CN104693936A - 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料 - Google Patents

一种新型陶瓷用耐碱丙烯酸树脂粉末涂料 Download PDF

Info

Publication number
CN104693936A
CN104693936A CN201510107321.6A CN201510107321A CN104693936A CN 104693936 A CN104693936 A CN 104693936A CN 201510107321 A CN201510107321 A CN 201510107321A CN 104693936 A CN104693936 A CN 104693936A
Authority
CN
China
Prior art keywords
parts
alkaline
powder coating
new ceramics
acrylic powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510107321.6A
Other languages
English (en)
Inventor
陆志强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huzhou Zhongchen Construction Co Ltd
Original Assignee
Huzhou Zhongchen Construction Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huzhou Zhongchen Construction Co Ltd filed Critical Huzhou Zhongchen Construction Co Ltd
Priority to CN201510107321.6A priority Critical patent/CN104693936A/zh
Publication of CN104693936A publication Critical patent/CN104693936A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03—Powdery paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

本发明公开了一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，原料为：丙烯酸丁酯、吡啶、丙烯酸-2-乙基己酯、尿素、丙烯酸乙酯、丁醇、流平剂、二甲苯、甲基丙烯酸羟乙酯、苯酐、增塑剂、硅油、异丙醇、钛白粉和甲基丙烯酸甲酯；涂膜光泽度100％-120％，邵氏硬度50-60H，水中浸泡30-40d后无起泡、脱落现象；拉伸强度20-30MPa，在5％盐酸溶液中浸泡25-35d无异常；附着力1-2级，冲击强度500-600N/cm，在饱和氢氧化钙中浸泡20-30d不起泡、皱皮；耐擦洗性1200-1500次。

Description

一种新型陶瓷用耐碱丙烯酸树脂粉末涂料
技术领域
本申请属于涂料领域，尤其涉及一种陶瓷用耐碱丙烯酸树脂粉末涂料。
背景技术
改革开放三十年来，中国陶瓷工业迅速发展，如今成为世界上名副其实的陶瓷生产大国、消费大国。中国生产的日用陶瓷产量占全世界的70％左右，陈设艺术陶瓷产量是全球的65％，建筑陶瓷产量也占世界总产量半壁江山。陶瓷产业在世界建材行业中占有举足轻重的地位。陶瓷涂料耐候性和加工性能优异，耐脏而且耐损伤。以往的陶瓷涂料虽然耐损伤，但是如果对涂装后的部件进行弯曲加工，容易产生裂纹，而且含氟树脂涂料和有机涂料，容易被沙石、灰尘等损坏。因此，陶瓷涂料的问世，受到了陶瓷行业的青睐，并正向其他行业渗透，前景看好。而随着人性化理念的普及，及新型和谐社会的构成，设计一种光泽度好、硬度高、耐擦洗和耐候性好的陶瓷用耐碱丙烯酸树脂粉末涂料是非常必要的。
发明内容
解决的技术问题：
本申请针对上述技术问题，提供一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，解决现有陶瓷用耐碱丙烯酸树脂粉末涂料光泽度低、硬度低、耐擦洗性和耐酸性差等技术问题。
技术方案：
一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，所述陶瓷用耐碱丙烯酸树脂粉末涂料的原料按重量份数配比如下：丙烯酸丁酯100份；吡啶10-20份；丙烯酸-2-乙基己酯2-8份；尿素15-35份；丙烯酸乙酯5-15份；丁醇30-50份；流平剂5-15份；二甲苯20-30份；甲基丙烯酸羟乙酯10-30份；苯酐40-60份；增塑剂1-10份；硅油0.1-0.5份；异丙醇50-70份；钛白粉30-40份；甲基丙烯酸甲酯35-55份。
作为本发明的一种优选技术方案：所述陶瓷用耐碱丙烯酸树脂粉末涂料的原料按重量份数配比如下：丙烯酸丁酯100份；吡啶15份；丙烯酸-2-乙基己酯5份；尿素25份；丙烯酸乙酯10份；丁醇40份；流平剂10份；二甲苯25份；甲基丙烯酸羟乙酯20份；苯酐50份；增塑剂5份；硅油0.3份；异丙醇60份；钛白粉35份；甲基丙烯酸甲酯45份。
作为本发明的一种优选技术方案：所述流平剂采用聚甲基苯基硅氧烷或三聚氰胺甲醛树脂。
作为本发明的一种优选技术方案：所述增塑剂采用DOP或DBP。
有益效果：
本发明所述一种新型陶瓷用耐碱丙烯酸树脂粉末涂料采用以上技术方案与现有技术相比，具有以下技术效果：1、产品光泽度100％-120％，邵氏硬度50-60H，水中浸泡30-40d后无起泡、脱落现象；2、拉伸强度20-30MPa，在5％盐酸溶液中浸泡25-35d无异常；3、附着力1-2级，冲击强度500-600N/cm，在饱和氢氧化钙中浸泡20-30d不起泡、皱皮；4、产品耐擦洗性1200-1500次，可以广泛生产并不断代替现有材料。
具体实施方式
实施例1:
一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其原料按重量份数配比如下：丙烯酸丁酯100份；吡啶10份；丙烯酸-2-乙基己酯2份；尿素15份；丙烯酸乙酯5份；丁醇30份；聚甲基苯基硅氧烷5份；二甲苯20份；甲基丙烯酸羟乙酯10份；苯酐40份；DBP1份；硅油0.1份；异丙醇50份；钛白粉30份；甲基丙烯酸甲酯35份。
将上述原料加入反应釜中，升温到80℃，保温反应4h，冷却后用粉碎机粉碎，用20mg筛过筛，制得涂料。
涂膜光泽度100％，邵氏硬度50H，水中浸泡30d后无起泡、脱落现象；拉伸强度20MPa，在5％盐酸溶液中浸泡25d无异常；附着力2级，冲击强度500N/cm，在饱和氢氧化钙中浸泡20d不起泡、皱皮；耐擦洗性1200次。
实施例2:
一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其原料按重量份数配比如下：丙烯酸丁酯100份；吡啶20份；丙烯酸-2-乙基己酯8份；尿素35份；丙烯酸乙酯15份；丁醇50份；聚甲基苯基硅氧烷15份；二甲苯30份；甲基丙烯酸羟乙酯30份；苯酐60份；DOP10份；硅油0.5份；异丙醇70份；钛白粉40份；甲基丙烯酸甲酯55份。
将上述原料加入反应釜中，升温到100℃，保温反应6h，冷却后用粉碎机粉碎，用100mg筛过筛，制得涂料。
涂膜光泽度110％，邵氏硬度55H，水中浸泡35d后无起泡、脱落现象；拉伸强度25MPa，在5％盐酸溶液中浸泡30d无异常；附着力2级，冲击强度550N/cm，在饱和氢氧化钙中浸泡25d不起泡、皱皮；耐擦洗性1350次。
实施例3:
一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其原料按重量份数配比如下：丙烯酸丁酯100份；吡啶15份；丙烯酸-2-乙基己酯5份；尿素25份；丙烯酸乙酯10份；丁醇40份；三聚氰胺甲醛树脂10份；二甲苯25份；甲基丙烯酸羟乙酯20份；苯酐50份；DOP5份；硅油0.3份；异丙醇60份；钛白粉35份；甲基丙烯酸甲酯45份。
将上述原料加入反应釜中，升温到90℃，保温反应5h，冷却后用粉碎机粉碎，用60mg筛过筛，制得涂料。
涂膜光泽度120％，邵氏硬度60H，水中浸泡40d后无起泡、脱落现象；拉伸强度30MPa，在5％盐酸溶液中浸泡35d无异常；附着力1级，冲击强度600N/cm，在饱和氢氧化钙中浸泡30d不起泡、皱皮；耐擦洗性1500次。
以上实施例中的组合物所有组分均可以商业购买。
上述实施例只是用于对本发明的内容进行阐述，而不是限制，因此在与本发明的权利要求书相当的含义和范围内的任何改变，都应该认为是包括在权利要求书的范围内。

Claims (4)

1.一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其特征在于所述陶瓷用耐碱丙烯酸树脂粉末涂料的原料按重量份数配比如下：丙烯酸丁酯100份；吡啶10-20份；丙烯酸-2-乙基己酯2-8份；尿素15-35份；丙烯酸乙酯5-15份；丁醇30-50份；流平剂5-15份；二甲苯20-30份；甲基丙烯酸羟乙酯10-30份；苯酐40-60份；增塑剂1-10份；硅油0.1-0.5份；异丙醇50-70份；钛白粉30-40份；甲基丙烯酸甲酯35-55份。
2.根据权利要求1所述的一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其特征在于所述陶瓷用耐碱丙烯酸树脂粉末涂料的原料按重量份数配比如下：丙烯酸丁酯100份；吡啶15份；丙烯酸-2-乙基己酯5份；尿素25份；丙烯酸乙酯10份；丁醇40份；流平剂10份；二甲苯25份；甲基丙烯酸羟乙酯20份；苯酐50份；增塑剂5份；硅油0.3份；异丙醇60份；钛白粉35份；甲基丙烯酸甲酯45份。
3.根据权利要求1所述的一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其特征在于：所述流平剂采用聚甲基苯基硅氧烷或三聚氰胺甲醛树脂。
4.根据权利要求1所述的一种新型陶瓷用耐碱丙烯酸树脂粉末涂料，其特征在于：所述增塑剂采用DOP或DBP。
CN201510107321.6A 2015-03-12 2015-03-12 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料 Pending CN104693936A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510107321.6A CN104693936A (zh) 2015-03-12 2015-03-12 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510107321.6A CN104693936A (zh) 2015-03-12 2015-03-12 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料

Publications (1)

Publication Number Publication Date
CN104693936A true CN104693936A (zh) 2015-06-10

Family

ID=53341503

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510107321.6A Pending CN104693936A (zh) 2015-03-12 2015-03-12 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料

Country Status (1)

Country Link
CN (1) CN104693936A (zh)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613698A (zh) * 2013-11-26 2014-03-05 王鹏飞 一种粉末涂料用热固性丙烯酸树脂及其合成方法和用途
CN104151894A (zh) * 2014-08-28 2014-11-19 苏州洛特兰新材料科技有限公司 一种陶瓷用紫外光固化聚丙烯酸酯涂料
CN104194441A (zh) * 2014-08-28 2014-12-10 苏州洛特兰新材料科技有限公司 一种陶瓷用丙烯酸酯涂料
CN104292903A (zh) * 2014-10-14 2015-01-21 苏州洛特兰新材料科技有限公司 一种陶瓷用丙烯酸环氧树脂粉末涂料

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103613698A (zh) * 2013-11-26 2014-03-05 王鹏飞 一种粉末涂料用热固性丙烯酸树脂及其合成方法和用途
CN104151894A (zh) * 2014-08-28 2014-11-19 苏州洛特兰新材料科技有限公司 一种陶瓷用紫外光固化聚丙烯酸酯涂料
CN104194441A (zh) * 2014-08-28 2014-12-10 苏州洛特兰新材料科技有限公司 一种陶瓷用丙烯酸酯涂料
CN104292903A (zh) * 2014-10-14 2015-01-21 苏州洛特兰新材料科技有限公司 一种陶瓷用丙烯酸环氧树脂粉末涂料

Similar Documents

Publication Publication Date Title
CN104292903A (zh) 一种陶瓷用丙烯酸环氧树脂粉末涂料
CN104194441B (zh) 一种陶瓷用丙烯酸酯涂料
CN104312235B (zh) 一种陶瓷用耐腐蚀丙烯酸环氧树脂粉末涂料
CN104371396A (zh) 一种建筑用耐擦洗内墙涂料
CN104152014B (zh) 一种陶瓷用聚酯粉末涂料
CN101613549A (zh) 金丝绸缎内墙漆
CN104312417A (zh) 一种陶瓷用丙烯酸羧基聚氨酯粉末涂料
CN104693936A (zh) 一种新型陶瓷用耐碱丙烯酸树脂粉末涂料
CN103897109A (zh) 一种丙烯酸改性聚硅氧烷树脂及其涂料
CN104312236A (zh) 一种陶瓷用丙烯酸树脂聚氨酯粉末涂料
CN104031448B (zh) 一种平光外墙涂料
CN104194594B (zh) 一种白色醇酸树脂外墙涂料
CN104312418A (zh) 一种陶瓷用丙烯酸聚氨酯粉末涂料
CN104031449B (zh) 一种水泥地面涂料
CN104312237B (zh) 一种陶瓷用含羧基丙烯酸酯树脂粉末涂料
CN104151895B (zh) 一种陶瓷用聚丙烯酸酯涂料
CN101440232A (zh) 多功能厚浆纳米多彩墙艺漆
CN104293063A (zh) 一种陶瓷用热固性丙烯酸树脂粉末涂料
CN104277614A (zh) 一种耐擦洗内墙涂料
CN104673040A (zh) 一种新型陶瓷用丙烯酸酯粉末涂料
CN104151899B (zh) 一种多彩花纹饰面涂料
CN104497740A (zh) 一种新型陶瓷用丙烯酸树脂粉末涂料
CN104371397A (zh) 一种新型内墙涂料
CN105062361A (zh) 一种快干防水建筑涂料及其制备方法
CN101613551A (zh) Zh强力建筑防水材料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150610

RJ01 Rejection of invention patent application after publication