CN104592914B - A kind of environment protection type multifunction architecture adhesive and preparation method thereof - Google Patents
A kind of environment protection type multifunction architecture adhesive and preparation method thereof Download PDFInfo
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- CN104592914B CN104592914B CN201510034800.XA CN201510034800A CN104592914B CN 104592914 B CN104592914 B CN 104592914B CN 201510034800 A CN201510034800 A CN 201510034800A CN 104592914 B CN104592914 B CN 104592914B
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- 239000000853 adhesive Substances 0.000 title claims abstract description 31
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 239000011347 resin Substances 0.000 claims abstract description 46
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 26
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 21
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001667 (E)-4-furan-2-ylbut-3-en-2-one Substances 0.000 claims abstract description 13
- GBKGJMYPQZODMI-SNAWJCMRSA-N (e)-4-(furan-2-yl)but-3-en-2-one Chemical compound CC(=O)\C=C\C1=CC=CO1 GBKGJMYPQZODMI-SNAWJCMRSA-N 0.000 claims abstract description 13
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 claims abstract description 13
- HPILSDOMLLYBQF-UHFFFAOYSA-N 2-[1-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COC(CCC)OCC1CO1 HPILSDOMLLYBQF-UHFFFAOYSA-N 0.000 claims abstract description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 13
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 13
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 13
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 13
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 13
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 13
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 13
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 13
- 235000019710 soybean protein Nutrition 0.000 claims abstract description 13
- 239000012745 toughening agent Substances 0.000 claims abstract description 13
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940117958 vinyl acetate Drugs 0.000 claims abstract description 13
- 238000012856 packing Methods 0.000 claims abstract description 10
- 230000002528 anti-freeze Effects 0.000 claims abstract description 9
- 239000000945 filler Substances 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 9
- 229910052755 nonmetal Inorganic materials 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 3
- 239000002585 base Substances 0.000 claims abstract description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 3
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 20
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 16
- 235000010469 Glycine max Nutrition 0.000 claims description 10
- 244000068988 Glycine max Species 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 235000018102 proteins Nutrition 0.000 claims description 10
- 108090000623 proteins and genes Proteins 0.000 claims description 10
- 102000004169 proteins and genes Human genes 0.000 claims description 10
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 239000011344 liquid material Substances 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 230000004913 activation Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000009965 odorless effect Effects 0.000 abstract description 3
- 231100000572 poisoning Toxicity 0.000 abstract description 3
- 230000000607 poisoning effect Effects 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000002153 concerted effect Effects 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000005543 nano-size silicon particle Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Abstract
nullThe invention discloses a kind of environment protection type multifunction architecture adhesive and preparation method thereof，Environment protection type multifunction architecture adhesive includes positive butanediol diglycidyl ether according to the raw material of weight portion、Epoxy resin、Natural rosin resins、Furfural acetone resin、Polyvinyl alcohol resin、Gypsum Fibrosum powder、Vinylacetate、Waterglass、Soybean protein isolate、Thiorubber.、Polyvinyl alcohol、Sodium silicate、Water tight packing、TMP、Antifreeze filler、Rubber toughening agent、Curing accelerator、Cross-linking agent、Ammonia and initiator，Water tight packing is metal-oxide、Nonmetal oxide、Metal acid salt、Metal base、Nonmetal acid salt or nonmetal alkali，The present invention has energy-conserving and environment-protective、Nontoxic、The feature of odorless，Will not be to production、User of service causes murder by poisoning，Gluing the strongest、Resistance to compression and tensile strength are high，Stable performance、Viscosity is relatively low、Easy to use，Film property and good waterproof performance，It is difficult to mouldy、Efficiency of construction is high、Service life is long.
Description
Technical field
The present invention relates to adhesive field, specifically a kind of environment protection type multifunction architecture adhesive and preparation method thereof.
Background technology
One of developing direction of China's adhesive, it is simply that the glue kind seriation of crude oil to be made, functionalization, glue kind newly developed should be specialization, high performance, to be applicable to each industry classification.The new demand that adhesive is proposed, no exception to Building Adhesive equally.
Building Adhesive is applied to each operation of building trade, or even each material, and it is probably divided into the following aspects: be applied to various construction；Application in interior/exterior decoration, finishing；The sealing use of various buildings, including door and window, big board wall, expansion joint, seam and extraordinary building etc.；Building maintenance, transform, reinforce and the application in reinforcement；The reinforcing of all kinds of means of transportation and hydraulic engineering and maintenance；Be widely used in composite building material produces that light weight, intensity is high, mostly function is the direction that composite building material develops；Being mixed and made into various high-performance with water and mix earth, this kind of application can provide high performance stock for building, solves traditional material and does not reaches the extraordinary many difficult problems required such as high-strength, quick-drying；Building adhesive can be also used for all many-sides such as road signs, dam leakproof, military engineering emergency maintenance, and leak stopping.
Human social development is to today; people are more and more higher to the requirement of environmental conservation; therefore thought, the selection of raw materials for production, the production process of adhesive and technique, the application of adhesive product in adhesive product design should be all environmental friendliness, nontoxic, harmless environment-friendly products; to reach the requirement that cleaning produces; not to environment; do not discharge the three wastes, fundamentally protect environment and the health of human body of producers and safety.
Summary of the invention
It is an object of the invention to provide a kind of energy-conserving and environment-protective, gluing strong environment protection type multifunction architecture adhesive and preparation method thereof of making a concerted effort, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of environment protection type multifunction architecture adhesive, include according to the raw material of weight portion: positive butanediol diglycidyl ether 80-100 part, epoxy resin 50-70 part, natural rosin resins 40-50 part, furfural acetone resin 40-50 part, polyvinyl alcohol resin 30-45 part, Gypsum Fibrosum powder 25-35 part, vinylacetate 20-25 part, waterglass 20-30 part, soybean protein isolate 15-25 part, thiorubber. 15-20 part, sodium silicate 10-15 part, water tight packing 10-15 part, TMP 10-12 part, antifreeze filler 10-12 part, rubber toughening agent 8-12 part, curing accelerator 5-10 part, cross-linking agent 3-8 part, ammonia 3-5 part, initiator 2-4 part.
As the further scheme of the present invention: described environment protection type multifunction architecture adhesive, include according to the raw material of weight portion: positive butanediol diglycidyl ether 90 parts, epoxy resin 60 parts, natural rosin resins 45 parts, furfural acetone resin 45 parts, polyvinyl alcohol resin 37 parts, Gypsum Fibrosum powder 30 parts, vinylacetate 22 parts, waterglass 25 parts, soybean protein isolate 20 parts, thiorubber. 18 parts, sodium silicate 12 parts, water tight packing 12 parts, TMP 11 parts, antifreeze filler 11 parts, rubber toughening agent 10 parts, curing accelerator 8 parts, cross-linking agent 5 parts, ammonia 4 parts, initiator 3 parts.
As the further scheme of the present invention: described water tight packing is metal-oxide, nonmetal oxide, metal acid salt, metal base, nonmetal acid salt or nonmetal alkali.
As the further scheme of the present invention: described antifreeze filler is the surface oxide through oxide, titanyl compound or the magnesium of the silicon of activation processing.
As the present invention further scheme: described initiator is Ammonium persulfate..
The preparation method of described environment protection type multifunction architecture adhesive, specifically comprises the following steps that
(1) by putting into after epoxy resin, natural rosin resins, furfural acetone resin and polyvinyl alcohol resin mix homogeneously, reactor is heated to 40-50 DEG C, adds positive butanediol diglycidyl ether, mix and blend 30-40min；
(2) adding water tight packing and antifreeze filler, stirring is until uniform filling is dispersed in liquid material；
(3) vinylacetate, thiorubber. and rubber toughening agent, mix and blend 10-15min are added；
(4) add polyvinyl alcohol resin, sodium silicate, TMP and curing accelerator, keep temperature to be 48-52 DEG C, stir 5-8min, sequentially add waterglass, ammonia, initiator and Gypsum Fibrosum powder, react 10-15min；
(5) being put into by soybean protein isolate in the water of 100-200 part, be warming up to 30-40 DEG C, add cross-linking agent after mix and blend 20-30min, stirring 3-5min obtains soybean isolated protein liquid；
(6) being added to reactor by soybean isolated protein liquid, cool the temperature to 20-30 DEG C while stirring, discharging obtains finished product.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention has energy-conserving and environment-protective, nontoxic, the feature of odorless, will not to producing, user of service cause murder by poisoning, gluing make a concerted effort strong, resistance to compression and tensile strength high, stable performance, viscosity are relatively low, easy to use, film property and good waterproof performance, be difficult to mouldy, efficiency of construction is high, service life is long.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the technical scheme of this patent is described in more detail.
Embodiment 1
A kind of environment protection type multifunction architecture adhesive, includes according to the raw material of weight portion: positive butanediol diglycidyl ether 80 parts, epoxy resin 50 parts, natural rosin resins 40 parts, furfural acetone resin 40 parts, polyvinyl alcohol resin 30 parts, Gypsum Fibrosum powder 25 parts, vinylacetate 20 parts, waterglass 20 parts, soybean protein isolate 15 parts, thiorubber. 15 parts, sodium silicate 10 parts, silica flour 10 parts, TMP 10 parts, super-fine silicon micro-powder 10 parts, rubber toughening agent 8 parts, curing accelerator 5 parts, cross-linking agent 3 parts, ammonia 3 parts, Ammonium persulfate. 2 parts.
The preparation method of described environment protection type multifunction architecture adhesive, specifically comprises the following steps that
(1) by putting into after epoxy resin, natural rosin resins, furfural acetone resin and polyvinyl alcohol resin mix homogeneously, reactor is heated to 40 DEG C, adds positive butanediol diglycidyl ether, mix and blend 30min；
(2) adding silica flour and super-fine silicon micro-powder, stirring is until uniform filling is dispersed in liquid material；
(3) vinylacetate, thiorubber. and rubber toughening agent, mix and blend 10min are added；
(4) adding polyvinyl alcohol resin, sodium silicate, TMP and curing accelerator, keeping temperature is 48 DEG C, stirs 5min, sequentially adds waterglass, ammonia, Ammonium persulfate. and Gypsum Fibrosum powder, reacts 10min；
(5) being put into by soybean protein isolate in the water of 100 parts, be warming up to 30 DEG C, add cross-linking agent after mix and blend 20min, stirring 3min obtains soybean isolated protein liquid；
(6) being added to reactor by soybean isolated protein liquid, cool the temperature to 20 DEG C while stirring, discharging obtains finished product.
Embodiment 2
A kind of environment protection type multifunction architecture adhesive, includes according to the raw material of weight portion: positive butanediol diglycidyl ether 90 parts, epoxy resin 60 parts, natural rosin resins 45 parts, furfural acetone resin 45 parts, polyvinyl alcohol resin 37 parts, Gypsum Fibrosum powder 30 parts, vinylacetate 22 parts, waterglass 25 parts, soybean protein isolate 20 parts, thiorubber. 18 parts, sodium silicate 12 parts, mica powder 12 parts, TMP 11 parts, nano titanium oxide 1 part, rubber toughening agent 10 parts, curing accelerator 8 parts, cross-linking agent 5 parts, ammonia 4 parts, Ammonium persulfate. 3 parts.
The preparation method of described environment protection type multifunction architecture adhesive, specifically comprises the following steps that
(1) by putting into after epoxy resin, natural rosin resins, furfural acetone resin and polyvinyl alcohol resin mix homogeneously, reactor is heated to 45 DEG C, adds positive butanediol diglycidyl ether, mix and blend 35min；
(2) adding mica powder and nano titanium oxide, stirring is until uniform filling is dispersed in liquid material；
(3) vinylacetate, thiorubber. and rubber toughening agent, mix and blend 12min are added；
(4) adding polyvinyl alcohol resin, sodium silicate, TMP and curing accelerator, keeping temperature is 50 DEG C, stirs 6min, sequentially adds waterglass, ammonia, Ammonium persulfate. and Gypsum Fibrosum powder, reacts 12min；
(5) being put into by soybean protein isolate in the water of 150 parts, be warming up to 35 DEG C, add cross-linking agent after mix and blend 25min, stirring 4min obtains soybean isolated protein liquid；
(6) being added to reactor by soybean isolated protein liquid, cool the temperature to 25 DEG C while stirring, discharging obtains finished product.
Embodiment 3
A kind of environment protection type multifunction architecture adhesive, includes according to the raw material of weight portion: positive butanediol diglycidyl ether 100 parts, epoxy resin 70 parts, natural rosin resins 50 parts, furfural acetone resin 50 parts, polyvinyl alcohol resin 45 parts, Gypsum Fibrosum powder 35 parts, vinylacetate 25 parts, waterglass 30 parts, soybean protein isolate 25 parts, thiorubber. 20 parts, sodium silicate 15 parts, titanium dioxide 15 parts, TMP 12 parts, nano-silicon nitride 12 parts, rubber toughening agent 12 parts, curing accelerator 10 parts, cross-linking agent 8 parts, ammonia 5 parts, Ammonium persulfate. 4 parts.
The preparation method of described environment protection type multifunction architecture adhesive, specifically comprises the following steps that
(1) by putting into after epoxy resin, natural rosin resins, furfural acetone resin and polyvinyl alcohol resin mix homogeneously, reactor is heated to 50 DEG C, adds positive butanediol diglycidyl ether, mix and blend 40min；
(2) adding titanium dioxide and nano-silicon nitride, stirring is until uniform filling is dispersed in liquid material；
(3) vinylacetate, thiorubber. and rubber toughening agent, mix and blend 15min are added；
(4) adding polyvinyl alcohol resin, sodium silicate, TMP and curing accelerator, keeping temperature is 52 DEG C, stirs 8min, sequentially adds waterglass, ammonia, Ammonium persulfate. and Gypsum Fibrosum powder, reacts 15min；
(5) being put into by soybean protein isolate in the water of 200 parts, be warming up to 40 DEG C, add cross-linking agent after mix and blend 30min, stirring 5min obtains soybean isolated protein liquid；
(6) being added to reactor by soybean isolated protein liquid, cool the temperature to 30 DEG C while stirring, discharging obtains finished product.
The present invention has energy-conserving and environment-protective, nontoxic, the feature of odorless, will not to producing, user of service cause murder by poisoning, gluing make a concerted effort strong, resistance to compression and tensile strength high, stable performance, viscosity are relatively low, easy to use, film property and good waterproof performance, be difficult to mouldy, efficiency of construction is high, service life is long.
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment, in the ken that one skilled in the relevant art is possessed, it is also possible to various changes can be made on the premise of without departing from this patent objective.
Claims (6)
1. an environment protection type multifunction architecture adhesive, it is characterized in that, include according to the raw material of weight portion: positive butanediol diglycidyl ether 80-100 part, epoxy resin 50-70 part, natural rosin resins 40-50 part, furfural acetone resin 40-50 part, polyvinyl alcohol resin 30-45 part, Gypsum Fibrosum powder 25-35 part, vinylacetate 20-25 part, waterglass 20-30 part, soybean protein isolate 15-25 part, thiorubber. 15-20 part, sodium silicate 10-15 part, water tight packing 10-15 part, TMP 10-12 part, antifreeze filler 10-12 part, rubber toughening agent 8-12 part, curing accelerator 5-10 part, cross-linking agent 3-8 part, ammonia 3-5 part, initiator 2-4 part.
Environment protection type multifunction architecture adhesive the most according to claim 1, it is characterized in that, described environment protection type multifunction architecture adhesive, include according to the raw material of weight portion: positive butanediol diglycidyl ether 90 parts, epoxy resin 60 parts, natural rosin resins 45 parts, furfural acetone resin 45 parts, polyvinyl alcohol resin 37 parts, Gypsum Fibrosum powder 30 parts, vinylacetate 22 parts, waterglass 25 parts, soybean protein isolate 20 parts, thiorubber. 18 parts, sodium silicate 12 parts, water tight packing 12 parts, TMP 11 parts, antifreeze filler 11 parts, rubber toughening agent 10 parts, curing accelerator 8 parts, cross-linking agent 5 parts, ammonia 4 parts, initiator 3 parts.
Environment protection type multifunction architecture adhesive the most according to claim 1, it is characterised in that described water tight packing is metal-oxide, nonmetal oxide, metal acid salt, metal base, nonmetal acid salt or nonmetal alkali.
Environment protection type multifunction architecture adhesive the most according to claim 1, it is characterised in that described antifreeze filler is the surface oxide through oxide, titanyl compound or the magnesium of the silicon of activation processing.
Environment protection type multifunction architecture adhesive the most according to claim 1, it is characterised in that described initiator is Ammonium persulfate..
6. the preparation method of the environment protection type multifunction architecture adhesive as described in claim 1 is arbitrary, it is characterised in that specifically comprise the following steps that
(1) by putting into after epoxy resin, natural rosin resins, furfural acetone resin and polyvinyl alcohol resin mix homogeneously, reactor is heated to 40-50 DEG C, adds positive butanediol diglycidyl ether, mix and blend 30-40min；
(2) adding water tight packing and antifreeze filler, stirring is until uniform filling is dispersed in liquid material；
(3) vinylacetate, thiorubber. and rubber toughening agent, mix and blend 10-15min are added；
(4) add polyvinyl alcohol resin, sodium silicate, TMP and curing accelerator, keep temperature to be 48-52 DEG C, stir 5-8min, sequentially add waterglass, ammonia, initiator and Gypsum Fibrosum powder, react 10-15min；
(5) being put into by soybean protein isolate in the water of 100-200 part, be warming up to 30-40 DEG C, add cross-linking agent after mix and blend 20-30min, stirring 3-5min obtains soybean isolated protein liquid；
(6) being added to reactor by soybean isolated protein liquid, cool the temperature to 20-30 DEG C while stirring, discharging obtains finished product；The polyvinyl alcohol resin 20-25 part wherein added in step 1, the polyvinyl alcohol resin 10-20 part added in step 4.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105175638A (en) * | 2015-11-05 | 2015-12-23 | 贵州遵义铭东商贸有限公司 | Building adhesive and preparation method thereof |
| CN106047279B (en) * | 2016-05-25 | 2018-02-13 | 合肥东彩印刷科技有限公司 | A kind of metal material epoxy adhesive |
| CN108251049A (en) * | 2018-03-02 | 2018-07-06 | 合肥欧仕嘉机电设备有限公司 | A kind of novel building field adhesive and preparation method thereof |
| CN110606706B (en) * | 2019-11-05 | 2022-12-23 | 浙江沃瑞科技有限公司 | Waterproof mortar and preparation method thereof, and mortar additive material and preparation method thereof |
| CN111219022A (en) * | 2020-01-10 | 2020-06-02 | 上海建为历保科技股份有限公司 | Construction method of terrazzo stair tread anti-slip copper strip |
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| "改性环氧树脂建筑结构胶研制与发展";贺曼罗;《热固性树脂》;19931231(第4期);第56-68页 * |
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| CN104592914A (en) | 2015-05-06 |
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