CN104522009A - Clorfenapir and fenobucarb-containing insecticidal composition - Google Patents
Clorfenapir and fenobucarb-containing insecticidal composition Download PDFInfo
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- CN104522009A CN104522009A CN201410680740.4A CN201410680740A CN104522009A CN 104522009 A CN104522009 A CN 104522009A CN 201410680740 A CN201410680740 A CN 201410680740A CN 104522009 A CN104522009 A CN 104522009A
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- bassa
- capillary
- fenobucarb
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Abstract
The invention discloses a clorfenapir and fenobucarb-containing insecticidal composition including active ingredients of chlorfenapyr and fenobucarb, the weight ratio of chlorfenapyr to fenobucarb is 1: 80 to 80: 1, the total weight of chlorfenapyr and fenobucarb accounts for 5%-70% of the weight of the composition, the composition can be prepared into any pesticide-acceptable dosage form, and a preferred dosage form is a suspending agent, a water dispersible granule, wettable powder, microemulsion and emulsion in water. The clorfenapir and fenobucarb-containing insecticidal composition has synergistic effect on pests by chlorfenapyr and fenobucarb compounding, improves the control effect, reduces pesticide use, is friendly to the environment, reduces the cost of farmers, is reasonable in components, is conducive to preventing and delaying of the resistance of the pests, expands the spectrum of prevention, can control a variety of insect pests by application for one time, has remarkable economic benefit and social benefit, and is used for the control of rice planthoppers and thrips.
Description
Technical field
The present invention relates to technical field of pesticide, particularly relating to a kind of Pesticidal combination containing capillary and Bassa, for preventing and treating agricultural chemicals insect, being particularly applied to the control of rice fulgorid, thrips.
Background technology
Capillary, english common name: chlorfenapyr, it is new pyrrole compounds, act on the mitochondria of insect bodies inner cell, worked by the mixed-functional oxidase in insect bodies, main suppression adenosine diphosphate (ADP) is to the conversion of adenosine triphosphate (ATP), and adenosine triphosphate stored cells maintains the necessary energy of its vital functions.This medical instrument has stomach toxicity and action of contace poison.Strong in blade face permeability, there is certain systemic action, and have the advantages that insecticidal spectrum is wide, preventive effect is high, holding effect is long, safe, effectively can prevent and treat aphid, thrips, diamond-back moth, aleyrodid etc. on vegetables, cotton.Its molecular structural formula is:
Bassa, English name: Fenobucarb, belongs to carbamate insecticide, has stronger action of contace poison, have stomach poison function concurrently, quick-acting, but the longevity of residure is shorter.Main control rice fulgorid, thrips, aphid etc.Its molecular structural formula is:
At present, agricultural chemicals does the Main Means application of agricultural pests widely as chemical control.But the agricultural chemicals of Long-Time Service single variety, easily impels insect to produce certain resistance, peasant household is often through adopting the consumption mode increasing the weight of agricultural chemicals for this reason, to reach the object eliminated destructive insects.But adopt and just also exist in this way, larger pollution and the problem of residue of pesticide are caused to environment, also indirectly improve the drug cost of peasant household simultaneously.There is not been reported for the complex composition of current capillary and Bassa.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind of Pesticidal combination containing capillary and Bassa be provided, its quick-acting and lasting effect good, cost is lower, good to pest controling effect, particularly has good control efficiency to rice fulgorid and thrips.
The present invention adopts following technical scheme to achieve these goals:
Contain a Pesticidal combination for capillary and Bassa, comprise active component capillary and Bassa, the weight ratio of capillary and Bassa is 1: 80-80: 1.
Preferably, the weight ratio of described capillary and Bassa is 1: 10-10: 1.
The weight percentage that described capillary and Bassa weight summation account for composition is 5%-70%.
Preferably, described capillary and Bassa weight summation account for the weight percentage of composition is 20%-55%.
Described composition can be mixed with any one formulation that agricultural chemicals allows.
Preferably, described formulation is the one in suspending agent, water dispersible granules, wetting powder, microemulsion and aqueous emulsion.
The present composition can be used for control rice fulgorid, thrips.
Composition pesticide of the present invention can be mixed with in suspending agent, water dispersible granules, wetting powder, microemulsion and aqueous emulsion according to method well-known in the art.Preparation is prepared in a known manner, normally active component is fully mixed with surfactant, solvent or solid carrier or grind, granulation.The auxiliary agent used in composition of the present invention comprises solvent, cosolvent, dispersant, emulsifier, wetting agent, stabilizing agent, antifreezing agent, thickener, defoamer, filler etc. and other is of value to the known substance that active ingredient is stablized in the formulation and drug effect plays, all various compositions that are conventional in pesticidal preparations or permission use, be not particularly limited, concrete composition and consumption are determined by test according to recipe requirements.
Compared with the prior art, beneficial effect of the present invention is as follows:
1, the present invention is by capillary and fenobucarb composite, has synergistic function to insect, improves control efficiency, reduces the usage amount of agricultural chemicals, environmentally friendly, reduces the use cost of peasant.
2, present composition component is reasonable, is conducive to the pesticide resistance overcoming and delay insect, and expanding prevention is composed, and a dispenser can prevent and treat various pests simultaneously, has significant economic benefit and social benefit.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is only limitted to absolutely not these examples.The percentage composition mentioned is weight percentage.
Contain a Pesticidal combination for capillary and Bassa, comprise active component capillary and Bassa, the weight ratio of capillary and Bassa is 1: 80-80: 1.
Preferably, the weight ratio of described capillary and Bassa is 1: 10-10: 1.
The weight percentage that described capillary and Bassa weight summation account for composition is 5%-70%.
Preferably, described capillary and Bassa weight summation account for the weight percentage of composition is 20%-55%.
Described composition can be mixed with any one formulation that agricultural chemicals allows.
Preferably, described formulation is the one in suspending agent, water dispersible granules, wetting powder, microemulsion and aqueous emulsion.
The present composition can be used for control rice fulgorid, thrips.
Embodiment 1:
The preparation of 5% capillary Bassa aqueous emulsion:
By capillary and Bassa dissolution with solvents, add emulsifier for mixing to transparent in oil phase, antifreezing agent will be stablized and mix with water homogeneous as aqueous phase.Under 5000 revs/min of shear conditions, oil phase is slowly added in aqueous phase and stirs 30 minutes, form the aqueous emulsion of favorable dispersibility.
Embodiment 2:
The preparation of 20% capillary Bassa microemulsion:
Two kinds of active component solvents, cosolvent are dissolved, adds emulsifier for mixing to transparent in oil phase, antifreezing agent will be stablized and mix with water homogeneous as aqueous phase.Oil phase is slowly added drop-wise in aqueous phase, stirs the microemulsion that 60 minutes form favorable dispersibility.
Embodiment 3:
The preparation of 24% capillary Bassa suspending agent:
Two kinds of active components, dispersant, wetting agent, thickener and water are mixed in the ratio of formula successively, after sand mill grinding, obtains suspending agent.
Embodiment 4:
The preparation of 55% capillary Bassa wetting powder:
The ratio in formula such as two kinds of active components, dispersant, wetting agent and fillers is fully mixed, below ultra-fine pulverizer disintegrating to 20 μm, obtains wetting powder.
Embodiment 5:
The preparation of 70% capillary Bassa water dispersible granules:
Active component, dispersant, wetting agent, binding agent, disintegrant and the filler ratio in formula is added in blender successively, mix, particle diameter less than 10 μm Wettable Powder are become through air-flow crushing, material is made in the water mixing extruding adding 5% ~ 15% again, obtains water-dispersible granules after drying screening.
Test example:
1, capillary and the various proportioning of Bassa are to the field efficiency test of Brown Planthopper.
Trial crops is paddy rice, and controlling object is Brown Planthopper.By embodiment 1,2,3,4,5 totally 5 kinds of medicaments carry out after respectively water evenly being diluted spraying process, if medicament contrast and blank clear water contrast.Group arrangement in random district between process, often kind of process repeats for three times.1 day, 3 days and 7 days investigation number of pest after medicine respectively, calculate lethality and control efficiency, result of the test is as shown in table 1:
After table 1 different disposal medicine, 1d, 3d and 7d are to the field test results of Brown Planthopper
Process | Mu dosage | 1 day preventive effect after medicine | 3 days preventive effects after medicine | 7 days preventive effects after medicine |
Example of formulations 1 | 20ml | 87.32% | 90.66% | 92.99% |
Example of formulations 2 | 20ml | 92.22% | 94.88% | 98.87% |
Example of formulations 3 | 20ml | 93.72% | 95.98% | 98.98% |
Example of formulations 4 | 20g | 94.99% | 96.99% | 99.33% |
Example of formulations 5 | 20g | 90.21% | 92.65% | 96.22% |
10% capillary suspending agent | 30ml | 70.62% | 80.45% | 83.09% |
20% Bassa soluble granule | 30g | 75.32% | 83.65% | 86.87% |
The blank CK of clear water | / | / | / | / |
Note: in table, data are repeat mean value 3 times.
As can be seen from the result of the test of table 1, after medicine, the preventive effect of the 1st day, 3 days, 7 days each example of formulations 1,2,3,4,5 pairs of Brown Planthoppers is all apparently higher than the preventive effect of 10% capillary suspending agent, 20% Bassa solvable pulvis two single dose, shows that two kinds of composite reagent synergy are obvious.
2, capillary and the various proportioning of Bassa are to the field efficiency test of paddy rice thrips.
Test controlling object paddy rice thrips.By embodiment 1,2,3,4,5 totally five kinds of medicaments carry out after respectively water evenly being diluted spraying process, if medicament contrast and blank clear water contrast.Group arrangement in random district between process, often kind of process repeats for three times.1 day, 3 days and 7 days investigation number of pest after medicine respectively, calculate lethality and control efficiency, result of the test is as shown in table 2:
After table 2 different disposal medicine, 1d, 3d and 7d are to the field test results of paddy rice thrips
Process | Mu dosage | 1 day preventive effect after medicine | 3 days preventive effects after medicine | 7 days preventive effects after medicine |
Example of formulations 1 | 20ml | 89.33% | 91.88% | 94.89% |
Example of formulations 2 | 20ml | 92.01% | 93.98% | 97.98% |
Example of formulations 3 | 20ml | 92.56% | 94.77% | 98.35% |
Example of formulations 4 | 20g | 93.66% | 95.78% | 99.05% |
Example of formulations 5 | 20g | 92.89% | 94.89% | 97.67% |
10% capillary suspending agent | 30ml | 74.69% | 82.79% | 85.66% |
20% Bassa soluble granule | 30g | 73.78% | 80.45% | 86.78% |
The blank CK of clear water | / | / | / | / |
Note: in table, data are repeat mean value 3 times.
As can be seen from the result of the test of table 2, after medicine, the preventive effect of the 1st day, 3 days, 7 days each example of formulations 1,2,3,4,5 pairs of paddy rice thrips is all apparently higher than the preventive effect of 10% capillary suspending agent, 20% Bassa solvable pulvis two single dose, shows that two kinds of composite reagent synergy are obvious.
In sum, the present invention contains the Pesticidal combination of capillary and Bassa, has good control efficiency to rice fulgorid, thrips, its activity and insecticidal effect are not the simple superposition of each composition activity, complex preparation not only increases preventive effect, has significant synergy and rents, and expand insecticidal spectrum, widen the scope of application, reduce costs, the double effect controlled of a medicine is played to multiple insect pest, slows down the generation of resistance, alleviate manpower and materials, improve productivity effect.
Claims (7)
1. contain a Pesticidal combination for capillary and Bassa, it is characterized in that: comprise active component capillary and Bassa, the weight ratio of capillary and Bassa is 1: 80-80: 1.
2. the Pesticidal combination containing capillary and Bassa according to claim 1, is characterized in that: the weight ratio of described capillary and Bassa is 1: 10-10: 1.
3. the Pesticidal combination containing capillary and Bassa according to claim 1, is characterized in that: the weight percentage that described capillary and Bassa weight summation account for composition is 5%-70%.
4. the Pesticidal combination containing capillary and Bassa according to claim 1, is characterized in that: the weight percentage that described capillary and Bassa weight summation account for composition is 20%-55%.
5. the Pesticidal combination containing capillary and Bassa according to claim 1, is characterized in that: described composition can be mixed with any one formulation that agricultural chemicals allows.
6. the Pesticidal combination containing capillary and Bassa according to claim 5, is characterized in that: described formulation is the one in suspending agent, water dispersible granules, wetting powder, microemulsion and aqueous emulsion.
7. the Pesticidal combination containing capillary and Bassa according to claim 1 is for preventing and treating the purposes of rice fulgorid, thrips.
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CN201410680740.4A CN104522009A (en) | 2014-11-21 | 2014-11-21 | Clorfenapir and fenobucarb-containing insecticidal composition |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10287512A (en) * | 1997-04-09 | 1998-10-27 | Sumitomo Chem Co Ltd | Harmful organism controlling agent composition |
CN1163131C (en) * | 1996-12-11 | 2004-08-25 | 美国氰胺公司 | Insecticidal and miticidal composition |
CN101606517A (en) * | 2009-07-27 | 2009-12-23 | 深圳诺普信农化股份有限公司 | A kind of farm chemical emulsion preparation |
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- 2014-11-21 CN CN201410680740.4A patent/CN104522009A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1163131C (en) * | 1996-12-11 | 2004-08-25 | 美国氰胺公司 | Insecticidal and miticidal composition |
JPH10287512A (en) * | 1997-04-09 | 1998-10-27 | Sumitomo Chem Co Ltd | Harmful organism controlling agent composition |
CN101606517A (en) * | 2009-07-27 | 2009-12-23 | 深圳诺普信农化股份有限公司 | A kind of farm chemical emulsion preparation |
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