CN104531000A - Waterproof roll free of folds and easy to weld - Google Patents

Waterproof roll free of folds and easy to weld Download PDF

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Publication number
CN104531000A
CN104531000A CN201510017711.4A CN201510017711A CN104531000A CN 104531000 A CN104531000 A CN 104531000A CN 201510017711 A CN201510017711 A CN 201510017711A CN 104531000 A CN104531000 A CN 104531000A
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China
Prior art keywords
waterproof roll
parts
easy
adhesive
self
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CN201510017711.4A
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CN104531000B (en
Inventor
王召军
高志涛
李秋林
李宁
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HEBEI CHUANGLONG ENGINEERING RUBBER&PLASTIC Co Ltd
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HEBEI CHUANGLONG ENGINEERING RUBBER&PLASTIC Co Ltd
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Abstract

The invention belongs to the technical field of waterproof materials used in water conservancy projects and building projects and particularly discloses a waterproof roll free of folds and easy to weld. According to the technical scheme, the waterproof roll free of folds and easy to weld comprises a sheet, non-asphalt self-adhesive flue layers and isolating films, wherein the non-asphalt self-adhesive flue layers are attached to one side face or two side faces of the sheet, and the self-adhesive flue layers are coated with the isolating films. The sheet comprises, by weight, 65-70 parts of polyethylene, 15-18 parts of POE, 10-12 parts of EVA, 5-7 parts of polyethylene flexibilizer, 4-6 parts of maleic anhydride compatilizer and 1-2 parts of polyolefin aging-proof agent. The waterproof roll free of folds and easy to weld has the advantages that the hot melting temperature is low, both welding and construction are easy, and compared with ordinary materials, on the premise that the excellent welding effect is guaranteed, the welding temperature is lowered by 50-80 DEG C, and power consumption of a welding device is greatly reduced; meanwhile, the tensile strength at break is high, the elongation at break is high, the tearing strength is high, and chemical corrosion resistance is achieved, and the requirement for conduction in a low-temperature environment is met.

Description

One easily welds waterproof roll without folding line
Technical field
The invention belongs to the water-proof material technical field used in water conservancy, civil engineering, relate to one specifically and easily weld waterproof roll and preparation method thereof without folding line.
Background technology
Waterproof roll is a kind of novel high-grade water-proof material grown up in recent years, is mainly used in the basal plane WATER REPELLENT in water conservancy, civil engineering.Waterproof roll includes the synthetic resin sheet material forming its tire basic unit, the separating film layer being compound in the tackiness agent formed by modifying asphalt on above-mentioned tire basic unit one or both sides and laminating surface of pressure-sensitive adhesive; All rolling is deposited or is transported in process of production.During use, coiled material is spread out and peels off separating film layer, bonded by binder layer and engineering basal plane, realize the function of WATER REPELLENT.But there is following defect in current used coiled material: one, after depositing for a long time or piling up transport, because extruding result in the distortion of coiled material, lay when launching to use that to be difficult to nature smooth, can must realize paving within the longer time by means of external force, especially construct at low ambient temperatures, be difficult to the laying completing water-proof material coiled material in the short period of time especially; Its two, hot melting temperature o'clock at about 450 DEG C, the welding procedure difficulty between sheet material.
Summary of the invention
Object of the present invention is just to provide one and easily welds waterproof roll and preparation method thereof without folding line.
The technical scheme realizing above-mentioned purpose of the present invention is:
One easily welds waterproof roll without folding line, the barrier film that its structure comprises sheet material, is compound in the non-bituminous self-adhesive glue layer on one side or two sides and is overlying in described self-adhesive aspect, is characterized in that: described sheet material comprises the polyolefine anti-aging agent of the polyethylene of 65-70 weight parts, the POE of 15-18 weight parts, the EVA of 10-12 weight parts, the polyethylene toughner of 5-7 weight parts, the maleic anhydride compatilizer of 4-6 weight parts and 1-2 weight parts.
Wherein, the thickness of described sheet material is arranged on 0.2mm-2.0mm, and the thickness of described non-bituminous self-adhesive glue layer is 0.3mm-1.0mm.
One provided by the present invention is easily welded waterproof roll without folding line and is compared with the existing technology had the following advantages: one, this coiled material has good elasticity restorability, after crimp, generally recover open and flat in expansion in 20 minutes, and can according to the conversion of formation level because gesture converts, lay docile property good, avoid producing because formation level is asynchronous with water-proof material water-proof material local stress and be out of shape even braking effect water resistance and change the generation of situation; Two, this product hot melting temperature is low, easy welding procedure, is ensureing that under the prerequisite that welding effect is superior, comparatively the low 50-80 DEG C of welding temperature compared by common material, greatly saves the energy consumption of welding set; Three, this coiled material has that fracture tensile strength is high, tension set is large, and tear strength is high, the performance of resistance to chemical attack etc., can be widely used in the underground waterproof engineering such as tunnel, culvert, subway.
Accompanying drawing explanation
Fig. 1 is the structural representation easily welding waterproof roll without folding line.
Embodiment
The structure of waterproof roll is easily welded without folding line and principle is described in further detail to provided by the present invention below in conjunction with accompanying drawing.
Be illustrated in figure 1 the structural representation easily welding waterproof roll without folding line provided by the present invention, this structure comprises the sheet material 1 of the 0.2mm-2.0mm thickness rolled by polyethylene, POE, EVA, polyethylene toughner, maleic anhydride compatilizer and polyolefine anti-aging agent cobasis mixed melting, the non-bituminous self-adhesive glue layer 2 that a layer thickness is 0.3mm-1.0mm is compounded with in a side of this sheet material, this self-adhesive aspect overlies separating film layer 3, namely forms single side self and easily welds waterproof roll without folding line.Easily welding the another side compound last layer self-adhesive glue layer of the structure plate 1 of waterproof roll without folding line and overlying separating film layer 3 in self-adhesive aspect as shown in Figure 1, namely form double-sided self-adhesive and easily weld waterproof roll without folding line.
The preparation process that above-mentioned single side self easily welds waterproof roll without folding line is, get polyethylene, POE, EVA, polyethylene toughner, maleic anhydride compatilizer and polyolefine anti-aging agent batching mix and blend in proportion, then heating plasticizing is extruded and is rolled into the sheet material of specific thickness, non-bituminous self-adhesive is drenched to above-mentioned plate surface calendering formation more simultaneously, after above-mentioned non-bituminous self-adhesive glue layer covers barrier film on the surface, through overcooling rolling.
Prepare and above-mentionedly easily to weld in the preparation technology of waterproof roll without folding line, form the selection of the various materials of sheet material:
Embodiment 1:
The polyolefine anti-aging agent of polyethylene 68 weight part, POE 18 weight part, EVA 11 weight part, polyethylene toughner 6 weight part, maleic anhydride compatilizer 5 weight part and 1 weight part.
In addition, the self-adhesive glue layer that formation easily welds waterproof roll without folding line is non-bituminous self-adhesive, separating film layer is PET polyester film.
After testing, the fracture tensile strength of the sheet material of the coiled material prepared by above-mentioned materials is 20MPa, and tension set is 810%, and tear strength is 105KN/m, and welding temperature is 360 DEG C, and under the environment of subzero 38 DEG C, it paves functional.
Embodiment 2:
The polyolefine anti-aging agent of polyethylene 70 weight part, POE 16 weight part, EVA 10 weight part, polyethylene toughner 7 weight part, maleic anhydride compatilizer 6 weight part and 1.5 weight parts.
In addition, the self-adhesive glue layer that formation easily welds waterproof roll without folding line is non-bituminous self-adhesive, separating film layer is PET polyester film.
After testing, the fracture tensile strength of the sheet material of the coiled material prepared by above-mentioned materials is 19.8MPa, and tension set is 820%, and tear strength is 110KN/m, and welding temperature is 340 DEG C, and under the environment of subzero 42 DEG C, it paves functional.
Embodiment 3:
The polyolefine anti-aging agent of polyethylene 65 weight part, POE 15 weight part, EVA 9 weight part, polyethylene toughner 5 weight part, maleic anhydride compatilizer 4 weight part and 1.6 weight parts.
In addition, the self-adhesive glue layer that formation easily welds waterproof roll without folding line is non-bituminous self-adhesive, separating film layer is PET polyester film.
After testing, the fracture tensile strength of the sheet material of the coiled material prepared by above-mentioned materials is 20.2MPa, and tension set is 805%, and tear strength is 102KN/m, and welding temperature is 350 DEG C, and under the environment of subzero 41 DEG C, it paves functional.
Embodiment 4:
The polyolefine anti-aging agent of polyethylene 66 weight part, POE 17 weight part, EVA 12 weight part, polyethylene toughner 5 weight part, maleic anhydride compatilizer 6 weight part and 2.0 weight parts.
In addition, the self-adhesive glue layer that formation easily welds waterproof roll without folding line is non-bituminous self-adhesive, separating film layer is PET polyester film.
After testing, the fracture tensile strength of the sheet material of the coiled material prepared by above-mentioned materials is 21MPa, and tension set is 800%, and tear strength is 108KN/m, and welding temperature is 320 DEG C, and under the environment of subzero 39 DEG C, it paves functional.
The fracture tensile strength that coiled material prepared by above-mentioned materials is used in all is greater than 19MPa, and tension set is greater than 800%, and tear strength is greater than 100KN/m.

Claims (2)

1. one kind is easily welded waterproof roll without folding line, the barrier film that its structure comprises sheet material, is compound in the non-bituminous self-adhesive glue layer on one side or two sides and is overlying in described self-adhesive aspect, is characterized in that: described sheet material comprises the polyolefine anti-aging agent of the polyethylene of 65-70 weight parts, the POE of 15-18 weight parts, the EVA of 10-12 weight parts, the polyethylene toughner of 5-7 weight parts, the maleic anhydride compatilizer of 4-6 weight parts and 1-2 weight parts.
2. one as claimed in claim 1 easily welds waterproof roll without folding line, and it is characterized in that: the thickness of described sheet material is arranged on 0.2mm-2.0mm, the thickness of described non-bituminous self-adhesive glue layer is 0.3mm-1.0mm.
CN201510017711.4A 2015-01-14 2015-01-14 One kind easily welds waterproof roll without folding line Active CN104531000B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106046530A (en) * 2016-08-15 2016-10-26 东莞市悠悠美居家居制造有限公司 Vinyl acetate resin sheet material and printing and laminating process
CN106220984A (en) * 2016-08-12 2016-12-14 广州大禹防漏技术开发有限公司 A kind of high anti-tearing strength EVA waterproof sheet and preparation method thereof
CN106543914A (en) * 2016-10-18 2017-03-29 广州大禹防漏技术开发有限公司 One kind overlays type polyolefin self-adhesion glued membrane waterproof sheet and preparation method thereof
CN106883493A (en) * 2017-03-22 2017-06-23 广西金雨伞防水装饰有限公司 A kind of CPS prespreadings waterproof roll and preparation method thereof
CN107521195A (en) * 2016-06-22 2017-12-29 潍坊市宏源防水材料有限公司 A kind of macromolecular compounded waterproof material and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001279226A (en) * 2000-01-25 2001-10-10 Mitsubishi Plastics Ind Ltd Laminated film
CN101694113A (en) * 2009-10-23 2010-04-14 衡水中铁建土工材料制造有限公司 Linear low-density polyethylene waterproof board
CN103059376A (en) * 2012-12-24 2013-04-24 常州南京大学高新技术研究院 Enhanced toughening recycled polyethylene material and preparation method thereof
CN103374162A (en) * 2012-04-18 2013-10-30 建德市嘉和新型材料有限公司 Toughening and rigidity-improving difunctional filling master batch and preparation method thereof
CN104059553A (en) * 2014-06-11 2014-09-24 胜利油田大明新型建筑防水材料有限责任公司 Preparation method of high-polymer self-adhesive waterproof roll

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001279226A (en) * 2000-01-25 2001-10-10 Mitsubishi Plastics Ind Ltd Laminated film
CN101694113A (en) * 2009-10-23 2010-04-14 衡水中铁建土工材料制造有限公司 Linear low-density polyethylene waterproof board
CN103374162A (en) * 2012-04-18 2013-10-30 建德市嘉和新型材料有限公司 Toughening and rigidity-improving difunctional filling master batch and preparation method thereof
CN103059376A (en) * 2012-12-24 2013-04-24 常州南京大学高新技术研究院 Enhanced toughening recycled polyethylene material and preparation method thereof
CN104059553A (en) * 2014-06-11 2014-09-24 胜利油田大明新型建筑防水材料有限责任公司 Preparation method of high-polymer self-adhesive waterproof roll

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107521195A (en) * 2016-06-22 2017-12-29 潍坊市宏源防水材料有限公司 A kind of macromolecular compounded waterproof material and preparation method thereof
CN106220984A (en) * 2016-08-12 2016-12-14 广州大禹防漏技术开发有限公司 A kind of high anti-tearing strength EVA waterproof sheet and preparation method thereof
CN106046530A (en) * 2016-08-15 2016-10-26 东莞市悠悠美居家居制造有限公司 Vinyl acetate resin sheet material and printing and laminating process
CN106046530B (en) * 2016-08-15 2018-07-27 东莞市悠悠美居家居制造有限公司 A kind of vinyl acetate resin sheet material and its printing attaching process
CN106543914A (en) * 2016-10-18 2017-03-29 广州大禹防漏技术开发有限公司 One kind overlays type polyolefin self-adhesion glued membrane waterproof sheet and preparation method thereof
CN106883493A (en) * 2017-03-22 2017-06-23 广西金雨伞防水装饰有限公司 A kind of CPS prespreadings waterproof roll and preparation method thereof

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