CN104541726A - Method for testing field nutrient release regulation of urea formaldehyde slow-release fertilizer - Google Patents

Method for testing field nutrient release regulation of urea formaldehyde slow-release fertilizer Download PDF

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CN104541726A
CN104541726A CN201510050354.1A CN201510050354A CN104541726A CN 104541726 A CN104541726 A CN 104541726A CN 201510050354 A CN201510050354 A CN 201510050354A CN 104541726 A CN104541726 A CN 104541726A
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soil
fertilizer
release
pipe
nitrogen
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CN104541726B (en
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陈宝成
李峰
丁济娜
张民
刘之广
王淳
李成亮
王晓琪
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Wuzhoufeng Agricultural Science & Technology Co Ltd
Shandong Agricultural University
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Wuzhoufeng Agricultural Science & Technology Co Ltd
Shandong Agricultural University
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Abstract

The invention relates to a method for testing the field nutrient release regulation of a urea formaldehyde slow-release fertilizer. The method comprises the following steps: respectively setting two groups of fertilizer soil tube and blank soil tube of a same number according to experiment requirements; adding the urea formaldehyde slow-release fertilizer and surface soil to be tested into each fertilizer soil tube; only adding surface soil into each blank soil tube; in the growth period of crops, confirming the sampling time and the sampling times according to specific experiment demands; taking out soil samples in the fertilizer soil tubes and the blank soil tubes; testing the valid nitrogen release rate or the nitrogen release activity rate of the urea formaldehyde slow-release fertilizer in soil, thereby judging the nutrient release situation of the urea formaldehyde slow-release fertilizer. Conditions such as the soil humidity, the temperature and the microorganisms in the environment where the urea formaldehyde slow-release fertilizer is used in the soil tubes are generally consistent to the crop growing environment, the practical fertilizer supply situating of a non-coated granular or powder urea formaldehyde slow-release fertilizer can be relatively well reflected through the valid nutrient release regulation tested by using the method, and scientific basis for evaluating the nutrient release regulation and judging whether the nutrient release and nutrient absorption of crops are synchronous is provided.

Description

A kind of method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule
One, technical field
The present invention relates to a kind of method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule.
Two, technical background
Whether the nutrient element releasing rule of slow-release or control-release fertilizer in field soil is evaluate the important means of slow-release or control-release fertilizer quality with Crop nutrient synchronised, and it more can reflect the actual conditions of nutrient supply than nutrients release method in Static Water.Slow-release or control-release fertilizer field nutrients release speed, accumulative total volume directly affect its nutrient supply situation, and then affect the quality of Crop nutrient situation and growth.Basic and the crop different phase Nutrient Absorption situation synchronised of its nutrients release speed of the slow-release or control-release fertilizer of high-quality, and the nutrients release total amount within crop whole vegetative period can not be less than 80%, otherwise, this slow-release or control-release fertilizer is just undesirable to nutrient controlled-release effect, can not reach the object of the abridged edition that well increases production and improves productivity.At present, the method of field test slow-release or control-release fertilizer nutrient element releasing rule mainly contains hydrostatic water culture, soil dissolution rate method, isotope method, mesh bag method etc., but above method is comparatively suitable for the mensuration of tunicary slow-release or control-release fertilizer nutrients release, and (the method cost had is very high, as isotope method), be not suitable for the graininess of non-coating or Powdered slow release fertilizer, as urea aldehyde slow-release fertilizer.Urea aldehyde slow release fertilizer reacts obtained organic microsolubility nitrogen slow release fertilizer under certain condition by urea and aldehydes, be slightly soluble in cold water, under water in soil and the effect of microorganism, slow releasing nitrogen wherein, the volatilization of nitrogen, leaching loss can be reduced and fix, its plant recovery of nutrient and effect of increasing production, higher than common nitrogenous fertilizer, are once used in a large number and are unlikelyly caused burning seedling, have good using value.Because urea aldehyde slow-release fertilizer finished product is generally in irregular graininess or Powdered, and mainly under edaphon effect decompose discharge nitrogen, if so its nutrients release supply situation in field soil will be measured, by general hydrostatic water culture, soil leaching, mesh bag method etc. can exist and stops that edaphon and urea-formaldehyde fertilizer produce and react, temperature and humidity conditions and field difference large, sampling determination process causes fertilizer loss, the nitrogen measured differs, and to establish a capital be the adverse effects such as available nutrient form, can not its nutrients release of Accurate Determining and nutrient supply situation.
Three, summary of the invention
For the deficiency of existing mensuration slow-release or control-release fertilizer field nutrients release method and technology, the invention provides a kind of method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule.
Measure a method for urea aldehyde slow-release fertilizer field nutrient element releasing rule, comprise the following steps:
(1) two groups of identical fertilizer soil pipes of quantity and blank soil pipe is set respectively according to test requirements document; Fertilizer soil pipe and blank soil pipe are the pvc pipe of the identical diameter 5 ~ 10 centimetres of specification, length 15 ~ 20 centimetres, and mark coding respectively with waterproof marking pen;
(2) on crop seeding and fertilizing same day, get the on-the-spot unmanured topsoil soils in field, cross 2 millimeters (10 orders) sieve;
Urea aldehyde slow release fertilizer 2 ~ 5 grams to be measured is added in every root manure material soil pipe, by urea aldehyde slow release fertilizer and topsoil soils mixing, be filled in fertilizer soil pipe, the two ends of every root manure material soil pipe are encased again with 80 ~ 120 object nylon mesh sheets, and tighten with thin nylon rope, drop out to prevent managing interior soil, moisture can't be hindered to enter in the interior soil of pipe.
In each fertilizer soil pipe, topsoil soils is all identical with urea aldehyde slow release fertilizer quantity to be measured, and should fill up fertilizer soil pipe, and the soil compactness after loading in every root manure material soil pipe is even, and identical with the elasticity of field topsoil soils;
In the native pipe of blank, only load the topsoil soils with fertilizer soil pipe equal number, do not add urea aldehyde slow release fertilizer, other operation is identical.
Measure the percent mass water content of described topsoil soils, according to earth weight in wet base and the water content of soil in loaded fertilizer soil pipe and blank soil pipe, calculate the soil dry ground weight in fertilizer soil pipe and blank soil pipe.
(3) in the side of crop seeding row, distance crops 10 ~ 50 centimetres, parallel two Tu Gou digging dark 10 ~ 40 centimetres, wide 15 ~ 20 centimetres, two ditch spacing are 0.5-1 rice; Wherein fertilizer soil pipe buried underground by a ditch, and blank soil pipe buried underground by another ditch, and the length of ditch enough should bury all soil pipes underground.By step 2) in the fertilizer soil pipe made and the native pipe of blank be placed on the bottom of two ditches respectively; Distance between the adjacent native pipe in same soil ditch, at 3-10 centimetre, is then carried out earthing according to elasticity identical with field soil and is filled and led up, and on native face, indicate the position that fertilizer soil pipe and the native pipe of blank bury in institute respectively, is convenient to promptly and accurately to find during post-sampling.
The time that soil loaded by fertilizer soil pipe and blank soil pipe should carry out with the crop seeding and fertilizing time simultaneously.
(4) during plant growth, in crop primary growth phase or separated in time section (also can need suitably to determine sampling time and number of times according to concrete test), the fertilizer soil pipe be embedded in field soil and blank soil pipe are taken out, fertilizer soil pipe and blank soil pipe respectively get 3 ~ 5 pipes at every turn at random, take back laboratory.
(5) soil in fertilizer soil pipe and blank soil pipe is taken out in time, air-dry, cross 2 mm sieve, measure urea aldehyde slow-release fertilizer effective nitrogen release rate or Nitrogen releasing activity rate in soil, judge the nutrients release situation of urea aldehyde slow-release fertilizer.
1. urea aldehyde slow-release fertilizer effective nitrogen release rate assay in soil:
The alkali-hydrolyzable nitrogen content of soil in the native pipe of fertilizer and the alkali-hydrolyzable nitrogen content of the interior soil of blank soil pipe is measured respectively by alkaline hydrolysis diffusion process, with the every one-phase of following formulae discovery use effective nitrogen rate that urea aldehyde slow-release fertilizer discharges (in this method urea aldehyde slow-release fertilizer transform after loss in native pipe few, can ignore):
In urea aldehyde slow-release fertilizer effective nitrogen release rate=(in the native pipe of fertilizer, alkali-hydrolyzable nitrogen content-blank soil of soil manages the alkali-hydrolyzable nitrogen content of interior soil) × soil pipe, soil dry ground weighs urea aldehyde slow-release fertilizer nitrogen total amount × 100% that ÷ applies
In crop growth period, the urea aldehyde slow-release fertilizer effective nitrogen release rate of the latter half deducts the urea aldehyde slow-release fertilizer effective nitrogen release rate of previous stage, is the urea aldehyde slow-release fertilizer effective nitrogen release rate in this stage.
According to the urea aldehyde slow-release fertilizer effective nitrogen release rate of the crop Different growth phases that measure and calculation goes out, in conjunction with Crop Nutrient Properties, the fertilizer evaluating urea aldehyde slow-release fertilizer is good and bad.
2. Nitrogen releasing activity rate:
Nitrogen releasing activity rate refers to that in urea aldehyde slow-release fertilizer, in certain phases-time, hot water soluble nitrogen accounts for the percentage of the total urea aldehyde slow-release fertilizer nitrogen applied, for evaluating the nitrogen release characteristic of urea-formaldehyde fertilizer.Be taken as fertilizer soil pipeclay earth and the blank soil pipeclay earth in thing vegetative period, in boiling water bath, measure the concentration of its hot water soluble nitrogen respectively, go out Nitrogen releasing activity rate according to following formulae discovery:
Urea aldehyde slow-release fertilizer nitrogen total amount × 100% that in Nitrogen releasing activity rate=(in fertilizer soil pipe in hot melt nitrogen concentration-blank native pipe hot melt nitrogen concentration) × soil pipe, the heavy ÷ of soil dry ground applies
In crop growth period, the Nitrogen releasing activity rate of the latter half deducts the Nitrogen releasing activity rate of previous stage, is the urea aldehyde slow-release fertilizer Nitrogen releasing activity rate in this stage.
Preferably, described step 1) in the diameter 6 ~ 7 centimetres of pvc pipe, long 20 centimetres.
Described step 3) in, when described crops are fruit tree, distance capable 50 centimetres of planting fruit trees, digs the ditch of dark 30 ~ 40 centimetres, wide 15 ~ 20 centimetres; Described crops be wheat, corn or vegetables time, distance capable 10 centimetres of crop-planting, dig the ditch of dark 10 ~ 15 centimetres, wide 15 ~ 20 centimetres.
Step 4) in, the pipe time of fetching earth is determined according to different crops, and when principle is crops fast growing period, sampling interval time is short, and when crop growth is slow, sampling interval time is long.Preferably, crops will sample each vegetative period; If according to regular intervals of time time sampling, then sample time is: non-protected ground crop is respectively March to May, every 2 weeks of September to November once, and June to August is every weekly, and every 4 weeks of February in December to the coming year once; Protectorate cultivation crop suitably adjusts according to plant growth feature and soil temperature; Determination period of the present invention is from crop seeding and fertilizing, until till crop maturity results.
Advantage of the present invention is:
1. determinator environment more tallies with the actual situation.
Moisture in urea aldehyde slow-release fertilizer nutrients release and environment, temperature height particularly microbe species quantity etc. is in close relations.The environment residing for urea aldehyde slow-release fertilizer in the present invention's soil pipe is as basic consistent with the environment facies of plant growth in conditions such as soil moisture, temperature, microorganisms; To graininess or pulverous urea aldehyde slow-release fertilizer of non-coating, the available nutrient release rule that this method measures more can reflect fertilizer actual conditions, for evaluating its nutrient element releasing rule and judging whether to provide scientific basis with Crop nutrient synchronism aspect, and water culture, mesh bag method are owing to contacting with edaphon not or having the reasons such as Nutrient water loss in mensuration process, be difficult to reach this ideal effect.
2. easy to operate, cost is low.
Compared with mesh bag method, isotope method, material, field mounting arrangements and the aspect such as sampling process, lab analysis chemical examination that the inventive method is used, more simple and easy to do, cost is also low.
Four, accompanying drawing explanation
Fig. 1 is the PVC soil pipe measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule;
In figure: 1 nylon wire; 2 native pipe numberings; 3PVC soil pipe; 4 nylon tie strings
The mixture (being directed to fertilizer soil to manage) of test soil used (being directed to blank soil pipe) or soil and urea aldehyde slow-release fertilizer is loaded as required in pipe.
Five, embodiment
Below in conjunction with embodiment, the present invention is done to the explanation of embodiment, but be not limited thereto.Urea aldehyde slow-release fertilizer used in example is that Wuzhoufeng Agricultural Technology Co., Ltd. produces, and Powdered, nitrogen content is 36.0%, and crop is wheat.
The concrete implementation step of example is as follows:
(1) prepare that diameter is 6 centimetres, length is the pvc pipe of 15 centimetres, quantity is 80, and wherein 40 pipe outer wall waterproof marking pens write numbering from F1 to F40, for loading soil and the process of urea aldehyde slow-release fertilizer as fertilizer soil pipe; Other 40 pipe outer wall waterproof marking pens write numbering from CK1 to CK40, only load soil as blank soil pipe.Prepare 100 object nylon mesh sheet 160 in addition, then prepare the nylon marline 160 of Perishing prevention function, for bundling the nylon mesh sheet encasing pvc pipe port.
(2) soil is prepared
On the same day of wheat cultivation fertilising, wheatland 0 ~ 15 centimetre of topsoil was selected at scene, field, crossed the sieve of 2 millimeters of sieve apertures (10 order), and mixing, soil moisture content is 15.0%, and total wet soil amount is 50 kilograms.
(3) field embedded device is made
First make the fertilizer soil pipe adding urea aldehyde slow-release fertilizer: according to the volume of topsoil soils unit weight size and pvc pipe, calculating every root manure material soil pipe needs the soil loaded to be 575 grams (amounting to dry ground 500 grams), every root manure material soil pipe takes urea aldehyde slow release fertilizer 3 grams again, after alleged soil and fertilizer mixing, all join in fertilizer soil pipe, limit Jia Tu limit compacting, make the elasticity of soil in fertilizer soil pipe even and identical with the elasticity of field topsoil soils, then encase the two ends of fertilizer soil pipe with ready gauze, and tighten with thin nylon rope.The fertilizer soil pipe that making 40 is so altogether.
Make 40 blank soil pipes again: only load in pipe and the native step 2 of managing identical amount of fertilizer) process after soil, do not add urea aldehyde slow-release fertilizer, other operation is identical.
(4) field embedded device
After Wheat Sowing finishes, in distance wheat capable side 10 centimeters, start to dig side by side dark 15 centimetres, wide 16 centimetres, the Liang Tiaogou of long 2.5 meters, place clay fertilizer pipe and blank tube respectively, the horizontal range of two ditches is 1 meter.By the fertilizer made soil pipe and the native pipe of blank respectively horizontal Tile be put into the bottom of ditch, in every bar soil ditch, adjacent native tube pitch is 5 centimetres, earthing is filled and led up, soil compactness is identical with land for growing field crops, sign board is plugged in face to soil respectively, be used to indicate the position of buried PVC soil pipe, be convenient to promptly and accurately to find during post-sampling.
(5) field trial sample is gathered
After wheat cultivation 1 day, the seeding stage, the early winter tillers phase, Wintering Period, period of seedling establishment, the shooting stage, heading stage, flowering stage, the pustulation period, harvest time, the PVC soil pipe be embedded in field soil is taken out, fertilizer soil pipe and blank soil pipe respectively get 4 pipes at every turn, take back laboratory.
(6) urea aldehyde slow-release fertilizer fertilizer situation is measured
Two kinds of native pipes take out all soil after fetching in time from native pipe, air-dry, cross 2 mm sieve, measure the alkali-hydrolyzable nitrogen in soil, according to formulae discovery urea aldehyde slow-release fertilizer available nutrient release rate (the results are shown in Table 1), judge the nutrients release situation of urea aldehyde slow-release fertilizer.
Computing formula:
Urea aldehyde slow-release fertilizer effective nitrogen release rate=(in the native pipe of fertilizer, alkali-hydrolyzable nitrogen content-blank soil of soil manages the alkali-hydrolyzable nitrogen content of interior soil) × 500 grams of ÷ 10 6÷ 3 × 36.0% × 100%
Urea aldehyde slow-release fertilizer effective nitrogen release rate during table 1 wheat growth
Shown by the determination data of table 1, from urea aldehyde slow-release fertilizer is manured into soil a few days ago, its nutrients release is comparatively slow, and along with passage of time, the decomposition of microorganism to urea aldehyde slow-release fertilizer is constantly carried out, nutrients release is accelerated to some extent, arrive overwintering season, because temperature is low, at the bottom of microbial activity, little to the decomposition of urea aldehyde slow-release fertilizer, nutrient release rate reduces; Spring in the coming year, from wheat period of seedling establishment, along with the rise of temperature, urea aldehyde slow-release fertilizer nutrients release is accelerated, until Wheat in Grain Filling Stage, keep higher nutrient release rate always, along with the decomposition of urea aldehyde slow-release fertilizer discharges, its supply quantity reduces, to wheat ripe harvest time, nutrient release rate reduces again, and last nitrogen adds up release rate and reaches 80.56%, from urea aldehyde slow-release fertilizer in wheat Nitrogen releasing analysis throughout the growing season, the basic and wheat of its nitrogen nutrient supply trend adapts to nitrogen nutrient demand.

Claims (3)

1. measure a method for urea aldehyde slow-release fertilizer field nutrient element releasing rule, it is characterized in that comprising the following steps:
1) two groups of identical fertilizer soil pipes of quantity and blank soil pipe is set respectively according to test requirements document; Fertilizer soil pipe and blank soil pipe are the pvc pipe of the identical diameter 5 ~ 10 centimetres of specification, length 15 ~ 20 centimetres, and mark coding respectively with waterproof marking pen;
2) on crop seeding and fertilizing same day, get the on-the-spot unmanured topsoil soils in field, cross 2 mm sieve;
Urea aldehyde slow release fertilizer 2 ~ 5 grams to be measured is added in every root manure material soil pipe, by urea aldehyde slow release fertilizer and topsoil soils mixing, be filled in fertilizer soil pipe, the two ends of every root manure material soil pipe are wrapped again with 80 ~ 120 object nylon mesh sheets, and tighten with thin nylon rope, drop out to prevent managing interior soil, moisture can't be hindered to enter in the interior soil of pipe;
In each fertilizer soil pipe, topsoil soils is all identical with urea aldehyde slow release fertilizer quantity to be measured, and should fill up fertilizer soil pipe, and the soil compactness after loading in every root manure material soil pipe is even, and identical with the elasticity of field topsoil soils;
In the blank native pipe of every root, only load the topsoil soils with fertilizer soil pipe equal number, do not add urea aldehyde slow release fertilizer to be measured, other operation is identical;
Measure the percent mass water content of described topsoil soils, according to earth weight in wet base and the water content of soil in loaded fertilizer soil pipe and blank soil pipe, calculate the soil dry ground weight in fertilizer soil pipe and blank soil pipe;
3) in the side of crop seeding row, distance crops 10 ~ 50 centimetres, parallel two Tu Gous digging dark 10 ~ 40 centimetre, wide 15 ~ 20 centimetre capable of proportion of crop planting, two native ditch spacing are 0.5-1 rice; Wherein a Tu Gou buries fertilizer soil pipe underground, and another Tu Gou buries blank soil pipe underground, and the length of Tu Gou enough should bury all soil pipes underground;
By step 2) in the fertilizer soil pipe made and the native pipe of blank be placed on the bottom of two Tu Gou respectively; Distance between the adjacent native pipe in same soil ditch, at 3-10 centimetre, is then carried out earthing according to elasticity identical with field soil and is filled and led up, and on native face, indicate the position that fertilizer soil pipe and the native pipe of blank bury in institute respectively, is convenient to promptly and accurately to find during post-sampling;
The time that soil loaded by fertilizer soil pipe and blank soil pipe should carry out with the crop seeding and fertilizing time simultaneously;
(4) during plant growth, test according to concrete the sampling time and number of times that need to determine, managed by the fertilizer soil be embedded in field soil and the taking-up of blank soil pipe, fertilizer soil pipe and the native pipe of blank respectively get 3 ~ 5 pipes at every turn at random;
(5) soil in fertilizer soil pipe and blank soil pipe is taken out in time, air-dry, cross 2 mm sieve, measure urea aldehyde slow-release fertilizer effective nitrogen release rate or Nitrogen releasing activity rate in soil, judge the nutrients release situation of urea aldehyde slow-release fertilizer;
1. urea aldehyde slow-release fertilizer effective nitrogen release rate assay in soil:
Measure the alkali-hydrolyzable nitrogen content of soil in the alkali-hydrolyzable nitrogen content of soil and blank soil pipe in fertilizer soil pipe by alkaline hydrolysis diffusion process respectively, use with the every one-phase of following formulae discovery the effective nitrogen rate that urea aldehyde slow-release fertilizer discharges:
In urea aldehyde slow-release fertilizer effective nitrogen release rate=(in the native pipe of fertilizer, alkali-hydrolyzable nitrogen content-blank soil of soil manages the alkali-hydrolyzable nitrogen content of interior soil) × soil pipe, soil dry ground weighs urea aldehyde slow-release fertilizer nitrogen total amount × 100% that ÷ applies
In crop growth period, the urea aldehyde slow-release fertilizer effective nitrogen release rate of the latter half deducts the urea aldehyde slow-release fertilizer effective nitrogen release rate of previous stage, is the urea aldehyde slow-release fertilizer effective nitrogen release rate in this stage;
According to the urea aldehyde slow-release fertilizer effective nitrogen release rate of the crop Different growth phases that measure and calculation goes out, in conjunction with Crop Nutrient Properties, the fertilizer evaluating urea aldehyde slow-release fertilizer is good and bad;
2. Nitrogen releasing activity rate:
Be taken as fertilizer soil pipeclay earth and the blank soil pipeclay earth in thing vegetative period, in boiling water bath, measure the concentration of its hot water soluble nitrogen respectively, go out Nitrogen releasing activity rate according to following formulae discovery:
Urea aldehyde slow-release fertilizer nitrogen total amount × 100% that in Nitrogen releasing activity rate=(in fertilizer soil pipe in hot melt nitrogen concentration-blank native pipe hot melt nitrogen concentration) × soil pipe, the heavy ÷ of soil dry ground applies
In crop growth period, the Nitrogen releasing activity rate of the latter half deducts the Nitrogen releasing activity rate of previous stage, is the urea aldehyde slow-release fertilizer Nitrogen releasing activity rate in this stage.
2. the method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule as claimed in claim 1, is characterized in that the diameter of described fertilizer soil pipe and blank soil pipe is 6 ~ 7 centimetres, long 20 centimetres.
3. the method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule as claimed in claim 1, when it is characterized in that described crops are fruit tree, Tu Gou distance capable 50 centimetres of planting fruit trees, dark 30 ~ 40 centimetres; Described crops be wheat, corn or vegetables time, Tu Gou distance capable 10 centimetres of proportion of crop planting, dark 10 ~ 15 centimetres.
CN201510050354.1A 2015-01-30 2015-01-30 A kind of method measuring urea aldehyde slow-release fertilizer field nutrient element releasing rule Expired - Fee Related CN104541726B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105875143A (en) * 2016-04-13 2016-08-24 安徽省农业科学院土壤肥料研究所 Testing method of field pipe planting fertilizer
CN109804747A (en) * 2019-03-28 2019-05-28 河北农业大学 Fertilizing method for slow release fertilizer of wheat

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105875143A (en) * 2016-04-13 2016-08-24 安徽省农业科学院土壤肥料研究所 Testing method of field pipe planting fertilizer
CN105875143B (en) * 2016-04-13 2018-08-21 安徽省农业科学院土壤肥料研究所 A kind of field pipe plants the test method of fertilizer
CN109804747A (en) * 2019-03-28 2019-05-28 河北农业大学 Fertilizing method for slow release fertilizer of wheat

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