CN104783293A - Gas regulation type deoxidation preservative - Google Patents
Gas regulation type deoxidation preservative Download PDFInfo
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- CN104783293A CN104783293A CN201510132127.3A CN201510132127A CN104783293A CN 104783293 A CN104783293 A CN 104783293A CN 201510132127 A CN201510132127 A CN 201510132127A CN 104783293 A CN104783293 A CN 104783293A
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- Prior art keywords
- air conditioning
- carbonate
- antistaling agent
- agent
- sodium
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3409—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
- A23L3/3418—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
- A23L3/3427—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
- A23L3/3436—Oxygen absorbent
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3562—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/358—Inorganic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Microbiology (AREA)
- Gas Separation By Absorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a gas regulation type deoxidation preservative which comprises fructose, ascorbic acid, sodium ascorbate, sodium bicarbonate, sodium carbonate, activated carbon, a carbon dioxide release regulator, a dispersant and water. The gas regulation type deoxidation preservative can absorb oxygen while releasing carbon dioxide, regulates the amount of carbon dioxide through the carbon dioxide release regulator, maintains the balance of the total volume of oxygen and carbon dioxide in a container bottle, ensures the consistency of pressures inside and outside the container, is high in practicability, meets the production and living needs, is wide in use, and has stronger promotion significance.
Description
Technical field
The present invention relates to a kind of antistaling agent, particularly relate to a kind of air conditioning shape deoxidizing antistaling agent.
Background technology
In recent years, along with the development of food industry and the improvement of packaging material, deoxidier more and more comes into one's own at home, applies also more and more extensive.Deoxidier, as food fresh keeping novel substance, is contained in same container with food, and deoxidier absorbs the oxygen in container, makes to be that food is preserved close to anaerobic state in container.
But, existing deoxidier function singleness, Main Function absorbs oxygen, do not have too much influence for general flexible package class is fresh-keeping, but then affect larger for bottled or canned class packaging, after oxygen in bottle or tank is absorbed by deoxidier, under the atmospheric effect in the external world, bottle or tank can be flat by suction, not only affect product appearance, and the food easily damaged in packaging, make food spoilage, greatly limit the scope of application of deoxidier.
Summary of the invention
Therefore, the object of the present invention is to provide a kind of maintain container bottle gas volume total amount balance, ensure the air conditioning shape deoxidizing antistaling agent that air pressure inside and outside container is consistent.
A kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, following component is comprised: fructose 0.5% ~ 6%, ascorbic acid 0.1% ~ 1%, sodium ascorbate 30% ~ 50%, sodium acid carbonate 23% ~ 40%, sodium carbonate 0.5% ~ 2%, active carbon 3% ~ 11%, release of carbonate dioxide conditioning agent 0.2% ~ 1%, dispersant 10% ~ 32%, water 1% ~ 8%.
Further, the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide.
Further, described calcium hydroxide, calcium oxide account for the mass percent of air conditioning shape deoxidizing antistaling agent and are:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
Further, the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
A kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, following component is comprised: fructose 2% ~ 6%, ascorbic acid 0.1% ~ 1%, sodium ascorbate 32% ~ 48%, sodium acid carbonate 23% ~ 35%, sodium carbonate 0.5% ~ 2%, active carbon 3% ~ 8%, release of carbonate dioxide conditioning agent 0.2% ~ 0.9%, dispersant 10% ~ 28%, water 1% ~ 6%.
Further, the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, and the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
Further, the mass percent that described calcium hydroxide, calcium oxide account for air conditioning shape deoxidizing antistaling agent is respectively:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
A kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, following component is comprised: fructose 3% ~ 5.5%, ascorbic acid 0.3% ~ 0.8%, sodium ascorbate 35% ~ 45%, sodium acid carbonate 23% ~ 35%, sodium carbonate 0.5% ~ 1.5%, active carbon 3% ~ 6%, release of carbonate dioxide conditioning agent 0.2% ~ 0.8%, dispersant 11% ~ 20%, water 1.5% ~ 4%.
Further, the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, and the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
Further, described calcium hydroxide, calcium oxide account for the mass percent of air conditioning shape deoxidizing antistaling agent and are:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
The beneficial effect of air conditioning shape deoxidizing antistaling agent of the present invention is: deoxidier can discharge carbon dioxide while absorbing oxygen, and pass through the amount of release of carbonate dioxide conditioning agent regulation of carbon dioxide, maintain the balance of oxygen and carbon dioxide volume total amount in container bottle, ensure that the air pressure inside and outside container is consistent, practical, meet production and life requirement, of many uses, there is stronger dissemination.
Detailed description of the invention
In order to make technical scheme of the present invention more clearly show, below the invention will be further described.
Embodiment one
The present embodiment provides a kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, comprises following component:
The component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil, and this dispersant has peptizaiton to air conditioning shape deoxidizing antistaling agent, improves ingredient flow.
Described sodium ascorbate is for absorbing the oxygen in container, with oxygen generation chemical reaction, carry out deoxygenation, it is the main absorption agent of oxygen, organic acid is generated when sodium ascorbate and oxygen reaction, newly-generated organic acid again with reaction of sodium bicarbonate, generate organic carbon hydrochlorate, water and carbon dioxide, thus while realizing oxygen uptake, discharge equivalent carbon dioxide.Described active carbon is as reaction promoter, and accelerated oxidation is reacted;
Described ascorbic acid and sodium acid carbonate directly react, and the water of generation is to improve batching humidity, and Ascorbic Acid sodium and reaction of sodium bicarbonate have facilitation; Meanwhile, ascorbic acid can absorb oxygen, increases batching oxygen scavenging ability.
It should be noted that, because sodium ascorbate and sodium acid carbonate are all Water-solubility Material, in two reactions of above-mentioned oxygen uptake and generation carbon dioxide, a certain amount of water must be added to ensure that reaction is carried out smoothly, but sodium ascorbate and sodium acid carbonate can all dissolve when adding hypervolia, cause ingredient flow poor, cannot produce; Add the water yield very few time prepare burden slowly reacted, reaction is thorough, does not reach application requirement, therefore, needs strict control to the water yield of air conditioning shape oxygen absorbent; In the present invention, moisture two parts are introduced: wherein, a part of water adopts the mode directly added; The water of another part, being by adding a certain amount of ascorbic acid in formula, having water to generate when ascorbic acid and reaction of sodium bicarbonate, improves batching humidity.
Because the reaction of ascorbic acid and sodium acid carbonate is easier to carry out, after adding ascorbic acid, sodium acid carbonate is understood fast and ascorbic acid reacts, sodium carbonate is added in formula, suitably can reduce sodium acid carbonate and ascorbic acid reaction speed, and sodium carbonate can generate sodium acid carbonate with organic acid reaction, supplementary sodium acid carbonate and ascorbic acid react the loss caused, and maintain formulation stability.
Understandably, in the present embodiment, adopt sodium carbonate to reduce ascorbic acid and reaction of sodium bicarbonate speed, in other embodiments, other carbonate also can be adopted to replace.
In addition, prepare burden and to apply under comparatively dry environment, loss of water is very fast, in order to reduce batching moisture loss rate, maintenance performance formula is stablized, in formula, introduce fructose, in the present invention, described fructose is used as hygroscopic agent, fructose has stronger water absorbing capacity, and fructose can and oxygen reaction, increase further batching oxygen scavenging ability, be conducive to formulation stable.
The component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, and wherein, the mass percent that calcium hydroxide, calcium oxide group account for deoxidier is as follows:
Calcium hydroxide 0.1% ~ 0.5%
Calcium oxide 0.1% ~ 0.5%
Under this patent formulation condition, one one's share of expenses for a joint undertaking sodium ascorbate and oxygen reaction can generate many one's shares of expenses for a joint undertaking organic acid, and product is complicated, therefore the amount of release of carbon dioxide can be more than the amount absorbing oxygen, cause release uneven, for this reason, in formula, introduce calcium hydroxide or calcium oxide regulation of carbon dioxide burst size, maintain oxygen uptake and release of carbon dioxide balance; And calcium hydroxide or calcium oxide improve batching alkalescence, improve the oxygen scavenging ability of sodium ascorbate.
Embodiment two
The present embodiment provides a kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, comprises following component:
Wherein, the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil, and the mass percent that described calcium hydroxide, calcium oxide group account for air conditioning shape deoxidizing antistaling agent is:
Calcium hydroxide 0.1% ~ 0.45%;
Calcium oxide 0.1% ~ 0.45%.
Embodiment three
The present embodiment provides a kind of air conditioning shape deoxidizing antistaling agent, by mass percentage, comprises following component:
Wherein, the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil, and the mass percent that described calcium hydroxide, calcium oxide group account for air conditioning shape deoxidizing antistaling agent is:
Calcium hydroxide 0.1% ~ 0.4%;
Calcium oxide 0.1% ~ 0.4%.
The beneficial effect of air conditioning shape deoxidizing antistaling agent of the present invention is: deoxidier can discharge carbon dioxide while absorbing oxygen, and pass through the amount of release of carbonate dioxide conditioning agent regulation of carbon dioxide, maintain the balance of oxygen and carbon dioxide volume total amount in container bottle, ensure that the air pressure inside and outside container is consistent, practical, meet production and life requirement, of many uses, there is stronger dissemination.
The above embodiment only have expressed numerous embodiments of the present invention, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (10)
1. an air conditioning shape deoxidizing antistaling agent, it is characterized in that: by mass percentage, comprise following component: fructose 0.5% ~ 6%, ascorbic acid 0.1% ~ 1%, sodium ascorbate 30% ~ 50%, sodium acid carbonate 23% ~ 40%, sodium carbonate 0.5% ~ 2%, active carbon 3% ~ 11%, release of carbonate dioxide conditioning agent 0.2% ~ 1%, dispersant 10% ~ 32%, water 1% ~ 8%.
2. air conditioning shape deoxidizing antistaling agent as claimed in claim 1, is characterized in that: the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide.
3. air conditioning shape deoxidizing antistaling agent as claimed in claim 2, is characterized in that: the mass percent that described calcium hydroxide, calcium oxide account for air conditioning shape deoxidizing antistaling agent is:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
4. air conditioning shape deoxidizing antistaling agent as claimed in claim 1, is characterized in that: the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
5. an air conditioning shape deoxidizing antistaling agent, it is characterized in that: by mass percentage, comprise following component: fructose 2% ~ 6%, ascorbic acid 0.1% ~ 1%, sodium ascorbate 32% ~ 48%, sodium acid carbonate 23% ~ 35%, sodium carbonate 0.5% ~ 2%, active carbon 3% ~ 8%, release of carbonate dioxide conditioning agent 0.2% ~ 0.9%, dispersant 10% ~ 28%, water 1% ~ 6%.
6. air conditioning shape deoxidizing antistaling agent as claimed in claim 5, is characterized in that: the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, and the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
7. air conditioning shape deoxidizing antistaling agent as claimed in claim 6, is characterized in that: the mass percent that described calcium hydroxide, calcium oxide account for air conditioning shape deoxidizing antistaling agent is respectively:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
8. an air conditioning shape deoxidizing antistaling agent, it is characterized in that: by mass percentage, comprise following component: fructose 3% ~ 5.5%, ascorbic acid 0.3% ~ 0.8%, sodium ascorbate 35% ~ 45%, sodium acid carbonate 23% ~ 35%, sodium carbonate 0.5% ~ 1.5%, active carbon 3% ~ 6%, release of carbonate dioxide conditioning agent 0.2% ~ 0.8%, dispersant 11% ~ 20%, water 1.5% ~ 4%.
9. air conditioning shape deoxidizing antistaling agent as claimed in claim 8, is characterized in that: the component of described release of carbonate dioxide conditioning agent is made up of calcium hydroxide and calcium oxide, and the component of described dispersant is one or more combinations in diatomite, zeolite, ore deposit soil.
10. air conditioning shape deoxidizing antistaling agent as claimed in claim 9, is characterized in that: the mass percent that described calcium hydroxide, calcium oxide account for air conditioning shape deoxidizing antistaling agent is:
Calcium hydroxide 0.1% ~ 0.5%;
Calcium oxide 0.1% ~ 0.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510132127.3A CN104783293A (en) | 2015-03-25 | 2015-03-25 | Gas regulation type deoxidation preservative |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510132127.3A CN104783293A (en) | 2015-03-25 | 2015-03-25 | Gas regulation type deoxidation preservative |
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| CN104783293A true CN104783293A (en) | 2015-07-22 |
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| CN201510132127.3A Pending CN104783293A (en) | 2015-03-25 | 2015-03-25 | Gas regulation type deoxidation preservative |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107048148A (en) * | 2016-08-28 | 2017-08-18 | 新昌县群星实业有限公司 | A kind of food packaging deoxidizing antistaling agent and preparation method thereof |
| WO2020189167A1 (en) * | 2019-03-20 | 2020-09-24 | 三菱瓦斯化学株式会社 | Gas concentration adjusting agent for use in culture of bacteria, and method for culturing bacterium using same |
| CN114617161A (en) * | 2022-04-01 | 2022-06-14 | 君合百安仓储科技(北京)有限公司 | Constant-pressure type air regulator |
| CN115444089A (en) * | 2022-09-15 | 2022-12-09 | 广东胜和发智能科技有限公司 | Antibacterial constant-pressure deoxidizer and preparation method and application thereof |
| CN118235792A (en) * | 2024-05-22 | 2024-06-25 | 海南省农业科学院三亚研究院(海南省实验动物研究中心) | Modified atmosphere preservative capable of simultaneously regulating oxygen and carbon dioxide as well as preparation method and application thereof |
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| CN1057757A (en) * | 1990-07-02 | 1992-01-15 | 辽宁省粮食科学研究所 | Deoxidation, antistaling agent |
| CN1131522A (en) * | 1995-03-20 | 1996-09-25 | 应关雄 | Multi-form fresh-retaining sealing agent |
| CN1545386A (en) * | 2001-03-02 | 2004-11-10 | 宝洁公司 | Devices and methods for prolonging the storage life of produce |
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| CN101252984A (en) * | 2005-10-21 | 2008-08-27 | 三菱瓦斯化学株式会社 | Solid oxygen scavenger composition and process for producing the same |
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| CN103028325A (en) * | 2012-12-05 | 2013-04-10 | 金陵科技学院 | Organic high-efficiency oxygen absorbent |
| CN104382185A (en) * | 2014-12-09 | 2015-03-04 | 广东广益科技实业有限公司 | Preparation method of deoxidization preservative agent |
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2015
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Patent Citations (8)
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| CN1057757A (en) * | 1990-07-02 | 1992-01-15 | 辽宁省粮食科学研究所 | Deoxidation, antistaling agent |
| CN1131522A (en) * | 1995-03-20 | 1996-09-25 | 应关雄 | Multi-form fresh-retaining sealing agent |
| CN1545386A (en) * | 2001-03-02 | 2004-11-10 | 宝洁公司 | Devices and methods for prolonging the storage life of produce |
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| CN103028325A (en) * | 2012-12-05 | 2013-04-10 | 金陵科技学院 | Organic high-efficiency oxygen absorbent |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107048148A (en) * | 2016-08-28 | 2017-08-18 | 新昌县群星实业有限公司 | A kind of food packaging deoxidizing antistaling agent and preparation method thereof |
| WO2020189167A1 (en) * | 2019-03-20 | 2020-09-24 | 三菱瓦斯化学株式会社 | Gas concentration adjusting agent for use in culture of bacteria, and method for culturing bacterium using same |
| JP2020150864A (en) * | 2019-03-20 | 2020-09-24 | 三菱瓦斯化学株式会社 | Gas concentration regulators for bacterial culture and culture method of bacteria using the same |
| CN114617161A (en) * | 2022-04-01 | 2022-06-14 | 君合百安仓储科技(北京)有限公司 | Constant-pressure type air regulator |
| CN115444089A (en) * | 2022-09-15 | 2022-12-09 | 广东胜和发智能科技有限公司 | Antibacterial constant-pressure deoxidizer and preparation method and application thereof |
| CN118235792A (en) * | 2024-05-22 | 2024-06-25 | 海南省农业科学院三亚研究院(海南省实验动物研究中心) | Modified atmosphere preservative capable of simultaneously regulating oxygen and carbon dioxide as well as preparation method and application thereof |
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