CN104594074B - A kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate - Google Patents
A kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate Download PDFInfo
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Abstract
The invention provides a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate。The method includes: be placed in the aqueous solution of alkaline matter by fiber being swelling to liquid carrying rate is 30%-200%, dries;Fiber after drying is mixed with the good solvent of reactive dye, reactive dye, adds the poor solvent of reactive dye, be incubated after being warming up to dyeing temperature;Fiber after dyeing is placed in the organic solution with two or more nucleophilic group compound insulation a period of time;Then again fiber is placed in the organic solution with two or more electrophilic group compound and reacts;Take out fiber, be neutralized, wash, complete dyeing, in said method, add and the aqueous solution of alkaline matter is staple in bulk or yarn, fabric or ready-made clothes that fiber is made。In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, the consumption of water is few, and dyestuff utilizes height。
Description
Technical field
The present invention relates to the colouring method of a kind of reactive dye, particularly to a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, belong to textile dyeing and finishing technical field。
Background technology
The dyeing of current reactive fibre adopts reactive dye mostly, due to active group hydrolysis in aqueous medium in dyeing course, not only result in the waste of a large amount of reactive dye, and need consume substantial amounts of water and discharge a large amount of reluctant high chroma sewage in dyeing course, this is the bottleneck being difficult to overcome that reactive dye exist all the time。
In order to be avoided that the hydrolysis of reactive dye, improving the utilization rate of reactive dye, scientists is very early it have been noted that and have studied reactive dye dyeing in non-aqueous media。The advantage adopting non-aqueous media dyeing is in that reactive dye will not be hydrolyzed in dyeing course, is expected to the extent of reaction that can improve reactive dye with fiber。But simultaneously, adopt non-aqueous media dyeing also to there is more problem always, mainly include reactive dye dissolubility in non-aqueous media, the fiber Swelling Capacity in non-aqueous media, the fixation alkaline agent dissolubility in non-aqueous media and the level-dyeing property of dyeing, through-dyeing etc.。Although reactive dye dye in non-aqueous media there is many difficult points, but present stage use water cost gradually rises, and environmental conservation is increasingly paid attention to by people, and the dyeing of reactive dye non-aqueous media also increasingly receives publicity with its good application prospect。
The eighties in last century, India's textile technology institute adopted dimethylformamide lytic activity dyestuff C.I. active red 12, is dividedly in some parts trichloro ethylene and is incubated 1h in being warming up to 80 DEG C of processes, and dyestuff is completely upper dye almost, and degree of fixation is 84%。Though said method provides a good solvent dyeing thinking, but degree of fixation to compare advantage than conventional coloring method little, remain a need for substantial amounts of water after dyeing and carry out high temperature and soap removal loose colour, prospects for commercial application is little, is therefore developed further。
Solvent reverse micelle staining is a kind of novel non-aqueous solvent dyeing technique in recent years occurred, this method be the aqueous dye solutions that fiber or fabric are placed in solubilising high concentration reverse micelle system in dyeing, dyeing institute water consumption greatly reduces compared with dyeing with traditional water bath, a kind of novel water saving dyeing of can yet be regarded as。But there is following problem in reverse micelle dyeing: 1, the large usage quantity of system internal surfactants and cosurfactant, the consumption of substantial amounts of surfactant and auxiliary agent causes adsorbing on cloth specimen in dyeing course substantial amounts of surfactant and auxiliary agent, can cause post processing difficulty equally, COD value of waste water of soaping is higher, environmental pollution and certain wasting of resources。2, owing to high concentration aqueous dye solutions scattered in dicyandiamide solution is high to the affinity of fiber, therefore dyestuff dyeing speed is fast, wayward, easy dyeing flower。3, during dyeing, first cotton fiber needs to pad certain density aqueous sodium carbonate, and enters dye with certain liquid rate for the treatment of, the water existed in system also results in the hydrolysis of dyestuff, and therefore, its degree of fixation is relatively low。
In order to overcome reverse micelle system dyeing drawback, Yida Textile Co., Ltd and Institutes Of Technology Of Zhejiang have developed organic solvent suspension system cooperatively to realize the dyeing of reactive dye。Reactive dye and a certain amount of dispersant are scattered in organic solvent system by ball milling by this dyeing, realize the upper dye to cotton fiber under certain dyeing condition。The dispersant adopted in this dyeing is only 0.15 times of dye dosage, and the dye-uptake of dyestuff can reach nearly 100%, fully demonstrate the advantage of non-aqueous solvent dyeing, but also due to scattered dye granule is high to the affinity of cotton fiber in dicyandiamide solution, therefore dyeing speed is fast, easy dyeing flower, equally, the water existed in system can cause the hydrolysis of dyestuff, and dye utilization rate is low。
Although the existing lot of documents report of reactive dye non-aqueous solvent dyeing technique, but the degree of fixation of reactive dye is still relatively low, the substantial amounts of water loose colour to wash away on fiber is remained a need for after dyeing, this also just loses non-aqueous solvent dyeing real significance, simultaneously, owing in dicyandiamide solution, dyestuff is high to the affinity of fiber, dyeing rate is wayward, causes easy dyeing flower of dyeing。
Summary of the invention
In order to solve the problems referred to above, it is an object of the invention to provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, this colouring method dye fixing rate is high, and the consumption of water is few。
In order to achieve the above object, the invention provides a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, it comprises the following steps:
Step one: be placed in the aqueous solution of alkaline matter being swelling to liquid carrying rate by fiber (or fiber make yarn, fabric or ready-made clothes) is 30%-200%, dries;
Step 2: the fiber (or fiber make yarn, fabric or ready-made clothes) after drying is mixed with the good solvent of reactive dye, reactive dye, the poor solvent of addition reactive dye, it is warming up to held for some time after dyeing temperature;Wherein, the volume ratio of the poor solvent of the good solvent of described reactive dye and described reactive dye is 1:3-20;The ratio of the quality of the volume of the good solvent of described reactive dye and described fiber (or fiber make yarn, fabric or ready-made clothes) is 2-50:1, it is preferably 3-10:1, wherein, the volume unit of good solvent is mL, and the mass unit of fiber (or fiber make yarn, fabric or ready-made clothes) is g;
Step 3: be placed in the organic solution with two or more nucleophilic group compound at 40-80 DEG C by the fiber (or fiber make yarn, fabric or ready-made clothes) after dyeing reaction 0.5-2h, is then placed in the organic solution with two or more electrophilic group compound at 40-80 DEG C by the fiber (or fiber make yarn, fabric or ready-made clothes) after dyeing reaction 0.5-2h;
Or, it is placed in the organic solution with two or more electrophilic group compound at 40-80 DEG C by the fiber (or fiber make yarn, fabric or ready-made clothes) after dyeing reaction 0.5-2h;Then it is placed in the organic solution with two or more nucleophilic group compound at 40-80 DEG C by the fiber (or fiber make yarn, fabric or ready-made clothes) after dyeing reaction 0.5-2h;
Or, the fiber (or fiber make yarn, fabric or ready-made clothes) after dyeing is placed in two or more electrophilic group compound and the organic solution with two or more nucleophilic group compound are reacted 0.5-2h at 40-80 DEG C;
Wherein, the consumption with two or more nucleophilic group compound is 0.1%o.m.f-10%o.m.f, and the fiber after dyeing and the solid-liquid ratio with the organic solution of two or more nucleophilic group compound are 1:5-30;Consumption with two or more electrophilic group compound is 0.1%o.m.f-10%o.m.f, and the solid-liquid ratio of fiber after dyeing (or fiber make yarn, fabric or ready-made clothes) and the organic solution with two or more electrophilic group compound is 1:5-30;
Step 4: take out fiber, be neutralized, wash, completes dyeing;
Wherein, the fiber of employing include cellulose fibre, protein fibre and there are the synthetic fibers of reactive group in the combination of one or more;
Preferably, described reactive group includes amino, hydroxyl, sulfydryl;
The cellulose fibre adopted includes the combination of one or more in cotton fiber, fiber crops and viscose rayon, and the protein fibre of employing includes Pilus Caprae seu Ovis and/or silk etc., and the synthetic fibers with reactive group of employing include nylon etc.;
Adding in the aqueous solution of alkaline matter can be staple in bulk, it is also possible to be yarn, fabric or the ready-made clothes made of fiber;
Organic solvent in the described organic solution with two or more nucleophilic group compound be can dissolve this with two or more nucleophilic group compound but not with the organic solvent of reactive dye generation chemical reaction;
Organic solvent in the described organic solution with two or more electrophilic group compound be can dissolve this with two or more electrophilic group compound but not with the organic solvent of reactive dye generation chemical reaction;
The good solvent of described reactive dye be can lytic activity dyestuff but not with the nonaqueous solvent of reactive dye generation chemical reaction;The poor solvent of described reactive dye be can not lytic activity dyestuff and not with the nonaqueous solvent of reactive dye generation chemical reaction;
The poor solvent of described reactive dye added before heating up or adds in temperature-rise period。
According to specific embodiments of the present invention, the operation neutralize, washed carries out in a conventional manner。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, preferably, yarn, fabric or ready-made clothes that fiber after drying or fiber are made are mixed by step 2 with the good solvent of reactive dye, reactive dye, temperature-rise period adds the poor solvent of reactive dye, after being warming up to dyeing temperature 80-130 DEG C, is incubated 1-2h。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, it is preferable that the good solvent of reactive dye used is polar solvent;More preferably, the good solvent of the reactive dye adopted includes N, the combination of one or more in dinethylformamide (DMF), N,N-dimethylacetamide (DMAC), dimethyl sulfoxide (DMSO), ionic liquid and alcohol ether solvents etc.。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, preferably, the poor solvent of described reactive dye includes the combination of one or more in alkane, chloride hydro carbons, alkene, aromatic hydrocarbons, ketones solvent, silanes solvent, esters solvent and ether solvent;It is highly preferred that the poor solvent of described reactive dye includes C6-C8N-alkane, C6-C8Isoparaffin, the combination of one or more in perchloroethylene and decamethylcyclopentaandoxane。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, it is preferable that the nucleophilic group in the organic solution with two or more nucleophilic group compound of employing is can with the nucleophilic group of reactive dye generation chemical reaction;It is highly preferred that the nucleophilic group adopted includes primary amino radical, secondary amino group, hydroxyl or sulfydryl;Most preferably, described polyethylene polyamine, polymine, ethylene glycol, Polyethylene Glycol, multi-thiol and multi-thiol derivant etc. are included with two or more nucleophilic group compound。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, preferably, the electrophilic group in the organic solution with two or more electrophilic group compound of employing is the electrophilic group that chemical reaction occurs the reactive group (hydroxyl, amino, sulfydryl etc.) in yarn, fabric or the ready-made clothes can made with nucleophilic group and fiber or fiber;It is highly preferred that electrophilic group includes epoxy radicals, aldehyde radical, cyano group, triazine ring base, methylol, acid chloride group, acryloyl group or NCO;Most preferably, described Cyanuric Chloride, cyanuric fluoride, binary acyl chlorides, 2D resin, polyurethane, urethane derivative, epoxychloropropane, dialdehyde and dicyandiamide etc. are included with two or more electrophilic group compound。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, it is preferable that described alkaline matter includes M (CO3)x, M (OH)y、M(HxPyOz)、R1R2R3N and R4O-In the combination of one or more, wherein, M is metal ion, R1、R2、R3、R4Respectively alkyl or Hydrogen Proton, the integer of X, Y, Z respectively 1-3;It is highly preferred that the alkaline matter adopted includes the combination of one or more in sodium carbonate, sodium bicarbonate, sodium hydroxide, Lithium hydrate and potassium hydroxide。
In the reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention, it is preferable that the concentration of the aqueous solution of the alkaline matter of employing is 1g/L-100g/L;It is highly preferred that the concentration of the aqueous solution of alkaline matter is 5-50g/L。
The reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention adopts nonaqueous solvent that reactive dye are dyeed, in dyeing course, active group is not hydrolyzed, after amount of activated dyestuff is combined with fiber generation covalent bond, remaining reactive dye are anchored on fiber by cross-linking system, degree of fixation nearly 100%。Fiber after dyeing is after simply washing neutralization, it is not necessary to high temperature is soaped。Thoroughly solve present stage reactive dye color fixing rate low, the problem that water consumption of soaping after dyeing is big。
The reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention is the colouring method of a kind of high colour-fast rate。First reactive dye react with fiber generation fixation in nonaqueous solvent, the active group of residual activity dyestuff is not destroyed, reactivity is higher, now add a small amount of cross-linking agent, make the complete reactive dye of unreacted, fiber and the reaction of cross-linking agent generation in-situ polycondensation, make dyestuff pass through bridged bond to be combined with covalent bond with fiber, finally make reactive dye have high degree of fixation on fiber。
The non-aqueous solvent dyeing method of reactive dye provided by the invention adopts the method for non-aqueous solvent dyeing, reactive dye completely on contaminate fiber, it is achieved that the real salt-free dyeing of fiber;Dyeing residual solvent only need to can be separated by simply distillation and again recycle, and dyeing course is pollution-free。
The reactive dye non-aqueous solvent dyeing method of high colour-fast rate provided by the invention have the beneficial effect that the following aspects:
The colouring method of the present invention solves for a long time that reactive dye utilization rate is low, need to adopt a large amount of high temperature to soap after dyeing problem that liquid soaps, and without the short dye of salt in dyeing course, dyestuff can completely upper dye;
The alkali consumption of the colouring method of the present invention is few, and will not discharge containing alkali waste water;
The dye utilization rate of the colouring method of the present invention is high, degree of fixation nearly 100%;
In the colouring method of the present invention, dyeing after only with in a small amount of cold water and aqueous acetic acid with, it is not necessary to high temperature is soaped, and water consumption is little, and effects of energy saving and emission reduction is notable。
Detailed description of the invention
In order to the technical characteristic of the present invention, purpose and beneficial effect are more clearly understood from, existing technical scheme is carried out described further below, but it is not intended that to the present invention can the restriction of practical range。
Embodiment 1
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
The pure cotton knitting cloth of 10g is carried out pretreatment in the sodium hydrate aqueous solution that concentration is 10g/L, dries, be then placed in dyeing cup;
Adding the dimethyl sulfoxide of (3%o.m.f) EBRRed3BS dyestuff of 0.3g, 50mL in dyeing cup, be incubated 2h after being warming up to 95 DEG C with 1 DEG C/min, add 150mL tetrachloroethylene in temperature-rise period, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the diethylenetriamine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the Cyanuric Chloride of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Bafta is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the bafta after the colouring method dyeing of the present embodiment is 98.8%。
The coloration result of the reactive dye non-aqueous solvent dyeing method of the high colour-fast rate of the present embodiment Yu traditional water bath colouring method is contrasted, comparing result is as shown in table 1, and table 1 is the reactive dye non-aqueous solvent dyeing method comparing result with the test data of traditional water bath colouring method of the high colour-fast rate of the present embodiment。
Traditional water bath colouring method: at 60 DEG C, is placed in bafta in the Matrii Sulfas Exsiccatus that concentration is 60g/L and the sodium carbonate that concentration is 20g/L and dyes, and bath raio is 1:12。
Table 1
Embodiment 2
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
The bafta of 10g is carried out pretreatment in the sodium hydrate aqueous solution that concentration is 10g/L, dries, be then placed in dyeing cup;
In dyeing cup, add the DMF of (3%o.m.f) SSYellow3RF dyestuff of 0.3g, 50mL, after being warming up to 95 DEG C with 1 DEG C/min, be incubated 2h, temperature-rise period adds the 1 of 150mL, 2-dichloroethanes, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the triethylene tetramine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add 1g Adipoyl Chloride, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Bafta is taken out, is neutralized, washes, complete dyeing。
After the colouring method dyeing of the high colour-fast rate of use the present embodiment, the degree of fixation of bafta is 99.1%。
The coloration result of the reactive dye non-aqueous solvent dyeing method of the height color rate of the present embodiment Yu traditional water bath colouring method is contrasted, comparing result is as shown in table 2, and table 2 is the reactive dye non-aqueous solvent dyeing method comparing result with the test data of traditional water bath colouring method of the high colour-fast rate of the present embodiment。
Traditional water bath colouring method: at 60 DEG C, is placed in bafta in the Matrii Sulfas Exsiccatus that concentration is 70g/L and the sodium carbonate that concentration is 20g/L and dyes, and bath raio is 1:12。
Table 2
Embodiment 3
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
Cotton/nylon (70% cotton+30% nylon) looped fabric of 10g is carried out pretreatment in the sodium hydrate aqueous solution that concentration is 10g/L, dries, be then placed in dyeing cup;
The N of (3%o.m.f) SSBlueBRF dyestuff of 0.3g, 50mL is added in dyeing cup, N-dimethyl acetylamide, is incubated 2h after being warming up to 95 DEG C with 1 DEG C/min, add 150mL decamethylcyclopentaandoxane in temperature-rise period, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the diethylenetriamine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the Cyanuric Chloride of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Fabric is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the fabric after the colouring method dyeing of the present embodiment is 99.2%。
The dyeing product that the reactive dye non-aqueous solvent dyeing method of the height color rate of the present embodiment is obtained carries out performance evaluation, evaluation result is as shown in table 3, and table 3 is the test data result of the product that the reactive dye non-aqueous solvent dyeing method of the high colour-fast rate of the present embodiment obtains。
Table 3
Embodiment 4
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
Cotton/Pilus Caprae seu Ovis (50% cotton+50% Pilus Caprae seu Ovis) the blended knitted cloth of 10g is carried out pretreatment in the aqueous sodium carbonate that concentration is 20g/L, dries, be then placed in dyeing cup;
The dimethyl sulfoxide of (3%o.m.f) NovacronsuprablackG dyestuff of 0.3g, 50mL is added in dyeing cup, 2h it is incubated after being warming up to 95 DEG C with 1 DEG C/min, adding 150mL tetrachloroethylene in temperature-rise period, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the diethylenetriamine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the epoxychloropropane of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Fabric is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the fabric after the colouring method dyeing of the present embodiment is 99.5%。
The dyeing product that the reactive dye non-aqueous solvent dyeing method of the height color rate of the present embodiment is obtained carries out performance evaluation, evaluation result is as shown in table 4, and table 4 is the test data result of the product that the reactive dye non-aqueous solvent dyeing method of the high colour-fast rate of the present embodiment obtains。
Table 4
Embodiment 5
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
Cotton/fiber crops (60% cotton+40% fiber crops) the blended knitted cloth of 10g is carried out pretreatment in the sodium bicarbonate aqueous solution that concentration is 40g/L, dries, be then placed in dyeing cup;
The N of (3%o.m.f) EverzolYellow3RS dyestuff of 0.3g, 50mL is added in dyeing cup, N-dimethyl acetylamide, is incubated 2h after being warming up to 95 DEG C with 1 DEG C/min, add 150mL normal heptane in temperature-rise period, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the polyethylene glycol 200 of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the hexandial of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Fabric is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the fabric after the colouring method dyeing of the present embodiment is 98.2%。
The dyeing product that the reactive dye non-aqueous solvent dyeing method of the height color rate of the present embodiment is obtained carries out performance evaluation, evaluation result is as shown in table 5, and table 5 is the test data result of the product that the reactive dye non-aqueous solvent dyeing method of the high colour-fast rate of the present embodiment obtains。
Table 5
Embodiment 6
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
The purified cotton yarns of 10g is carried out pretreatment in the aqueous sodium carbonate that concentration is 20g/L, dries, be then placed in dyeing cup;
Adding (3%o.m.f) EverzolRed3BS dyestuff of 0.3g, the N,N-dimethylacetamide of 50mL and 150mL isoheptane in dyeing cup, be incubated 2h after being warming up to 95 DEG C with 1 DEG C/min, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the polymine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the dicyanodiamine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Yarn is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the dyestuff after the colouring method dyeing of the present embodiment is 98.3%。
Embodiment 7
Present embodiments provide a kind of reactive dye non-aqueous solvent dyeing method of high colour-fast rate, specifically include following steps:
10g is carried out pretreatment, dewatered drying through the Cotton Gossypii of boiling-off in the aqueous sodium carbonate that concentration is 20g/L, is then placed in dyeing cup;
Adding (3%o.m.f) EverzolRed3BS dyestuff of 0.3g, the dimethyl sulfoxide of 50mL and 150mL trichloro ethylene in dyeing cup, be incubated 2h after being warming up to 95 DEG C with 1 DEG C/min, dye-uptake is 100%, is poured out by solvent and reclaims;
In dyeing cup, add the diethylenetriamine of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
In dyeing cup, add the Adipoyl Chloride of 1g, 100mL acetone, at 80 DEG C, be incubated 30min, solvent poured out and reclaims;
Fiber is taken out, is neutralized, washes, complete dyeing。
The degree of fixation using the dyestuff after the colouring method dyeing of the present embodiment is 98.4%。
As seen from the above embodiment, the alkali consumption of the reactive dye non-aqueous solvent dyeing method of the high colour-fast rate of the present invention is few, and will not discharge containing alkali waste water;Dye utilization rate is high, degree of fixation nearly 100%;Dyeing after only with in a small amount of cold water and aqueous acetic acid with, it is not necessary to high temperature is soaped, and water consumption is little, is the colouring method of a kind of high-efficiency environment friendly energy-conservation。
Claims (17)
1. a reactive dye non-aqueous solvent dyeing method for high colour-fast rate, it comprises the following steps:
Step one: it is 30%-200% that yarn, fabric or ready-made clothes fiber or fiber made be placed in the aqueous solution of alkaline matter to be swelling to liquid carrying rate, dries;
Step 2: yarn, fabric or ready-made clothes that the fiber after drying or fiber are made are mixed with the good solvent of reactive dye, reactive dye, add the poor solvent of reactive dye, is incubated after being warming up to dyeing temperature;Wherein, the volume ratio of the poor solvent of the good solvent of described reactive dye and described reactive dye is 1:3-20;The ratio of the quality of yarn, fabric or ready-made clothes that the volume of the good solvent of described reactive dye is made with described fiber or fiber is 2-50:1, and wherein, the volume unit of good solvent is the mass unit of yarn, fabric or ready-made clothes that mL, fiber or fiber are made is g;
Step 3: yarn, fabric or ready-made clothes that the fiber after dyeing or fiber are made are placed in the organic solution with two or more nucleophilic group compound at 40-80 DEG C and are incubated 0.5-2h, is then placed in the organic solution with two or more electrophilic group compound at 40-80 DEG C is incubated 0.5-2h by yarn, fabric or ready-made clothes that the fiber after dyeing or fiber are made;
Or, yarn, fabric or ready-made clothes that the fiber after dyeing or fiber are made are placed in the organic solution with two or more electrophilic group compound at 40-80 DEG C and are incubated 0.5-2h;Then yarn, fabric or ready-made clothes that the fiber after dyeing or fiber are made are placed in the organic solution with two or more nucleophilic group compound at 40-80 DEG C and are incubated 0.5-2h;
Or, yarn, fabric or ready-made clothes that the fiber after dyeing or fiber are made are placed in two or more electrophilic group compound and the organic solution with two or more nucleophilic group compound are incubated 0.5-2h at 40-80 DEG C;
Wherein, consumption with two or more nucleophilic group compound is 0.1%o.m.f-10%o.m.f, yarn, fabric or ready-made clothes that fiber after dyeing or fiber are made and the solid-liquid ratio with the organic solution of two or more nucleophilic group compound are 1:5-30, the mass unit of yarn, fabric or ready-made clothes that fiber after dyeing or fiber are made is g, and the volume unit with the organic solution of two or more nucleophilic group compound is mL;Consumption with two or more electrophilic group compound is 0.1%o.m.f-10%o.m.f, yarn, fabric or ready-made clothes that fiber after dyeing or fiber are made and the solid-liquid ratio with the organic solution of two or more electrophilic group compound are 1:5-30, the mass unit of yarn, fabric or ready-made clothes that fiber after dyeing or fiber are made is g, and the volume unit with the organic solution of two or more electrophilic group compound is mL;
Step 4: yarn, fabric or the ready-made clothes that taking-up fiber or fiber are made, is neutralized, washes, and completes dyeing;
Wherein, described fiber include cellulose fibre, protein fibre and there are the synthetic fibers of reactive group in the combination of one or more;
Organic solvent in the described organic solution with two or more nucleophilic group compound be can dissolve this with two or more nucleophilic group compound but not with the organic solvent of reactive dye generation chemical reaction;
Organic solvent in the described organic solution with two or more electrophilic group compound be can dissolve this with two or more electrophilic group compound but not with the organic solvent of reactive dye generation chemical reaction;
The good solvent of described reactive dye be can lytic activity dyestuff but not with the nonaqueous solvent of reactive dye generation chemical reaction;The poor solvent of described reactive dye be can not lytic activity dyestuff and not with the nonaqueous solvent of reactive dye generation chemical reaction;
The poor solvent of described reactive dye added before heating up or adds in temperature-rise period。
2. non-aqueous solvent dyeing method according to claim 1, wherein, is warming up to dyeing temperature 80-130 DEG C insulation 1-2h in step 2。
3. non-aqueous solvent dyeing method according to claim 1, wherein, described reactive group includes amino, hydroxyl, sulfydryl。
4. non-aqueous solvent dyeing method according to claim 1, wherein, described cellulose fibre includes the combination of one or more in cotton fiber, fiber crops and viscose rayon, and described protein fibre includes Pilus Caprae seu Ovis and/or silk, described in there are the synthetic fibers of reactive group include nylon。
5. non-aqueous solvent dyeing method according to claim 1, wherein, the good solvent of described reactive dye is polar solvent。
6. non-aqueous solvent dyeing method according to claim 1 or 5, wherein, the good solvent of described reactive dye includes the combination of one or more in DMF, N,N-dimethylacetamide, dimethyl sulfoxide, ionic liquid and alcohol ether solvents。
7. non-aqueous solvent dyeing method according to claim 1, wherein, the poor solvent of described reactive dye includes the combination of one or more in alkane, chloride hydro carbons, alkene, aromatic hydrocarbons, ketones solvent, silanes solvent, esters solvent and ether solvent。
8. the non-aqueous solvent dyeing method according to claim 1 or 7, wherein, the poor solvent of described reactive dye includes C6-C8N-alkane, C6-C8Isoparaffin, the combination of one or more in perchloroethylene and decamethylcyclopentaandoxane。
9. non-aqueous solvent dyeing method according to claim 1, wherein, described is can with the nucleophilic group of reactive dye generation chemical reaction with the nucleophilic group in two or more nucleophilic group compound。
10. the non-aqueous solvent dyeing method according to claim 1 or 9, wherein, described includes polyethylene polyamine, polymine, ethylene glycol, Polyethylene Glycol, multi-thiol and multi-thiol derivant with two or more nucleophilic group compound。
11. non-aqueous solvent dyeing method according to claim 1, wherein, described with the electrophilic group that the electrophilic group in two or more electrophilic group compound is reactive group generation chemical reaction in yarn, fabric or the ready-made clothes can made with described nucleophilic group and fiber or fiber。
12. the non-aqueous solvent dyeing method according to claim 1 or 11, wherein, described Cyanuric Chloride, cyanuric fluoride, binary acyl chlorides, 2D resin, polyurethane, urethane derivative, epoxychloropropane, dialdehyde and dicyandiamide are included with two or more electrophilic group compound。
13. non-aqueous solvent dyeing method according to claim 1, wherein, the ratio of the quality of yarn, fabric or ready-made clothes that the volume of the good solvent of described reactive dye is made with described fiber or fiber is 3-10:1, wherein, the volume unit of good solvent is the mass unit of yarn, fabric or ready-made clothes that mL, fiber or fiber are made is g。
14. non-aqueous solvent dyeing method according to claim 1, wherein, described alkaline matter includes M (CO3)x, M (OH)y、M(HxPyOz)、R1R2R3N and R4O-In the combination of one or more, wherein, M is metal ion, R1、R2、R3、R4Respectively alkyl or Hydrogen Proton, the integer of X, Y, Z respectively 1-3。
15. non-aqueous solvent dyeing method according to claim 14, wherein, described alkaline matter includes the combination of one or more in sodium carbonate, sodium bicarbonate, sodium hydroxide, Lithium hydrate and potassium hydroxide。
16. according to the non-aqueous solvent dyeing method described in claim 1,14 or 15, wherein, the concentration of the aqueous solution of described alkaline matter is 1g/L-100g/L。
17. non-aqueous solvent dyeing method according to claim 16, wherein, the concentration of the aqueous solution of described alkaline matter is 5-50g/L。
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