CN104559455A - Improved rosin resin printing ink - Google Patents
Improved rosin resin printing ink Download PDFInfo
- Publication number
- CN104559455A CN104559455A CN201410847286.7A CN201410847286A CN104559455A CN 104559455 A CN104559455 A CN 104559455A CN 201410847286 A CN201410847286 A CN 201410847286A CN 104559455 A CN104559455 A CN 104559455A
- Authority
- CN
- China
- Prior art keywords
- ink
- water
- modified rosin
- rosin resin
- printing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Abstract
The invention provides improved rosin resin printing ink and a preparation method thereof. The printing ink comprises the following components in percentage by weight: 20-30% of pentaerythritol, 30-50% of a fumaric acid modified rosin condensation polymer, 10-20% of a water-based acrylic mill base, 1-2% of a wetting agent, 2-3% of an organic silicon defoamer, and the balance of water. The preparation method comprises the following steps: firstly mixing and heating pentaerythritol and the fumaric acid modified rosin condensation polymer; then adding the water-based acrylic mill base, the wetting agent, the organic silicon defoamer and water; uniformly stirring and mixing by using a dispersing machine; then filtering; adding the organic silicon defoamer into the filtrate to obtain the improved rosin resin printing ink. The ink film is firm and good in glossiness.
Description
Technical field
The present invention relates to a kind of ink, particularly a kind of modified resin ink, belongs to ink manufacture field.
Summary of the invention
Ink is that one is mixed equably by pigment, low-melting ink vehicle and auxiliary agent etc. and forms the gluey fluid of a kind of viscosity through repeat-rolling.It by printing by pattern, literal table now on the substrate, is the important materials for packages printing.
Along with social demand increases, ink kind and output is respective extension and growth also, and current domestic ink industry size just maintains sustained and rapid growth with the speed of more than 10%, emerges rapidly and becomes one of ink manufacture big country of the world.
Tradition manufacture ink is the raw material using industrial petroleum resin as ink, this not only consumes a large amount of organic solvents, but also pollute the environment, high point petroleum solvent containing 35%-40% in this kind of ink, thus containing more multiring aromatic hydrocarbon substance, and 3,4-benzo pyrroles, 3-nitro benzo ketone etc. are wherein also containing carcinogenic components, can endanger user's health.
Environmental consciousness due to people strengthens and people improve the security requirement that food product pack is printed, developed country launches respectively policy, the application of restriction solvent borne ink in the field such as food and medical package, in facilitating ink to form, aromatic hydrocarbon toxic volatile organic composition ratio reduces, the trend of the environment-friendly ink transfer that ink industry has occurred from traditional solvent-borne ink to such as water-based flexographic ink, Soybean Oil Ink, UV ink are such.The development and production ability of environment-friendly ink has become one of following key factor of winning victory of ink manufacturer.The research and development of China's water color ink are started late, and product exists the problems such as poor water resistance, glossiness are low, the requirement of high-grade water-based, and ink is main dependence on import also, and therefore the research and development of high-grade water color ink have important economy and social value with application.
The essential distinction of water color ink and solvent type ink is to take water as solvent or dispersion medium.The stuctures and properties of waterborne polymeric is the key factor determining water color ink performance.Waterborne polymeric used for water color ink is the earliest the shellac that can be dissolved in ethanol and basic solution, modified rosin resin replaced the binder that pure natural resin becomes water color ink afterwards, improve the printability of water color ink, but be also short of to some extent in glossiness and water tolerance, the use of acrylic ester emulsion substantially increases stability and the water tolerance of water color ink, but its over-all properties and solvent type ink also have certain gap.In order to improve the performance of water color ink further, starting with from the design of polymer molecular structure and Particle configuration, to Gum Rosin modification, connecting with tetramethylolmethane and fumaric acid modified rosin polycondensate and expecting to prepare a kind of novel ink.Overcome the shortcoming of water color ink in glossiness and water tolerance.
Summary of the invention
The invention provides a kind of modified rosin resin ink and preparation technology thereof, for realizing this purpose, this ink comprises the material of following weight percent:
Tetramethylolmethane 20-30%
Fumaric acid modified rosin polycondensate 30-50%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 2-3%
Water surplus.
The preparation method of this ink carries out as follows:
(1) get a container, drop into a certain proportion of tetramethylolmethane, fumaric acid modified rosin polycondensate, heating, makes it fully react; (2) add water soluble acrylic acid mill base, wetting agent and silicone antifoam agent and water successively again, be uniformly mixed with dispersion machine;
(3) use metre filter, collect filtrate;
(4) finally add appropriate silicone antifoam agent, a kind of modified rosin resin ink.
The present invention has following advantages and characteristic:
(1) ink film is hard;
(2) be easily cross-linked film forming;
(3) glossiness is good.
Embodiment
Embodiment one:
Get a container, load the tetramethylolmethane of 20 parts, the fumaric acid modified rosin polycondensate of 50 parts, heating, make it fully react, then add the water soluble acrylic acid mill base of 10 parts, the wetting agent of 1 part and the silicone antifoam agent of 1 part and the water of 17 parts successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1 part, a kind of modified rosin resin ink.
Embodiment two:
Get a container, load the tetramethylolmethane of 30 parts, the fumaric acid modified rosin polycondensate of 40 parts, heating, make it fully react, then add the water soluble acrylic acid mill base of 10 parts, the wetting agent of 2 parts and the silicone antifoam agent of 1 part and the water of 16 parts successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1 part, a kind of modified rosin resin ink.
Embodiment three:
Get a container, load the tetramethylolmethane of 20 parts, the fumaric acid modified rosin polycondensate of 30 parts, heating, make it fully react, then add the water soluble acrylic acid mill base of 20 parts, the wetting agent of 2 parts and the silicone antifoam agent of 1.5 parts and the water of 25 parts successively, be uniformly mixed with dispersion machine, mix rear metre filter, collect filtrate, finally add the silicone antifoam agent of 1.5 parts, a kind of modified rosin resin ink.
Claims (2)
1. a modified rosin resin ink, is characterized in that, this ink comprises the material of following weight percent:
Tetramethylolmethane 20-30%
Fumaric acid modified rosin polycondensate 30-50%
Water soluble acrylic acid mill base 10-20%
Wetting agent 1-2%
Silicone antifoam agent 2-3%
Water surplus.
2. a kind of modified rosin resin ink according to claim 1, is characterized in that, the preparation method of this ink carries out as follows:
(1) get a container, drop into a certain proportion of tetramethylolmethane, fumaric acid modified rosin polycondensate, heating, makes it fully react; (2) add water soluble acrylic acid mill base, wetting agent and silicone antifoam agent and water successively again, be uniformly mixed with dispersion machine;
(3) use metre filter, collect filtrate;
(4) finally add appropriate silicone antifoam agent, a kind of modified rosin resin ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847286.7A CN104559455A (en) | 2014-12-31 | 2014-12-31 | Improved rosin resin printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410847286.7A CN104559455A (en) | 2014-12-31 | 2014-12-31 | Improved rosin resin printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104559455A true CN104559455A (en) | 2015-04-29 |
Family
ID=53076559
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410847286.7A Pending CN104559455A (en) | 2014-12-31 | 2014-12-31 | Improved rosin resin printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104559455A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038389A (en) * | 2015-09-06 | 2015-11-11 | 屈婧婧 | Printing ink added with high carbon alcohol aliphatic ester compound defoaming agent and preparation technology thereof |
| CN105038390A (en) * | 2015-09-08 | 2015-11-11 | 黎晚清 | Waterproof modified rosin resin printing ink composition and preparing technology |
| CN105062194A (en) * | 2015-09-06 | 2015-11-18 | 屈婧婧 | Ink with modified defoaming agent |
| CN105062195A (en) * | 2015-09-06 | 2015-11-18 | 屈婧婧 | Ink with polydimethylsiloxane defoaming agent and preparation method thereof |
| CN105062191A (en) * | 2015-09-01 | 2015-11-18 | 黎晚清 | Glossiness modified resin ink composition and preparation method thereof |
| CN105086597A (en) * | 2015-09-01 | 2015-11-25 | 黎晚清 | Rosin resin ink compound with addition of isopropyl alcohol |
| CN105086593A (en) * | 2015-09-06 | 2015-11-25 | 屈婧婧 | Modified rosin resin printing ink added with ethanol and preparation method of modified rosin resin printing ink |
| CN105086598A (en) * | 2015-09-08 | 2015-11-25 | 黎晚清 | Novel ester modified resin ink composition |
| CN106046922A (en) * | 2016-08-19 | 2016-10-26 | 广东南海启明光大科技有限公司 | Modified rosin resin for aqueous ink thickener and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013144765A (en) * | 2012-01-16 | 2013-07-25 | Toyo Ink Sc Holdings Co Ltd | Offset printing ink composition |
| CN103627250A (en) * | 2013-11-19 | 2014-03-12 | 张家港威迪森化学有限公司 | Water-based ink |
-
2014
- 2014-12-31 CN CN201410847286.7A patent/CN104559455A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013144765A (en) * | 2012-01-16 | 2013-07-25 | Toyo Ink Sc Holdings Co Ltd | Offset printing ink composition |
| CN103627250A (en) * | 2013-11-19 | 2014-03-12 | 张家港威迪森化学有限公司 | Water-based ink |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105062191A (en) * | 2015-09-01 | 2015-11-18 | 黎晚清 | Glossiness modified resin ink composition and preparation method thereof |
| CN105086597A (en) * | 2015-09-01 | 2015-11-25 | 黎晚清 | Rosin resin ink compound with addition of isopropyl alcohol |
| CN105038389A (en) * | 2015-09-06 | 2015-11-11 | 屈婧婧 | Printing ink added with high carbon alcohol aliphatic ester compound defoaming agent and preparation technology thereof |
| CN105062194A (en) * | 2015-09-06 | 2015-11-18 | 屈婧婧 | Ink with modified defoaming agent |
| CN105062195A (en) * | 2015-09-06 | 2015-11-18 | 屈婧婧 | Ink with polydimethylsiloxane defoaming agent and preparation method thereof |
| CN105086593A (en) * | 2015-09-06 | 2015-11-25 | 屈婧婧 | Modified rosin resin printing ink added with ethanol and preparation method of modified rosin resin printing ink |
| CN105038390A (en) * | 2015-09-08 | 2015-11-11 | 黎晚清 | Waterproof modified rosin resin printing ink composition and preparing technology |
| CN105086598A (en) * | 2015-09-08 | 2015-11-25 | 黎晚清 | Novel ester modified resin ink composition |
| CN106046922A (en) * | 2016-08-19 | 2016-10-26 | 广东南海启明光大科技有限公司 | Modified rosin resin for aqueous ink thickener and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150429 |