CN104744962A - Electrical laminated board material - Google Patents
Electrical laminated board material Download PDFInfo
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- CN104744962A CN104744962A CN201510166239.0A CN201510166239A CN104744962A CN 104744962 A CN104744962 A CN 104744962A CN 201510166239 A CN201510166239 A CN 201510166239A CN 104744962 A CN104744962 A CN 104744962A
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- resin
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- laminate panel
- electrical laminate
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Abstract
The invention relates to an electrical material, in particular to an electrical laminated board material. The electrical laminated board material is characterized by comprising ES-216 resin, thermoplastic polyester resin, ASA (acrylonitrile styrene acrylate) resin, polyether-ether-ketone, filling, a curing agent and an organic solvent, wherein the mass ratio of the ES-216 resin, thermoplastic polyester resin, ASA (acrylonitrile styrene acrylate) resin, polyether-ether-ketone and filling is 1:(0.5-1.2):(0.2-1.5):(0.1-0.8):(0.1-2). The electrical laminated board material has good heat resistance, electrical insulation, forming manufacturability, high strength, and the like, is reinforced in heat resistance and strength due to the addition of filling, capable of realizing industrial production, and is wide in application prospect in electrical engineering.
Description
Technical field
The present invention relates to electric material, particularly relate to a kind of electrical laminate panel material.
Background technology
Along with the development of electrical industry, high-insulativity, high strength, laminated plastics that is high temperature resistant and that adapt to various environment for use occur in succession, and the copper-clad laminate of printed electronic circuit is also because the needs of electronic industry develop rapidly.China electrician and electronics laminated product after liberation progressively grow up.China's thermosetting laminate has been formed than more complete series.
Laminated plastics is divided into veneer sheet, laminated tube, laminated rod and moulding layer stampings by shape and purposes, copper-clad laminate used for printed circuit and hold the gummed paper capacitance graded bushing core of formula sleeve pipe as high-voltage electric appliance, is the special laminated plastics of two classes.
Insulating laminated sheet is the one of laminated product, cross the woven fiber glass of resin or fabric through insulating composite material that is superimposed, hot pressing by multilayer Jin Stains, it act as the effect guaranteeing that insulating property etc. are important in electric, electronic product, is the requisite basic raw material of a class.Insulating laminated sheet, by processing, becomes various insulation and structural elements, is applied in widely in motor, transformer, high and low voltage electrical equipment, electrical instrument and electronics.China's insulating laminated sheet industry is the important component part of China's insulating material industry.Actual output according to investigation statistics China insulating laminated sheet reaches about 8.2 ten thousand tons in 2010, and sales volume reaches 15.4 hundred million yuan, and its output accounts for about 35% of the ultimate production of whole world insulating laminated sheet.From several years ago, the insulating laminated sheet turnout of China and the output value have exceeded America and Europe and Japan, become producing country the biggest in the world.Eleventh Five-Year Plan period at the beginning of 21 century, sustainable, low-carbon economy development strategy is realized and under the overall situation of building a Harmonious Society in China, the installed capacity of China's generating set increases year by year with the speed of about 10%, the high speed development such as household electronic products, railway construction, provides greater room and the market of development to China's insulating laminated sheet industry.During this period, environment-friendly type, energy-saving, high-performance type product production obtain growth very.No matter a collection of novel enterprise is in industrial scale, or has had in manufacturing technology and newly stride forward.
The quality problems of veneer sheet are the concentrated expression of resin material, gluing, each process quality problem of compacting, and the exploitation of electrical laminate and the insulativity of excellence, intensity, the characteristic such as high temperature resistant improve, and are still growth requirement.
Summary of the invention
The object of this invention is to provide a kind of electrical laminate panel material, this material there is the performances such as good thermotolerance, electric insulating quality, moulded manufacturability, high strength.
In order to reach above-mentioned technical purpose, technical scheme of the present invention is specially, a kind of electrical laminate panel material, comprise ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler, solidifying agent that mass ratio is 1:0.5-1.2:0.2-1.5:0.1-0.8:0.1-2, and organic solvent.
Further, described thermoplastic polyester is selected from polyethylene terephthalate, polybutylene terephthalate, PEN, Poly(Trimethylene Terephthalate).
Further, described solidifying agent be selected from vinyl triamine, diamino-cyclohexane, methylene-bis hexamethylene alkanamine, poly-isocyanide ester one or more.
Further, described filler is the one of aromatics polyamides fiber, cellulosic fibre, glass fibre, tetrafluoroethylene.
Further, described organic solvent is the one of ethanol, acetone, chloroform, methylene dichloride, benzene, tetrahydrofuran (THF), dimethyl sulfoxide (DMSO).
Beneficial effect of the present invention: the present invention can realize suitability for industrialized production, has good thermotolerance, electric insulating quality, moulded manufacturability, high strength etc., strengthening its resistance toheat and intensity, having broad application prospects in electric works by adding filler.
Embodiment
The present invention is explained further below in conjunction with embodiments of the invention.Should be appreciated that specific embodiment described herein only for explaining the present invention, being not intended to limit the present invention.Described method is ordinary method if no special instructions.Described raw material all can obtain from open commercial sources if no special instructions.
Embodiment 1
The preparation of electrical laminate panel material, ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler are added in reactor and is uniformly mixed, under certain temperature after reaction, add organic solvent, stirred at ambient temperature is molten adds solidifying agent, stirs.
A kind of electrical laminate panel material, comprise ES-216 resin, thermoplastic polyester (Poly(Trimethylene Terephthalate)), ASA resin, polyether-ether-ketone, filler aromatics polyamides fiber, solidifying agent vinyl triamine that mass ratio is 1:0.5:0.2:0.1:0.1, and organic solvent ethanol.
Embodiment 2
The preparation of electrical laminate panel material, ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler are added in reactor and is uniformly mixed, under certain temperature after reaction, add organic solvent, stirred at ambient temperature is molten adds solidifying agent, stirs.
A kind of electrical laminate panel material, comprise ES-216 resin, thermoplastic polyester (Poly(Trimethylene Terephthalate)), ASA resin, polyether-ether-ketone, filler fibre cellulose fiber, solidifying agent diamino-cyclohexane that mass ratio is 1:0.8:0.5:0.2:0.3, and organic solvent-acetone.
Embodiment 3
The preparation of electrical laminate panel material, ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler are added in reactor and is uniformly mixed, under certain temperature after reaction, add organic solvent, stirred at ambient temperature is molten adds solidifying agent, stirs.
A kind of electrical laminate panel material, comprise ES-216 resin, thermoplastic polyester (PEN), ASA resin, polyether-ether-ketone, filler glass fibre, solidifying agent methylene-bis hexamethylene alkanamine that mass ratio is 1:0.9:0.7:0.3:0.5, and organic solvents, chloroform.
Embodiment 4
The preparation of electrical laminate panel material, ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler are added in reactor and is uniformly mixed, under certain temperature after reaction, add organic solvent, stirred at ambient temperature is molten adds solidifying agent, stirs.
A kind of electrical laminate panel material, comprise ES-216 resin that mass ratio is 1:1:1:0.8:0.8, thermoplastic polyester (polybutylene terephthalate), ASA resin, polyether-ether-ketone, filler tetrafluoroethylene, solidifying agent gather isocyanide ester, and organic solvent tetrahydrofuran.
Embodiment 5
The preparation of electrical laminate panel material, ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler are added in reactor and is uniformly mixed, under certain temperature after reaction, add organic solvent, stirred at ambient temperature is molten adds solidifying agent, stirs.
A kind of electrical laminate panel material, comprise ES-216 resin that mass ratio is 1:1.2:1.5:0.8:2, thermoplastic polyester (Poly(Trimethylene Terephthalate)), ASA resin, polyether-ether-ketone, filler fibre cellulose fiber, solidifying agent gather isocyanide ester, and organic solvent dimethyl sulfoxide (DMSO).
Embodiment 6
Electric property and insulating property test are carried out to embodiment 1-5 gained electrical laminate panel material, by testing its relative permittivity, and its voltage breakdown.
Dielectric properties are tested according to the regulation of GB1409-88.Sample production, process and test procedure are as follows: first, veneer sheet to be measured are made into five pieces, the foursquare sample that the length of side is 55cm, and make diameter d and be slightly less than the copper foil of the testing sample length of side as electrode.Then, sample and electrode are put into climatic chamber, be 23 DEG C ± 2 DEG C in temperature, relative humidity is process 48 hours under the condition of (50% ± 5), takes out sample and all hooks at specimen surface and smear a small amount of Vaseline and test after circular electrode is affixed on specimen surface closely.
Voltage breakdown is tested according to the regulation of GB/T1048.1-2006, and it is method of boosting step by step or the experiment of 60s proof voltage method that trial voltage applies mode.Sample production, process and test procedure are as follows: first, and the longitudinal direction along tested sheet material processes five samples, and the specimen size of testing shock strength in this paper is the wide X thickness=l00mmx25mmx4min of long X; Then, sample is pressed the (temperature 23 DEG C ± 2 DEG C of specified standards air B in GB/T1058.1-2003, relative humidity (50% ± 5)) under process 24h, take out in latter 3 minutes sample to be placed in meet after mineral oil that IEC60296:2003 specifies soaks preheating 0.5h ~ lh and test immediately.
Through testing the specific inductivity of embodiment 1-5, its relative permittivity is respectively 4.24,4.28,4.24,4.23,4.26, in 4.24 ~ 4.28 scopes, has good insulating property; Through testing the electrical laminate panel material voltage breakdown of embodiment 1-5, its electric breakdown voltage reaches 42V, has good electric property.
Apply specific case herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping, and this description should not be construed as limitation of the present invention.
Claims (5)
1. an electrical laminate panel material, is characterized in that, comprises ES-216 resin, thermoplastic polyester, ASA resin, polyether-ether-ketone, filler, solidifying agent that mass ratio is 1:0.5-1.2:0.2-1.5:0.1-0.8:0.1-2, and organic solvent.
2. a kind of electrical laminate panel material according to claim 1, it is characterized in that, described thermoplastic polyester is selected from polyethylene terephthalate, polybutylene terephthalate, PEN, Poly(Trimethylene Terephthalate).
3. a kind of electrical laminate panel material according to claim 1, is characterized in that, described solidifying agent be selected from vinyl triamine, diamino-cyclohexane, methylene-bis hexamethylene alkanamine, poly-isocyanide ester one or more.
4. a kind of electrical laminate panel material according to claim 1, is characterized in that, described filler is the one of aromatics polyamides fiber, cellulosic fibre, glass fibre, tetrafluoroethylene.
5. a kind of electrical laminate panel material according to claim 1, is characterized in that, described organic solvent is the one of ethanol, acetone, chloroform, methylene dichloride, benzene, tetrahydrofuran (THF), dimethyl sulfoxide (DMSO).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510166239.0A CN104744962A (en) | 2015-04-10 | 2015-04-10 | Electrical laminated board material |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510166239.0A CN104744962A (en) | 2015-04-10 | 2015-04-10 | Electrical laminated board material |
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| CN104744962A true CN104744962A (en) | 2015-07-01 |
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| CN201510166239.0A Pending CN104744962A (en) | 2015-04-10 | 2015-04-10 | Electrical laminated board material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892791A (en) * | 2017-10-19 | 2018-04-10 | 太仓恒阳金属制品有限公司 | Laminate and preparation method thereof |
| CN109486068A (en) * | 2018-10-25 | 2019-03-19 | 合肥沃龙彦高分子材料有限公司 | A kind of high-strength polytetrafluoroethylboard board |
| CN111103506A (en) * | 2018-10-25 | 2020-05-05 | 浙江荣泰电工器材有限公司 | Method for detecting insulating strength and breakdown voltage of special-shaped plate |
| US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
Citations (5)
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| CN102134376A (en) * | 2010-12-29 | 2011-07-27 | 四川东材科技集团股份有限公司 | Halogen-free flame-retardant resin composition and preparation method of prepreg and laminated plate |
| CN102585437A (en) * | 2011-12-27 | 2012-07-18 | 广东生益科技股份有限公司 | High heat-resisting epoxy resin compound and bonding sheet and copper clad laminate made from same |
| CN102775733A (en) * | 2012-08-09 | 2012-11-14 | 广东生益科技股份有限公司 | Thermosetting resin composition as well as prepreg and copper clad laminate made from thermosetting resin composition |
| CN103223762A (en) * | 2013-04-01 | 2013-07-31 | 四川东材科技集团股份有限公司 | Preparation method of glass fiber cloth laminate with epoxide-group benzoxazine |
| CN103298882A (en) * | 2011-07-22 | 2013-09-11 | 株式会社Lg化学 | Heat-curable resin composition, and prepreg and metal foil-stacked plate using same |
-
2015
- 2015-04-10 CN CN201510166239.0A patent/CN104744962A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134376A (en) * | 2010-12-29 | 2011-07-27 | 四川东材科技集团股份有限公司 | Halogen-free flame-retardant resin composition and preparation method of prepreg and laminated plate |
| CN103298882A (en) * | 2011-07-22 | 2013-09-11 | 株式会社Lg化学 | Heat-curable resin composition, and prepreg and metal foil-stacked plate using same |
| CN102585437A (en) * | 2011-12-27 | 2012-07-18 | 广东生益科技股份有限公司 | High heat-resisting epoxy resin compound and bonding sheet and copper clad laminate made from same |
| CN102775733A (en) * | 2012-08-09 | 2012-11-14 | 广东生益科技股份有限公司 | Thermosetting resin composition as well as prepreg and copper clad laminate made from thermosetting resin composition |
| CN103223762A (en) * | 2013-04-01 | 2013-07-31 | 四川东材科技集团股份有限公司 | Preparation method of glass fiber cloth laminate with epoxide-group benzoxazine |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11352480B2 (en) | 2016-03-18 | 2022-06-07 | Ticona Llc | Polyaryletherketone composition |
| CN107892791A (en) * | 2017-10-19 | 2018-04-10 | 太仓恒阳金属制品有限公司 | Laminate and preparation method thereof |
| CN109486068A (en) * | 2018-10-25 | 2019-03-19 | 合肥沃龙彦高分子材料有限公司 | A kind of high-strength polytetrafluoroethylboard board |
| CN111103506A (en) * | 2018-10-25 | 2020-05-05 | 浙江荣泰电工器材有限公司 | Method for detecting insulating strength and breakdown voltage of special-shaped plate |
| CN111103506B (en) * | 2018-10-25 | 2021-06-22 | 浙江荣泰电工器材有限公司 | Method for detecting breakdown voltage of special-shaped plate |
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Application publication date: 20150701 |
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