CN104497664A - Novel acrylate coating for ceramics - Google Patents
Novel acrylate coating for ceramics Download PDFInfo
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- CN104497664A CN104497664A CN201510008837.5A CN201510008837A CN104497664A CN 104497664 A CN104497664 A CN 104497664A CN 201510008837 A CN201510008837 A CN 201510008837A CN 104497664 A CN104497664 A CN 104497664A
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- acrylate
- glycidyl
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Abstract
The invention discloses a novel acrylate coating for ceramics. The novel acrylate coating is prepared from the following raw materials: toluene diisocyanate, glycidyl acrylate, keto-aldehyde resin, glycidyl methacrylate, dimethylethanolamine, trimethylolpropane triacrylate, a photoinitiator, butyl acrylate, bisphenol A, methyl methacrylate, a crosslinking agent, hydroxyethyl methacrylate, acrylic acid, styrene and carbamate. The novel acrylate coating has grade 1-3 adhesion, can keep the same adhesion after being irradiated with heat and sunlight, can resist the temperature of 130-150 DEG C, can not be changed after being soaked in a 5% hydrochloric acid liquid for 3-5 days, can not blister and peel off after being soaked in saturated calcium hydroxide for 4-8 hours, can resist washing and scrubbing for 2,500-3,000 times, can be produced on a large scale and can replace the existing coatings constantly.
Description
Technical field
The application belongs to paint field, particularly relates to a kind of new ceramics acrylate paint.
Background technology
Along with the development of national economy every profession and trade, progressively develop into the requisite important industry of all fields of national economy as its supporting coatings industry from an extremely unobtrusive little industry.Through the struggling hard of several generations, pioneer and keep forging ahead, China has become second-biggest-in-the-world coating material production state and country of consumption, enters into the main flow of world's coating industry development.Ceramic coating is that one can make organism and inorganics react, thus has had both the novel ceramic coating of both advantages.The hardness of the ceramic coating of a new generation can reach more than 6H.High temperature resistant 400 degree, not sticky effect, color is multiple.And dimethylaminoethanol ceramic coating can be made.Ceramic coating weathering resistance and processing characteristics excellence, bear dirty and resistant to damage.Although ceramic coating resistant to damage in the past, if carry out bending machining to the parts after application, easily cracks, and fluorine resin paints and organic coating, easily by the damage such as sandstone, dust.Therefore, the appearance of ceramic coating, receives the favor of ceramic industry, and the infiltration of forward other industry, promise well.And universal along with humanity concept, and the formation of novel harmonious society, designs that a kind of sticking power is good, protection against corrosion, solvent resistant and wear-resisting pottery acrylate paint is very important.
Summary of the invention
The technical problem solved:
The application, for above-mentioned technical problem, provides a kind of new ceramics acrylate paint, solves that existing pottery acrylate paint sticking power is low, not anticorrosion, not solvent resistant and the technical problem such as to wear no resistance.
Technical scheme:
A kind of new ceramics acrylate paint, the raw materials by weight portion proportioning of described pottery acrylate paint is as follows: tolylene diisocyanate 100 parts; Glycidyl acrylate 30-40 part; Ketone resin 20-40 part; Glycidyl methacrylate 10-30 part; Dimethylaminoethanol 80-100 part; Viscoat 295 1-5 part; Light trigger 5-15 part; Butyl acrylate 40-60 part; Dihydroxyphenyl propane 10-20 part; Methyl methacrylate 10-20 part; Linking agent 1-5 part; Hydroxyethyl methylacrylate 5-10 part; Vinylformic acid 20-30 part; Vinylbenzene 30-40 part; Carbamate 15-25 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described pottery acrylate paint is as follows: tolylene diisocyanate 45 parts; Glycidyl acrylate 20 parts; Ketone resin 25 parts; Glycidyl methacrylate 25 parts; Dimethylaminoethanol 15 parts; Viscoat 295 100 parts; Light trigger 10 parts; Butyl acrylate 10 parts; Dihydroxyphenyl propane is 3 parts; Methyl methacrylate 30 parts; Linking agent 5 parts; Hydroxyethyl methylacrylate 5 parts; 5 parts, vinylformic acid; Vinylbenzene 35 parts; Carbamate 15 parts.
As a preferred technical solution of the present invention: described light trigger adopts Benzoin ethyl ether or benzophenone.
As a preferred technical solution of the present invention: described linking agent adopts hexamethoxymethyl melamine.
Beneficial effect:
A kind of new ceramics acrylate paint of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product sticking power 1-3 level, thermal radiation and tan by the sun sticking power and do not decline; 2, resistance to 130-150 DEG C high temperature, soaks 3-5d without exception in 5% hydrochloric acid soln; 3, in saturated calcium hydroxide, soak that 4-8d is non-foaming, elephant skin; 4, product scrub resistance 2500-3500 time, the widespread production not division of history into periods can replace current material.
Embodiment
Embodiment 1:
A kind of new ceramics acrylate paint, its raw materials by weight portion proportioning is as follows: tolylene diisocyanate 40 parts; Glycidyl acrylate 10 parts; Ketone resin 20 parts; Glycidyl methacrylate 15 parts; Dimethylaminoethanol 10 parts; Viscoat 295 100 parts; Benzoin ethyl ether 5 parts; Butyl acrylate 5 parts; Dihydroxyphenyl propane is 1 part; Methyl methacrylate 25 parts; Hexamethoxymethyl melamine 1 part; Hydroxyethyl methylacrylate 1 part; 2 parts, vinylformic acid; Vinylbenzene 30 parts; Carbamate 10 parts.
Above-mentioned raw materials is heated to 60 degrees Celsius in a kettle., after stirring 6h, is coated on pottery, film ultra violet lamp.
Product sticking power 3 grades, thermal radiation and tan by the sun sticking power and do not decline; Resistance to 130 DEG C of high temperature, soak 3d without exception in 5% hydrochloric acid soln; In saturated calcium hydroxide, soak that 4d is non-foaming, elephant skin, scrub resistance 2500 times.
Embodiment 2:
A kind of new ceramics acrylate paint, its raw materials by weight portion proportioning is as follows: tolylene diisocyanate 50 parts; Glycidyl acrylate 30 parts; Ketone resin 30 parts; Glycidyl methacrylate 35 parts; Dimethylaminoethanol 20 parts; Viscoat 295 100 parts; Benzoin ethyl ether 15 parts; Butyl acrylate 15 parts; Dihydroxyphenyl propane is 5 parts; Methyl methacrylate 35 parts; Hexamethoxymethyl melamine 10 parts; Hydroxyethyl methylacrylate 10 parts; 8 parts, vinylformic acid; Vinylbenzene 40 parts; Carbamate 20 parts.
Above-mentioned raw materials is heated to 80 degrees Celsius in a kettle., after stirring 8h, is coated on pottery, film ultra violet lamp.
Product sticking power 2 grades, thermal radiation and tan by the sun sticking power and do not decline; Resistance to 140 DEG C of high temperature, soak 4d without exception in 5% hydrochloric acid soln; In saturated calcium hydroxide, soak that 6d is non-foaming, elephant skin, scrub resistance 3000 times.
Embodiment 3:
A kind of new ceramics acrylate paint, its raw materials by weight portion proportioning is as follows: tolylene diisocyanate 45 parts; Glycidyl acrylate 20 parts; Ketone resin 25 parts; Glycidyl methacrylate 25 parts; Dimethylaminoethanol 15 parts; Viscoat 295 100 parts; Benzophenone 10 parts; Butyl acrylate 10 parts; Dihydroxyphenyl propane is 3 parts; Methyl methacrylate 30 parts; Hexamethoxymethyl melamine 5 parts; Hydroxyethyl methylacrylate 5 parts; 5 parts, vinylformic acid; Vinylbenzene 35 parts; Carbamate 15 parts.
Above-mentioned raw materials is heated to 70 degrees Celsius in a kettle., after stirring 7h, is coated on pottery, film ultra violet lamp.
Product adhesion 1 grade, thermal radiation and tan by the sun sticking power and do not decline; Resistance to 150 DEG C of high temperature, soak 5d without exception in 5% hydrochloric acid soln; In saturated calcium hydroxide, soak that 8d is non-foaming, elephant skin, scrub resistance 3500 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for setting forth content of the present invention, instead of restriction, and any change therefore in the implication suitable with claims of the present invention and scope, all should think to be included in the scope of claims.
Claims (4)
1. a new ceramics acrylate paint, is characterized in that the raw materials by weight portion proportioning of described pottery acrylate paint is as follows: tolylene diisocyanate 40-50 part; Glycidyl acrylate 10-30 part; Ketone resin 20-30 part; Glycidyl methacrylate 15-35 part; Dimethylaminoethanol 10-20 part; Viscoat 295 100 parts; Light trigger 5-15 part; Butyl acrylate 5-15 part; Dihydroxyphenyl propane is 1-5 part; Methyl methacrylate 25-35 part; Linking agent 1-10 part; Hydroxyethyl methylacrylate 1-10 part; Vinylformic acid 2-8 part; Vinylbenzene 30-40 part; Carbamate 10-20 part.
2. a kind of new ceramics acrylate paint according to claim 1, is characterized in that the raw materials by weight portion proportioning of described pottery acrylate paint is as follows: tolylene diisocyanate 45 parts; Glycidyl acrylate 20 parts; Ketone resin 25 parts; Glycidyl methacrylate 25 parts; Dimethylaminoethanol 15 parts; Viscoat 295 100 parts; Light trigger 10 parts; Butyl acrylate 10 parts; Dihydroxyphenyl propane is 3 parts; Methyl methacrylate 30 parts; Linking agent 5 parts; Hydroxyethyl methylacrylate 5 parts; 5 parts, vinylformic acid; Vinylbenzene 35 parts; Carbamate 15 parts.
3. a kind of new ceramics acrylate paint according to claim 1, is characterized in that: described light trigger adopts Benzoin ethyl ether or benzophenone.
4. a kind of new ceramics acrylate paint according to claim 1, is characterized in that: described linking agent adopts hexamethoxymethyl melamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510008837.5A CN104497664A (en) | 2015-01-08 | 2015-01-08 | Novel acrylate coating for ceramics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510008837.5A CN104497664A (en) | 2015-01-08 | 2015-01-08 | Novel acrylate coating for ceramics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104497664A true CN104497664A (en) | 2015-04-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510008837.5A Pending CN104497664A (en) | 2015-01-08 | 2015-01-08 | Novel acrylate coating for ceramics |
Country Status (1)
| Country | Link |
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| CN (1) | CN104497664A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045116A (en) * | 1988-12-22 | 1990-09-05 | 美国Basf公司 | The electric clad compositions of polyamine self-condensed epoxy adduct and the coating of making |
| CN1526770A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured plastic paint |
| CN1856556A (en) * | 2004-02-03 | 2006-11-01 | 德古萨公司 | Utilization of radiohardenable resins based on ketone and/or urea aldehyde resins |
-
2015
- 2015-01-08 CN CN201510008837.5A patent/CN104497664A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045116A (en) * | 1988-12-22 | 1990-09-05 | 美国Basf公司 | The electric clad compositions of polyamine self-condensed epoxy adduct and the coating of making |
| CN1526770A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured plastic paint |
| CN1856556A (en) * | 2004-02-03 | 2006-11-01 | 德古萨公司 | Utilization of radiohardenable resins based on ketone and/or urea aldehyde resins |
Non-Patent Citations (1)
| Title |
|---|
| 吴海霞等: "《精细化工生产技术》", 31 August 2013, 中国石化出版社 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150408 |