CN104772151A - 一种用于废水处理的三元共结晶臭氧氧化催化剂的制备方法 - Google Patents
一种用于废水处理的三元共结晶臭氧氧化催化剂的制备方法 Download PDFInfo
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- CN104772151A CN104772151A CN201510133122.2A CN201510133122A CN104772151A CN 104772151 A CN104772151 A CN 104772151A CN 201510133122 A CN201510133122 A CN 201510133122A CN 104772151 A CN104772151 A CN 104772151A
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- 238000006555 catalytic reaction Methods 0.000 abstract 2
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- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105080523A (zh) * | 2015-07-23 | 2015-11-25 | 武汉钢铁(集团)公司 | 一种处理含有机物废水臭氧催化氧化的催化剂的制备方法 |
CN110963617A (zh) * | 2018-09-28 | 2020-04-07 | 宝山钢铁股份有限公司 | 一种去除冷轧生化出水中苯甲醛和苯并***的装置及方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102151567A (zh) * | 2011-02-25 | 2011-08-17 | 哈尔滨工业大学 | 臭氧氧化分解水中有机污染物的催化剂及其催化臭氧处理污水的方法 |
CN102794182A (zh) * | 2012-08-21 | 2012-11-28 | 泰山医学院 | 复合臭氧氧化固体催化剂的制备方法及催化剂 |
CN103721563A (zh) * | 2013-12-18 | 2014-04-16 | 浙江省环境保护科学设计研究院 | 一种催化臭氧氧化有机废气的处理装置及处理方法 |
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Patent Citations (3)
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CN102151567A (zh) * | 2011-02-25 | 2011-08-17 | 哈尔滨工业大学 | 臭氧氧化分解水中有机污染物的催化剂及其催化臭氧处理污水的方法 |
CN102794182A (zh) * | 2012-08-21 | 2012-11-28 | 泰山医学院 | 复合臭氧氧化固体催化剂的制备方法及催化剂 |
CN103721563A (zh) * | 2013-12-18 | 2014-04-16 | 浙江省环境保护科学设计研究院 | 一种催化臭氧氧化有机废气的处理装置及处理方法 |
Non-Patent Citations (4)
Title |
---|
JUSTIN M ET AL.: ""Microstructural, electrical and reliability aspects of chromium doped Ni–Mn–Fe–O NTC thermistor materials"", 《MATERIALS SCIENCE&ENGINEERING B》 * |
Y. KOSEOGLU ET AL.: ""Magnetic and dielectric properties of Mn0.2Ni0.8Fe2O4 nanoparticles synthesized by PEG-assisted hydrothermal method"", 《JOURNAL OF NANOPARTICLE RESEARCH》 * |
Y.TORII ET AL.: ""Chemical processing and characterization of spinel-type thermistor powder in the Mn-Ni-Fe oxide system"", 《JOURNAL OF MATERIALS SCIENCE》 * |
张寿华等: "《放射化学》", 30 June 1983 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105080523A (zh) * | 2015-07-23 | 2015-11-25 | 武汉钢铁(集团)公司 | 一种处理含有机物废水臭氧催化氧化的催化剂的制备方法 |
CN110963617A (zh) * | 2018-09-28 | 2020-04-07 | 宝山钢铁股份有限公司 | 一种去除冷轧生化出水中苯甲醛和苯并***的装置及方法 |
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