CN104772014A - Combined denitration device for flue gas of cement rotary kiln and denitration technology for flue gas - Google Patents
Combined denitration device for flue gas of cement rotary kiln and denitration technology for flue gas Download PDFInfo
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- CN104772014A CN104772014A CN201510167595.4A CN201510167595A CN104772014A CN 104772014 A CN104772014 A CN 104772014A CN 201510167595 A CN201510167595 A CN 201510167595A CN 104772014 A CN104772014 A CN 104772014A
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Abstract
The invention provides a combined denitration device for flue gas of a cement rotary kiln, which can effectively improve the denitration efficiency of the flue gas and better meet the atmospheric pollutant emission standard in the cement industry. The system is simple, the construction investment is low, the operation is convenient, and the operation cost is better reduced. The combined denitration device is characterized in that a decomposing furnace is connected with the cement rotary kiln; a preheater is connected with the decomposing furnace; an afterheat treatment device is connected with the preheater; a fan is connected with the afterheat treatment device; a cloth bag dust collector is connected with the fan; an outlet flue is connected with the cloth bag dust collector; an SCR reactor is connected with the outlet flue and is connected with a chimney through an exhaust fan; a first reducer spraying device is arranged on the decomposing furnace; a second reducer spraying device is arranged on the outlet flue. The invention further provides a combined denitration technology for the flue gas of the cement rotary kiln.
Description
Technical field
The present invention relates to the technical field of cement industry denitrating flue gas process, be specially a kind of cement rotary kiln kiln gas combined denitration device and denitrating technique thereof.
Background technology
Cement industry pollutes one of industry as China's emphasis, and cement industry year discharge nitrogen oxide about 2,000,000 tons, accounts for about 10% of national nitrogen oxide emission, the 3rd after occupying thermal power generation and motor vehicle exhaust emission.Country's clear stipulaties " 12 " nitrogen oxide in " " 12 " energy-saving and emission-reduction planning " reduces discharging index, wherein, and Thermal Power Generation Industry nitrogen oxide emission requirement reduction 29%; Cement industry cuts down 12%, and therefore the situation is tense for cement industry nitrogen oxide emission reduction.
The difficulty that cement industry removes nitrogen oxide need be probed into by NOx formation mechenism from cement production process.Cement industry NOx is in kiln combustion process, in the N2 in air and fuel containing N composition by the oxidized generation of burning approach.Whether strongly thermal NO x and fuel type NOx is mainly divided into according to furnace flame temperature height, oxidation.Clinker burning temperatures as high 1600 DEG C in cement rotary kiln, therefore in kiln hood region, higher than under the conditions of 1300 DEG C, main that formed is thermal NO x, and its major influence factors has temperature, oxygen concentration, gas residence time and fuel combustion degree etc.; In kiln tail, dore furnace region lower than under 1300 DEG C of conditions, main formation fuel type NOx, the factor affecting fuel type NOx generation mainly contains propellant composition, gas residence time, excess air coefficient etc.
From the difference of cement industry nitrogen oxide formation mechenism, the denitration technology adapting to cement industry generally has three kinds: one to be the low nitrogen grading combustion technology generated from Sources controlling thermal NO x, as adopted low NO, control AIR Proportional realizes fractional combustion, control excess air coefficient makes fuel burn in low-oxygen environment.Its denitration effect is subject to cement clinker calcining process restriction, and denitration efficiency be it is generally acknowledged 15% ~ 30%, and stability is not good, generally as compounding technique, reduces initial NOx emission concentration, saves reducing agent consumption; Two is SNCR denitration technology, and SNCR method is under the hot conditions of 850 DEG C ~ 1000 DEG C, sprays into containing NH in flue gas
3the reducing agent of base, is reduced into nitrogen and water by NOx.The removal efficiency of this technology NOx in actual applications generally about 50% ~ 70%, the advantage that system is simple, construction investment is few, easy to operate, but also have that operating cost is high, denitration efficiency is difficult to the shortcomings such as control; Three is SCR denitration technology, and SCR method is under certain catalytic reaction condition, is harmless nitrogen and water with ammonia, urea etc. containing the reducing agent of NH3 base by the NOx conversion in flue gas.This method NO_x removal efficiency is high, often can reach about 60% ~ 90% in actual applications, be widely used in power industry, station boiler NOx discharge can be down to 100mg/Nm
3below.
In above three kinds of denitration technologies, what current cement industry was conventional is low nitrogen grading combustion technology and SNCR denitration technology, or the cooperation of two kinds of denitration technologies.Conventional scr denitration technology is used widely in power industry, but be difficult to promote at cement industry, domesticly also have no relevant report, external cement production enterprise is only had to have application case few in number, as Italian Cementeria di Monselice cement plant, German Solnhofer Zementwerkes cement plant, the arrangement of what these two cement plants all adopted is high-temperature high dust.
Conventional SCR denitration technology is difficult to the reason realizing engineering application at cement industry, is determined by new dry process for cement production.Cement rotary kiln calcination process and high-temp waste gas all more complicated than other heat power engineering systems, cement kiln end heater outlet temperature is between 300 DEG C ~ 400 DEG C, and this temperature is comparatively close to the Process window temperature of SCR, but cement dust content is about 60-70g/Nm
3, arrange SCR reactor in the flue gas section of high dustiness like this, not only will solve the poisoning problem of catalyst blockage, equipment investment, Systematical control are also quite complicated, for the highstrung cement industry of cost control, are difficult to bear.Dust still more contained by high-temperature flue gas, the inherently raw material of cement or semi-finished product, cement industry has the technique of a whole set of maturation for recycling these dust, to control carry-over loss, reduce costs, as increased SCR reactor in this section, the original operational system of cement industry will be destroyed, transformation difficulty.If high-temperature flue gas is first carried out after depositing dust process SCR reaction again can solve dust problem, but cement industry dust pelletizing system is 200 DEG C ~ 250 DEG C operations, the window temperature that after purification, flue-gas temperature is reacted away from conventional scr, cannot adopt conventional scr technology; If flue-gas temperature is in SCR Process window temperature range after making purification, dust pelletizing system need 350 DEG C of operations, and this is by the treatment quantity of increase by 30%, in general, for 5000t/d cement clinker burning system, dust pelletizing system treatment quantity will increase 200000m
3/ h, will adopt resistant to elevated temperatures filter bag of dust collector simultaneously, and cost will significantly increase.In addition, according to requirement in " cement factory energy-saving design specification " (GB 50443-2007), newly-built, enlarging cement factory answers Synchronization Design bootstrap system or its position reserved, during existing improvement of manufacturing line, bootstrap system should be set up, therefore domestic each large-scale or medium-sized concrete plant is provided with device for generating power by waste heat or reserved device for generating power by waste heat substantially, after SCR reactor is arranged in deduster, before SP waste heat boiler, existing process system certainly will be destroyed, add the resistance of system, transformation difficulty is large, cost is high.Therefore, consider from smoke property, catalyst life, energy recovery, improvement cost, operating cost, promote conventional SCR denitration technology at cement industry very difficult.
When current China cement industry does not take denitration technology, NOx emission level is generally at 600 ~ 800mg/Nm
3, in " cement industry atmosphere pollutants emission standards " (GB 4915-2013), regulation cement industry NOx emission concentration is 400mg/Nm
3, key area performs 320mg/Nm
3, current most domestic enterprise, by measures such as low nitrogen burning transformation, SNCR technological transformations, can be reduced to 400mg/Nm substantially
3below, generally 320 ~ 350 mg/Nm can be reached
3, then reduction just difficult for very much.But the NOx emission of cement industry is the 3rd after power industry, motor vehicle exhaust emission, the 100mg/Nm during power industry is implemented " fossil-fuel power plant atmospheric pollutant emission standard " (GB 13223-2011)
3regulation, far below the emission request of cement industry.State by national policy and the public and ask, energy-saving and emission-reduction are that industry existence is basic, if country proposes higher reduction of discharging requirement to cement industry, so prior art is just hard to carry on.
Summary of the invention
For the problems referred to above, the invention provides a kind of cement rotary kiln kiln gas combined denitration device, it can improve the denitration efficiency of flue gas effectively, the atmosphere pollutants emission standards in cement industry can be met preferably, and its system is simple, construction investment is few, easy to operate, reduce operating cost preferably, the present invention additionally provides a kind of cement rotary kiln kiln gas combined denitration technique simultaneously.
A kind of cement rotary kiln kiln gas combined denitration device, it comprises cement rotary kiln, dore furnace connects described cement rotary kiln, preheater connects described dore furnace, Heat Treatment device connects described preheater, blower fan connects described Heat Treatment device, sack cleaner connects described blower fan, exhaust pass connects described sack cleaner, it is characterized in that: SCR reactor connects described exhaust pass, described SCR reactor connects chimney by exhaust blower, described dore furnace is provided with the first injection of reducing agent injection device, described exhaust pass is provided with the second injection of reducing agent injection device.
It is further characterized in that: described first injection of reducing agent injection device is reducing agent spray gun; Described second injection of reducing agent injection device is that reducing agent sprays grid; Described preheater comprises for five-stage whirlwind cylinder pre-heating; Described Heat Treatment device is SP waste heat boiler.
A kind of cement rotary kiln kiln gas combined denitration technique, is characterized in that, comprise the following steps:
(1), cement rotary kiln fuel combustion produce flue gas enter in dore furnace, in dore furnace, temperature range is the region of 800 DEG C ~ 1000 DEG C, sprays into reducing agent and carries out SNCR reaction, remove NOx in flue gas by the first injection of reducing agent injection device;
(2), carry out flue gas through SNCR reduction reaction in dore furnace in preheater, in preheater with cement slurry heat exchange after, decline at heater outlet temperature;
(3) flue gas, after cooling enters subsequently in Heat Treatment device and processes;
(4) flue gas, after Heat Treatment is delivered in sack cleaner through blower fan and removes dust in flue gas;
(5), flue gas enters in SCR reactor by exhaust pass, sprays into reducing agent, after reducing agent fully mixes with flue gas in exhaust pass, enter in SCR reactor in exhaust pass by the second injection of reducing agent injection device.Under the effect of the low temperature catalyst in SCR reactor, in reducing agent and flue gas, NOx carries out SCR reaction, removes the NOx in flue gas;
(6), after purification, flue gas drains into smoke stack emission by exhaust blower.
It is further characterized in that: described reducing agent is liquefied ammonia, ammoniacal liquor or urea liquid;
Described catalyst is manganese-based low-temperature catalyst Mn/TiO
2, its shape is cellular, and carrier is TiO
2.
In said structure of the present invention, SNCR reaction is carried out owing to spraying into reducing agent by the first injection of reducing agent injection device in dore furnace, first time removes the NOx in flue gas, exhaust pass after sack cleaner sprays into reducing agent by the second injection of reducing agent injection device, SCR reaction is carried out in SCR reactor, second time removes the NOx in flue gas, greatly improves the denitration efficiency of flue gas, can realize the discharge lower than cement industry atmosphere pollutants emission standards; Owing to arranging SCR reactor after sack cleaner, in SCR reactor, adopt low temperature catalyst to carry out flue gas reduction reaction, do not need too high temperature can ensure the reduction reaction of flue gas in SCR reactor yet, and then the common sack cleaner before SCR reactor is normally run, not only solve the problem that catalyst blockage is poisoning, its system is simple, construction investment is few, easy to operate, reduce operating cost preferably.
Accompanying drawing explanation
Fig. 1 is cement rotary kiln kiln gas combined denitration apparatus structure schematic diagram.
Detailed description of the invention
See Fig. 1, a kind of cement rotary kiln kiln gas combined denitration device, comprise new type nonaqueous cement rotary kiln 1, dore furnace 2 connects cement rotary kiln 1, preheater 3 conjunctive decomposition stove 2, dore furnace 2 is provided with reducing agent spray gun 21, Heat Treatment device 4 connects preheater 3, high-temperature blower 5 connects Heat Treatment device 4, sack cleaner 6 connects high-temperature blower, exhaust pass 7 connects sack cleaner 6, SCR reactor 8 connection outlet flue 7, exhaust pass is provided with reducing agent and sprays grid 71, SCR reactor 8 connects chimney 10 by exhaust blower 9, achieve the eliminating of the rear flue gas of process.
Heat Treatment device 4 is SP waste heat boiler, effectively carries out Appropriate application to waste heat, carries out heat recovery for generating as flue gas enters SP waste heat boiler 4.
A kind of cement rotary kiln kiln gas combined denitration technique, comprises the following steps:
(1) flue gas that, new type nonaqueous cement rotary kiln 1 fuel combustion produces enters in dore furnace 2, in dore furnace 2, temperature range is the region of 800 DEG C ~ 1000 DEG C, spray into reducing agent by reducing agent spray gun 3 and carry out SNCR reaction, reducing agent is liquefied ammonia, ammoniacal liquor or urea liquid, removes NOx in flue gas;
(2), carry out flue gas through SNCR reduction reaction in dore furnace 2 in preheater 3, in preheater 3 with cement slurry heat exchange after, decline 320 DEG C ~ 400 DEG C in preheater 3 outlet temperature, dust content about 60 ~ 70g/Nm in flue gas
3;
(3) flue gas, after cooling enters the recycling process of waste heat in SP waste heat boiler 4 subsequently, and as carried out cogeneration etc., flue-gas temperature is down to 180 DEG C ~ 220 DEG C, and dust Control is at 10 ~ 20g/Nm
3;
(4) flue gas, after Heat Treatment is delivered in sack cleaner 6 through high-temperature blower 5 and removes dust in flue gas, lower the temperature in sack cleaner 6 simultaneously, high-temperature blower pressure head is about 7200Pa ~ 8500Pa, and in sack cleaner exiting flue gas, dust content controls at 30mg/Nm
3below;
(5), flue gas enters in SCR reactor 8 by exhaust pass 7, in exhaust pass 7, spray grid by reducing agent spray into reducing agent, after reducing agent fully mixes with flue gas in exhaust pass, under entering the effect of the low temperature catalyst of flue gas in SCR reactor 8 in SCR reactor 8, in flue gas, NOx and reducing agent carry out SCR reaction, and catalyst is manganese-based low-temperature catalyst Mn/ TiO
2, its shape is cellular, and carrier is TiO
2, remove the NOx in flue gas, in control SCR reactor outlet flue gas, escape ammonia content is at 8mg/Nm
3below;
(6), after purification flue gas drains into chimney 10 by exhaust blower 9 and discharges, and the height of chimney designs according to related specifications.。
Cement rotary kiln kiln gas combined denitration of the present invention (the low dirt SCR of SNCR+ low temperature) technique, the flue gas that cement rotary kiln fuel combustion produces enters in dore furnace, in dore furnace, temperature range is the region of 850 DEG C ~ 1000 DEG C, spray into reducing agent by the first injection of reducing agent injection device and carry out SNCR reaction, remove NOx in flue gas; Carry out flue gas through SNCR reduction reaction in dore furnace in preheater, in preheater with cement slurry heat exchange after, drop to 320 DEG C ~ 400 DEG C at heater outlet temperature, dust content about 60 ~ 70g/Nm in flue gas
3; Flue gas after cooling enters subsequently in Heat Treatment device and processes, and after process, flue-gas temperature is down to 180 DEG C ~ 220 DEG C, and dust Control is at 10 ~ 20g/Nm
3; Flue gas after Heat Treatment is delivered in sack cleaner through high-temperature blower and removes dust in flue gas, high-temperature blower pressure head is about 7200Pa ~ 8500Pa, according to " cement industry atmosphere pollutants emission standards " (GB 4915-2013), in sack cleaner exiting flue gas, dust content controls at 30mg/Nm
3below; Flue gas enters in SCR reactor by exhaust pass, in exhaust pass, spray into reducing agent by the second injection of reducing agent injection device, after reducing agent fully mixes with flue gas in exhaust pass, enters in SCR reactor.Under the effect of the low temperature catalyst in SCR reactor, in reducing agent and flue gas, NOx carries out SCR reaction, remove the NOx in flue gas, according to " cement industry atmosphere pollutants emission standards " (GB 4915-2013), in control SCR reactor outlet flue gas, escape ammonia content is at 8mg/Nm
3below; After purification, flue gas drains into smoke stack emission by exhaust blower, and the height of chimney designs according to related specifications.
The SNCR+SCR combination method of power plant's CFBB only arranges the first injection of reducing agent injection device, does not arrange the second injection of reducing agent injection device, the reducing agent that the escape ammonia utilizing SNCR to react reacts as SCR.This technique with it difference is, arranges the second injection of reducing agent injection device at exhaust pass, the reducing agent that the escape ammonia not utilizing SNCR to react reacts as SCR.The reason done like this is: a large amount of escape ammonia of SNCR system can cause cement production process system skinning and upstream device as the blocking of waste heat boiler, sack cleaner etc., and harm device security, increases SR; Simultaneously because the process equipment experienced from SNCR conversion zone to SCR conversion zone is many and flow process complicated, in the process of heat collection, depositing dust ash discharge, the loss of escape ammonia can be caused; In addition, because SNCR runs in high temperature section, as increased the amount that reducing agent sprays, the spray gun quantity of the first injection of reducing agent injection device, specification need to increase, and dore furnace transformation difficulty strengthens, and price, maintenance cost are higher, and the second injection of reducing agent injection device is set on sack cleaner exhaust pass, because being arranged on the low dirt section of low temperature, its technology maturation, cost is lower.
When current cement industry does not take denitration technology, NOx emission level is generally at 600 ~ 800mg/Nm
3.Get median 700mg/Nm
3calculate, controlling SNCR denitration efficiency is 50%, and after denitration, in flue gas, NOx content is 350mg/Nm
3, this can meet the middle NOx discharge 400mg/Nm of " cement industry atmosphere pollutants emission standards " (GB 4915-2013) at present
3regulation.Low temperature low dirt SCR denitration control from view of profit is 70 ~ 80%, and after denitration, in flue gas, NOx content is 70 ~ 105mg/Nm
3.SNCR+ low temperature low dirt SCR combined denitration gross efficiency is 85% ~ 90%, can realize low level of emissions.Adopt SNCR+ low temperature low dirt SCR combined denitration technique, the discharge of nitrogen oxide will reduce further, meet national energy-saving and reduce discharging policy.Present invention process has following advantage with device compared with existing technology:
1, the method adopting SNCR and the low dirt SCR denitration of low temperature to combine, realize the mutual supplement with each other's advantages of different technologies, system is flexible.Make full use of hot environment in dore furnace and carry out SNCR transformation, reduce investment and the processing pressure of follow-up SCR system;
2, based on cement industry production technology, affect less on burning clinker of cement, fume treatment, flying dust recovery, bootstrap system, have adaptability widely;
3, SCR system is run in the low dirt section of low temperature, and process air quantity operating mode volume is little, reduces the structure investment of SCR reactor; Dust concentration is low, decreases catalyst blockage, reduces and blows ash handling plant expense; SR is little, stable, and system availability is high, plant maintenance and operating cost lower;
4, the present invention is not only applicable to the construction of new production line, is applicable to the transformation of existing cement producing line yet, and construction is simple, and floor space is little;
5, the present invention is the associating of new type nonaqueous cement kiln system high temperature SNCR denitration and low-temperature smoke air SCR technology, the discharge capacity of final nitrogen oxide, far below the regulation of national Present Cement industrial discharge standard, has wide application space, huge market value and social value.
Claims (9)
1. a cement rotary kiln kiln gas combined denitration device, it comprises cement rotary kiln, it is characterized in that: dore furnace connects described cement rotary kiln, preheater connects described dore furnace, Heat Treatment device connects described preheater, blower fan connects described Heat Treatment device, sack cleaner connects described blower fan, exhaust pass connects described sack cleaner, SCR reactor connects described exhaust pass, described SCR reactor connects chimney by exhaust blower, described dore furnace is provided with the first injection of reducing agent injection device, described exhaust pass is provided with the second injection of reducing agent injection device.
2. a kind of cement rotary kiln kiln gas combined denitration device according to claim 1, is characterized in that: described first injection of reducing agent injection device is reducing agent spray gun.
3. a kind of cement rotary kiln kiln gas combined denitration device according to claim 1, is characterized in that: described second injection of reducing agent injection device is that reducing agent sprays grid.
4. a kind of cement rotary kiln kiln gas combined denitration device according to claim 1, is characterized in that: described preheater is five-stage whirlwind cylinder pre-heating.
5. a kind of cement rotary kiln kiln gas combined denitration device according to claim 1, is characterized in that: described Heat Treatment device is SP waste heat boiler.
6. a cement rotary kiln kiln gas combined denitration technique, is characterized in that, comprise the following steps:
(1), cement rotary kiln fuel combustion produce flue gas enter in dore furnace, in dore furnace, spray into reducing agent by the first injection of reducing agent injection device and carry out SNCR reaction, remove NOx in flue gas;
(2), in dore furnace through the flue gas of SNCR reduction reaction in preheater, in preheater with cement slurry heat exchange after, decline at heater outlet temperature;
(3) flue gas, after cooling enters subsequently in Heat Treatment device and processes;
(4) flue gas, after Heat Treatment is delivered in sack cleaner through blower fan and removes dust in flue gas;
(5), flue gas enters in SCR reactor by exhaust pass, reducing agent is sprayed into by the second injection of reducing agent injection device in exhaust pass, after reducing agent fully mixes with flue gas in exhaust pass, enter in SCR reactor, under the effect of the low temperature catalyst in SCR reactor, in reducing agent and flue gas, NOx carries out SCR reaction, removes the NOx in flue gas;
(6), after purification, flue gas drains into smoke stack emission by exhaust blower.
7. a kind of cement rotary kiln kiln gas combined denitration technique according to claim 6, is characterized in that:
(1), new type nonaqueous cement rotary kiln 1 fuel combustion produce flue gas enter in dore furnace, in dore furnace, temperature range is the region of 800 DEG C ~ 1000 DEG C, sprays into reducing agent carry out SNCR reaction by reducing agent spray gun;
(2), carry out flue gas through SNCR reduction reaction in dore furnace in preheater, in preheater with cement slurry heat exchange after, decline 320 DEG C ~ 400 DEG C at heater outlet temperature, dust content about 60 ~ 70g/Nm in flue gas
3;
(3) flue gas, after cooling enters the recycling process of waste heat in SP waste heat boiler subsequently, and flue-gas temperature is down to 180 DEG C ~ 220 DEG C, and dust Control is at 10 ~ 20g/Nm
3;
(4) flue gas, after Heat Treatment is delivered in sack cleaner through high-temperature blower and removes dust in flue gas, lower the temperature in sack cleaner simultaneously, high-temperature blower pressure head is about 7200Pa ~ 8500Pa, and in sack cleaner exiting flue gas, dust content controls at 30mg/Nm
3below;
(5), flue gas enters in SCR reactor 8 by exhaust pass, in exhaust pass, spray grid by reducing agent spray into reducing agent, after reducing agent fully mixes with flue gas in exhaust pass, under entering the effect of the low temperature catalyst of flue gas in SCR reactor in SCR reactor, in flue gas, NOx and reducing agent carry out SCR reaction, remove the NOx in flue gas, in control SCR reactor outlet flue gas, escape ammonia content is at 8mg/Nm
3below.
8. a kind of cement rotary kiln kiln gas combined denitration technique according to claim 6 or 7, it is characterized in that, described reducing agent is liquefied ammonia, ammoniacal liquor or urea liquid.
9. a kind of cement rotary kiln kiln gas combined denitration technique according to claim 6 or 7, it is characterized in that, described catalyst is manganese-based low-temperature catalyst Mn/TiO
2, its shape is cellular, and carrier is TiO
2.
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| CN105889975A (en) * | 2016-04-18 | 2016-08-24 | 廖引家 | NOx emission reduction method for cement plant |
| CN107174927A (en) * | 2017-07-13 | 2017-09-19 | 北京建筑材料科学研究总院有限公司 | The method of denitration and system of a kind of cement rotary kiln |
| CN108554144A (en) * | 2018-06-07 | 2018-09-21 | 中国科学院过程工程研究所 | A kind of SCR denitration system suitable for the high-alkali flue gas of the high dirt of cement kiln tail |
| CN108686476A (en) * | 2018-07-13 | 2018-10-23 | 天津水泥工业设计研究院有限公司 | A kind of cement industry dedusting denitrating technique, equipment and its remodeling method |
| CN108686475A (en) * | 2018-07-13 | 2018-10-23 | 天津水泥工业设计研究院有限公司 | A kind of dedusting denitration device and its remodeling method |
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| CN109876662A (en) * | 2019-04-19 | 2019-06-14 | 中国科学院过程工程研究所 | SCR denitration system and method for denitration suitable for cement producing line kiln exit gas |
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| CN114797432A (en) * | 2022-03-29 | 2022-07-29 | 中国中材国际工程股份有限公司 | Device and method for adjusting temperature and spraying ammonia for denitration by using flue gas of cement plant |
| CN115228266A (en) * | 2022-06-12 | 2022-10-25 | 安阳中联水泥有限公司 | Rotary cement kiln flue gas degree of depth dust removal denitration device that heat does not run off |
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| CN111013348A (en) * | 2019-12-23 | 2020-04-17 | 西安西矿环保科技有限公司 | Dust and nitrate integrated system and method suitable for multi-dust section in cement kiln |
| CN112058064A (en) * | 2020-09-23 | 2020-12-11 | 南京凯盛国际工程有限公司 | Circulating spouting NOx emission reduction system and working method thereof |
| CN114797432A (en) * | 2022-03-29 | 2022-07-29 | 中国中材国际工程股份有限公司 | Device and method for adjusting temperature and spraying ammonia for denitration by using flue gas of cement plant |
| CN115228266A (en) * | 2022-06-12 | 2022-10-25 | 安阳中联水泥有限公司 | Rotary cement kiln flue gas degree of depth dust removal denitration device that heat does not run off |
| CN115228266B (en) * | 2022-06-12 | 2023-12-01 | 安阳中联水泥有限公司 | Cement rotary kiln flue gas degree of depth dust removal denitration equipment that heat does not run off |
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