CN104607022A - H-shaped flue gas dust removal desulfurization reactor and flue gas desulfurization method - Google Patents
H-shaped flue gas dust removal desulfurization reactor and flue gas desulfurization method Download PDFInfo
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Abstract
The present invention discloses an H-shaped flue gas dust removal desulfurization reactor and a flue gas desulfurization method. The reactor of the present invention comprises a pre-treatment unit and a deep treatment unit, wherein the two units form an H-shaped double-tower structure, the pre-treatment unit sequentially comprises a flue gas inlet, a turbulent scrubber, a common jujube seed-shaped regular packing assembly, and a first-stage liquid holding tank from top to bottom, the deep treatment unit comprises a second-stage liquid holding tank, a packing assembly, a demister assembly and a purified flue gas outlet from bottom to top, and the pre-treatment unit and the deep treatment unit are communicated through the flue gas channel on the middle portion. The reactor of the present invention can achieve functions of one spraying and two-stage absorption/purification, has advantages of high contaminant removal rate, low energy consumption and the like, and is especially suitable for the dust removal desulfurization process of high dust content flue gas.
Description
Technical field
The invention discloses a kind of H type flue-gas dust-removing and desulfurization reactor and fume desulphurization method, belong to field of environment protection, be applicable to flue gas and the process of process tail gas dust-removal and desulfurizing, the field such as petrochemical industry and environmental protection can be widely used in.
Background technology
In the atmosphere pollution of China, acid rain and floating dust are topmost pollutions.During the last ten years, because the discharge capacity of sulfur dioxide and nitrogen oxide day by day increases, the problem of acid rain is more and more outstanding.Present China has been the third-largest Acid Rain Zone being only second to Europe and North America.SO
2the major reason causing China's atmosphere pollution with dust, the atmosphere pollution of the current priority control of Ye Shi China.China SO
2total emission volumn is for years more than 2,000 ten thousand tons, within 2005, total emission volumn reaches 2,549 ten thousand tons, occupy first place in the world, although the target that China the Eleventh Five-Year Plan period cuts down sulfur dioxide 10% realizes, the current Acid Rain Pollution area (accounting for 30% of area) of China is still in continuous expansion.Annual because of acid rain and SO
2polluting causes the economic loss of the aspects such as crops, forest and health more than 1,000 hundred million yuan, and sulfur dioxide (SO2) emissions control still to can not be ignored.Dust refers to the particle of particle diameter 1 ~ 75 micron.Generally produced by broken in industrial production, runs.According to analysis, China is entered the dust of air every year by industry and life cellar for storing things fire grate, more than 1,000 ten thousand tons.Dust is easily inhaled into human respiratory tract's system, directly threatens the life of people, and the environment being especially in dust pollution can cause multiple cardiovascular, breathing problem etc.
The kind that desulfurizing agent is pressed in flue gas desulfurization divides, and can be divided into following Lung biopsy: with CaCO
3calcium method based on (lime stone), the magnesium processes based on MgO, with Na
2sO
3based on sodium method, with NH
3based on ammonia process, the organic alkaline process based on organic base.At present, the desulfurization dust-removing technique of generally acknowledging comprises water film type, fountain, impact type and water-bath type etc.Venturi and rapid punching are as strengthening gas-liquid mass transfer (contact) equipment, be widely used in flue-gas dust-removing and desulfurization device, wherein venturi height is about 16m ~ 19m, and when exhaust gas volumn is larger, whole desulfurizer is that form encircled by multiple venturi and desulfurizing tower, take up room and invest all larger, as the flue gas desulfurization technique of Norton.Rapid punching needs liquid phase to raise 6 ~ 8m, to produce froth zone, and by the continuous renewal of foam, keep efficient gas-liquid mass transfer effect, but therefore the height of reactor and infrastructure investment also increases greatly.
Patent US3894563A and patent US2012000366A1 all adopts venturi and cyclone separator to combine and realizes dedusting and gas-liquid separation.In the desulfurizer that patent CN200920247553.1, CN200920200026.5 and CN03142049.4 introduce or technique, rapids rushes scrubbing tower and is independent setting, and floor space is large, and investment cost is high.
Patent US4110088 describes the cooling of a kind of high-temperature flue gas chilling, dedusting and removes technique and the device of water soluble contaminants.The high-temperature flue gas of 927 ~ 1038 DEG C is after two-stage spraying cooling, enter cyclone separator and isolate drop and dust, carry out removing pollutant in waste gas through packed tower again, after Purge gas enters the deflection plate demister demist of band fin plate, finally spray through venturi and enter aiutage, Purge gas, when venturi sprays at a high speed, produces negative pressure, suction venturi surrounding air, makes Purge gas humidity reduce.This technological process is long, and pressure drop is very large, and be provided with twice blower fan in technique, with thinking that flue gas provides power, energy consumption is larger.
CN101301574A discloses a kind of multi-stage flue gas desulfurization spray column, comprises elementary desulfurizing scrubber and secondary desulfuration spray tower, and the outlet of described elementary desulfurizing scrubber is connected with the entrance of secondary desulfuration spray tower.This multi-stage flue gas desulfurization tower also comprises return duct, this tube connector is connected between the bottom of elementary desulfurizing scrubber and secondary desulfuration spray tower, thus, absorbing liquid is back to secondary desulfuration spray tower through this return duct, is equivalent to two-step desulfurization units shared circulatory pool.The technique effect that this technology realizes is once desulfurization in elementary desulfurizing scrubber, secondary desulfuration in secondary desulfuration spray tower, this technology two-step desulfurization units shared circulatory pool, do not form the grating region of absorbing liquid, desulfurization degree is not high, and this absorption of technology agent adopts lime stone slurry, and the return duct between two-step desulfurization unit is only by gravity reflux, therefore reflux pipeline is easy to blocking, this Chief Technology Officer period run reliability is not enough.
CN2608111Y discloses a kind of high-concentration fume desulfurating dust-removing equipment, this technology is cascaded the above desulfurization unit of 2 cover, with a shell, the desulfurization unit of series connection is covered on together, bottom shares a circulating slot, this technology circulatory pool does not process for the feature of high-concentration fume, and be only cascaded by the above desulfurization unit of two covers, desulfuration efficiency can ensure, but take up an area comparatively large, be not suitable for reserving less region in place and use.
In prior art, though the cooling/dedusting of high-temperature flue gas/desulfurization adopts two-stage or multi-stage gas-liquid contact absorption technique, reach pollutant removing effect, every one-level spray-absorption is provided with corresponding equipment for liquid transportation and absorbing liquid atomization plant, and energy consumption is higher.
Summary of the invention
For the deficiency of existing Venturi scrubber and turbulent impulse scrubber fume treatment technology, the invention provides a kind of H type flue-gas dust-removing and desulfurization reactor and fume desulphurization method, utilize the high potential energy of turbulent impulse scrubber absorbing liquid and date core shaped structured packing to carry out pretreatment to flue gas, wherein turbulent impulse scrubber is positioned at the top of date core shaped structured packing simultaneously.Turbulent impulse scrubber absorbing liquid is in decline process, because of the wind-force dissection by pretreatment unit flue gas, be dispersed into tiny drop/droplet, when gas-liquid two-phase is simultaneously through date core shaped structured packing, strengthening effect of mass transmitting is there is at this between gas-liquid two-phase, thus achieve and once spray, twice strengthening mass transfer absorbs, and equipment for liquid transportation effect is fully used to the energy of turbulent impulse scrubber absorbing liquid.
The invention provides a kind of H type flue-gas dust-removing and desulfurization reactor, it is characterized in that, described reactor comprises pretreatment unit and advanced treatment unit, and the two forms " H " shape or " U " shape Double-Tower Structure; Wherein said pretreatment unit comprises smoke inlet, turbulent impulse scrubber, date core shaped structured packing assembly and one-level from top to bottom and holds liquid bath, and described advanced treatment unit comprises secondary from bottom to top and holds the outlet of liquid bath, filler assembly, demister group and purifying smoke; Described pretreatment unit is communicated with the exhaust gases passes of advanced treatment unit by middle part.
According to H type flue-gas dust-removing and desulfurization reactor of the present invention, wherein said pretreatment unit also comprises primary cycle pump and primary cycle pipeline; Equally, described advanced treatment unit also comprises secondary cycle pump, secondary cycle pipeline and secondary spray system.Described secondary spray system is positioned at above or below filler.
According to H type flue-gas dust-removing and desulfurization reactor of the present invention, wherein in described pretreatment unit, on the top of wall of reactor, the connecting portion of preferred reactor wall and smoke inlet reducing arranges moisture film assembly.Described moisture film assembly can adopt the structure of any suitable form in this area, and as arranged endless tube in wall of reactor surrounding, on endless tube, installation surface is to the nozzle of tower wall.And in the present invention, preferably overflow-type moisture film assembly is set at the connecting portion of wall of reactor and smoke inlet reducing.The structure of described overflow-type moisture film assembly is: the lower end of smoke inlet reducing connects one section of straight tube, the diameter of this direct tube section is greater than the reactor diameter of pretreatment unit, the uncovered cannelure in a bottom lock, upper end is formed, preferably at the uncovered employing tooth-shape structure of cannelure at the connecting portion of wall of reactor and reducing.This cannelure is held liquid bath with one-level and is connected by pipeline.When liquid constantly injects annular space, liquid constantly can flow down along the inwall of cylindrical shell with the upper edge of overflow type along cylindrical shell, from top to bottom, thus covers whole wall of reactor.Owing to doing/wet interface at reactor inlet; heat smoke first time touches shower water; the acid mist of high concentration can be produced; so very serious at the corrosion condition at dry/wet interface, by adopting the form of moisture film protection, the corrosion condition at dry/wet interface can be reduced; and the fouling be attached on reactor wall is rinsed at any time; avoid underdeposit corrosion, improve the antiseptic power of material or reduce the consumption of high anticorrosion material, thus significantly reducing cost.
According to H type flue-gas dust-removing and desulfurization reactor of the present invention, wherein, described turbulent impulse scrubber is made up of nozzle and pipeline.
According to H type flue-gas dust-removing and desulfurization reactor of the present invention, described date core shaped structured packing assembly, comprise date core shaped structured packing, it comprise at least one deck, preferred two-layer above by some parallel connections, packing layer that the date core shaped special pipe of horizontal positioned is formed, described some parallel connections, the date core shaped special pipe of horizontal positioned constitute multiple parallel channels with collection section, aditus laryngis and dispersion section.Date core shaped structured packing can be made into one or is divided into some pieces of block combiner to use.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, the cross section (i.e. end face) of described date core shaped special pipe is date core shaped, and its top and bottom are acute triangle, and middle part is circular arc, forms the date core shaped of " middle circle pointed at both ends ".The middle part of date core shaped special pipe is arc surface, by the dust that is conducive to containing in gas under hygrometric state, under the brushing of self gravitation and gas phase, by the downward landing of this slip flow regime, thus avoids channel blockage phenomenon occurs.
Two end faces of described date core shaped special pipe can be closed or not close.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, preferably on the both sides tube wall of date core shaped special pipe bottom, offer groove, described groove preferably can have certain inclination angle.The cross section of described groove can be the shape that triangle, rectangle or circular arc etc. are suitable, preferred triangle.The groove that special pipe both sides tube wall is offered, can be symmetrical, and the lower end of symmetrical groove can be communicated with, and also can not be communicated with.And the upper end starting point of groove is preferably lower than the phase tangent line of downside tube wall and the circular arc tube wall on both sides.
The groove that both sides, date core shaped special pipe bottom tube wall is offered, is conducive to after wall flow liquid drip goes out aditus laryngis, blows lower drop and is blown and enter groove, and realize coalescence in groove, thus can eliminate entrainment, be convenient to realize gas-liquid separation in gas phase.
Along can also zigzag be arranged under date core shaped special pipe, will be conducive to after wall flow liquid drip goes out special pipe, forming equally distributed Continuous Flow.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, described date core shaped special pipe structured packing is defined the passage with collection section, aditus laryngis and dispersion section by some special pipes of parallel connection.Flow to into this packing area when the flue gas after turbulent impulse scrubber spray-absorption and absorbing liquid, first collection section (aisle spare contraction) is entered, gas velocity increases, realize solution dispersion, liquid phase specific surface area increases, and the grit attachment be captured not yet is moistening, the atomic drop of dispersion is under the contention effect of high-speed gas, due to the ductility of water, will be attached on tube wall and form liquid film, achieve coalescence and the samming process of drop.When liquid film is by aditus laryngis, due to the further increase of gas velocity, create strong compressing and dissection again to liquid film, liquid film is thinning further, creates twice dispersing effect; After aditus laryngis, gas velocity declines rapidly, in the process, the a large amount of dust contained in gas are due to the change of gas velocity, realize mud and drip coalescence, dust along interface landing, thus will realize dedusting function, and liquid film on the tube wall of two side lower parts of date core shaped special pipe toward current downflow time, clamp-oned in groove by gas again, achieve coalescence again, and the continuous wire of final one-tenth is dripped by the bottom of date core shaped special pipe, thus eliminate entrainment, complete mass transfer reaction.
Owing to employing date core shaped structured packing, H type flue-gas dust-removing and desulfurization reactor of the present invention is specially adapted to operating mode larger containing Dust Capacity in flue gas.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, random packing or the structured packing assemblies such as rectangular saddle ring, Pall ring, Raschig ring are generally selected in the packing area of advanced treatment unit.What the present invention preferably adopted is date core shaped structured packing, and the structure of the date core shaped structured packing assembly that its structure is used with pretreatment unit is identical, and it is not both this filler assembly and preferably only adopts the structured packing of one deck date core shaped.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, described secondary spray system is positioned at above or below filler assembly, flue gas and spray liquid adverse current or and flow contact mass transfer.Spray liquid, under flue gas upwards blows, will produce the froth bed of the turbulence of certain altitude above filler assembly, and at this moment not only contact surface is large for gas-liquid two-phase, and contact surface alkali lye is constantly upgraded, the fierce collisional mixing of gas-liquid two-phase, reaches efficient mass transfer reaction, realizes mass transport process.And liquid phase falls into secondary in the effect of self gravitation holds in liquid bath.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, described demister can adopt conventional demister, as adopted broken line type or streamlined demister.In the present invention, the preferred deflector type demister of described demister, it comprises several demist assemblies arranged side by side, and each demist assembly includes riser and urceolus, and urceolus is arranged on the outside of riser, and with riser on the same axis; Riser is fixed on tower tray, and the top of riser arranges capping plate, has some seams at the circumference of riser, is circumferentially provided with the tangential flow guiding wing at the riser near each bar seam.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, the urceolus of wherein said demister is made up of direct tube section and conical cylinder section.The inner surface (inwall) of urceolus can also arrange projection, and the projection described in the present invention preferably adopts cross section to be the clapper structure of rectangle.Wherein, the direction of rotation of hyoplastron should be contrary with the direction of rotation of the tangential flow guiding wing.In deflector type demister of the present invention, the lower ending opening of described urceolus can also be arranged to zigzag structure, thus advantageously becomes Continuous Flow to drip in isolated liquid from the inwall of urceolus.
In H type flue-gas dust-removing and desulfurization reactor of the present invention, described deflector type demister realizes efficiently being separated of drop and gas by the repeatedly baffling of fluid in flow process.
The present invention can also hold in liquid bath in the one-level of pretreatment unit and place floating basket, places oxidation catalyst such as iron ore in floating basket.Holding absorbing liquid in liquid bath due to one-level is faintly acid, and iron ore can be converted into the manganese ion or iron ion with catalysis by dissolving.Containing manganese ion or iron ion first order absorption liquid by primary cycle transport pump to turbulent impulse scrubber, its spray liquid contacts with flue gas adverse current, in flue gas oxygen is transferred in liquid phase.SO in first order absorption liquid and flue gas
2reaction generates sulphite or bisulfites, afterwards under dissolved oxygen and the manganese ion with catalysis or iron ion action, is oxidizedly converted into sulfate, thus reduces the COD in waste water, make discharged wastewater met the national standard.
Another technical problem to be solved by this invention is to provide a kind of process for dusting and dsulfurizing fume, the method uses H type flue-gas dust-removing and desulfurization reactor recited above.
A kind of process for dusting and dsulfurizing fume of the present invention, specifically comprises following content:
(1) high-temperature flue gas is after over-quenching cooling, enter pretreatment unit, the pH value sprayed with turbulent impulse scrubber is neutral or acid first order absorption liquid counter current contacting, rapids rushes absorbing liquid in decline process, be subject to the wind-force dissection of gas in tower and be dispersed into tiny drop/droplet, carrying out in this process lowering the temperature, dedusting and pre-desulfurization;
(2) flue gas after step (1) first order absorption and absorbing liquid continue and flow to current downflow, enter date core shaped structured packing assembly, and complete the cooling absorbing flue gas, dedusting and pre-desulfurization further at this;
(3) the first order absorption liquid absorbing sulfur dioxide enters one-level and holds liquid bath, and is recycled by primary cycle pump and primary cycle pipeline;
(4) flue gas after pretreatment unit absorption is under the promotion of upper pressure, by the passage penetration depth processing unit between pretreatment unit and advanced treatment unit, and upwards pass through filler assembly, and with filler assembly below or the secondary absorbing liquid of the spray system pH value of spraying in top in alkalescence in the abundant contact mass transfer of filler assembly, complete final sweetening process;
(5) pass through demist assembly by flue gas after the purification of filler assembly, after gas-liquid separation, discharge from dust-removal and desulfurizing reactor exhanst gas outlet.
In process for dusting and dsulfurizing fume of the present invention, arrange respectively at pretreatment unit and advanced treatment unit and hold liquid bath, define independently Two-way Cycle flue-gas dust-removing and desulfurization system.Hold in the middle of liquid bath for two and arrange passage, one-level holds liquid bath for pretreatment unit provides absorbing liquid, and secondary holds liquid bath for advanced treatment unit provides absorbing liquid.This technique proposes desulfurization absorbing liquid concentration grating theory, and first original absorbance liquid enter secondary and hold liquid bath, then enters one-level by center-aisle and hold liquid bath, and it is final absorbing liquid discharge pond that one-level holds liquid bath.For guaranteeing the utilization rate of absorbing liquid, the pH value of holding liquid bath by controlling one-level controls to enter the alkali lye amount that secondary holds liquid bath, because this technological process can guarantee that secondary holds the pH value of liquid bath for alkalescence, thus greatly can improve desulfurization degree.Holding the pH value of liquid bath by controlling I and II, both ensure that the high efficiency of this fume desulphurization method, the utilization rate that desulfurization absorbing liquid is higher can be guaranteed again.
In process for dusting and dsulfurizing fume of the present invention, flue gas can be the sulfur-bearing dust-laden high-temperature flue gas coming from various device, the wherein SO of flue gas
2concentration is 500 ~ 5000mg/Nm
3, preferably 1000 ~ 4000mg/Nm
3; Dust concentration 200 ~ 800mg/Nm
3, preferably 300 ~ 500mg/Nm
3.
In process for dusting and dsulfurizing fume of the present invention, the operating condition of reactor is: operating temperature is 100 ~ 350 DEG C, preferably 150 ~ 200 DEG C; Operating pressure is that normal pressure is to 1MPa; Treatment quantity is 500 ~ 200000m
3/ h, preferably 700 ~ 190000m
3/ h; Absorbing liquid internal circulating load is 0.4m
3/ h ~ 7m
3/ h, preferred 0.5m
3/ h ~ 6m
3/ h.
In process for dusting and dsulfurizing fume of the present invention, described absorbing liquid can be NaOH solution, Na
2cO
3solution, Mg (OH)
2solution or limewash Ca (OH)
2, the preferred NaOH solution of absorbing liquid that this technique adopts, wherein one-level holds the pH value of the first order absorption liquid in liquid bath between 6 ~ 7, and described secondary holds secondary absorbing liquid pH value in liquid bath between 8 ~ 10.
The present invention can also hold in liquid bath in the one-level of pretreatment unit and place floating basket, and place iron ore in floating basket, holding absorbing liquid in liquid bath due to one-level is faintly acid, and iron ore can be converted into the manganese ion or iron ion with catalysis by dissolving.Containing manganese ion or iron ion first order absorption liquid by primary cycle transport pump to turbulent impulse scrubber, its spray liquid contacts with flue gas adverse current, in flue gas oxygen is transferred in liquid phase.SO in first order absorption liquid and flue gas
2reaction generates sulphite or bisulfites, afterwards under dissolved oxygen and the manganese ion with catalysis or iron ion action, is oxidizedly converted into sulfate, thus reduces the COD in waste water, make discharged wastewater met the national standard.
Compared with prior art, flue-gas dust-removing and desulfurization reactor of the present invention and process for dusting and dsulfurizing fume tool have the following advantages:
1, the cooling of flue gas chilling and dust-removal and desulfurizing treatment effect are strengthened greatly.Rapids rushes absorbing liquid in decline process, and be subject to the wind-force dissection of gas in tower and be dispersed into tiny drop/droplet, in date core shaped structured packing, the effect of mass transmitting between gas-liquid two-phase is further strengthened.
2, the present invention can make full use of the high potential energy that rapids rushes absorbing liquid.Invention achieves absorbing liquid once to spray, the effect of twice absorption, compare existing two-stage or multi-stage flue gas treatment technology, save the energy consumption that venturi slurry circulating pump is set separately.
3, flue-gas dust-removing and desulfurization reactor of the present invention; adopt moisture film assembly; achieve and the moisture film of pretreatment unit wall of reactor is protected; decrease the equipment corrosion of pretreatment unit; improve the antiseptic power of material or reduce the consumption of high-grade anticorrosion material, thus significantly reducing construction costs.
4, process for dusting and dsulfurizing fume of the present invention, proposes desulfurization absorbing liquid concentration grating theory.Holding liquid bath by arranging respectively at pretreatment unit and advanced treatment unit, defining independently Two-way Cycle flue-gas dust-removing and desulfurization system.The pH value of being held liquid bath by one-level controls to enter the fresh soda liquid measure that secondary holds liquid bath, thus guarantees that the pH value that secondary holds liquid bath maintains higher basicity, thus substantially increases desulfurization degree.The zonal control of the pH value that one-level holds liquid bath, secondary holds liquid bath, both ensure that the high efficiency of this fume desulphurization method, can guarantee again the utilization rate that desulfurization absorbing liquid is higher.
Accompanying drawing explanation
Fig. 1 is H type flue-gas dust-removing and desulfurization structure of reactor schematic diagram of the present invention.
In Fig. 1: 1-moisture film assembly; 2-turbulent impulse scrubber; 3-date core shaped structured packing assembly; 4-primary cycle pipeline; 5-primary cycle pump; 6-one-level holds liquid bath; 7-secondary holds liquid bath; 8-passage; 9-secondary cycle pump; 10-secondary cycle pipeline; 11-filler assembly; 12-secondary spray system; 13-demister; 14-purifying smoke exports; 15-smoke inlet; 16-urceolus; 17-base plate; 18-cylindrical shell; Edge on 19-cylindrical shell; 20-reducing.
Fig. 2 is the structural representation of date core shaped structured packing assembly of the present invention.
In Fig. 2: 31-pull bar; 32-date core shaped special pipe; 33-housing; 34-flange, 35-collection section; 36-aditus laryngis; 37-disperses section; 18-cylindrical shell.
Fig. 3 is the structural representation of date core shaped structured packing shape tube.
In figure, 321-groove.
Fig. 4 is the deflector type demister structural representation of demister assembly of the present invention.
In Fig. 4: 131-tower tray; 132-riser; 133-urceolus; The 134-tangential flow guiding wing; 135-capping plate; 136-bar stitches; 137-groove; 138-direct tube section; 139-conical cylinder section.
Fig. 5 is the A-A sectional top view of demist assembly.
Detailed description of the invention
Technology contents of the present invention and effect is further illustrated below in conjunction with drawings and Examples.
As shown in Figure 1, flue-gas dust-removing and desulfurization reactor of the present invention comprises pretreatment unit and advanced treatment unit, the two forms " H " type Double-Tower Structure, and wherein said pretreatment unit comprises smoke inlet 15, moisture film assembly 1, turbulent impulse scrubber 2, date core shaped structured packing assembly 3 and one-level from top to bottom successively and holds liquid bath 6; Described advanced treatment unit comprises secondary from bottom to top and holds liquid bath 7, filler assembly 11, demister assembly 13 and purifying smoke outlet 14, and pretreatment unit is communicated with the exhaust gases passes 8 of advanced treatment unit by middle part.
Flue-gas dust-removing and desulfurization reactor of the present invention, wherein said pretreatment unit also comprises primary cycle pump 5 and primary cycle pipeline 4; Described advanced treatment unit also comprises secondary cycle pump 9, secondary cycle pipeline 10 and secondary spray system 12.Described secondary spray system 12 is positioned at the top of filler assembly 11, and certainly, secondary spray system 12 also can be positioned at the below of filler assembly 11.
In flue-gas dust-removing and desulfurization reactor of the present invention, described moisture film assembly 1 can adopt the structure of any suitable form in this area.In Fig. 1, moisture film assembly 1 comprise direct tube section 16 that smoke inlet reducing 20 lower end connects, base plate 17 and pretreatment unit reactor shell 18 on along 19, define a cannelure by direct tube section 16, base plate 17 and cylindrical shell along 19, and hold liquid bath 6 by primary cycle pipeline 4, primary cycle pump 5 with one-level and be connected.Wherein the diameter of direct tube section 16 is greater than the diameter of cylindrical shell 18.Wherein preferably on cylindrical shell along the opening of 19(and cannelure) be preferably arranged to tooth-shape structure.
Flue-gas dust-removing and desulfurization reactor of the present invention, described turbulent impulse scrubber 2 can select the rapids of arbitrary form to rush nozzle.
Flue-gas dust-removing and desulfurization reactor of the present invention, described date core shaped structured packing assembly is connected by pull bar 31 by the date core shaped special pipe 32 of some horizontal positioned in parallel, date core shaped special pipe 32, and is fixed on housing 33.Cylindrical shell 18 inwall arranges support lugn 34, for installing fixing date core shaped structured packing.Define many parallel channels between some parallel date core shaped special pipes 32, constitute gas liquid two-phase flow passage, described passage comprises collection section 35, aditus laryngis 36 and dispersion section 37.As shown in Figure 3, on the tube wall of special pipe, some parallel grooves 321 are preferably offered.
Flue-gas dust-removing and desulfurization reactor of the present invention, demister in described demister assembly comprises riser 132 and urceolus 133, urceolus 133 is arranged on the outside of riser 132, and with riser 132 on the same axis, urceolus 133 is made up of direct tube section 138 and conical cylinder section 139.Riser 132 is fixed on tower tray 131, and the top of riser arranges capping plate 135, has some seams 136 at the circumference of riser, is circumferentially provided with the tangential flow guiding wing 134 at the riser near each bar seam.The inner surface (inwall) of inversed conical drum 133 also offers hyoplastron 137, as shown in Figure 4 and Figure 5.
During work, high-temperature flue gas through over-quenching cooling after by smoke inlet 15, first pretreatment unit is entered, the primary cycle liquid that one-level is held in liquid bath 6 flows to moisture film assembly 1 by primary cycle pump 5 part, liquid film protection is formed to reactor, another part is transported to turbulent impulse scrubber 2, the first order absorption liquid counter current contacting that high-temperature flue gas and turbulent impulse scrubber 2 spray, rapids rushes absorbing liquid in decline process, be subject to the wind-force dissection of gas in tower and be dispersed into tiny drop/droplet, carrying out in this process lowering the temperature, dedusting and pre-desulfurization; Flue gas after first order absorption and absorbing liquid continue and flow to current downflow, enter date core shaped structured packing assembly 3, and complete the cooling absorbing flue gas, dedusting and pre-desulfurization further at this; The first order absorption liquid absorbing sulfur dioxide falls into one-level and holds liquid bath 6, and is recycled by primary cycle pump 5 and primary cycle pipeline 4; And the flue gas after pretreatment unit absorption is under the promotion of upper pressure, by the passage 8 penetration depth processing unit between pretreatment unit and advanced treatment unit.Flue gas after first order absorption is upwards by filler assembly 11, and the secondary absorbing liquid sprayed with the secondary spray system above filler assembly 11 is in filler assembly 11 fully contact mass transfer, the secondary absorbing liquid absorbing sulfur dioxide falls into secondary and holds liquid bath 7, and recycled by secondary cycle pump 9 and secondary cycle pipeline 10, complete final sweetening process.By flue gas after the purification of filler assembly 11 by demist assembly 13, after gas-liquid separation, discharge from dust-removal and desulfurizing reactor exhanst gas outlet 14.
Embodiment 1
Certain high-temperature flue-gas 180 DEG C, tolerance 180000Nm
3/ h, SO
2concentration is 800mg/Nm
3, dust content 500 mg/Nm
3.
Reactor operating condition: operating temperature 170 DEG C, operating pressure normal pressure, first order absorption liquid pH value is 6 ~ 7, and secondary absorbing liquid pH value is 8 ~ 9.Rapids rushes liquid-gas ratio 6:1, take NaOH solution as absorbent, and gas-liquid counter current contacts; Filler assembly operation liquid-gas ratio 3:1.
After process of the present invention, flue-gas temperature 60 DEG C, desulfuration efficiency 98%, efficiency of dust collection 99%.
Claims (21)
1. a H type flue-gas dust-removing and desulfurization reactor, is characterized in that, described reactor comprises pretreatment unit and advanced treatment unit, and the two forms " H " shape or " U " shape Double-Tower Structure; Wherein said pretreatment unit comprises smoke inlet, turbulent impulse scrubber, date core shaped structured packing assembly and one-level from top to bottom and holds liquid bath, and described advanced treatment unit comprises secondary from bottom to top and holds the outlet of liquid bath, filler assembly, demister and purifying smoke; Described pretreatment unit is communicated with the exhaust gases passes of advanced treatment unit by middle part.
2. according to reactor according to claim 1, it is characterized in that, described date core shaped structured packing assembly comprise at least two-layer some parallel connections, the date core shaped special pipe of horizontal positioned, the some parallel connections described in every layer, the date core shaped special pipe of horizontal positioned constitute multiple parallel channels with collection section, aditus laryngis and dispersion section; Wherein adjacent two-layer date core shaped special pipe up and down staggered, interval shifts to install.
3. according to reactor according to claim 2, it is characterized in that, the cross section of described date core shaped special pipe is date core shaped, and its top and bottom are acute triangle, and middle part is circular arc.
4. according to the reactor described in claim 1,2 or 3, it is characterized in that, the both sides tube wall of described date core shaped special pipe bottom offers groove, and described groove has certain inclination angle.
5. according to reactor according to claim 1, it is characterized in that, in described pretreatment unit, on the wall top of reactor, preferably the connecting portion of wall of reactor top and smoke inlet reducing is provided with moisture film assembly.
6. according to reactor according to claim 5, it is characterized in that, arrange endless tube in wall of reactor surrounding, on endless tube, installation surface is to the nozzle of wall.
7. according to reactor according to claim 5, it is characterized in that, described moisture film assembly is overflow-type moisture film assembly, the structure of overflow-type moisture film assembly is: connect one section of straight tube in the lower end of smoke inlet reducing, the diameter of this direct tube section is greater than the reactor diameter of pretreatment unit, form the uncovered cannelure in a bottom lock, upper end in wall of reactor and reducing connecting portion, this cannelure is held liquid bath with one-level and is connected by pipeline.
8. according to reactor according to claim 7, it is characterized in that, the uncovered employing tooth-shape structure of described cannelure.
9. according to reactor according to claim 1, it is characterized in that, the filler assembly in described advanced treatment unit selects structured packing assembly.
10. according to reactor according to claim 9, it is characterized in that, described filler assembly adopts the structured packing of one deck date core shaped special pipe.
11., according to reactor according to claim 1, is characterized in that, described pretreatment unit also comprises primary cycle pump and primary cycle pipeline; Described advanced treatment unit also comprises secondary cycle pump, secondary cycle pipeline and secondary spray system.
12., according to reactor according to claim 11, is characterized in that, described secondary spray system is positioned at above or below filler assembly.
13., according to reactor according to claim 1, is characterized in that, deflector type demister selected by described demister; Deflector type demister comprises several demist assemblies arranged side by side, and each demist assembly includes riser and urceolus, and urceolus is arranged on the outside of riser, and with riser on the same axis; Riser is fixed on tower tray, and the top of riser arranges capping plate, has some seams at the circumference of riser, is circumferentially provided with the tangential flow guiding wing at the riser near each bar seam; Wherein said urceolus is made up of direct tube section and conical cylinder section.
14., according to reactor according to claim 13, is characterized in that, arrange projection, preferably arrange hyoplastron at the inner surface of described urceolus, and the direction of rotation of hyoplastron is contrary with the direction of rotation of the tangential flow guiding wing.
15., according to reactor according to claim 1, is characterized in that, hold in liquid bath and place floating basket, place oxidation catalyst in floating basket in the one-level of pretreatment unit.
16. 1 kinds of process for dusting and dsulfurizing fume, is characterized in that, the method use the arbitrary described H type flue-gas dust-removing and desulfurization reactor of claim 1 to 15.
17., according to process for dusting and dsulfurizing fume according to claim 16, is characterized in that, described method comprises following content:
(1) high-temperature flue gas is after over-quenching cooling, enters pretreatment unit, and pH value spray with turbulent impulse scrubber is neutral or acid first order absorption liquid counter current contacting, carries out lowering the temperature, dedusting and desulfurization in advance;
(2) flue gas in step (1) after first order absorption and absorbing liquid continue and flow to current downflow, enter date core shaped structured packing assembly, complete the cooling absorbing flue gas, dedusting and pre-desulfurization further;
(3) the first order absorption liquid of sulfur dioxide absorption enters one-level and holds liquid bath, and is recycled by primary cycle pump and primary cycle pipeline;
(4) and pretreatment unit absorb after flue gas penetration depth processing unit, upwards by filler assembly, and with the secondary absorbing liquid of pH value in alkalescence in the abundant contact mass transfer of filler assembly, complete deep desulfurization process;
(5) pass through demister by flue gas after the purification of filler assembly, after gas-liquid separation, discharge from dust-removal and desulfurizing reactor exhanst gas outlet.
18., according to process for dusting and dsulfurizing fume according to claim 17, is characterized in that, the SO in described flue gas
2concentration is 500 ~ 5000mg/Nm
3, preferably 1000 ~ 4000mg/Nm
3; Dust concentration 200 ~ 800mg/Nm
3, preferably 300 ~ 500mg/Nm
3.
19., according to process for dusting and dsulfurizing fume according to claim 17, is characterized in that, the operating condition of described reactor is: operating temperature is 100 ~ 350 DEG C, preferably 150 ~ 200 DEG C; Operating pressure is that normal pressure is to 1MPa; Treatment quantity is 500 ~ 200000m
3/ h, preferably 700 ~ 190000 m
3/ h; Absorbing liquid internal circulating load is 0.4m
3/ h ~ 7m
3/ h, preferred 0.5m
3/ h ~ 6m
3/ h.
20., according to process for dusting and dsulfurizing fume according to claim 17, is characterized in that, described absorbing liquid is NaOH solution, Na
2cO
3solution, Mg (OH)
2solution or limewash Ca (OH)
2, preferred NaOH solution.
21., according to process for dusting and dsulfurizing fume according to claim 17, is characterized in that, the pH value of described first order absorption liquid is between 6 ~ 7, and described secondary absorbing liquid pH value is between 8 ~ 10.
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| CN106215660A (en) * | 2016-08-25 | 2016-12-14 | 灵宝金源晨光有色矿冶有限公司 | SO in a kind of recovery tail gas2system |
| CN107875776A (en) * | 2017-12-21 | 2018-04-06 | 双盾环境科技有限公司 | A kind of rapid punching injection coupling integrated flue gas purifier of the difficult flue gas of complexity |
| CN108043145A (en) * | 2017-12-21 | 2018-05-18 | 双盾环境科技有限公司 | A kind of rapid punching injection coupling integrated flue gas purification technique of the difficult flue gas of complexity |
| CN111760422A (en) * | 2020-06-30 | 2020-10-13 | 双盾环境科技有限公司 | Variable-flow turbulent bubble type pre-absorption process for removing sulfur dioxide by flue gas organic amine method |
| CN115315303A (en) * | 2020-02-26 | 2022-11-08 | 环球油品有限责任公司 | Process and apparatus for quenching a reactor effluent stream |
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|---|---|
| CN104607022B (en) | 2017-01-04 |
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