CN104513607B - A kind of wear-resisting anti-fog coating of photocuring and construction method thereof - Google Patents
A kind of wear-resisting anti-fog coating of photocuring and construction method thereof Download PDFInfo
- Publication number
- CN104513607B CN104513607B CN201410814150.6A CN201410814150A CN104513607B CN 104513607 B CN104513607 B CN 104513607B CN 201410814150 A CN201410814150 A CN 201410814150A CN 104513607 B CN104513607 B CN 104513607B
- Authority
- CN
- China
- Prior art keywords
- coating
- wear
- photocuring
- resisting
- resisting anti
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of wear-resisting anti-fog coating of photocuring, by mass percentage, consist of: light-cured resin 17～52%；The low functionality monomer of photocuring 12～37%；Photocuring high functionality monomer 10～55%；Organosiloxane 10～35%；Light trigger 0.7～6%；Catalyst 0.3～4%；The molecular formula of organosiloxane is as shown in formula I, in formula, and R1、R2、R3、R4Independently selected from: C1～C8Alkyl, C1～C3Alkoxyl, aryl, amido, thiazolinyl, epoxy radicals, acryloyl group, methylacryloyl or sulfydryl, and formula at least three be alkoxyl；Catalyst is photoacid generator or Photobase generator.The wear-resisting anti-fog coating of photocuring of the present invention, the SiO that only through a step solidification, hydrophobic dura mater and coating situ need to be generated2Nanoparticle combines, it is ensured that inorganic nanoparticles in the coating dispersed, improves the anti-wear performance of coating；
Description
Technical field
The present invention relates to coating manufacture field, particularly relate to a kind of wear-resisting anti-fog coating of photocuring and execute
Work method.
Background technology
Polymer coating has been widely used in needing substrate surface that is to be protected or that increase aesthetic feeling,
Such as automobile polishing paint, floor varnish, thickening presoma and improve wear-resisting scratch resistance performance coating.This
Wherein, along with transparent base is employed more and more widely, such as optical glass, automobile headlamp, build
Building glass, all kinds of instrument and meter dish etc., its wear-resisting anti-fog performance has obtained numerous researcher the most gradually
Attention.
In the wear-resisting field of polymer coating, current the most frequently used most efficient method has two kinds, and one is excellent
Changing coating formula, another kind is then to add filler in the coating.It is known that nano-particle can be
Significantly improve coating machine performance, the transparency of coating is not produced impact.Under normal circumstances, these
Nano-particle is (such as SiO2、ZrO2And TiO2) surface modification can be carried out by organosilicon, to improve
Granule dispersibility in polymer support, also there are some researches prove, is filled with these nano-particle gained
To coating there is good anti-wear performance.
But, filling nano inoganic particle has a critically important problem, that is, they are at organic group
Being homogeneously difficult in body disperses, and is easily caused macroface and separates.Even when nano-particle is organic
When matrix disperses in order, still it may happen that phenomenon of phase separation in follow-up solidification process, affect whole
The mechanical performance of coating.It addition, the high concentration of nano-particle, may unexpectedly improve viscous
Degree, affects the application of coating.
For these problems of inorganic nano, alternative method currently mainly is to use sol-gel process.
Sol-gel process is inorganic salt or metal alkoxide to be dissolved in solvent, adds after forming uniform solution
, at a certain temperature, there is a series of hydrolysis and condensation reaction, generate nanometer particle in other component
And forming colloidal sol, drying and sintering etc. process and make material requested the most again.Although, this method
The hybrid system obtained, it is possible to realize coating occur without be separated while, improve material
Mechanical performance, but this method still has a limitation for preparation coating: preparation and coated
Journey is complicated, and energy consumption is high, and reaction temperature is higher than base material ability to bear etc..
At present, in coating industry, photocureable coating is because of its high-efficiency and economic, wide adaptability, energy-conservation
The features such as environmental protection and be widely applied very much.The most domestic the most in the world, photocuring be coated with
The annual production of material is all increasing year by year.Particularly with transparent plastic substrate (such as the daily eye worn
Thin film on mirror, warmhouse booth etc.) for, in the case of photocureable coating even spread,
UV illumination 1-5min, speed is fast, easy and simple to handle, energy consumption is low, need not be as heat cure
Worry base material heated problem.
Antifog is another big problem of transparent base.When transparent solid surfaces mist formation, light passes
Reflection that " mist " (actual formed at the surface of solids for water recovery droplet) can occur and refraction,
The light transmittance making this solid declines, and also reduces the service efficiency of this transparent material.Often adopt people
In the heating, convection current method and the Coating Method that take, although first two method can be by preventing water vapour
The mode that condenses and the most antifog, but energy consumption is high, operating cost height, and has the biggest operation office
Sex-limited.And coating rule by constructing certain structure or can pass through the coating performance to water itself,
Reach the most excellent anti-fog effect, the most any energy loss.So, from energy-conservation
Angle considers, Coating Method or even photocureable coating method are one more preferably anti-fog methods.
Summary of the invention
The invention provides a kind of wear-resisting anti-fog coating of photocuring, can solidify through a step, by hydrophobic firmly
The SiO that film and coating situ generate2Nanoparticle combines, it is ensured that inorganic nanoparticles is being coated with
Dispersed in Ceng, improves the anti-wear performance of coating.
A kind of wear-resisting anti-fog coating of photocuring, by mass percentage, the wear-resisting antifog painting of described photocuring
Consisting of of material:
The molecular formula of described organosiloxane is as shown in formula I:
In formula, R1、R2、R3、R4Independently selected from: C1～C8Alkyl, C1～C3Alcoxyl
Base, aryl, amido, thiazolinyl, epoxy radicals, acryloyl group, methylacryloyl or sulfydryl, and formula
In at least three be alkoxyl；
Described catalyst is photoacid generator or Photobase generator.
As preferably, described light-cured resin is epoxy acrylate, urethane acrylate, gathers
At least one in ester acrylate, acrylated epoxy, polyether acrylate, enters one
Preferably, degree of functionality >=3 of selected light-cured resin, wherein, urethane acrylate is more preferably for step
Aromatic urethane acrylate；The low functionality monomer of described photocuring is selected from Polyethylene Glycol two propylene
Acid esters, polyethylene glycol dimethacrylate, polyethylene glycol monoacrylate, methoxy poly (ethylene glycol)
Mono acrylic ester, methoxy poly (ethylene glycol) monomethacrylates, 2-(Acryloyloxy)ethanol, metering system
Acid hydroxyl ethyl ester, Hydroxypropyl acrylate, Hydroxypropyl methacrylate, 2-(ethoxyethoxy) ethylene glycol third
At least one in olefin(e) acid ester, bisphenol-A-propyl-dimethyl acrylate；
Described photocuring high functionality monomer is selected from trimethylolpropane trimethacrylate, glycerol 3 third
Olefin(e) acid ester, tetramethylol methane tetraacrylate, Dipentaerythritol Pentaacrylate, dipentaerythritol 6 third
At least one in olefin(e) acid ester.
As preferably, described photoacid generator is selected from salt, aryl diazonium salt, metallocene salt or adjacent nitre
Benzaldehyde；Described Photobase generator is selected from carbamates, ketoxime ester, benzamide type.
Further preferably, by mass percentage, the consisting of of the wear-resisting anti-fog coating of described photocuring:
Further preferably:
Described light-cured resin is aromatic urethane acrylate and/or polyester acrylate resin；
The low functionality monomer of described photocuring is polyethylene glycol dimethacrylate and/or methyl-prop
Olefin(e) acid hydroxyl ethyl ester；
Described photocuring high functionality monomer is trimethylolpropane trimethacrylate and/or Ji Wusi
Alcohol tetraacrylate；
Described organosiloxane is glycidyl ether oxygen propyl trimethoxy silicane and/or acryloyl-oxy
Base propyl trimethoxy silicane；
Described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone, by mass percentage,
The consumption of described light trigger is 3%；
Described catalyst is diaryl group iodized salt, triaryl sulfonium salts or benzyq carbamate, by matter
Amount percentages, the consumption of described catalyst is 1%.
A kind of construction method of the described wear-resisting anti-fog coating of photocuring, by described each raw material mixing,
It is coated on after being uniformly dispersed in substrate, after ultraviolet light polymerization, obtains the wear-resisting antifogging coating of photocuring.
Compared with prior art, present invention have the advantage that
The present invention is through one-step method, the SiO hydrophobic dura mater and coating situ generated2Nanoparticle phase
In conjunction with, it is ensured that inorganic nanoparticles in the coating dispersed, improve the anti-wear performance of coating,
Add the anti-fog performance of coating simultaneously.
The coating that the present invention prepares has that curing rate is fast, operating cost is low, clean and effective is without dirt
The features such as dye.
Detailed description of the invention
The performance test methods preparing coating in following example is as follows:
1, the method for testing of coating anti-fog performance:
1) coating after solidification being placed on relative humidity is 80%, and temperature is in the environment of 37 DEG C, sees
Examine whether surface hazes, record the time without vaporific state；
2) being placed on by the coating after solidification above the hot water of 60 DEG C at 5cm, whether observation surface rises
Mist, records the time without vaporific state；
3) coating after solidification is placed in the refrigerator of-20 DEG C, takes out after 30min, observe surface
Whether haze.
2, the pencil hardness test of coating is carried out according to GB/T 6739-2006.
Embodiment 1
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 2
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 3
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 4
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 5
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 6
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 7
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 8
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 9
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 10
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 11
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 12
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 13
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 14
Change the aromatic urethane acrylate resin in embodiment 1 into epoxy acrylic resin, its
Its raw material, consumption and step are the most in the same manner as in Example 1, it is thus achieved that wear-resisting antifog article, product
1 can be shown in Table.
Embodiment 15
Change the glycidyl ether oxygen propyl trimethoxy silicane in embodiment 1 into acryloxypropyl
Trimethoxy silane, other raw material, consumption and step are the most in the same manner as in Example 1, it is thus achieved that wear-resisting
Antifog article, properties of product are shown in Table 1.
Embodiment 16
In addition to using 10 μm bar spreaders that coating is coated in clean polyester (PET) film surface,
Other step is the most in the same manner as in Example 1, it is thus achieved that wear-resisting antifog article, and properties of product are shown in Table 1.
Embodiment 17
In addition to using 50 μm bar spreaders that coating is coated in polyester (PET) film surface, its
Its step is the most in the same manner as in Example 1, it is thus achieved that wear-resisting antifog article, and properties of product are shown in Table 1.
Embodiment 18
In addition to changing clean transparent polyester (PET) film into clean sheet glass, other step all with
In embodiment 1 identical, it is thus achieved that wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 19
In addition to making light intensity into 50mW, other step is the most in the same manner as in Example 1, it is thus achieved that resistance to
The antifog article of mill, properties of product are shown in Table 1.
Embodiment 20
In addition to light application time is reduced to 1min, other step is the most in the same manner as in Example 1,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 21
In addition to light application time is increased to 5min, other step is the most in the same manner as in Example 1,
Obtaining wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 22
Except changing diaryl group iodized salt into triaryl sulfonium salts, other raw material, consumption and step all with
In embodiment 1 identical, it is thus achieved that wear-resisting antifog article, properties of product are shown in Table 1.
Embodiment 23
Except changing diaryl group iodized salt into benzyq carbamate, other raw material, consumption and step all with
In embodiment 1 identical, it is thus achieved that wear-resisting antifog article, properties of product are shown in Table 1.
Comparative example 1
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining the poor goods of wear-resisting anti-fog performance, properties of product are shown in Table 1.
Comparative example 2
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining the poor goods of wear-resisting anti-fog performance, properties of product are shown in Table 1.
Comparative example 3
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining the poor goods of wear-resisting anti-fog performance, properties of product are shown in Table 1.
Comparative example 4
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining the poor goods of wear-resisting anti-fog performance, properties of product are shown in Table 1.
Comparative example 5
Coating is carried out according to following formulation for coating material:
It is dispersed to the clarification of whole coating system with ultrasonator, is coated in dry with 20 μm bar spreaders
On clean transparent polyester (PET) film surface, it is 20mW/cm by light intensity2Ultraviolet light curing 3min,
Obtaining the poor goods of wear-resisting anti-fog performance, properties of product are shown in Table 1.
Table 1
Note: zero represents that coating has anti-fog effect in this test；
× represent coating the most anti-fog effect in this test.
Claims (1)
1. the wear-resisting anti-fog coating of photocuring, it is characterised in that by mass percentage, described
Consisting of of the wear-resisting anti-fog coating of photocuring:
Described light-cured resin is aromatic urethane acrylate and/or polyester acrylate resin；
The low functionality monomer of described photocuring is polyethylene glycol dimethacrylate and/or methyl-prop
Olefin(e) acid hydroxyl ethyl ester；
Described photocuring high functionality monomer is trimethylolpropane trimethacrylate and/or Ji Wusi
Alcohol tetraacrylate；
Described organosiloxane is glycidyl ether oxygen propyl trimethoxy silicane and/or acryloyl-oxy
Base propyl trimethoxy silicane；
Described light trigger is 2-hydroxy-2-methyl-1-phenyl-1-acetone；
Described catalyst is diaryl group iodized salt, triaryl sulfonium salts or benzyq carbamate；
The construction method of the wear-resisting anti-fog coating of described photocuring is:
By described each raw material mixing, it is coated on after being uniformly dispersed in substrate, after ultraviolet light polymerization,
Obtain the wear-resisting antifogging coating of photocuring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410814150.6A CN104513607B (en) | 2014-12-24 | 2014-12-24 | A kind of wear-resisting anti-fog coating of photocuring and construction method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410814150.6A CN104513607B (en) | 2014-12-24 | 2014-12-24 | A kind of wear-resisting anti-fog coating of photocuring and construction method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104513607A CN104513607A (en) | 2015-04-15 |
| CN104513607B true CN104513607B (en) | 2016-09-28 |
Family
ID=52789489
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410814150.6A Active CN104513607B (en) | 2014-12-24 | 2014-12-24 | A kind of wear-resisting anti-fog coating of photocuring and construction method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104513607B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251716A (en) * | 2018-06-29 | 2019-01-22 | 张家港康得新光电材料有限公司 | Ultraviolet light curing anti fogging glue and preparation method thereof |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877554A (en) * | 2015-05-29 | 2015-09-02 | 成都纳硕科技有限公司 | Photocureable coating for metal and preparation method of photocureable coating |
| CN105295842A (en) * | 2015-09-30 | 2016-02-03 | 江苏耀兴安全玻璃有限公司 | Preparation method of antifogging agent used for windshield |
| TWI758475B (en) * | 2017-05-10 | 2022-03-21 | 學校法人東京理科大學 | Active energy ray-curable composition, method for producing cured film and cured product |
| CN110054758A (en) * | 2019-04-30 | 2019-07-26 | 广州五行材料科技有限公司 | A kind of Water/oil dual-purpose water boiling resistance photo-curing epoxy resin and its preparation method and application that water solubility is transparent |
| CN110616034B (en) * | 2019-10-24 | 2022-02-22 | 芜湖春风新材料有限公司 | Anti-fog UV coating for automobile exterior trimming part and automobile lamp, preparation method of anti-fog UV coating and paint film formed by anti-fog UV coating |
| JP7370817B2 (en) * | 2019-11-01 | 2023-10-30 | 古河電気工業株式会社 | Coating material, resin coating structure using the same, and electric wire with terminal |
| CN112029399B (en) * | 2020-08-17 | 2022-02-18 | 湖南尚鑫新材料科技有限公司 | Antifogging coating and preparation method thereof |
| CN111978861B (en) * | 2020-09-01 | 2021-11-23 | 淮阴工学院 | Preparation method of phenyl polysiloxane super-hydrophobic coating |
| CN112094586B (en) * | 2020-09-22 | 2021-11-09 | 丹阳市精通眼镜技术创新服务中心有限公司 | High-wear-resistance hydrophobic coating and preparation method thereof |
| CN113956781B (en) * | 2021-09-22 | 2022-10-21 | 杭州梵因科技有限公司 | Preparation method of nano enhanced ultraviolet curing antifogging agent |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875710A (en) * | 2010-06-30 | 2010-11-03 | 长兴化学材料(珠海)有限公司 | Siloxane-group light-initiated polyacrylic ester/silicon dioxide nanometer material and preparation method thereof |
| CN102329557A (en) * | 2011-08-10 | 2012-01-25 | 湖南松井新材料有限公司 | Ultraviolet curing paint |
| CN102559038A (en) * | 2012-02-16 | 2012-07-11 | 长沙市原鹏化工科技有限公司 | Organosilicon-modified polyurethane-acrylic ester photocurable coating and preparation method thereof |
| CN102993440A (en) * | 2011-09-16 | 2013-03-27 | 北京化工大学 | Photocuring nano hybrid material, and synthesis method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3938528B2 (en) * | 2002-08-05 | 2007-06-27 | 株式会社豊田中央研究所 | Coating composition, method for producing abrasion-resistant coating film using coating composition, and abrasion-resistant coating film comprising coating composition |
-
2014
- 2014-12-24 CN CN201410814150.6A patent/CN104513607B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875710A (en) * | 2010-06-30 | 2010-11-03 | 长兴化学材料(珠海)有限公司 | Siloxane-group light-initiated polyacrylic ester/silicon dioxide nanometer material and preparation method thereof |
| CN102329557A (en) * | 2011-08-10 | 2012-01-25 | 湖南松井新材料有限公司 | Ultraviolet curing paint |
| CN102993440A (en) * | 2011-09-16 | 2013-03-27 | 北京化工大学 | Photocuring nano hybrid material, and synthesis method and application thereof |
| CN102559038A (en) * | 2012-02-16 | 2012-07-11 | 长沙市原鹏化工科技有限公司 | Organosilicon-modified polyurethane-acrylic ester photocurable coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109251716A (en) * | 2018-06-29 | 2019-01-22 | 张家港康得新光电材料有限公司 | Ultraviolet light curing anti fogging glue and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104513607A (en) | 2015-04-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104513607B (en) | A kind of wear-resisting anti-fog coating of photocuring and construction method thereof | |
| Wong et al. | Ultra-durable and transparent self-cleaning surfaces by large-scale self-assembly of hierarchical interpenetrated polymer networks | |
| Manabe et al. | Optical phenomena and antifrosting property on biomimetics slippery fluid-infused antireflective films via layer-by-layer comparison with superhydrophobic and antireflective films | |
| CN1176756C (en) | Method for producing microstructured surface relief by embossing thixotropic layers | |
| Li et al. | Facile synthesis of highly transparent polymer nanocomposites by introduction of core–shell structured nanoparticles | |
| England et al. | Anti-fogging/self-healing properties of clay-containing transparent nanocomposite thin films | |
| JP5520237B2 (en) | Transparent coating material of nanoparticle sol-gel composite hybrid | |
| Liu et al. | High-refractive-index polymer/inorganic hybrid films containing high TiO2 contents | |
| CN102985499B (en) | Antireflection film and method for manufacturing same | |
| TWI707932B (en) | Hardcoat and related compositions, methods, and articles | |
| CN102239222B (en) | Silica coating for enhanced hydrophilicity | |
| CN107075304A (en) | High-gain durability ARC | |
| Wu et al. | Smooth water-based antismudge coatings for various substrates | |
| Janowicz et al. | Fluorine-free transparent superhydrophobic nanocomposite coatings from mesoporous silica | |
| Yang et al. | Superhydrophobic thermoplastic polyurethane films with transparent/fluorescent performance | |
| CN105916675B (en) | Multi-layer composite materials material products | |
| CN103201349A (en) | Surface treatment process, composition for use therein, and treated article | |
| JP2015511254A (en) | Nanostructured material and method for producing the same | |
| CN101765791A (en) | antireflection laminate | |
| CN101805434A (en) | Super hydrophobic silicon-fluorine polymer/nanometer silica hybridization nanometer material and preparation method thereof | |
| Guo et al. | High-quality hollow closed-pore silica antireflection coatings based on styrene–acrylate emulsion@ organic–inorganic silica precursor | |
| CN102712783A (en) | Plastic substrates having a scratch-resistant coating, in particular housings of electronic devices, having high transparency, method for the production thereof, and use thereof | |
| TWI480345B (en) | Paint, preparing method thereof, and film formed from the paint | |
| CN102460226A (en) | Curable coating composition modified with a cleavable surfactant for improving adhesion in multilayered coating stacks | |
| Luo et al. | Transparent super-repellent surfaces with low haze and high jet impact resistance |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |