CN104761952A - Ceramic inkjet printing ink with adjustable penetration depth and method thereof - Google Patents
Ceramic inkjet printing ink with adjustable penetration depth and method thereof Download PDFInfo
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- CN104761952A CN104761952A CN201510141827.9A CN201510141827A CN104761952A CN 104761952 A CN104761952 A CN 104761952A CN 201510141827 A CN201510141827 A CN 201510141827A CN 104761952 A CN104761952 A CN 104761952A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
Abstract
The invention discloses a ceramic inkjet printing ink with adjustable penetration depth and a method thereof. The ink is composed of a staining ink and an oil-penetration assisting ink, wherein the staining ink is composed of a leveling agent, a color development organic metal salt and a solvent; the color development organic metal salt is dissolved in the solvent and can be converted into colored metal oxide at high temperature; and the oil-penetration assisting ink is composed of a solvent and polysiloxane. The ink has simple composition, and has low penetration anisotropy on the billet or glaze. By compounding the oil-penetration assisting ink, the penetration depth of the staining ink can be conveniently regulated, so that the ceramic can be printed, fired and polished to obtain the ceramic decorative brick with delicate pattern and high stereo perception and has the stone-like tactile sensation and stereoscopic effect. By adopting the soluble organic metal salt as the color body, the ceramic inkjet printing ink can be stored for a long time, does not have the possibility of precipitation or nozzle head blockage, and has favorable inkjet printing performance. The ceramic inkjet printing ink is easy to prepare; and the raw materials can be directly purchased in the market or prepared by simple synthesis.
Description
Technical field
The present invention relates to ceramic ink jet printing technical field, be specifically related to a kind of ceramic ink jet printing ink of adjustable depth of penetration.
Background technology
Lithotome texture is soft, texture is natural, in a great variety, stereoscopic sensation strong, is the ideal material of building decoration.But stone material is a kind of scarce resource, and lithotome has radioactivity, uses in the interior space and do not meet environmental protection life idea.So the texture of natural-like stone and stereoeffect are all pursuing a goal of ceramic tile decorative effect all the time.
Along with the development of digitizing printing technique is with universal, inkjet technology obtains overall application in ceramic decoration field, and progressively instead of the printing technology such as traditional silk screen or roller printing, the diversification future development of the decoration technique of ceramic ink jet printing technology and pottery can be realized by the exploitation of various jetted ink novel material.Current ceramic ink is mainly mineral dye type ink, although can decorate on concavo-convex surface, also just decorate in the plane of adobe, and pattern is also exist with the form of ink dot, pattern texture is natural and soft not, is difficult to realize the three-dimensional decorative effect as imitative stone material.
In ceramic decoration field, have for a long time and adopt the soluble salt of coloring metal oxide compound to decorate, as pattern permeating tile, directly the soluble metallic salt containing coloring oxide, add carboxymethyl cellulose, glycerine, sugar etc. to make through certain art breading and ooze fancy glaze, recycling screen printing technique, is printed onto the trailing on porcelain brick surface.Although certain stereoeffect decoration can be realized, poor by silk-screen printing technique pattern accuracy, texture is soft not, and preparation technology is comparatively complicated.CN1420916A and CN101896563A be refer to and adopt soluble metallic salt to be prepared into ink and to be decorated ceramic material surfaces by spray ink Printing.But ink disclosed in CN1420916A is only applicable on Ceramic glaze, and applicability is restricted, the ceramic tile of simultaneously burning till can not present three-dimensional decorative effect without polishing; Ink disclosed in CN101896563A can be applicable in base substrate or glaze paint, and cannot control the penetrating quality of ink, because the infiltration orientation of soluble salt on base substrate or glaze paint is uncontrollable, is therefore difficult to reach the decorative effect as imitative stone.
Need to be further improved prior art, to obtain the more excellent ceramic ink jet decorative ink of effect.
Summary of the invention
One object of the present invention is the ceramic ink jet printing ink providing a kind of adjustable depth of penetration.
Another object of the present invention is to provide a kind of ceramic ink jet printing technique.
The technical solution used in the present invention is:
A ceramic ink jet printing ink for adjustable depth of penetration, by coloring printing ink and help oil impregnate ink to form, wherein:
Coloring printing ink is by flow agent, color development organic metal salt and solvent composition, and color development organic metal salt is dissolved in solvent and can be at high temperature converted into colored metal oxide;
Help oil impregnate ink to be made up of solvent and polysiloxane, its viscosity is 1 ~ 10mPas, and surface tension is 20 ~ 35mN/m.
As the further improvement of above-mentioned ceramic ink jet printing ink, in coloring printing ink, with metal ion, the mass percentage of color development organic metal salt is 3 ~ 11%, and the mass percentage of flow agent is 0.05 ~ 0.2%, and surplus is solvent.
As the further improvement of above-mentioned ceramic ink jet printing ink, coloring printing ink comprises blue-colored ink, red colored ink, yellow coloring ink and black colorant ink, wherein:
Color development organic metal salt in blue-colored ink is organic cobalt salt, and with metal ion, its mass percentage in coloring printing ink is 3 ~ 8%;
Color development organic metal salt in red colored ink is organic molysite, and with metal ion, its mass percentage in coloring printing ink is 5 ~ 7%;
Color development organic metal salt in yellow coloring ink is the mixing salt of organic titanium salt and organic chromic salts, and with metal ion, its mass percentage in coloring printing ink is respectively 3 ~ 6% and 0.5 ~ 1%;
Color development organic metal salt in black colorant ink is organic cobalt salt and organic molysite, and with metal ion, its mass percentage in coloring printing ink is respectively 2 ~ 4% and 3 ~ 7%.
As the further improvement of above-mentioned ceramic ink jet printing ink, help oil impregnate ink to comprise A, B two kinds and help oil impregnate ink, two kinds are helped the viscosity of oil impregnate ink, surface tension different, and wherein, the viscosity helping oil impregnate ink A is 1 ~ 5mPas, and surface tension is 20 ~ 26mN/m; The viscosity helping oil impregnate ink B is 5 ~ 10mPa s, and surface tension is 26 ~ 35mN/m.
As the further improvement of above-mentioned ceramic ink jet printing ink, organic metal salt is carboxylate salt.Better, organic metal salt is diethyl, the naphthenate of metal.
As the further improvement of above-mentioned ceramic ink jet printing ink, flow agent is at least one in polyacrylic ester or organic silicon modified by polyether.
As the further improvement of above-mentioned ceramic ink jet printing ink, coloring printing ink and the solvent helping oil impregnate ink to use independently are selected from alkane solvent, esters solvent or aromatic hydrocarbon solvent.
A kind of ceramic ink jet printing method, comprises the steps:
1) first by coloring printing ink by ceramic ink jet printer at base substrate or face glazing print pattern;
2) as required, on pattern, printing helps oil impregnate ink;
Wherein, coloring printing ink and help the composition of oil impregnate ink described above.
As above-mentioned ceramic ink jet printing further improvements in methods, when printing helps oil impregnate black, what mixing two kinds of viscosity were different with surface tension in real time helps oil impregnate ink.
The invention has the beneficial effects as follows:
Ink of the present invention, composition is simple, ink is low in the anisotropy of base substrate or glaze paint infiltration, by with the use of help oil impregnate ink, the depth of penetration of coloring printing ink can be regulated and controled easily, pattern exquisiteness, ceramic decorative brick that stereoscopic sensation is strong can be obtained after pottery is printed after burning till polishing, there is the texture as imitative stone material and stereoeffect.
Ink of the present invention, adopts the organic metal salt of solubility as color bodies, can preserve for a long time, there is not the possibility of precipitation or blocking shower nozzle, and has good Ink Jet Printing Performance.By helping the degree of depth of oil impregnate ink regulation and control coloring printing ink infiltration, realize the regulation and control of ceramic decoration stereoeffect.
Ceramic ink jet printing ink of the present invention is easy to preparation, and raw material is directly bought by market or carried out simple synthesis and allocates.
Embodiment
A ceramic ink jet printing ink for adjustable depth of penetration, by coloring printing ink and help oil impregnate ink to form, wherein:
Coloring printing ink is by flow agent, color development organic metal salt and solvent composition, and color development organic metal salt is dissolved in solvent and can be at high temperature converted into colored metal oxide;
Help oil impregnate ink to be made up of solvent and polysiloxane, the viscosity at its 25 DEG C is 1 ~ 10mPas, and surface tension is 20 ~ 35mN/m.
As the further improvement of above-mentioned ceramic ink jet printing ink, in coloring printing ink, with metal ion, the mass percentage of color development organic metal salt is 3 ~ 11%, and the mass percentage of flow agent is 0.05 ~ 0.2%, and surplus is solvent.
As the further improvement of above-mentioned ceramic ink jet printing ink, coloring printing ink comprises blue-colored ink, red colored ink, yellow coloring ink and black colorant ink, wherein:
Color development organic metal salt in blue-colored ink is organic cobalt salt, and with metal ion, its mass percentage in coloring printing ink is 3 ~ 8%, is more preferred from 3 ~ 6%;
Color development organic metal salt in red colored ink is organic molysite, and with metal ion, its mass percentage in coloring printing ink is 5 ~ 7%, is more preferred from 5.5 ~ 7%;
Color development organic metal salt in yellow coloring ink is the mixing salt of organic titanium salt and organic chromic salts, and with metal ion, its mass percentage in coloring printing ink is respectively 3 ~ 6% and 0.5 ~ 1%, is more preferred from 3.5 ~ 6% and 0.5 ~ 1%;
Color development organic metal salt in black colorant ink is organic cobalt salt and organic molysite, and with metal ion, its mass percentage in coloring printing ink is respectively 2 ~ 4% and 3 ~ 7%, is more preferred from 2 ~ 3.5% and 3 ~ 5.2%.
As the further improvement of above-mentioned ceramic ink jet printing ink, help oil impregnate ink to comprise A, B two kinds and help oil impregnate ink, two kinds are helped the viscosity of oil impregnate ink, surface tension different, and wherein, the viscosity helping oil impregnate ink A is 1 ~ 5mPas, and surface tension is 20 ~ 26mN/m; The viscosity helping oil impregnate ink B is 5 ~ 10mPa s, and surface tension is 26 ~ 35mN/m.
As the further improvement of above-mentioned ceramic ink jet printing ink, organic metal salt is carboxylate salt.Better, organic metal salt is diethyl, the naphthenate of metal.
As the further improvement of above-mentioned ceramic ink jet printing ink, flow agent is at least one in polyacrylic ester or organic silicon modified by polyether.
As the further improvement of above-mentioned ceramic ink jet printing ink, coloring printing ink and the solvent helping oil impregnate ink to use independently are selected from alkane solvent, esters solvent or aromatic hydrocarbon solvent.
A kind of ceramic ink jet printing method, comprises the steps:
1) first by coloring printing ink by ceramic ink jet printer at base substrate or face glazing print pattern;
2) as required, on pattern, printing helps oil impregnate ink;
Wherein, coloring printing ink and help the composition of oil impregnate ink described above.
As above-mentioned ceramic ink jet printing further improvements in methods, when printing helps oil impregnate black, what mixing two kinds of viscosity were different with surface tension in real time helps oil impregnate ink.
In coloring printing ink, organic metal salt is mainly organic carboxyl acid salt, and organic carboxyl acid salt is including but not limited to hexanoate, naphthenate, octylate, 2-ethyl-hexanoate, caprate, lauroleate, myristate, palmitate, stearate etc.; These metal-salts dissolve in organic solvent, can at high temperature change into colored metal oxide; Preferably have naphthenate or 2-ethylhexoate, these compound business can be bought or can carry out simple chemosynthesis.
Solvent in coloring printing ink is at least one in alkane solvent, esters solvent or aromatic hydrocarbon solvent; Wherein alkane solvent is at least one in the normal paraffin of C10-C25, isoparaffin or naphthenic hydrocarbon, esters solvent is including but not limited to sad isopropyl ester, capric acid isopropyl ester, isopropyl laurate, Isopropyl myristate, Wickenol 111, iso-octyl palmitate, the different monooctyl ester of coconut oil etc., and aromatic hydrocarbon solvent is isopropyl biphenyl or two isopropyl biphenyls etc.
Flow agent in coloring printing ink is at least one in polyacrylic ester or organic silicon modified by polyether, the trade(brand)name that can enumerate has Tego Flow300, Tego Flow370, Afcona 3700, Afcona 3775, BYK306, BYK333, ELEMENTIS Levaslip 8629 etc., but is not limited thereto.Regulate the dynamic surface tension of coloring printing ink by flow agent, control the ink drop formation of ink when spray ink Printing and performance, reduce the anisotropy of coloring printing ink infiltration, realize vertically permeating.
The solvent of oil impregnate ink is helped to be alkane solvent or esters solvent; Wherein alkane solvent is at least one in the normal paraffin of C10-C25, isoparaffin or naphthenic hydrocarbon, esters solvent is including but not limited to sad isopropyl ester, capric acid isopropyl ester, isopropyl laurate, Isopropyl myristate, Wickenol 111, iso-octyl palmitate, the different monooctyl ester of coconut oil etc., and aromatic hydrocarbon solvent is isopropyl biphenyl or two isopropyl biphenyls etc.
Help the penetration-assisting agent of oil impregnate ink to be polysiloxane, the trade(brand)name that can enumerate has Tego Twin4000, Tego Twin4100, Tego wet270, BYK333, BYK378 etc., but is not limited thereto.The surface tension of ink can be regulated by penetration-assisting agent, substrate wetting energy is provided, and improves perviousness.
Below in conjunction with embodiment, further illustrate technical scheme of the present invention.In following examples, if no special instructions, the content of organic metal salt is the mass percentage meter of metal ion.Help that the viscosity of oil impregnate ink and surface tension are 25 DEG C, record in normal ambient pressure situation.
Embodiment 1
The viscosity wherein helping oil impregnate ink A is 3.2mPa s, and surface tension is 23.0mN/m; The viscosity helping oil impregnate ink B is 5.7mPas, and surface tension is 26.7mN/m.
Embodiment 2
The viscosity wherein helping oil impregnate ink A is 3.6mPa s, and surface tension is 25.1mN/m; The viscosity helping oil impregnate ink B is 7.5mPas, and surface tension is 28.1mN/m.
Embodiment 3
The viscosity wherein helping oil impregnate ink A is 1.5mPa s, and surface tension is 24.5mN/m; The viscosity helping oil impregnate ink B is 9.8mPas, and surface tension is 30.0mN/m.
Its application method comprises following steps:
(1) each separate ink is respectively charged into six passages of ink-jet printer;
(2) by spray ink Printing, coloring printing ink is decorated on ceramic body or the surface of the ceramic body containing cover-coat enamel; After then print help oil impregnate ink;
(3) by stupalith complete for spray ink Printing after drying, calcine in the kiln of 1000 ~ 1300 DEG C;
(4) polishing is carried out on the surface of the ceramic tile goods after calcining, namely obtain the ceramic tile with solid decorative patterns.
Especially, this ink is applicable to fabric that calcic, magnesium, barium, zinc or its content are extremely not low prints, and wherein fabric or can be executed on ceramic body in the mode of drenching glaze by Dry powder material distribution, and the principal constituent of fabric is SiO
260 ~ 80 parts, Al
2o
310 ~ 30 parts, (K
2o+Na
2o) 2 ~ 10 parts, (CaO+MgO) 0 ~ 1 part, ZrO
20 ~ 2 part, Sb
2o
30.5 ~ 5 part.
Spray ink Printing is tested:
1) get the coloring printing ink of 4 kinds of different colours, monochrome prints to the pattern of 200mm × 300mm respectively, and printing gray scale is 100%, detects its depth of penetration.
2) get the coloring printing ink of 4 kinds of different colours, monochrome prints to the pattern of 200mm × 300mm respectively, and printing gray scale is print after 100% to help oil impregnate ink on pattern;
3) fabric printed consists of SiO
272 parts, Al
2o
320 parts, (K
2o+Na
2o) 6 parts, (CaO+MgO) 0.5 part, ZrO
20.5 part, Sb
2o
31 part, described number is mass parts;
4) after having printed, dry, then in 1200 DEG C of calcining 1h, surface finish (detecting depth of penetration before surface finish), obtains ceramic tile.
Experimental result is as shown in the table:
Known from the data table, help oil impregnate ink effectively can promote the infiltration of ink, make ink can infiltrate into darker glaze or base layer, by regulating the viscosity and the surface tension that help oil impregnate ink, the depth of penetration of ink can be controlled easily, be conducive to the depth of penetration controlling different color dot as required, obtain better decorative effect.
Use ceramic ink jet printing ink print of the present invention pattern out, the visual observation after sintering polishing shows, pattern edge is clear, without obvious color dot, excessively naturally, color gos deep into adobe, there is certain three-dimensional decorative effect, be specially adapted to the printing of imitative feldspar brick.
Find in actual production, ceramic ink jet printing ink of the present invention, printing effect is good, can conveniently by regulating the proportioning and the consumption that help oil impregnate ink, and control the depth of penetration of ink, ceramic tile also can not be caused to be out of shape, yield rate is close to 100% simultaneously.
Claims (10)
1. a ceramic ink jet printing ink for adjustable depth of penetration, by coloring printing ink and help oil impregnate ink to form, wherein:
Coloring printing ink is by flow agent, color development organic metal salt and solvent composition, and color development organic metal salt is dissolved in solvent and can be at high temperature converted into colored metal oxide;
Help oil impregnate ink to be made up of solvent and polysiloxane, its viscosity is 1 ~ 10 mPas, and surface tension is 20 ~ 35 mN/m.
2. ceramic ink jet printing ink according to claim 1, is characterized in that: in coloring printing ink, and with metal ion, the mass percentage of color development organic metal salt is 3 ~ 11%, and the mass percentage of flow agent is 0.05 ~ 0.2%, and surplus is solvent.
3. ceramic ink jet printing ink according to claim 1 and 2, is characterized in that: organic metal salt is carboxylate salt.
4. ceramic ink jet printing ink according to claim 1 and 2, is characterized in that: coloring printing ink and the solvent helping oil impregnate ink to use independently are selected from alkane solvent, esters solvent or aromatic hydrocarbon solvent.
5. ceramic ink jet printing ink according to claim 1 and 2, is characterized in that: flow agent is at least one in polyacrylic ester or organic silicon modified by polyether.
6. ceramic ink jet printing ink according to claim 1, is characterized in that: coloring printing ink comprises blue-colored ink, red colored ink, yellow coloring ink and black colorant ink, wherein:
Color development organic metal salt in blue-colored ink is organic cobalt salt, and with metal ion, its mass percentage in coloring printing ink is 3 ~ 8%;
Color development organic metal salt in red colored ink is organic molysite, and with metal ion, its mass percentage in coloring printing ink is 5 ~ 7%;
Color development organic metal salt in yellow coloring ink is the mixing salt of organic titanium salt and organic chromic salts, and with metal ion, its mass percentage in coloring printing ink is respectively 3 ~ 6% and 0.5 ~ 1%;
Color development organic metal salt in black colorant ink is organic cobalt salt and organic molysite, and with metal ion, its mass percentage in coloring printing ink is respectively 2 ~ 4% and 3 ~ 7%.
7. the ceramic ink jet printing ink according to claim 1 or 6, is characterized in that: organic metal salt is diethyl, the naphthenate of metal.
8. ceramic ink jet printing ink according to claim 1, it is characterized in that: help oil impregnate ink to comprise A, B two kinds and help oil impregnate ink, two kinds are helped the viscosity of oil impregnate ink, surface tension different, wherein, the viscosity helping oil impregnate ink A is 1 ~ 5 mPas, and surface tension is 20 ~ 26 mN/m; The viscosity helping oil impregnate ink B is 5 ~ 10mPa s, and surface tension is 26 ~ 35 mN/m.
9. a ceramic ink jet printing method, comprises the steps:
First by coloring printing ink by ceramic ink jet printer print pattern on base substrate or cover-coat enamel;
As required, on pattern, printing helps oil impregnate ink;
Wherein, coloring printing ink and help the composition of oil impregnate ink as described in claim 1 ~ 8 any one.
10. ceramic ink jet printing method according to claim 9, when printing helps oil impregnate black, what mixing two kinds of viscosity were different with surface tension in real time helps oil impregnate ink.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510141827.9A CN104761952B (en) | 2015-03-27 | 2015-03-27 | The ceramic ink jet printing ink and method of a kind of adjustable penetration depth |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105175027A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Ceramic with three-dimensional decoration effect and preparation method thereof |
| CN105219153A (en) * | 2015-10-12 | 2016-01-06 | 佛山市明朝科技开发有限公司 | A kind of oozing spends ceramic ink permeation and preparation method thereof |
| CN105461358A (en) * | 2015-11-19 | 2016-04-06 | 杭州诺贝尔陶瓷有限公司 | A stone-imitating porcelain tile with three-dimensional decoration effects and a producing method thereof |
| CN105819869A (en) * | 2016-04-07 | 2016-08-03 | 佛山市迈瑞思科技有限公司 | Method for improving permeability of oily permeation ink in green tile |
| CN105838144A (en) * | 2015-12-23 | 2016-08-10 | 广东道氏技术股份有限公司 | Pink penetrating ink of ceramic inkjet |
| CN106189501A (en) * | 2016-07-25 | 2016-12-07 | 山东国瓷康立泰新材料科技有限公司 | A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN108218235A (en) * | 2017-12-18 | 2018-06-29 | 佛山科学技术学院 | A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105175027A (en) * | 2015-09-11 | 2015-12-23 | 蒙娜丽莎集团股份有限公司 | Ceramic with three-dimensional decoration effect and preparation method thereof |
| CN105219153A (en) * | 2015-10-12 | 2016-01-06 | 佛山市明朝科技开发有限公司 | A kind of oozing spends ceramic ink permeation and preparation method thereof |
| CN105461358A (en) * | 2015-11-19 | 2016-04-06 | 杭州诺贝尔陶瓷有限公司 | A stone-imitating porcelain tile with three-dimensional decoration effects and a producing method thereof |
| CN105461358B (en) * | 2015-11-19 | 2019-04-19 | 杭州诺贝尔陶瓷有限公司 | A kind of Imitation Rock Porcelain Tiles and its production method of imitative stone pattern three-dimensional decorative effect |
| CN105838144A (en) * | 2015-12-23 | 2016-08-10 | 广东道氏技术股份有限公司 | Pink penetrating ink of ceramic inkjet |
| CN105819869A (en) * | 2016-04-07 | 2016-08-03 | 佛山市迈瑞思科技有限公司 | Method for improving permeability of oily permeation ink in green tile |
| CN106189501A (en) * | 2016-07-25 | 2016-12-07 | 山东国瓷康立泰新材料科技有限公司 | A kind of praseodymium yellow color ceramic ink jet oozes colored ink and preparation method thereof |
| CN107033673A (en) * | 2017-05-25 | 2017-08-11 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of preparation method of inkjet printing cobalt blue ceramic ink |
| CN107033673B (en) * | 2017-05-25 | 2020-12-15 | 佛山市三水区康立泰无机合成材料有限公司 | Preparation method of cobalt blue ceramic ink for ink-jet printing |
| CN108218235A (en) * | 2017-12-18 | 2018-06-29 | 佛山科学技术学院 | A kind of production technology of energy-saving environment-friendly ceramic ink-jet polished bricks |
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