CN104585355A - Double-layer equilibrium edible vegetable blend oil and preparation method thereof - Google Patents
Double-layer equilibrium edible vegetable blend oil and preparation method thereof Download PDFInfo
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Abstract
The invention provides double-layer equilibrium edible vegetable blend oil and a preparation method thereof. The fatty acid in the double-layer equilibrium edible vegetable blend oil comprises omega-3 fatty acid and omega-6 fatty acid in mass ratio of 1 to (2.5-3.5), wherein the fatty acid comprises 10 to 18wt% of omega-3 fatty acid; the total content of omega-3 fatty acid and omega-6 fatty acid in the double-layer equilibrium edible vegetable blend oil is 40 to 72wt%; the double-layer equilibrium edible vegetable blend oil has AOM value not less than 10. The invention further provides the preparation method of the double-layer equilibrium edible vegetable blend oil. According to the double-layer equilibrium edible vegetable blend oil and the preparation method of the double-layer equilibrium edible vegetable blend oil, the problem of unreasonable proportion of essential fatty acid in the general vegetable oil can be solved, and the practical significance on avoiding of heart disease and other diseases due to cell disordering caused by serious imbalance in ratio of omega-3 fatty acid to omega-6 fatty acid as well as improvement on national health level is great; the preparation method is simple, the industrialization is easy, and the blend oil and the preparation method have reference significance on formulating of national standard for edible blend oil.
Description
Technical field
The present invention relates to a kind of edible vegetable blend oil and preparation method thereof, particularly relate to a kind of double-deck balanced edible vegetable blend oil and preparation method thereof, belong to food processing preparing technical field.
Background technology
In September, 1977, FAO (Food and Agriculture Organization of the United Nation) and the World Health Organization (FAO/WHO) have held in Rome and have been entitled as " dietary fat in human nutrition " scientific seminar, and conference first time proposes the concept about balanced fatty acid.In current conference, the ratio that expert proposes saturated fatty acid in dietary fat, monounsaturated fatty acids and polyunsaturated fatty acid should be l:l:l, but this ratio is not recommended as the final conclusion of conference.After the meeting, extensively recommended as a kind of dietary standard by the nutritionist of some countries about dietary fatty acid " 1:l:l ".
2000, Chinese Soclety of Nutrition was while suggestion Chinese residents dietary fat is suitable for intake (AI), and the suitable absorption ratio giving two kinds of essential fatty acid omega-fatty acids and ω-6 aliphatic acid is 1:4-6.Based on this concept, afterwards for many years in, " edible vegetable blend oil " research and development and Related product are as emerged rapidly in large numbersBamboo shoots after a spring rain, emerge in an endless stream, apply for that also disclosed relevant Chinese patent application just reaches 214, wherein production technology patent application 120 remainder, cause the confusion of edible vegetable blend oil produce market to be grown thickly, but national standard is not yet put into effect.
" edible vegetable blend oil " national standard was formulated from 2005, and within 2008, exposure draft completes, and submitted to national grain and oil technical committee for standardization (TCST) to authorize.So far the national standard of edible blend oil still " in formulation ".Wherein, topmost reason is that correlation technique detection means is not enough.The main component of various oils is all triglycerides, fatty acid structure composition difference is little, ready-mixed oil is once blend, can only be told by detecting instrument and whether plant containing specific oil, concrete ratio is difficult to detect, the standard of current edible vegetable blend oil proportioning many dependences enterprise oneself and conscience behavior.
Modern scientific research finds, humoral factor-arachidonic acid series important in the lipid material in food and body is closely related.These are a series of mainly comprises prostaglandin, thromboxane, leukotrienes etc.These humoral factors can cause blood vessel embolism, cause cerebral function to go down and various inflammatory reaction, headache, malignant tumour etc.And the primary raw material synthesizing these factors is lipid factor ω-6 aliphatic acid in food.In contrast, omega-fatty acid be then converted in vivo some can anti-platelet aggregation, vasodilator, improve cerebral function, reduce inflammation reaction and avoid the material such as DHA and EPA of cellular damage.If take in ω-6 aliphatic acid in a large number, and omega-fatty acid takes in wretched insufficiency, omega-fatty acid and ω-6 fatty acid proportion numerous imbalances will be caused, this causes cell functional disorders, and then cardiac trigger is sick, diabetes, one of reason of the various diseases such as cancer, Aging and arthritis.So scientifically adjusting the ratio of ω-6 aliphatic acid and omega-fatty acid in edible vegetable oil, is a kind of trend of health diet.
For the ratio of ω-6 aliphatic acid and omega-fatty acid in adjustment edible vegetable oil, there is the saturated fatty acid (SFA) adjusted in plant blend oil at present: monounsaturated fatty acids (MUSFA): polyunsaturated fatty acid is to 1:1:1, and technological means for the purpose of ω-6 and ω-3 essential fatty acid ratio to 4-6:1.Wherein, CN1448061A " the rational plant blend oil of a kind of fatty acid proportion ", CN101069532A " linoleic acid is 4:1 ready-mixed oil with the ratio of leukotrienes ", CN101690526A " being mixed with the ready-mixed oil of balanced fatty acid proportion by walnut oil and other vegetable oil ", CN102742675A " a kind of edible vegetable blend oil balanced in nutrition ", CN101502290A " a kind of nutrient blend oil of balanced fatty acid proportion ", CN101715840A " a kind of edible vegetable blend oil with balanced fatty acid ", CN100546487 " nutritional balanced mixed oil ", CN102742671A " nutrient plant blend oil ", CN102599269A " a kind of plant blend oil " etc.In addition, " the microcomputer modelling method development nutrition rice ready-mixed oil " of Zhang Zhi (2014), " formula Design of Novel edible ready-mixed oil and the analysis " of Xie Yanli (2009), " research of nutrient balance edible blend oil " of Hu Xiaojun (2011), " formulating of nutrient blend oil " of Zhang Zesheng (2008), " foundation of nutritional type plant ready-mixed oil formula Mathematical Modeling and the application " of Li Xinhua (2010), " research of the rational ready-mixed oil of Fatty acids composition " of Hu Xiaojun (2006), " the golden ratio model of purple perilla ready-mixed oil and the factory formula " of Ma Zuo army (2012), research work such as " investigation of dietary fatty acid balance and the researchs of nutritional balanced mixed oil " of topaz China (2007) all belongs to this type of technology.
Although technique scheme is had nothing in common with each other, but all to adjust the saturated fatty acid (SFA) in plant blend oil: monounsaturated fatty acids (MUSFA): polyunsaturated fatty acid is to 1:1:1, and ω-6 is be for the purpose of essential fatty acid ratio to 4-6:1 with ω-3.Saturated fatty acid (SFA): monounsaturated fatty acids (MUSFA): polyunsaturated fatty acid=1:1:1 refers to the ratio of three kinds of aliphatic acid in human body dietary int ake every day lipoid substance, in actual life, no matter which class crowd can not take in animal fat, completely so 1:1:1 edible vegetable blend oil does not exist realistic meaning; Equally, Chinese staple food is rice and wheat flour substantially, no matter how meticulous processing, wherein all can contain the fat of about 1-1.5%, and ω-3 is that aliphatic acid is almost nil in these fat, the absorption being not aliphatic acid cereal grease containing ω-3 of every day 3-5 gram is just enough to break the balance of 4-6:1.
At present, also have to improve the preparation that ω-9 is the plant blend oil for the purpose of content of fatty acid, because be aliphatic acid based on ω-9 in the aliphatic acid composition of thing from abroad olive oil, and, olive oil fancy price and propagandized out the health-care effect of " Mediterranean diet ", cause a lot of producer even research institution go after like a flock of ducks.Wherein, CN101664078A " a kind of ready-mixed oil and preparation method thereof ", CN102165976A " a kind of vigor nutritional balanced mixed oil ", CN101926394A " a kind of edible blend oil of good stability " all disclose technique scheme.
But ω-9 is aliphatic acid is not essential fatty acid, for a long time uninterruptedly being that the ready-mixed oil that aliphatic acid is main fatty acid eats as cooking oil using ω-9, essential fatty acid certainly will be caused to lack phenomenon.
Also there is the plant blend oil that some add health-care efficacy composition at present.Wherein, what CN103005009A " a kind of functional nutrient ready-mixed oil " provided is exactly a kind of edible health-care oil.
But the health-care efficacy claimed must be verified by national Notified body and just can produce after being approved for health food, and product must be specific crowd, can not be popular.
And some add the plant blend oil of DHA.The DHA derived from deep sea fish oil and algae oil has health-care efficacy significantly, domestic market there is the ready-mixed oil adding DHA, such as CN101142947A " a kind of nutrition balanced mixed oil and production method thereof containing fish oil or Fish oil ", CN101822295A " a kind of ready-mixed oil of balanced fatty acid and production method thereof " etc.Correlative study has: " algal oil, fish oil and DHA ready-mixed oil be the DHA loss research in gastronomical process " of Cao Wanxin (2011), " frying adds the ready-mixed oil of deep sea fish oil to the safety research of SD rat " of Chen Qi (2014) etc.
But the oxidation stability technology of adding the plant blend oil of DHA not yet breaks through, and the shelf-life of product is too short.
In sum, provide a kind of essential fatty acid to take in balanced, the plant blend oil that oxidation stability is good is this area technical problem urgently to be resolved hurrily.
Summary of the invention
In order to solve the problems of the technologies described above, the object of the present invention is to provide a kind of double-deck edible vegetable blend oil with balanced and preparation method thereof, double-deck edible vegetable blend oil with balanced of the present invention meets the requirement of our people to omega-fatty acid and ω-6 aliphatic acid intake, its preparation method is simple, is easy to suitability for industrialized production.
In order to achieve the above object, the invention provides a kind of double-deck edible vegetable blend oil with balanced, in this double-deck edible vegetable blend oil with balanced, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:2.5-3.5, and the content of omega-fatty acid is 10wt%-18wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 40wt%-72wt%, and the AOM value of double-deck edible vegetable blend oil with balanced is not less than 10; Be preferably 10-20.
Active oxygen method (AOM) is Fast Measurement and the internationally recognized method evaluating edible oil and fat oxidation stabilities, and measurement result is hour to represent, AOM value is higher, and edible oil oxidation stability is better.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, this double-deck edible vegetable blend oil with balanced comprises matrix edible vegetable oil, linseed oil, adjustment oil and natural VE, wherein, the addition of adjustment oil is the 0wt%-0.1wt% of double-deck edible vegetable blend oil with balanced total amount, and the addition of described natural VE is the 0.03wt%-0.1wt% of double-deck edible vegetable blend oil with balanced total amount.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, described matrix edible vegetable oil comprises the combination of one or more in soybean oil, rapeseed oil, peanut oil, corn oil and sunflower oil.
The soybean oil that the present invention adopts is that (in soybean oil, the mass content of ω-3 essential fatty acid is 5.0-11.0% to the one-level cold press/leaching soybean oil complied with the national standard requirements, the mass content of ω-6 essential fatty acid is 49.8-59%), rapeseed oil is that (in rapeseed oil, the mass content of ω-3 essential fatty acid is 3.0-9.0% to one-level cold press/leaching rapeseed oil, the mass content of ω-6 essential fatty acid is 15.0-30.0%), peanut oil is that (in peanut oil, the mass content of ω-3 essential fatty acid is 0.0-0.3% to one-level cold press/extracted peanut oil, the mass content of ω-6 essential fatty acid is 13.0-43.0%), corn oil is that (in corn oil, the mass content of ω-3 essential fatty acid is 0-2% to one-level cold press/leaching corn oil, the mass content of ω-6 essential fatty acid is 34.0-65.5%), sunflower oil is that (in sunflower oil, the mass content of ω-3 essential fatty acid is 0-0.3% to one-level cold press/leaching sunflower oil, the mass content of ω-6 essential fatty acid is 48.3-74.0%), linseed oil is that (in linseed oil, the mass content of ω-3 essential fatty acid is 39.0-62.0% to one-level cold pressed flax seed oil, the mass content of ω-6 essential fatty acid is 12.0-30.0%).
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of linseed oil is A, the consumption of matrix edible vegetable oil is B, in double-deck edible vegetable blend oil with balanced, the content of omega-fatty acid is ω-3, the content of ω-6 aliphatic acid is ω-6, A+B=1000, and (ω-6 × A+ ω-6 × B)/(ω-3 × A+ ω-3 × B)=3.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of matrix edible vegetable oil and linseed oil is soybean oil 751-855 kilogram, linseed oil 145-249 kilogram.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of matrix edible vegetable oil and linseed oil is peanut oil 744-839 kilogram, linseed oil 161-256 kilogram.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of matrix edible vegetable oil and linseed oil is rapeseed oil 744-839 kilogram, linseed oil 161-256 kilogram.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of matrix edible vegetable oil and linseed oil is corn oil 744-839 kilogram, linseed oil 161-256 kilogram.
In double-deck edible vegetable blend oil with balanced provided by the invention, preferably, in every 1000 kilograms of double-deck edible vegetable blend oil with balanced, the consumption of matrix edible vegetable oil and linseed oil is sunflower oil 744-839 kilogram, linseed oil 161-256 kilogram.
The adjustment oil adopted in double-deck edible vegetable blend oil with balanced provided by the invention can be the combination of each Plants, such as, the combination of one or more in rapeseed oil, walnut oil, corn oil, sunflower oil, peanut oil, olive oil, sesame oil, rice bran oil.
Present invention also offers the preparation method of above-mentioned double-deck edible vegetable blend oil with balanced, this preparation method comprises the following steps:
By appropriate matrix edible vegetable oil and linseed oil mixing, add simultaneously and regulate oil and natural VE;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, the mass ratio selecting omega-fatty acid and ω-6 aliphatic acid in the aliphatic acid composition of product oil is 1:2.5-3.5, and the content of omega-fatty acid is 10wt%-18wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are that 40wt%-72wt%, AOM value is not less than the product oil of 10 for described double-deck edible vegetable blend oil with balanced.
According to the specific embodiment of the present invention, carry out analysis to product oil in concrete preparation process and measure, the testing result as fruit product oil does not reach requirement, then re-start allotment, until obtain satisfactory product.
According to the specific embodiment of the present invention, in concrete preparation process, linseed oil is kept in nitrogen atmosphere for subsequent use.
The present invention adopts soybean oil (accounting for 51.7% of edible oil total quantity consumed), rapeseed oil (accounting for 22.9% of edible oil total quantity consumed), peanut oil (accounting for 5.8% of edible oil total quantity consumed), in corn oil (accounting for 3.8% of edible oil total quantity consumed) and sunflower oil (accounting for 1.0% of edible oil total quantity consumed) one or more be combined as matrix edible vegetable oil, with the proportion adjustment agent that the linseed oil being rich in ω-3 essential fatty acid is ω-3 essential fatty acid and ω-6 essential fatty acid, add a small amount of other plant oil simultaneously, in order to improve local flavor and the mouthfeel of this double-deck edible vegetable blend oil with balanced, produce while basic maintenance matrix edible vegetable oil characteristic index does not have substantial variations ready-mixed oil, guarantee that the ratio of ω-3 essential fatty acid and ω-6 essential fatty acid in ready-mixed oil is 1:2.5-3.5, and ω-3 essential fatty acid content is 10%-18%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 40wt%-72wt%, the AOM value of double-deck edible vegetable blend oil with balanced is not less than the plant blend oil of 10.
" ground floor " in " bilayer " of double-deck edible vegetable blend oil with balanced provided by the invention is the ratio of omega-fatty acid and ω-6 aliphatic acid is 1:2.5-3.5 (preferred 1:3); " second layer " refers to content >=10% of omega-fatty acid, and total amount >=40% of omega-fatty acid and ω-6 aliphatic acid; Ensure that double-deck edible vegetable blend oil with balanced has good oxidation stability simultaneously.
" Chinese residents nutrition and Health Situation " that Ministry of Health of the People's Republic of China, Ministry of Science & Technique of PRC, National Bureau of Statistics of the People's Republic of China (2004) issue shows, and takes in fat mass per day for human beings just reach 85.6 grams as far back as China town dweller in 2002." Chinese adult resident edible oil current condition of consumption " (Ma Guansheng, Hao Linan, Li Yan equality, Chinese food and nutrition, 2008,9,29-32) use these data, to 25556 families, the consumption of totally 50425 18 years old and above resident's edible oils is analyzed, result shows, the average edible oil for each person every day for cooking consumption of China's adult residents has reached 40g, and (city dweller is 38g, and urban residents are 42g; Two class rural areas are up to 44g, and small and medium-sized cities are minimum is 37g), wherein (city dweller is 35g to vegetable oil 32g, and urban residents are 31g; Big city is up to 39g, and four class rural areas are minimum is 20g), (city dweller is 3g to animal oil 8g, and urban residents are 11g; Four class rural areas are up to 20g); The male sex is 44g, and women is 38g.Draw: China's adult residents on average consumes salad oil 9g, rapeseed oil 8g, soybean oil 8g, peanut oil 5g, lard 3g, other edible oils 5g for each person every day simultaneously, the ratio of consuming rapeseed oil, lard (refining), peanut oil, salad oil, soya-bean oil, sesame oil and siritch in China's residential households is followed successively by 33.5%, 29.0%, 16.8%, 13.8%, 13.5%, 10.3% and 3.8%, and rapeseed oil and lard are the high and edible oil kinds of often consumption of China's adult residents consumption figure.The ratio that China's adult residents edible oil exceedes Chinese residents dietary guidelines recommended amounts reaches 65.2%; The male sex, higher than women, is respectively 67.4% and 63.2%; City and country is close, is respectively 65.3% and 65.1%; Two class rural areas are higher is 72.8%, four class rural areas minimum (59.3%).Totally it seems, the consumption figure of China resident edible oil is higher, and edible oil kind is more single, and the consumption of urban residents' animal oil is on the high side.
" between Chinese residents 20 years, food fat acid is taken the photograph people and measured investigation and analysis " (Deng Zeyuan, Zhou Xiaoqi, topaz China etc., food and biotechnology journal, 2008,27 (1), 7-18) on the basis of 1982,1992 and 2002 Chinese Diet survey datas, in conjunction with kind and the quantity of analysis of statistical data Chinese residents meals, utilize gas Chromatographic Determination food fat acid content, calculate and take in dietary fat acid content every day.Result shows, in these 20 years, take in total fatty acid content in Chinese residents meals significantly to raise, the ratio of saturated fatty acid raises, and the absorption ratio of monounsaturated fatty acids and polyunsaturated fatty acid declines, born of the same parents and aliphatic acid (SFA): monounsaturated fatty acids (MUFA): polyunsaturated fatty acid (PUFA) is in zone of reasonableness, but ω-3/ ω-6 changes very unobvious, between 1:8.8-1:9.56, do not reach more suitable ratio.
" the sour intake investigation and analysis of China six big city resident's edible vegetable oil fat " (Deng Bin, Shang Gang, Ji Zhenjie, Chinese oil, 2013,38 (5), 48-50) according to the difference of China's the North and South cooking culture, respectively the absorption ratio of edible vegetable oil and the intake of aliphatic acid in resident's meals in six, north and south representative cities and Beijing, Shenyang, Shanghai, Chongqing, Xi'an, Guangzhou are investigated.Analyze by inquiry and draw: ω-6 aliphatic acid that in six city dweller's meals every day, edible vegetable oil provides and omega-fatty acid ratio, only Xi'an is 4.4:1, meets the suitable proportion of 4-6:1, and other cities are 7-13:1; The ratio of the saturated fatty acid (SFA) in six city dweller's meals in edible vegetable oil, monounsaturated fatty acids (MUFA), polyunsaturated fatty acid (PUFA) three does not all reach suitable proportion (1:1:1) (see table 1 and table 2).
The intake of table 1 six city dweller edible vegetable oil accounts for the ratio (%) of total vegetable oil
Title | Shanghai | Guangzhou | Chongqing | Xi'an | Beijing | Shenyang |
Corn oil | 8.6 | 10.2 | 0.7 | 1.9 | 5.7 | 3.7 |
Rapeseed oil | 2.2 | 1.1 | 64.7 | 36.4 | 0.0 | 0.0 |
Peanut oil | 3.1 | 41.0 | 1.0 | 6.4 | 17.7 | 17.8 |
Soybean oil | 49.3 | 2.2 | 6.8 | 8.1 | 40.5 | 18.2 |
Sunflower oil | 9.8 | 5.4 | 1.1 | 3.0 | 5.4 | 4.0 |
Ready-mixed oil | 23.6 | 38.4 | 22.5 | 42.7 | 24.9 | 54.0 |
Olive oil | 0.2 | 0.3 | 0.1 | 0.1 | 0.4 | 0.3 |
Sesame oil | 1.3 | 0.8 | 3.1 | 1.4 | 4.2 | 1.7 |
The aliphatic acid intake of table 2 six city dweller edible vegetable oil and ratio
City | SFA% | MUSFA% | PUSFA% | m(SFA):m(MUSFA):m(PUSFA) | m(ω-3):m(ω-6) |
Shenyang | 15.04 | 39.06 | 45.59 | 0.39:1:1.17 | 1:7.2 |
Shanghai | 14.51 | 30.14 | 53.45 | 0.48:1:1.77 | 1:9.6 |
Xi'an | 11.68 | 49.63 | 38.65 | 0.24:1:0.78 | 1:4.4 |
Guangzhou | 15.80 | 42.94 | 40.49 | 0.37:1:0.94 | 1:12.8 |
Chongqing | 9.16 | 55.18 | 35.64 | 0.17:1:0.65 | 1:3 |
Beijing | 14.88 | 33.78 | 49.24 | 0.44:1:1.46 | 1:9.9 |
As can be seen from Table 1, people from Chongqing likes eating rapeseed oil, people of Guangzhou likes eating peanut oil.Simultaneously, also can find out, ready-mixed oil has occupied suitable ratio in the consumption of six big city residents, and the resident in Shenyang is up to 54%,, in their edible vegetable oil, the ratio of two kinds of essential fatty acids (omega-fatty acid and ω-6 aliphatic acid) is still 1:7.2.
Two kinds in double-deck edible vegetable blend oil with balanced provided by the invention must the ratio of aliphatic acid (omega-fatty acid and ω-6 aliphatic acid) be 1:2.5-3.5 (preferred 1:3), " double-deck balanced " ready-mixed oil series is proposed simultaneously: " double-deck balanced " soybean ready-mixed oil, " double-deck balanced " peanut ready-mixed oil, " double-deck balanced " vegetable seed ready-mixed oil, " double-deck balanced " sunflower seeds ready-mixed oil, " double-deck balanced " corn mediation wet goods, this a series of " double-deck balanced " ready-mixed oil can according to different geographical, different crowd is to the consumption habit of edible vegetable oil, make consumer when selecting oil for cooking, not only can select corresponding " double-deck balanced " edible vegetable blend oil according to the eating habit of oneself, and only need this ready-mixed oil of 50% selection, other vegetable oil can be selected according to oneself original hobby, just can reach the object effectively regulating balanced fatty acid, as shown in table 3, table 3 is the adjustment carried out on table 1 basis.
After table 3 adjusts, the intake of six city dweller's edible vegetable oils accounts for the ratio (%) of total vegetable oil
" the sour intake investigation and analysis of China six big city resident's edible vegetable oil fat " (Deng Bin, Shang Gang, Ji Zhenjie, Chinese oil, 2013,38 (5), 48-50) six city dwellers are taken in aliphatic acid intake and the ratio (see table 4) of the rear six city dweller's edible vegetable oils of Analysis result calculation acquisition adjustment of edible vegetable oil fat acid content.
Table 4 adjusts aliphatic acid intake and the ratio of rear six city dweller's edible vegetable oils
City | ω-3(%) | ω-6(%) | PUSFA total amount (%) | m(ω-3):m(ω-6) |
Shenyang | 10.27 | 47.72 | 57.99 | 1:4.65 |
Shanghai | 9.72 | 49.45 | 59.17 | 1:5.09 |
Xi'an | 11.34 | 39.72 | 51.06 | 1:3.50 |
Guangzhou | 6.43 | 37.26 | 43.69 | 1:5.79 |
Chongqing | 9.24 | 30.90 | 40.14 | 1:3.34 |
Beijing | 9.11 | 45.86 | 54.974 | 1:5.03 |
As can be seen from Table 4, after adjustment, the resident in six cities eats and takes in vegetable oil that two kinds of essential fatty acids are substantially all at the optimum range of 1:4-6, and this is the ground floor object that " double-deck balanced " of the present invention edible vegetable blend oil reaches.
As can be seen from the aliphatic acid intake of six city dweller's edible vegetable oils in table 2 and the data of ratio, although the ratio of two kinds of essential fatty acid omega-fatty acids and ω-6 aliphatic acid reaches that 1:3 and 1:4.4 is this seems suitable ratio respectively in the edible vegetable oil that Chongqing, Xi'an resident take in, but, polyunsaturated fatty acid (two kinds of essential fatty acids) total amount is respectively 35.64% and 38.65%, does not all reach the minimum total amount of 40%.Trace it to its cause, mainly two places resident all with rapeseed oil, ready-mixed oil for mainly to cook edible vegetable oil, the ratio that Chongqing resident takes in rapeseed oil, ready-mixed oil accounts for total vegetable oil is respectively 64.7% and 22.5%, and the ratio that Xi'an resident takes in rapeseed oil, ready-mixed oil accounts for total vegetable oil is respectively 36.4% and 42.7% (see table 2).
By making content >=10% of omega-fatty acid wherein in double-deck edible vegetable blend oil with balanced provided by the invention, and total amount >=40% of omega-fatty acid and ω-6 aliphatic acid, the ready-mixed oil obtained is made to meet the dietary of our people and the absorption of two kinds of aliphatic acid can be made balanced, meet the requirement of rational diet, this is also the second layer object of double-deck edible vegetable blend oil with balanced provided by the invention.
As can be seen from the common edible vegetable oil unrighted acid composition that table 5 provides, most of edible vegetable oil is hardly containing omega-fatty acid, and the essential fatty acid insufficient total amount 40% of the larger edible vegetable oil of partial consumption amount.Oxidized value represents food plant oil oxidation stability, oxidized value is higher, poorer (the Rossi M of food plant oil oxidation stability, Alamprese C, Ratti is and tocotrienols as freeradical-scavengers in refined vegetable oils and their stability during deep-fat frying.FoodChemistry S.2007.Tocopherols, (102), 812-817).As can be seen from the oxidized value of the common edible vegetable oil that table 5 provides, although be rich in omega-fatty acid in Purple Perilla Seed Oil and linseed oil, because oxidized value is too high, when adding high-load, high performance antioxidation agent, oxidation stability still can not meet the requirement of shelf-life.
Table 5 common edible vegetable oil unrighted acid composition and oxidized value thereof
In double-deck edible vegetable blend oil with balanced of the present invention, omega-fatty acid content is 10%-18%, the total content of two kinds of essential fatty acids (omega-fatty acid and ω-6 aliphatic acid) is 40%-72%, be aided with natural VE as antioxidant, there is good oxidation stability, can preserve for a long time.
Double-deck edible vegetable blend oil with balanced of the present invention and linseed oil, one-level soybean oil are sent out respectively by active oxidation and measures respective AOM value, as shown in Figure 2, Figure 3 and Figure 4, Fig. 2 is the AOM curve that the active oxygen method of linseed oil measures, Fig. 3 is the AOM curve that the active oxygen method of one-level soybean oil measures, and Fig. 4 is the AOM curve that the active oxygen method of double-deck equalize plant ready-mixed oil measures.Can be found out by Fig. 2, Fig. 3 and Fig. 4, the AOM value of linseed oil, one-level soybean oil, double-deck edible vegetable blend oil with balanced is respectively 0.37,7.58,15 hour, illustrates that double-deck edible vegetable blend oil with balanced of the present invention has good oxidation stability.
Double-deck edible vegetable blend oil with balanced provided by the invention and preparation method thereof, not only correct for the irrational problem of essential fatty acid ratio in the conventional vegetable oil accounting for China's edible vegetable oil consumption figure more than 85%, cell functional disorders is caused because of omega-fatty acid and ω-6 fatty acid proportion numerous imbalances to avoiding, and then cardiac trigger is sick, diabetes, cancer, the various disease such as Aging and arthritis, improve national health level to be of great immediate significance, and, the preparation method of ready-mixed oil provided by the invention is simple, be easy to industrialization, standardized production, for the national standard of working out edible blend oil, there is certain reference significance.
Accompanying drawing explanation
Fig. 1 is the process chart of the preparation method of double-deck edible vegetable blend oil with balanced of the present invention;
Fig. 2 is the AOM curve that the active oxygen method of linseed oil measures;
Fig. 3 is the AOM curve that the active oxygen method of one-level soybean oil measures;
Fig. 4 is the AOM curve that the active oxygen method of double-deck equalize plant ready-mixed oil measures.
Detailed description of the invention
In order to there be understanding clearly to technical characteristic of the present invention, object and beneficial effect, existing following detailed description is carried out to technical scheme of the present invention, but can not be interpreted as to of the present invention can the restriction of practical range.
Embodiment 1
Present embodiments provide the preparation method of the balanced edible soybean oil ready-mixed oil of a kind of bilayer, as shown in Figure 1, this preparation method comprises the following steps concrete technology flow process:
The linseed oil of the soybean oil of 804 kilograms and 195 kilograms is mixed, adds the natural VE regulating oil (rapeseed oil+walnut oil+corn oil+sunflower oil+peanut oil+olive oil+sesame oil+rice bran oil=1 kilogram) and bilayer balanced human consumption soybean ready-mixed oil gross mass 0.1% simultaneously; Wherein, the content of the omega-fatty acid (alpha-linolenic acid) of soybean oil be 8g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 55g/100g; The content of the omega-fatty acid (alpha-linolenic acid) of linseed oil be 50g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 20g/100g;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in the aliphatic acid composition of product oil, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:3, and the content of omega-fatty acid is 16.19wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 64.76wt%, the AOM value of product oil is 11.5, obtains the balanced edible soybean oil ready-mixed oil of described bilayer.
Relevant parameter as fruit product oil does not meet afore mentioned rules, then according to the step shown in Fig. 1, re-start allotment.
Embodiment 2
Present embodiments provide the preparation method of the balanced edible peanut oil ready-mixed oil of a kind of bilayer, this preparation method comprises the following steps:
The linseed oil of the peanut oil of 769 kilograms and 230 kilograms is mixed, adds the natural VE regulating oil (rapeseed oil+sunflower oil+walnut oil+Purple Perilla Seed Oil+corn oil+olive oil+sesame oil+rice bran oil=1 kilogram) and bilayer balanced human consumption soybean ready-mixed oil gross mass 0.05% simultaneously; Wherein, the content of the omega-fatty acid (alpha-linolenic acid) of peanut oil be 0g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 39g/100g; The content of the omega-fatty acid (alpha-linolenic acid) of linseed oil be 50g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 20g/100g;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in the aliphatic acid composition of product oil, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:3, and the content of omega-fatty acid is 11.9wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 47.6wt%, the AOM value of product oil is 13.5, obtains the balanced edible peanut oil ready-mixed oil of described bilayer.
Embodiment 3
Present embodiments provide the preparation method of the balanced edible rapeseed oil ready-mixed oil of a kind of bilayer, this preparation method comprises the following steps:
The linseed oil of the rapeseed oil of 832 kilograms and 167 kilograms is mixed, adds the natural VE regulating oil (sunflower oil+walnut oil+Purple Perilla Seed Oil+corn oil+peanut oil+olive oil+sesame oil+rice bran oil=1 kilogram) and bilayer balanced human consumption soybean ready-mixed oil gross mass 0.03% simultaneously; Wherein, the content of the omega-fatty acid (alpha-linolenic acid) of rapeseed oil be 3g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 30g/100g; The content of the omega-fatty acid (alpha-linolenic acid) of linseed oil be 45g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 20g/100g;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in the aliphatic acid composition of product oil, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:3, and the content of omega-fatty acid is 10wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 40wt%, the AOM value of product oil is 15.5, obtains the balanced edible rapeseed oil ready-mixed oil of described bilayer.
Embodiment 4
Present embodiments provide a kind of preparation method of double-deck balanced edible sunflower oil ready-mixed oil, this preparation method comprises the following steps:
The linseed oil of the sunflower oil of 681 kilograms and 318 kilograms is mixed, adds the natural VE regulating oil (rapeseed oil+walnut oil+Purple Perilla Seed Oil+corn oil+peanut oil+olive oil+sesame oil+rice bran oil=1 kilogram) and bilayer balanced human consumption soybean ready-mixed oil gross mass 0.05% simultaneously; Wherein, the content of the omega-fatty acid (alpha-linolenic acid) of sunflower oil be 0g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 62g/100g; The content of the omega-fatty acid (alpha-linolenic acid) of linseed oil be 51g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 20g/100g;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in the aliphatic acid composition of product oil, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:3, and the content of omega-fatty acid is 16.22wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 64.88wt%, the AOM value of product oil is 10.5, obtains described double-deck balanced edible sunflower oil ready-mixed oil.
Embodiment 5
Present embodiments provide the preparation method of the balanced edible corn oil ready-mixed oil of a kind of bilayer, this preparation method comprises the following steps:
The linseed oil of the corn oil of 699 kilograms and 300 kilograms is mixed, adds the natural VE regulating oil (rapeseed oil+walnut oil+Purple Perilla Seed Oil+sunflower oil+peanut oil+olive oil+sesame oil+rice bran oil=1 kilogram) and bilayer balanced human consumption soybean ready-mixed oil gross mass 0.05% simultaneously; Wherein, the content of the omega-fatty acid (alpha-linolenic acid) of corn oil be 0g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 57g/100g; The content of the omega-fatty acid (alpha-linolenic acid) of linseed oil be 51g/100g, ω-6 the content of aliphatic acid (linoleic acid) be 20g/100g;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in the aliphatic acid composition of product oil, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:3, and the content of omega-fatty acid is 15.3wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 61.2wt%, the AOM value of product oil is 10.5, obtains described double-deck balanced edible sunflower oil ready-mixed oil.
Claims (10)
1. a double-deck edible vegetable blend oil with balanced, in this double-deck edible vegetable blend oil with balanced, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:2.5-3.5, and the content of omega-fatty acid is 10wt%-18wt%, omega-fatty acid and the total content of ω-6 aliphatic acid in double-deck edible vegetable blend oil with balanced are 40wt%-72wt%, and the AOM value of double-deck edible vegetable blend oil with balanced is not less than 10; Be preferably 10-20.
2. double-deck edible vegetable blend oil with balanced according to claim 1, wherein, this double-deck edible vegetable blend oil with balanced comprises matrix edible vegetable oil, linseed oil, adjustment oil and natural VE, the content of described adjustment oil is the 0wt%-0.1wt% of double-deck edible vegetable blend oil with balanced total amount, and the content of described natural VE is the 0.03wt%-0.1wt% of double-deck edible vegetable blend oil with balanced total amount.
3. double-deck edible vegetable blend oil with balanced according to claim 2, wherein, described matrix edible vegetable oil comprises the combination of one or more in soybean oil, rapeseed oil, peanut oil, corn oil and sunflower oil.
4. double-deck edible vegetable blend oil with balanced according to claim 1 and 2, wherein, the content of linseed oil described in every 1000 kilograms of double-deck edible vegetable blend oil with balanced is A, the content of described matrix edible vegetable oil is B, in double-deck edible vegetable blend oil with balanced, the content of omega-fatty acid is ω-3, the content of ω-6 aliphatic acid is ω-6, then: A+B=1000, and (ω-6 × A+ ω-6 × B)/(ω-3 × A+ ω-3 × B)=3.
5. double-deck edible vegetable blend oil with balanced according to claim 4, wherein, the content of every 1000 kilograms of double-deck edible vegetable blend oil with balanced mesostroma edible vegetable oils and linseed oil is soybean oil 751-855 kilogram, linseed oil 145-249 kilogram.
6. double-deck edible vegetable blend oil with balanced according to claim 4, wherein, the content of every 1000 kilograms of double-deck edible vegetable blend oil with balanced mesostroma edible vegetable oils and linseed oil is peanut oil 744-839 kilogram, linseed oil 161-256 kilogram.
7. double-deck edible vegetable blend oil with balanced according to claim 4, wherein, the content of every 1000 kilograms of double-deck edible vegetable blend oil with balanced mesostroma edible vegetable oils and linseed oil is rapeseed oil 744-839 kilogram, linseed oil 161-256 kilogram.
8. double-deck edible vegetable blend oil with balanced according to claim 4, wherein, the content of every 1000 kilograms of double-deck edible vegetable blend oil with balanced mesostroma edible vegetable oils and linseed oil is corn oil 744-839 kilogram, linseed oil 161-256 kilogram.
9. double-deck edible vegetable blend oil with balanced according to claim 4, wherein, the content of every 1000 kilograms of double-deck edible vegetable blend oil with balanced mesostroma edible vegetable oils and linseed oil is sunflower oil 744-839 kilogram, linseed oil 161-256 kilogram.
10. the preparation method of the double-deck edible vegetable blend oil with balanced described in any one of claim 1-9, this preparation method comprises the following steps:
By appropriate matrix edible vegetable oil and linseed oil mixing, add simultaneously and regulate oil and natural VE;
Nitrogen atmosphere, 20 DEG C-30 DEG C, stir 30 minutes under the rotating speed of 200-300 rev/min, obtain product oil;
Carry out analysis to product oil to measure, in aliphatic acid composition, the mass ratio of omega-fatty acid and ω-6 aliphatic acid is 1:2.5-3.5, and the content of omega-fatty acid is 10wt%-18wt%, the total content of omega-fatty acid and ω-6 aliphatic acid is the product oil that 40wt%-72wt%, AOM value is not less than 10 is described double-deck edible vegetable blend oil with balanced.
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