CN104674242A - Heat exchanger detergent - Google Patents

Heat exchanger detergent Download PDF

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Publication number
CN104674242A
CN104674242A CN201310639210.0A CN201310639210A CN104674242A CN 104674242 A CN104674242 A CN 104674242A CN 201310639210 A CN201310639210 A CN 201310639210A CN 104674242 A CN104674242 A CN 104674242A
Authority
CN
China
Prior art keywords
parts
water
interchanger
clean
detergent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310639210.0A
Other languages
Chinese (zh)
Inventor
张欣
高晓东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Hao Tai Water Utilities Co Ltd
Original Assignee
Qingdao Hao Tai Water Utilities Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Hao Tai Water Utilities Co Ltd filed Critical Qingdao Hao Tai Water Utilities Co Ltd
Priority to CN201310639210.0A priority Critical patent/CN104674242A/en
Publication of CN104674242A publication Critical patent/CN104674242A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a heat exchanger detergent which is compounded from the following components in parts by mass: 0.01-0.02 part of tetrahydrofuran, 5-7 parts of sulfamic acid, 2-4 parts of maleic anhydride, 8-11 parts of citric acid, 0.05-0.1 part of thiocarbamide, 1-2 parts of EDTA (ethylene diamine tetraacetic acid) and the balance of water. The heat exchanger detergent can quickly eliminate and dissolve various water scales, rusty scales and other deposits in various heat exchangers, and can form a protective film on the metal surface to prevent the metal corrosion and water scales from quick formation. The heat exchanger detergent has excellent eliminating effects on cement films, dirty bacterium algae and etch pits on the surfaces of various devices and sanitary facilities.

Description

A kind of interchanger clean-out system
Technical field
The invention belongs to chemical field, specifically relate to a kind of interchanger clean-out system.
Background technology
By the impact of Traditional Thinking idea and the factor such as cleaning technique scarcity of resources and disappearance, the impact of most enterprises and individual heat exchanger fouling and remove technique and also rest on traditional " destructiveness " technique and the idea aspects such as machinery, high pressure water, chemical pickling; And think that equipment washing only just can be considered when having a strong impact on production simply, what it did not know incrustation scale is created on the energy consumption constantly affecting enterprise, engulfs the profit of enterprise.And the single expense in order to reduce cleaning, have selected purging method equipment being had to infringement and corrosion, the stagnation causing interchanger seepage even to scrap and produce, has paid than clean-out system high the hundred times even cost of thousands of times.
Current each state is all developing Environment protection cleaning technology with all strength, and in the hope of reducing energy consumption, choke suppress is to the excess destruction of environment.In developed country, each scientific research institution especially focuses on the research and development of green technology, and China is also progressively being drawn close to environment-friendly cleaning agent new technology at present.
Summary of the invention
The present invention relates to a kind of interchanger clean-out system, it can remove the incrustation scale, rust deposite and other settling that dissolve in various heat-exchange equipment fast, meanwhile, forms protective membrane, prevent the quick formation of metallic corrosion and incrustation scale in metallic surface; To the cement thin layer on various equipment and sanitary facility surface, dirt bacterium algae, plaque have splendid scavenging(action).
Interchanger clean-out system of the present invention is made up of following formula and the cooperation of quality component forms: tetrahydrofuran (THF) 0.01 ~ 0.02 part, thionamic acid 5 ~ 7 parts, maleic anhydride 2 ~ 4 parts, citric acid 8 ~ 11 parts, thiocarbamide 0.05 ~ 0.1 part, EDTA1 ~ 2 part, surplus is water.
A kind of manner of formulation of interchanger clean-out system is: the tetrahydrofuran (THF) of aforementioned proportion, thionamic acid, maleic anhydride, citric acid, thiocarbamide, EDTA are joined in a certain amount of water, stir and can obtain this interchanger clean-out system.
Embodiment
Embodiment 1:
To prepare interchanger clean-out system 100g:
Tetrahydrofuran (THF) 0.01g, thionamic acid 5.5g, maleic anhydride 2.5g, citric acid 9g, thiocarbamide 0.06g, EDTA1.2g, surplus is water.
A kind of manner of formulation of interchanger clean-out system is: the tetrahydrofuran (THF) of aforementioned proportion, thionamic acid, maleic anhydride, citric acid, thiocarbamide, EDTA are joined in a certain amount of water, stir and can obtain this interchanger clean-out system.
In above-described embodiment, apply rational quality proportioning, enable the product obtained remove the incrustation scale, rust deposite and other settling that dissolve in various heat-exchange equipment fast.
Embodiment 2:
To prepare interchanger clean-out system 100g:
Tetrahydrofuran (THF) 0.02g, thionamic acid 6.5g, maleic anhydride 3g, citric acid 10g, thiocarbamide 0.07g, EDTA1.5g, surplus is water.
The manner of formulation of interchanger clean-out system is identical with embodiment 1.
In above-described embodiment, have changed the mass fraction of each material, the present invention while scale removal, can form protective membrane in metallic surface, prevents the quick formation of metallic corrosion and incrustation scale.
Embodiment 3:
To prepare interchanger clean-out system 100g:
Tetrahydrofuran (THF) 0.015g, thionamic acid 7g, maleic anhydride 4g, citric acid 11g, thiocarbamide 0.1g, EDTA2g, surplus is water.
In above-described embodiment, by changing the mass fraction of each material, this product is to the cement thin layer on various equipment and sanitary facility surface, and dirt bacterium algae, plaque have splendid scavenging(action).
In sum, the present invention can remove the incrustation scale, rust deposite and other settling that dissolve in various heat-exchange equipment fast, meanwhile, forms protective membrane, prevent the quick formation of metallic corrosion and incrustation scale in metallic surface; To the cement thin layer on various equipment and sanitary facility surface, dirt bacterium algae, plaque have splendid scavenging(action).
Although done detailed description, protection domain has been not limited thereto.

Claims (5)

1. an interchanger clean-out system, is characterized in that, each component material and mass fraction thereof are: tetrahydrofuran (THF) 0.01 ~ 0.02 part, thionamic acid 5 ~ 7 parts, maleic anhydride 2 ~ 4 parts, citric acid 8 ~ 11 parts, thiocarbamide 0.05 ~ 0.1 part, EDTA1 ~ 2 part, and surplus is water.
2. interchanger clean-out system according to claim 1, it is characterized in that each component materials and mass fraction thereof are: tetrahydrofuran (THF) 0.01 part, thionamic acid 5.5 parts, maleic anhydride 2.5 parts, citric acid 9 parts, thiocarbamide 0.06 part, EDTA1.2 part, surplus is water.
3. interchanger clean-out system according to claim 1, it is characterized in that each component materials and mass fraction thereof are: tetrahydrofuran (THF) 0.02 part, thionamic acid 6.5 parts, maleic anhydride 3 parts, citric acid 10 parts, thiocarbamide 0.07 part, EDTA1.5 part, surplus is water.
4. interchanger clean-out system according to claim 1, it is characterized in that each component materials and mass fraction thereof are: tetrahydrofuran (THF) 0.015 part, thionamic acid 7 parts, maleic anhydride 4 parts, citric acid 11 parts, thiocarbamide 0.1 part, EDTA2 part, surplus is water.
5. interchanger clean-out system according to claim 1, it is characterized in that manner of formulation is: the tetrahydrofuran (THF) of aforementioned proportion, thionamic acid, maleic anhydride, citric acid, thiocarbamide, EDTA are joined in a certain amount of water, stir and can obtain this interchanger clean-out system.
CN201310639210.0A 2013-12-02 2013-12-02 Heat exchanger detergent Pending CN104674242A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310639210.0A CN104674242A (en) 2013-12-02 2013-12-02 Heat exchanger detergent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310639210.0A CN104674242A (en) 2013-12-02 2013-12-02 Heat exchanger detergent

Publications (1)

Publication Number Publication Date
CN104674242A true CN104674242A (en) 2015-06-03

Family

ID=53309807

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310639210.0A Pending CN104674242A (en) 2013-12-02 2013-12-02 Heat exchanger detergent

Country Status (1)

Country Link
CN (1) CN104674242A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2654070C1 (en) * 2017-06-26 2018-05-16 Федеральное государственное бюджетное образовательное учреждение высшего образования "Уфимский государственный нефтяной технический университет" Composition for cleaning heat-exchange equipment from lodgments
CN109797056A (en) * 2019-01-24 2019-05-24 白璐 Scale removal agent
CN113416959A (en) * 2021-06-30 2021-09-21 铁岭市龙首精细化工有限公司 Efficient quick oil-removing cleaning agent for heat exchanger

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2654070C1 (en) * 2017-06-26 2018-05-16 Федеральное государственное бюджетное образовательное учреждение высшего образования "Уфимский государственный нефтяной технический университет" Composition for cleaning heat-exchange equipment from lodgments
CN109797056A (en) * 2019-01-24 2019-05-24 白璐 Scale removal agent
CN113416959A (en) * 2021-06-30 2021-09-21 铁岭市龙首精细化工有限公司 Efficient quick oil-removing cleaning agent for heat exchanger

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PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20150603