic matter Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 239000000047 product Substances 0.000 abstract description 10
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 7
- 239000007791 liquid phase Substances 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000013065 commercial product Substances 0.000 abstract description 2
- 239000004065 semiconductor Substances 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- IGRCWJPBLWGNPX-UHFFFAOYSA-N 3-(2-chlorophenyl)-n-(4-chlorophenyl)-n,5-dimethyl-1,2-oxazole-4-carboxamide Chemical compound C=1C=C(Cl)C=CC=1N(C)C(=O)C1=C(C)ON=C1C1=CC=CC=C1Cl IGRCWJPBLWGNPX-UHFFFAOYSA-N 0.000 description 2
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 2
- 230000005621 ferroelectricity Effects 0.000 description 2
- 239000007775 ferroic material Substances 0.000 description 2
- 230000005690 magnetoelectric effect Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
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CN201510101659.0A CN104788505B (zh) | 2015-03-09 | 2015-03-09 | 一种金属‑有机框架单晶外延生长的DMCoF/DMMnF异质结材料及其制备方法 |
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CN104788505B true CN104788505B (zh) | 2017-07-28 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105541926B (zh) * | 2015-12-30 | 2018-05-01 | 武汉工程大学 | 一种掺Fe金属有机框架晶体及其制备方法 |
CN106637414A (zh) * | 2016-12-15 | 2017-05-10 | 浙江理工大学 | 一种金属‑有机框架DMMnF/甲酸锶异质结单晶光学材料及其制备方法 |
CN112295866B (zh) * | 2019-07-26 | 2022-03-22 | 中国科学院福建物质结构研究所 | 一种全金属有机框架范德华异质结层薄膜的制备方法及其所制备的薄膜和用途 |
CN110591110A (zh) * | 2019-10-08 | 2019-12-20 | 浙江理工大学 | 一种Mn基金属-有机框架材料、制备方法和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102414255A (zh) * | 2009-02-27 | 2012-04-11 | 环球油品公司 | 嵌段配位共聚物 |
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102414255A (zh) * | 2009-02-27 | 2012-04-11 | 环球油品公司 | 嵌段配位共聚物 |
CN102962036A (zh) * | 2012-10-30 | 2013-03-13 | 中国科学院大连化学物理研究所 | 基于过渡金属钴的多孔金属有机骨架材料及其制备方法 |
Non-Patent Citations (4)
Title |
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Elastic relaxation behavior, magnetoelastic coupling, and order-disorder processes in multiferroic metal-organic frameworks;R. I. Thomson等;《PHYSICAL REVIEW B》;American Physical Society;20121221;第86卷(第21期);第214304-1至214304-7页 * |
First-order structural transition in the multiferroic perovskite-like formate [(CH3)2NH2][Mn(HCOO)3];M. Sánchez-Andújar等;《CrystEngComm》;RSC;20140213;第16卷;第3558–3566页 * |
Multiferroic Behavior Associated with an Order-Disorder Hydrogen Bonding Transition in Metal-Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture;Prashant Jain 等;《J. AM. CHEM. SOC.》;ACS;20090902;第131卷(第38期);第37818-37822页 * |
One-Pot Multiple Metal–Organic Framework Formation:Concomitant Generation of Structural Isomers or of Drastically Distinct Materials;Achareeya Cheansirisomboon等;《Eur. J. Inorg. Chem.》;Wiley;20150727;第2014卷(第26期);第4385–4393页 * |
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