CN104762113B - A kind of derv fuel micro-emulsifier and application thereof - Google Patents
A kind of derv fuel micro-emulsifier and application thereof Download PDFInfo
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- CN104762113B CN104762113B CN201410005906.2A CN201410005906A CN104762113B CN 104762113 B CN104762113 B CN 104762113B CN 201410005906 A CN201410005906 A CN 201410005906A CN 104762113 B CN104762113 B CN 104762113B
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Abstract
The invention discloses a kind of derv fuel micro-emulsifier and application thereof, this micro-emulsifier is made up of following component: the first synthesis material, and Organic Ingredients and inorganic raw material by polarity form；Second synthesis material, is made up of low pole Organic Ingredients；3rd synthesis material, is made up of combustion adjuvant and stabilizer；And the weight ratio of above-mentioned three kinds of synthesis materials is 5:5:1.The derv fuel micro-emulsifier holding time of the present invention is long, burns within the engine unrestricted.
Description
Technical field
The invention belongs to fuel technology field, be specifically related to a kind of derv fuel micro-emulsifier and application thereof.
Background technology
At present, the service efficiency improving diesel oil is the important topic of energy-saving and emission-reduction, and the whole world is all paid close attention to diesel oil efficiency and improved,
Also the pollution emission reduction such as sulfur dioxide, nitrogen oxides and non-methane hydrocarbon that diesel oil uses is attached great importance to.This invention contributes to energy-conservation
Reduce discharging.
For solving the problems referred to above, after the one of development adds water to microemulsified additive at present, generate microemulsified with diesel oil
The method of diesel oil.By using this micro emulsion diesel fuel, dilute fuel active ingredient concentration, improve active ingredient service efficiency,
Thus reduce the effect of the usage amount of fuel.Issue about the formula of additive and the patent of manufacture method, but existing
The preparation method having a micro-emulsifier of technology is complicated, burning is restricted, and uses diesel oil holding time of above-mentioned micro-emulsifier short.
Summary of the invention
It is an object of the invention to overcome prior art defect, it is provided that a kind of derv fuel micro-emulsifier and application thereof.
Another object of the present invention is to provide the preparation method of this derv fuel micro-emulsifier.
It is still another object of the present invention to provide a kind of micro emulsion diesel fuel prepared with above-mentioned derv fuel micro-emulsifier.
It is still another object of the present invention to provide the preparation method of a kind of above-mentioned micro emulsion diesel fuel.
Technical scheme is as follows:
A kind of derv fuel micro-emulsifier, is made up of following component:
First synthesis material, Organic Ingredients and inorganic raw material by polarity form；
Second synthesis material, is made up of low pole Organic Ingredients；
3rd synthesis material, is made up of combustion adjuvant and stabilizer；
And the weight ratio of above-mentioned three kinds of synthesis materials is 5:5:1.
In a preferred embodiment of the invention, described first synthesis material is made up of the component of following weight portion:
In a preferred embodiment of the invention, described second synthesis material is made up of the component of following weight portion:
Antioxidant 1010 2 weight portion
Nisin 3 weight portion
Magnetized liquid 3 weight portion.
In a preferred embodiment of the invention: described 3rd synthesis material is made up of the component of following weight portion:
Industrial methanol 2 weight portion
Diesel cetane-number dose 1 weight portion.
Another technical scheme of the present invention is as follows:
The preparation method of a kind of above-mentioned derv fuel micro-emulsifier, comprises the steps:
(1) the first synthesis material, the second synthesis material and the 3rd synthesis material are prepared.
(2) above-mentioned each raw material is weighed in the ratio of 5:5:1, first the second synthesis material is added in the first synthesis material and stir
After mixing uniformly, then the 3rd synthesis material addition is stirred, obtain described diesel oil micro-emulsifier.
In a preferred embodiment of the invention, described first synthesis material is made up of the component of following weight portion:
Its preparation method is: in order by aphthenic acids, vegetable oil acid, this 25, Op-7, sodium carbonate and sodium acid carbonate add
In water, after stirring, i.e. obtain described first synthesis material.
In a preferred embodiment of the invention, described second synthesis material is made up of the component of following weight portion:
Antioxidant 1010 2 weight portion
Nisin 3 weight portion
Magnetized liquid 3 weight portion；
Its preparation method is: antioxidant 1010 and nisin is added in magnetized liquid and stirs, obtains described
Second synthesis material.
In a preferred embodiment of the invention, described 3rd synthesis material is made up of the component of following weight portion:
Industrial methanol 2 weight portion
Diesel cetane-number dose 1 weight portion；
Its preparation method is: both mixed, and obtains described 3rd synthesis material.
The yet another aspect of the present invention is as follows:
A kind of micro emulsion diesel fuel prepared with above-mentioned derv fuel micro-emulsifier, is made up of the component of following weight portion:
Diesel oil 7 weight portion
Derv fuel micro-emulsifier 1～2 weight portion
Water 2 weight portion.
The yet another aspect of the present invention is as follows:
The preparation method of a kind of above-mentioned micro emulsion diesel fuel, comprises the steps:
(1) described derv fuel micro-emulsifier is added to the water, be sufficiently stirred for 20 minutes to mix, obtain microemulsified
The agent aqueous solution；
(2) the above-mentioned micro-emulsifier aqueous solution is joined in diesel oil, be sufficiently stirred for 20 minutes to mix, obtain described
Micro emulsion diesel fuel.
The invention has the beneficial effects as follows:
1, the micro-emulsifier of the present invention is made up of following component: the first synthesis material, by the Organic Ingredients of polarity and inorganic
Raw material forms；Second synthesis material, is made up of low pole Organic Ingredients；3rd synthesis material, is made up of combustion adjuvant and stabilizer；
And the weight ratio of above-mentioned three kinds of synthesis materials is 5:5:1, its holding time is long, burns within the engine unrestricted；
2, the micro emulsion diesel fuel of the present invention and isopyknic general fuel oil have basic equal usefulness, decrease fossil combustion
Material consumption, saves the energy；In post combustion emission waste gas, sulfur dioxide, nitrogen oxides, non-methane hydrocarbon concentration and total amount are less than
The density and gross volume of such pollutants to be discharged of general diesel oil, pollute few, and at normal temperatures, after more than 1 year preserves, profit does not separates.
3, the preparation method of micro-emulsifier of the present invention is simple, does not produce sewage and waste emission, it is not necessary to be heated or cooled,
Energy-conserving and environment-protective.
Detailed description of the invention
Below by way of detailed description of the invention technical scheme it is further detailed and describes.
Embodiment 1
The preparation method of the derv fuel micro-emulsifier of the preparation present invention, comprises the steps:
(1) preparing the first synthesis material, described first synthesis material is made up of the component of following weight portion:
Its preparation method is: in order by aphthenic acids, vegetable oil acid, this 25, Op-7, sodium carbonate and sodium acid carbonate add
In water, after stirring, i.e. obtain described first synthesis material.
(2) preparing the second synthesis material, described second synthesis material is made up of the component of following weight portion:
Antioxidant 1010 (antioxidant AT10, CAS:6683-19-88) 2 weight portions
Nisin (CAS:234, standard: active principle content: 3.5(%) 3 weight portions
Magnetized liquid 3 weight portion；
Its preparation method is: antioxidant 1010 and nisin is added in magnetized liquid and stirs, obtains described
Second synthesis material.The preparation method of described magnetized liquid refers to " for development and the application thereof of Spectral Analysis Technology magnetized liquid "
(Liu Yubin etc., " lubricate and seal " the 2nd phase in 2002) and bibliography thereof.
(3) preparing the 3rd synthesis material, described 3rd synthesis material is made up of the component of following weight portion:
Industrial methanol 2 weight portion
Diesel cetane-number dose 1 weight portion；
Above-mentioned diesel cetane-number dose is colourless to slightly yellow liquid, acidity (mgKOH/100ml)≤6.0, flash-point
(remaining silent) >=75, density (20 DEG C) kg/m3950-980
Its preparation method is: both mixed, and obtains described 3rd synthesis material.
(4) above-mentioned each raw material is weighed in the ratio of 5:5:1, first the second synthesis material is added in the first synthesis material and stir
After mixing uniformly, then the 3rd synthesis material addition is stirred, obtain described diesel oil micro-emulsifier.
Embodiment 2
The micro emulsion diesel fuel prepared with above-mentioned derv fuel micro-emulsifier, is made up of the component of following weight portion:
0# diesel oil 7 weight portion
Derv fuel micro-emulsifier 1～2 weight portion
Water 2 weight portion；
Its preparation method is as follows:
(1) described derv fuel micro-emulsifier is added to the water, be sufficiently stirred for 20 minutes to mix, obtain microemulsified
The agent aqueous solution；
(2) the above-mentioned micro-emulsifier aqueous solution is joined in 0# diesel oil, be sufficiently stirred for 20 minutes to mix, obtain institute
State micro emulsion diesel fuel, this micro emulsion diesel fuel normal preserve and use under the conditions of, preserve 1 year not stratified.
Through inspection, CA4118ZL type Diesel engine is carried out use 0# diesel oil and the platform of above-mentioned micro emulsion diesel fuel sample
Frame performance comparison is checked, and calculates by GB/T14951-2007 " vehicle fuel saving technique assessment method ", and acquired results is as follows:
1, part throttle characteristics comparison test
City ride pattern rate of economizing gasoline :-22.5%
Operational mode rate of economizing gasoline between city :-19.8%
Fast speed running mode rate of economizing gasoline :-10.5%
2, general power comparison test
Torque versus's coefficient: 0.81
Power contrast's coefficient: 0.89
3, five kinds of rotating speed average exhaust smoke intensity purifying rates of diesel engine: 68.2%.
The above, only presently preferred embodiments of the present invention, therefore the scope that the present invention implements can not be limited according to this, i.e.
The equivalence change made according to the scope of the claims of the present invention and description with modify, all should still belong in the range of the present invention contains.
Claims (8)
1. a derv fuel micro-emulsifier, it is characterised in that: it is made up of following component:
First synthesis material, Organic Ingredients and inorganic raw material by polarity form, and described first synthesis material is by following weight portion
Component composition:
Second synthesis material, is made up of low pole Organic Ingredients, and described second synthesis material is made up of the component of following weight portion:
Antioxidant 1010 2 weight portion
Nisin 3 weight portion
Magnetized liquid 3 weight portion；
3rd synthesis material, is made up of combustion adjuvant and stabilizer；
And the weight ratio of above-mentioned three kinds of synthesis materials is 5:5:1.
2. a kind of derv fuel micro-emulsifier as claimed in claim 1, it is characterised in that: described 3rd synthesis material is by as follows
The component composition of weight portion:
Industrial methanol 2 weight portion
Diesel cetane-number dose 1 weight portion.
3. the preparation method of the derv fuel micro-emulsifier described in a claim 1, it is characterised in that: comprise the steps:
(1) the first synthesis material, the second synthesis material and the 3rd synthesis material are prepared；
(2) above-mentioned each raw material is weighed in the ratio of 5:5:1, first the second synthesis material is added stirring in the first synthesis material equal
After even, then the 3rd synthesis material addition is stirred, obtain described diesel oil micro-emulsifier.
4. the preparation method of derv fuel micro-emulsifier as claimed in claim 3, it is characterised in that: described first synthesis material
Preparation method be: in order by aphthenic acids, vegetable oil acid, this 25, Op-7, sodium carbonate and sodium acid carbonate be added to the water, stir
Described first synthesis material is i.e. obtained after mixing uniformly.
5. the preparation method of derv fuel micro-emulsifier as claimed in claim 4, it is characterised in that: described second synthesis material
Preparation method be: antioxidant 1010 and nisin are added in magnetized liquid and stir, obtain described second synthesis
Raw material.
6. the preparation method of derv fuel micro-emulsifier as claimed in claim 5, it is characterised in that:
Described 3rd synthesis material is made up of the component of following weight portion:
Industrial methanol 2 weight portion
Diesel cetane-number dose 1 weight portion；
Its preparation method is: both mixed, and obtains described 3rd synthesis material.
7. the micro emulsion diesel fuel prepared with the derv fuel micro-emulsifier described in claim 1 or 2, it is characterised in that: by
The component composition of following weight portion:
Diesel oil 7 weight portion
Derv fuel micro-emulsifier 1～2 weight portion
Water 2 weight portion.
8. the preparation method of the micro emulsion diesel fuel described in a claim 7, it is characterised in that: comprise the steps:
(1) described derv fuel micro-emulsifier is added to the water, be sufficiently stirred for 20 minutes to mix, obtain micro-emulsifier water
Solution；
(2) the above-mentioned micro-emulsifier aqueous solution is joined in diesel oil, be sufficiently stirred for 20 minutes to mix, obtain described micro emulsion
Change diesel oil.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410005906.2A CN104762113B (en) | 2014-01-06 | 2014-01-06 | A kind of derv fuel micro-emulsifier and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410005906.2A CN104762113B (en) | 2014-01-06 | 2014-01-06 | A kind of derv fuel micro-emulsifier and application thereof |
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| CN104762113A CN104762113A (en) | 2015-07-08 |
| CN104762113B true CN104762113B (en) | 2016-09-07 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079499A (en) * | 1992-05-27 | 1993-12-15 | 孙德贵 | Method for preparing water in oil emulsified diesel oil |
| CN1425743A (en) * | 2002-12-28 | 2003-06-25 | 李盛秋 | Non-toxic oxidation and deterioration preventing process for finished oil made from petroleum |
| CN103087792A (en) * | 2011-10-31 | 2013-05-08 | 薛成才 | Micro-emulsified composite diesel oil fuel additive |
| WO2013177512A1 (en) * | 2012-05-25 | 2013-11-28 | Cerion Enterprises Llc | Iron oxide nanoparticle dispersions and fuel additives for soot combustion |
-
2014
- 2014-01-06 CN CN201410005906.2A patent/CN104762113B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079499A (en) * | 1992-05-27 | 1993-12-15 | 孙德贵 | Method for preparing water in oil emulsified diesel oil |
| CN1425743A (en) * | 2002-12-28 | 2003-06-25 | 李盛秋 | Non-toxic oxidation and deterioration preventing process for finished oil made from petroleum |
| CN103087792A (en) * | 2011-10-31 | 2013-05-08 | 薛成才 | Micro-emulsified composite diesel oil fuel additive |
| WO2013177512A1 (en) * | 2012-05-25 | 2013-11-28 | Cerion Enterprises Llc | Iron oxide nanoparticle dispersions and fuel additives for soot combustion |
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| Publication number | Publication date |
|---|---|
| CN104762113A (en) | 2015-07-08 |
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