CN104638277B - 一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 - Google Patents
一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 Download PDFInfo
- Publication number
- CN104638277B CN104638277B CN201510051217.XA CN201510051217A CN104638277B CN 104638277 B CN104638277 B CN 104638277B CN 201510051217 A CN201510051217 A CN 201510051217A CN 104638277 B CN104638277 B CN 104638277B
- Authority
- CN
- China
- Prior art keywords
- layer
- electrochemical reaction
- carbon
- slurry
- battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 48
- 239000000446 fuel Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000007787 solid Substances 0.000 title claims abstract description 21
- 230000006870 function Effects 0.000 claims abstract description 64
- 238000002407 reforming Methods 0.000 claims abstract description 61
- 238000003487 electrochemical reaction Methods 0.000 claims abstract description 60
- 230000007704 transition Effects 0.000 claims abstract description 41
- 239000002131 composite material Substances 0.000 claims abstract description 14
- 238000001994 activation Methods 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims description 119
- 239000003054 catalyst Substances 0.000 claims description 55
- 238000000034 method Methods 0.000 claims description 50
- 239000002002 slurry Substances 0.000 claims description 50
- 239000011230 binding agent Substances 0.000 claims description 40
- 235000015895 biscuits Nutrition 0.000 claims description 33
- 239000003792 electrolyte Substances 0.000 claims description 32
- 239000011148 porous material Substances 0.000 claims description 32
- 238000002156 mixing Methods 0.000 claims description 25
- 238000000498 ball milling Methods 0.000 claims description 21
- 238000007650 screen-printing Methods 0.000 claims description 17
- 238000005245 sintering Methods 0.000 claims description 17
- 239000000919 ceramic Substances 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 239000001856 Ethyl cellulose Substances 0.000 claims description 12
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical group CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 12
- 229920001249 ethyl cellulose Polymers 0.000 claims description 12
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 12
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 11
- 238000004513 sizing Methods 0.000 claims description 11
- 230000004913 activation Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000011195 cermet Substances 0.000 claims description 9
- 229920002472 Starch Polymers 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000008107 starch Substances 0.000 claims description 8
- 235000019698 starch Nutrition 0.000 claims description 8
- 230000003197 catalytic effect Effects 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 7
- 238000007493 shaping process Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000006229 carbon black Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 238000005470 impregnation Methods 0.000 claims description 6
- 239000011297 pine tar Substances 0.000 claims description 6
- 229940068124 pine tar Drugs 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 241000894007 species Species 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 3
- 229910002340 LaNiO3 Inorganic materials 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 127
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 9
- 150000004706 metal oxides Chemical class 0.000 abstract description 9
- 238000006555 catalytic reaction Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 238000009825 accumulation Methods 0.000 abstract description 5
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract description 2
- 239000002346 layers by function Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 239000003245 coal Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003034 coal gas Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000010339 dilation Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 208000000058 Anaplasia Diseases 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- -1 Ni YSZ Substances 0.000 description 1
- YMVZSICZWDQCMV-UHFFFAOYSA-N [O-2].[Mn+2].[Sr+2].[La+3] Chemical compound [O-2].[Mn+2].[Sr+2].[La+3] YMVZSICZWDQCMV-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8636—Inert electrodes with catalytic activity, e.g. for fuel cells with a gradient in another property than porosity
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
- H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8825—Methods for deposition of the catalytic active composition
- H01M4/8828—Coating with slurry or ink
- H01M4/8835—Screen printing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/88—Processes of manufacture
- H01M4/8878—Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
- H01M4/8882—Heat treatment, e.g. drying, baking
- H01M4/8885—Sintering or firing
- H01M4/8889—Cosintering or cofiring of a catalytic active layer with another type of layer
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M2004/8678—Inert electrodes with catalytic activity, e.g. for fuel cells characterised by the polarity
- H01M2004/8689—Positive electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Composite Materials (AREA)
- Inert Electrodes (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510051217.XA CN104638277B (zh) | 2015-01-30 | 2015-01-30 | 一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510051217.XA CN104638277B (zh) | 2015-01-30 | 2015-01-30 | 一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104638277A CN104638277A (zh) | 2015-05-20 |
CN104638277B true CN104638277B (zh) | 2017-03-22 |
Family
ID=53216771
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510051217.XA Active CN104638277B (zh) | 2015-01-30 | 2015-01-30 | 一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104638277B (zh) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105161743B (zh) * | 2015-10-14 | 2018-01-30 | 中国科学院宁波材料技术与工程研究所 | 一种高温固态燃料电池的阳极以及电池堆单元 |
CN109904497B (zh) * | 2019-01-09 | 2020-07-10 | 华中科技大学 | 一种抗积碳金属支撑固体氧化物燃料电池及其制备方法 |
CN112751041B (zh) * | 2021-01-17 | 2021-12-03 | 大连理工大学 | 一种制备NiO/磷灰石型硅酸镧亚微-纳米多孔阳极功能层的方法 |
CN113346118B (zh) * | 2021-08-05 | 2021-11-05 | 北京思伟特新能源科技有限公司 | 一种采用共流延法制备金属支撑单体的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1960048A (zh) * | 2006-11-23 | 2007-05-09 | 上海交通大学 | 多孔金属支撑的低温固体氧化物燃料电池的结构 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2948373B2 (ja) * | 1991-09-06 | 1999-09-13 | 三菱重工業株式会社 | 固体電解質型燃料電池の燃料電極 |
-
2015
- 2015-01-30 CN CN201510051217.XA patent/CN104638277B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1960048A (zh) * | 2006-11-23 | 2007-05-09 | 上海交通大学 | 多孔金属支撑的低温固体氧化物燃料电池的结构 |
Non-Patent Citations (1)
Title |
---|
Nanocast LaNiO3 Perovskites as Precursors for the Preparation of Coke-Resistant Dry Reforming Catalysts;Mahesh Muraleedharan Nair等;《ACS Catalysis》;20141111;第4卷;第3837-3846页 * |
Also Published As
Publication number | Publication date |
---|---|
CN104638277A (zh) | 2015-05-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Jiang et al. | Challenges in developing direct carbon fuel cells | |
Yu et al. | Recent progress in direct carbon solid oxide fuel cell: Advanced anode catalysts, diversified carbon fuels, and heat management | |
Zhu et al. | A symmetrical solid oxide fuel cell prepared by dry-pressing and impregnating methods | |
Cai et al. | A high performance direct carbon solid oxide fuel cell fueled by Ca-loaded activated carbon | |
CN102290589B (zh) | 一种阴极支撑型直接碳燃料电池 | |
Li et al. | High-performance and stable La0. 8Sr0. 2Fe0. 9Nb0. 1O3-δanode for direct carbon solid oxide fuel cells fueled by activated carbon and corn straw derived carbon | |
Heidari et al. | Optimization of BSCF-SDC composite air electrode for intermediate temperature solid oxide electrolyzer cell | |
Chen et al. | Sm0. 2 (Ce1− xTix) 0.8 O1. 9 modified Ni–yttria-stabilized zirconia anode for direct methane fuel cell | |
CN104078687A (zh) | 含有碱金属或碱土金属元素的固体氧化物燃料电池的阳极材料及其制备方法和用途 | |
CN103811772A (zh) | 含有钙钛矿型结构氧化物的复合材料及其制备方法和用途 | |
Xing et al. | Preparation and characterization of La0. 75Sr0. 25Cr0. 5Mn0. 5O3− δ-yttria stabilized zirconia cathode supported solid oxide electrolysis cells for hydrogen generation | |
CN111244470B (zh) | 一种纳米复合阴极及其制备和应用 | |
CN104103838A (zh) | 固体氧化物燃料电池的阳极保护层及其制备方法和应用 | |
CN104638277B (zh) | 一种碳基固体氧化物燃料电池用梯度功能阳极及制备方法 | |
Wejrzanowski et al. | Multi-modal porous microstructure for high temperature fuel cell application | |
KR20130047534A (ko) | Ni-YSZ 연료(수소)전극을 포함하는 고체산화물 연료전지와 전해셀 및 이의 제조방법 | |
JP2011204416A (ja) | 固体酸化物形燃料電池用燃料極材料、それを用いた燃料極、並びに固体酸化物形燃料電池用セル。 | |
Ahsan et al. | The effect of calcination temperature on the properties of Ni-SDC cermet anode | |
Sun et al. | Evaluation of Sr0. 88Y0. 08TiO3–CeO2 as composite anode for solid oxide fuel cells running on CH4 fuel | |
Wu et al. | Preparation and electrochemical performance of silver impregnated Ni-YSZ anode for solid oxide fuel cell in dry methane | |
Li et al. | CO2 high-temperature electrolysis technology toward carbon neutralization in the chemical industry | |
Li et al. | Enhancing triple-phase boundary at fuel electrode of direct carbon fuel cell using a fuel-filled ceria-coated porous anode | |
CN113506905A (zh) | 一种质子传导型半电池、质子传导型固体氧化物电池及其制备方法和应用 | |
Liu et al. | Study of high active and redox-stable La0. 9Ca0. 1Fe0. 9Nb0. 1O3-δ/Sm0. 1Ce0. 9O2− δ composite ceramic electrode for solid oxide reversible cells | |
Han et al. | A novel Boudouard reaction catalyst derived from strontium slag for enhanced performance of direct carbon solid oxide fuel cells |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240611 Address after: 710061 3rd Floor, No. 88 Aerospace East Road, National Civil Aerospace Industry Base, Xi'an City, Shaanxi Province Patentee after: Shaanxi Qingke Energy Technology Co.,Ltd. Country or region after: China Address before: 710077 Shaanxi Coal Industry Chemical Group Co., Ltd. No. 2 Jinye Road, Xi'an High-tech Zone, Shaanxi Province Patentee before: SHAANXI COAL AND CHEMICAL TECHNOLOGY INSTITUTE Co.,Ltd. Country or region before: China |