CN104714264A - High reflection aluminum mirror and preparation method thereof - Google Patents
High reflection aluminum mirror and preparation method thereof Download PDFInfo
- Publication number
- CN104714264A CN104714264A CN201510137883.5A CN201510137883A CN104714264A CN 104714264 A CN104714264 A CN 104714264A CN 201510137883 A CN201510137883 A CN 201510137883A CN 104714264 A CN104714264 A CN 104714264A
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- mirror
- layer
- glass substrate
- bias
- aluminum
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/085—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3405—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of organic materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/3663—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties specially adapted for use as mirrors
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Optical Elements Other Than Lenses (AREA)
- Physical Vapour Deposition (AREA)
Abstract
The invention discloses a high reflection aluminum mirror. The high reflection aluminum mirror comprises a glass substrate and a mirror surface clad layer which is deposited on the glass substrate. The high reflection aluminum mirror is characterized in that the mirror surface clad layer sequentially comprises a reflection improving composite layer, an aluminum layer, a protective layer, a primer layer and a finish paint layer in an outward mode from the glass substrate. Compared with the prior art, before a functional layer and an aluminum layer reflection layer of the high reflection aluminum mirror are plated, the reflection improving composite layer is plated, the light reflecting rate (larger than 90%) of the high reflection aluminum mirror is greatly improved, the mirror can even compare favorably with a silver mirror, and the bonding force between the aluminum layer and the glass substrate can further be reinforced. A Si3N4 layer is additionally arranged behind the aluminum layer, the aluminum layer can be protected from being oxidized, the aluminum layer can be prevented from being damaged in the varnishing process, and the reflective rate of the aluminum mirror can also be increased. In addition, the aluminum mirror does not contain silver and copper like the silver mirror, and therefore heavy metal pollution is reduced.
Description
Technical field
The present invention relates to a kind of catoptron, particularly, aluminium mirror relating to a kind of high reverse--bias and preparation method thereof.
Background technology
Catoptron can be divided into silver mirror and aluminium mirror.
Silver mirror reflectivity is high, long service life, is therefore widely used in daily life.But silver mirror production cost is high.The primary raw material that silver mirror adopts in production technology is generally silver nitrate and copper, and silver and copper are all heavy metal elements, production run and all making an extremely bad impression to environment when scrapping, and the industrial waste water produced in production run is also extremely difficult.
Aluminium mirror raw materials cost is lower, is easy to large-scale production.But intensity and the reflectivity of existing aluminium mirror are all lower, reflecting properties is greatly about about 70%, and easily distortion on shape and color, and the life-span is short, corrosion resistivity is poor.
Summary of the invention
The object of the invention is to the above-mentioned defect overcoming prior art, provide a kind of reflectivity can to match in excellence or beauty silver mirror, long service life, novel high reverse--bias aluminium mirror that production cost is lower.
In order to realize foregoing invention object; the present invention discloses a kind of high reverse--bias aluminium mirror; comprise glass substrate; and the minute surface coating be deposited on described glass substrate; it is characterized in that, described minute surface coating is outwards followed successively by from glass substrate and improves reflection composite bed, aluminium lamination, protective seam, prime coat, top coat layer.
Preferably, describedly composite film that reflection composite bed forms for a kind of or two or more material in TiO2, SiO2, AlNx, Si3N4 is improved also or the rete that forms of the potpourri of two or more material.
Preferably, the composite film that forms for a kind of or two or more material in ZrO2N, C3N4, Si3N4 of described protective seam.
Preferably, described raising reflection composite bed thickness is 50 ~ 200nm, and preferred thickness is 120 ~ 150nm, and more preferred thickness is 130 ~ 140nm, adopts magnetron sputtering deposition to form.
Preferably, described aluminium lamination adopts magnetron sputtering deposition to form, and thickness is 20 ~ 100nm, and preferred thickness is 25 ~ 50nm, and more preferred thickness is 30 ~ 40nm.
Preferably, described protective layer thickness is 0 ~ 50nm, and preferred thickness is 5 ~ 30nm, and more preferred thickness is 10 ~ 20nm, adopts magnetron sputtering deposition to form.
Preferably, described prime coat is acrylate resin layer, and thickness is 160 ~ 220 mg/m
2, adopt the showering of curtain-type filming equipment to form; Described top coat layer is alkyde resin top-coat layer, and thickness is 100 ~ 160 mg/m
2, adopt the showering of curtain-type filming equipment to form.
Prepare a method for above-mentioned high reverse--bias aluminium mirror, it is characterized in that, comprise the steps:
A () uses the cerium oxide suspension of 10% ~ 20%, by glass substrate by developing machine, use deionized water to carry out degree of depth cleaning, then air-dry;
B () glass substrate enters vacuum magnetic control film coating device and carries out forevacuum transition, remove the steam of glass substrate further;
C () glass substrate enters the magnetron sputtering region of coating apparatus, be coated with on the glass substrate and improve reflection composite bed, aluminium lamination and protective seam, go out magnetron sputtering region;
D () primer and top coat layer, after minute surface plates prime coat, carry out drying, cooling, then on minute surface surfacing enamelled coating, carry out afterwards drying, cooling.
Preferably, in described step (d), drying time is greater than 1mins, and bake out temperature is greater than 100 DEG C.
Compared with prior art, the present invention, before being coated with the functional layer of high reverse--bias aluminium mirror-aluminium lamination reflection horizon, first plating and improves reflection composite bed, not only substantially increase the reflecting rate (being greater than 90%) of high reverse--bias aluminium mirror, even can match in excellence or beauty silver mirror, also can strengthen the adhesion between aluminium lamination and glass substrate.After aluminium lamination, increase one deck Si3N4, protection aluminium lamination in case oxidation and japanning time injury that aluminium lamination is caused, also can increase the reflectivity of aluminium mirror.In addition, aluminium mirror is not silvery, and mirror contains silver and copper, thus decreases the pollution of heavy metal.
Accompanying drawing explanation
Can be further understood by following detailed Description Of The Invention and institute's accompanying drawings about the advantages and spirit of the present invention.
Fig. 1 is high reverse--bias aluminium mirror structural representation of the present invention;
Fig. 2 is high reverse--bias aluminium mirror first example structure schematic diagram of the present invention;
Fig. 3 is high reverse--bias aluminium mirror second example structure schematic diagram of the present invention;
Fig. 4 is high reverse--bias aluminium mirror the 3rd example structure schematic diagram of the present invention.
Embodiment
Specific embodiments of the invention are described in detail below in conjunction with accompanying drawing.
Fig. 1 is high reverse--bias aluminium mirror structural representation of the present invention.As shown in Figure 1, high reverse--bias aluminium mirror of the present invention comprises glass substrate 1, and is deposited on the minute surface coating on glass substrate 1.Glass substrate 1 is preferably the white glass of fresh float glass process.Minute surface coating is outwards followed successively by from glass substrate 1 and improves reflection composite bed 2, aluminium lamination 3, protective seam 4, prime coat 5, top coat layer 6.Improve composite film that reflection composite bed 2 forms for a kind of or two or more material in TiO2, SiO2, AlNx, Si3N4 also or the rete of the potpourri formation of two or more material.Improving reflection composite bed 2 thickness is 50 ~ 200nm, and preferred thickness is 120 ~ 150nm, and more preferred thickness is 130 ~ 140nm, adopts magnetron sputtering deposition to form.Aluminium lamination 3 adopts magnetron sputtering deposition to form, and thickness is 20 ~ 100nm, and preferred thickness is 25 ~ 50nm, and more preferred thickness is 30 ~ 40nm.The composite film that protective seam 4 forms for a kind of or two or more material in ZrO2N, C3N4, Si3N4.Protective layer thickness is 0 ~ 50nm, and preferred thickness is 5 ~ 30nm, and more preferred thickness is 10 ~ 20nm, adopts magnetron sputtering deposition to form.Prime coat 5 is acrylate resin layer, and thickness is 160 ~ 220 mg/m
2, adopt the showering of curtain-type filming equipment to form.Top coat layer 6 is alkyde resin top-coat layer, and thickness is 100 ~ 160 mg/m
2, adopt the showering of curtain-type filming equipment to form.
embodiment 1
In the first embodiment of the present invention, as shown in Figure 2, high reverse--bias aluminium mirror comprises glass substrate 1, improves reflection composite bed 2, aluminium lamination 3, prime coat 5, top coat layer 6.Wherein improve the composite film that reflection composite bed 2 is made up of TiO2, SiO2 and Si3N4.
The preparation method of high reverse--bias aluminium mirror comprises the steps:
A () is to the white glass surface fine polishing of fresh float glass process and degree of depth cleaning:
The cerium oxide suspension of service property (quality) mark 10% ~ 20%, by developing machine, use deionized water to carry out degree of depth cleaning, spray to glass substrate, the degree of depth is cleaned, then air-dry;
B () glass substrate enters vacuum magnetic control film coating device and carries out forevacuum transition, remove the steam of glass substrate further;
C () glass substrate enters the magnetron sputtering region of coating apparatus,
Be coated with on the glass substrate and improve reflection composite bed:
A, plating TiO2 layer, sputtered in oxygen, argon atmosphere by the ceramic titanium target of rotary AC negative electrode, wherein process gas
Volume ratio oxygen: argon gas=1:20, thicknesses of layers is 50.3nm;
B, plating SiO2 layer, sputtered in oxygen, argon atmosphere by the sial target (mass ratio Si:Al=92:8) of rotary AC negative electrode, wherein process gas volume ratio oxygen: argon gas=5:4, thicknesses of layers is 80.3nm;
C, plating Si3N4 layer, sputtered in nitrogen, argon atmosphere by the sial target (mass ratio Si:Al=92:8) of rotary AC negative electrode, wherein process gas volume ratio nitrogen: argon gas=1:4, thicknesses of layers is 10.0nm.
Sputter aluminium lamination: at raising reflection composite bed plated surface aluminium lamination, aluminum layer thickness is 30.3nm, adopts magnetron sputtering deposition to form;
D () adopts curtain-type plating paint equipment showering prime coat, top coat layer:
Glass-mirror plates acrylic primer layer post-drying, and drying time is greater than 1min, and bake out temperature is greater than 100 DEG C, after being cooled to certain degree of hardness after oven dry, then the top coat layer plated above, prime coat thickness 180g/m
2;
Plate alkyde resin top-coat layer post-drying, drying time is greater than 1min, and bake out temperature is greater than 100 DEG C, is cooled to certain degree of hardness after oven dry.
Carry out after having prepared testing, packing:
Aluminium mirror after plated film completes, through series of experiments such as Schweinfurt green test, ferric chloride test, hundred lattice tests, salt water test, edging tests, is packed after stand the test.
The high reverse--bias aluminium mirror visible reflectance of the present embodiment manufacture is adopted to reach 93.8%.
embodiment 2
In the second embodiment of the present invention, as shown in Figure 3, high reverse--bias aluminium mirror comprises glass substrate 1, improves reflection composite bed 2, aluminium lamination 3, protective seam 4, top coat layer 6.Wherein improve the composite film that reflection composite bed 2 is made up of TiO2 and SiO2.Protective seam 4 is Si3N4 retes.
The preparation method of high reverse--bias aluminium mirror comprises the steps:
A () is to the white glass surface fine polishing of fresh float glass process and degree of depth cleaning:
The cerium oxide suspension of service property (quality) mark 10% ~ 20%, by developing machine, use deionized water to carry out degree of depth cleaning, spray to glass substrate, the degree of depth is cleaned, then air-dry;
B () glass substrate enters vacuum magnetic control film coating device and carries out forevacuum transition, remove the steam of glass substrate further;
C () glass substrate enters the magnetron sputtering region of coating apparatus,
Be coated with high reflection layer on the glass substrate:
A, plating TiO2 layer, sputtered in oxygen, argon atmosphere by the ceramic titanium target of rotary AC negative electrode, wherein process gas
Volume ratio oxygen: argon gas=1:20, thicknesses of layers is 55.3nm;
B, plating SiO2 layer, by the sial target (mass ratio Si:Al=92:8) of rotary AC negative electrode at oxygen, argon
Sputter in atmosphere, wherein process gas volume ratio oxygen: argon gas=5:4, thicknesses of layers is 78.1nm.
Sputter aluminium lamination: at raising reflection composite bed plated surface aluminium lamination, aluminum layer thickness is 43.5nm, adopts magnetron sputtering deposition to form.
Plating Si3N4 protective seam: sputtered in nitrogen, argon atmosphere by the sial target (mass ratio Si:Al=92:8) of rotary AC negative electrode, wherein process gas volume ratio nitrogen: argon gas=1:4, thicknesses of layers is 12.1nm.
D () adopts curtain-type plating paint equipment showering top coat layer:
Glass-mirror plates alkyde resin top-coat layer post-drying, and drying time is greater than 1min, and bake out temperature is greater than 100 DEG C, is cooled to certain degree of hardness after oven dry.
After having prepared, carry out testing, packing:
Aluminium mirror after plated film completes, through series of experiments such as Schweinfurt green test, ferric chloride test, hundred lattice tests, salt water test, edging tests, is packed after stand the test.
The high reverse--bias aluminium mirror visible reflectance of the present embodiment manufacture is adopted to reach 95.7%.
embodiment 3
In the third embodiment of the present invention, as shown in Figure 4, high reverse--bias aluminium mirror comprises glass substrate 1, improves reflection composite bed 2, aluminium lamination 3, protective seam 4, prime coat 5, top coat layer 6.Wherein improve the composite film that reflection composite bed 2 is made up of TiO2 and SiO2.Protective seam 4 is Si3N4 retes.
The preparation method of high reverse--bias aluminium mirror comprises the steps:
A () is to the white glass surface fine polishing of fresh float glass process and degree of depth cleaning:
The cerium oxide suspension of service property (quality) mark 10% ~ 20%, by developing machine, use deionized water to carry out degree of depth cleaning, spray to glass substrate, the degree of depth is cleaned, then air-dry;
B () glass substrate enters vacuum magnetic control film coating device and carries out forevacuum transition, remove the steam of glass substrate further;
C () glass substrate enters the magnetron sputtering region of coating apparatus,
Be coated with high reflection layer on the glass substrate:
A, plating TiO2 layer, sputtered in oxygen, argon atmosphere by the ceramic titanium target of rotary AC negative electrode, wherein process gas
Volume ratio oxygen: argon gas=1:20, thicknesses of layers is 54.6nm;
B, plating SiO2 layer, by sial target (mass ratio Si:Al=92: 8) at oxygen, argon of rotary AC negative electrode
Sputter in atmosphere, wherein process gas volume ratio oxygen: argon gas=5:4, thicknesses of layers is 77.4nm.
Sputter aluminium lamination: at raising reflection composite bed plated surface aluminium lamination, aluminum layer thickness is 41.2nm, adopts magnetron sputtering deposition to form.
Plating Si3N4 protective seam: sputtered in nitrogen, argon atmosphere by the sial target (mass ratio Si:Al=92:8) of rotary AC negative electrode, wherein process gas volume ratio nitrogen: argon gas=1:4, thicknesses of layers is 19.8nm.
D () adopts curtain-type filming equipment showering prime coat, top coat layer:
Glass-mirror plates acrylic primer layer post-drying, and drying time is greater than 1min, and bake out temperature is greater than 100 DEG C, after being cooled to certain degree of hardness after oven dry, then the top coat layer plated above, prime coat thickness 180g/m
2;
Plate alkyde resin top-coat layer post-drying, drying time is greater than 1min, and bake out temperature is greater than 100 DEG C, is cooled to certain degree of hardness after oven dry.
After having prepared, carry out testing, packing:
Aluminium mirror after plated film completes, through series of experiments such as Schweinfurt green test, ferric chloride test, hundred lattice tests, salt water test, edging tests, is packed after stand the test.
The high reverse--bias aluminium mirror visible reflectance of the present embodiment manufacture is adopted to reach 94.1%.
Compared with prior art, the present invention, before being coated with the functional layer of high reverse--bias aluminium mirror-aluminium lamination reflection horizon, first plating and improves reflection composite bed, not only substantially increase the reflecting rate (being greater than 90%) of high reverse--bias aluminium mirror, even can match in excellence or beauty silver mirror, also can strengthen the adhesion between aluminium lamination and glass substrate.After aluminium lamination, increase one deck Si3N4, protection aluminium lamination in case oxidation and japanning time injury that aluminium lamination is caused, also can increase the reflectivity of aluminium mirror.In addition, aluminium mirror is not silvery, and mirror contains silver and copper, thus decreases the pollution of heavy metal.
Just preferred embodiment of the present invention described in this instructions, above embodiment is only in order to illustrate technical scheme of the present invention but not limitation of the present invention.All those skilled in the art, all should be within the scope of the present invention under this invention's idea by the available technical scheme of logical analysis, reasoning, or a limited experiment.
Claims (9)
1. a high reverse--bias aluminium mirror, comprises glass substrate, and is deposited on the minute surface coating on described glass substrate, it is characterized in that, described minute surface coating is outwards followed successively by from glass substrate and improves reflection composite bed, aluminium lamination, protective seam, prime coat, top coat layer.
2. high reverse--bias aluminium mirror as claimed in claim 1, it is characterized in that, describedly improve composite film that reflection composite bed forms for a kind of or two or more material in TiO2, SiO2, AlNx, Si3N4 also or the rete that forms of the potpourri of two or more material.
3. high reverse--bias aluminium mirror as claimed in claim 1, is characterized in that, the composite film that described protective seam forms for a kind of or two or more material in ZrO2N, C3N4, Si3N4.
4. high reverse--bias aluminium mirror as claimed in claim 1, is characterized in that, described raising reflection composite bed thickness is 50 ~ 200nm, and preferred thickness is 120 ~ 150nm, and more preferred thickness is 130 ~ 140nm, adopts magnetron sputtering deposition to form.
5. high reverse--bias aluminium mirror as claimed in claim 1, is characterized in that, described aluminium lamination adopts magnetron sputtering deposition to form, and thickness is 20 ~ 100nm, and preferred thickness is 25 ~ 50nm, and more preferred thickness is 30 ~ 40nm.
6. high reverse--bias aluminium mirror as claimed in claim 1, it is characterized in that, described protective layer thickness is 0 ~ 50nm, and preferred thickness is 5 ~ 30nm, and more preferred thickness is 10 ~ 20nm, adopts magnetron sputtering deposition to form.
7. high reverse--bias aluminium mirror as claimed in claim 1, it is characterized in that, described prime coat is acrylate resin layer, and thickness is 160 ~ 220 mg/m
2, adopt the showering of curtain-type filming equipment to form; Described top coat layer is alkyde resin top-coat layer, and thickness is 100 ~ 160 mg/m
2, adopt the showering of curtain-type filming equipment to form.
8. a preparation method for the high reverse--bias aluminium mirror as described in one of claim 1-6, is characterized in that, comprise the steps:
A () uses the cerium oxide suspension of 10% ~ 20%, by glass substrate by developing machine, use deionized water to carry out degree of depth cleaning, then air-dry;
B () glass substrate enters vacuum magnetic control film coating device and carries out forevacuum transition, remove the steam of glass substrate further;
C () glass substrate enters the magnetron sputtering region of coating apparatus, be coated with on the glass substrate and improve reflection composite bed, aluminium lamination and protective seam, go out magnetron sputtering region;
D () primer and top coat layer, after minute surface plates prime coat, carry out drying, cooling, then on minute surface surfacing enamelled coating, carry out afterwards drying, cooling.
9. the preparation method of high reverse--bias aluminium mirror as claimed in claim 7, is characterized in that, in described step (d), drying time is greater than 1mins, and bake out temperature is greater than 100 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510137883.5A CN104714264A (en) | 2015-03-27 | 2015-03-27 | High reflection aluminum mirror and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510137883.5A CN104714264A (en) | 2015-03-27 | 2015-03-27 | High reflection aluminum mirror and preparation method thereof |
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| CN104714264A true CN104714264A (en) | 2015-06-17 |
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| CN201510137883.5A Pending CN104714264A (en) | 2015-03-27 | 2015-03-27 | High reflection aluminum mirror and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111204987A (en) * | 2018-11-21 | 2020-05-29 | 中国建筑材料科学研究总院有限公司 | Glass type thermal control coating and preparation method thereof |
| CN113814137A (en) * | 2021-09-10 | 2021-12-21 | 佛山市晶玻科技有限公司 | Paint spraying mode for curved surface mirror |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201892754U (en) * | 2010-12-10 | 2011-07-06 | 中国建筑材料科学研究总院 | Solar reflecting mirror |
| CN102419459A (en) * | 2011-11-25 | 2012-04-18 | 林嘉宏 | Solar reflecting glass silver mirror and manufacturing technology of the same |
| CN102809769A (en) * | 2012-08-12 | 2012-12-05 | 兰州大成科技股份有限公司 | Solar energy reflector and preparation method thereof |
| CN202829841U (en) * | 2012-07-12 | 2013-03-27 | 浙江大明玻璃有限公司 | Composite aluminum mirror |
| US20130215500A1 (en) * | 2010-10-27 | 2013-08-22 | Konica Minolta , Inc. | Film mirror for solar power generation purposes and reflection device for solar power generation purposes |
-
2015
- 2015-03-27 CN CN201510137883.5A patent/CN104714264A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130215500A1 (en) * | 2010-10-27 | 2013-08-22 | Konica Minolta , Inc. | Film mirror for solar power generation purposes and reflection device for solar power generation purposes |
| CN201892754U (en) * | 2010-12-10 | 2011-07-06 | 中国建筑材料科学研究总院 | Solar reflecting mirror |
| CN102419459A (en) * | 2011-11-25 | 2012-04-18 | 林嘉宏 | Solar reflecting glass silver mirror and manufacturing technology of the same |
| CN202829841U (en) * | 2012-07-12 | 2013-03-27 | 浙江大明玻璃有限公司 | Composite aluminum mirror |
| CN102809769A (en) * | 2012-08-12 | 2012-12-05 | 兰州大成科技股份有限公司 | Solar energy reflector and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111204987A (en) * | 2018-11-21 | 2020-05-29 | 中国建筑材料科学研究总院有限公司 | Glass type thermal control coating and preparation method thereof |
| CN111204987B (en) * | 2018-11-21 | 2022-12-20 | 中国建筑材料科学研究总院有限公司 | Glass type thermal control coating and preparation method thereof |
| CN113814137A (en) * | 2021-09-10 | 2021-12-21 | 佛山市晶玻科技有限公司 | Paint spraying mode for curved surface mirror |
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Application publication date: 20150617 |