CN104652156B - 木糖渣制备木质素磺酸盐联产微晶纤维素的方法 - Google Patents
木糖渣制备木质素磺酸盐联产微晶纤维素的方法 Download PDFInfo
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- CN104652156B CN104652156B CN201510122093.XA CN201510122093A CN104652156B CN 104652156 B CN104652156 B CN 104652156B CN 201510122093 A CN201510122093 A CN 201510122093A CN 104652156 B CN104652156 B CN 104652156B
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- sulfonation
- residue
- corn cob
- microcrystalline cellulose
- xylose
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 229920001732 Lignosulfonate Polymers 0.000 title claims abstract description 31
- 229920000168 Microcrystalline cellulose Polymers 0.000 title claims abstract description 20
- 235000019813 microcrystalline cellulose Nutrition 0.000 title claims abstract description 20
- 239000008108 microcrystalline cellulose Substances 0.000 title claims abstract description 20
- 229940016286 microcrystalline cellulose Drugs 0.000 title claims abstract description 20
- 240000008042 Zea mays Species 0.000 title abstract description 16
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 title abstract description 16
- 235000002017 Zea mays subsp mays Nutrition 0.000 title abstract description 16
- 235000005822 corn Nutrition 0.000 title abstract description 16
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 238000005406 washing Methods 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 12
- 238000004061 bleaching Methods 0.000 claims abstract description 11
- 239000012466 permeate Substances 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 9
- 238000012216 screening Methods 0.000 claims abstract description 3
- 238000006277 sulfonation reaction Methods 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 51
- 239000012528 membrane Substances 0.000 claims description 37
- 125000000969 xylosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)CO1)* 0.000 claims description 34
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 30
- 239000003814 drug Substances 0.000 claims description 20
- 230000018044 dehydration Effects 0.000 claims description 18
- 238000006297 dehydration reaction Methods 0.000 claims description 18
- 239000003513 alkali Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical group [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 10
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000012141 concentrate Substances 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 6
- 210000000988 bone and bone Anatomy 0.000 claims description 6
- 229910001882 dioxygen Inorganic materials 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 239000006199 nebulizer Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 238000010025 steaming Methods 0.000 claims description 6
- 235000010265 sodium sulphite Nutrition 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- OTBHDFWQZHPNPU-UHFFFAOYSA-N 1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CCCC2 OTBHDFWQZHPNPU-UHFFFAOYSA-N 0.000 claims description 3
- YBSDCDSHFUWLDQ-UHFFFAOYSA-N anthracene-9,10-diol;sodium Chemical compound [Na].[Na].C1=CC=C2C(O)=C(C=CC=C3)C3=C(O)C2=C1 YBSDCDSHFUWLDQ-UHFFFAOYSA-N 0.000 claims description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004056 anthraquinones Chemical class 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 claims description 3
- 235000010261 calcium sulphite Nutrition 0.000 claims description 3
- 238000010298 pulverizing process Methods 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 claims description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 claims description 2
- 235000019252 potassium sulphite Nutrition 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 abstract description 30
- 235000010980 cellulose Nutrition 0.000 abstract description 20
- 229920002678 cellulose Polymers 0.000 abstract description 20
- 239000001913 cellulose Substances 0.000 abstract description 20
- 239000000047 product Substances 0.000 abstract description 19
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 abstract description 15
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 abstract description 15
- 238000001914 filtration Methods 0.000 abstract description 10
- 229920005610 lignin Polymers 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 description 11
- 238000000926 separation method Methods 0.000 description 10
- 238000000746 purification Methods 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 150000004676 glycans Chemical class 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 6
- 230000011218 segmentation Effects 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229910017053 inorganic salt Inorganic materials 0.000 description 5
- 150000002500 ions Chemical group 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 150000003384 small molecules Chemical class 0.000 description 5
- 230000033228 biological regulation Effects 0.000 description 4
- 238000000402 conductometric titration Methods 0.000 description 4
- 238000000502 dialysis Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000009897 hydrogen peroxide bleaching Methods 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000001694 spray drying Methods 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000005903 acid hydrolysis reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- -1 wheat Chemical compound 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000014676 Phragmites communis Nutrition 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 244000186561 Swietenia macrophylla Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- VLOJXAQYHIVPFI-UHFFFAOYSA-H lead(2+);diacetate;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].CC([O-])=O.CC([O-])=O VLOJXAQYHIVPFI-UHFFFAOYSA-H 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/22—Other features of pulping processes
- D21C3/222—Use of compounds accelerating the pulping processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/18—De-watering; Elimination of cooking or pulp-treating liquors from the pulp
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
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CN201510122093.XA CN104652156B (zh) | 2015-03-20 | 2015-03-20 | 木糖渣制备木质素磺酸盐联产微晶纤维素的方法 |
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CN201510122093.XA CN104652156B (zh) | 2015-03-20 | 2015-03-20 | 木糖渣制备木质素磺酸盐联产微晶纤维素的方法 |
Publications (2)
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CN104652156A CN104652156A (zh) | 2015-05-27 |
CN104652156B true CN104652156B (zh) | 2017-01-18 |
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CN201510122093.XA Active CN104652156B (zh) | 2015-03-20 | 2015-03-20 | 木糖渣制备木质素磺酸盐联产微晶纤维素的方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109457524B (zh) * | 2018-12-29 | 2023-10-20 | 珠海市东辰制药有限公司 | 纳米微晶纤维素的纯化方法及纯化设备 |
CN111747779A (zh) * | 2019-03-29 | 2020-10-09 | 崔强 | 一种黄腐酸的制备方法及其应用 |
CN111019154A (zh) * | 2019-12-30 | 2020-04-17 | 上海昶法新材料有限公司 | 一种从化机浆处理废液中提取木质素和微晶纤维素的方法 |
CN111499768B (zh) * | 2020-03-02 | 2022-03-01 | 中科如米(北京)生态农业科技发展有限公司 | 一种两性离子化的木糖渣纤维素纳米晶的制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381754A (zh) * | 2008-10-21 | 2009-03-11 | 华南理工大学 | 一种纤维素组分磺化分离藕合酶水解生产可发酵糖的方法 |
CN102558571A (zh) * | 2011-04-02 | 2012-07-11 | 济南圣泉集团股份有限公司 | 一种利用木糖渣制备碱木质素的方法 |
CN102995477A (zh) * | 2012-12-17 | 2013-03-27 | 山东福田药业有限公司 | 一种以木糖渣为原料制备微晶纤维素的方法 |
CN103254318A (zh) * | 2013-06-04 | 2013-08-21 | 常州和方环保科技有限公司 | 一种秸秆制备纤维素钠的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG174746A1 (en) * | 2006-10-26 | 2011-10-28 | Xyleco Inc | Processing biomass |
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2015
- 2015-03-20 CN CN201510122093.XA patent/CN104652156B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381754A (zh) * | 2008-10-21 | 2009-03-11 | 华南理工大学 | 一种纤维素组分磺化分离藕合酶水解生产可发酵糖的方法 |
CN102558571A (zh) * | 2011-04-02 | 2012-07-11 | 济南圣泉集团股份有限公司 | 一种利用木糖渣制备碱木质素的方法 |
CN102995477A (zh) * | 2012-12-17 | 2013-03-27 | 山东福田药业有限公司 | 一种以木糖渣为原料制备微晶纤维素的方法 |
CN103254318A (zh) * | 2013-06-04 | 2013-08-21 | 常州和方环保科技有限公司 | 一种秸秆制备纤维素钠的方法 |
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