CN104497640A - Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment - Google Patents
Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment Download PDFInfo
- Publication number
- CN104497640A CN104497640A CN201410822024.5A CN201410822024A CN104497640A CN 104497640 A CN104497640 A CN 104497640A CN 201410822024 A CN201410822024 A CN 201410822024A CN 104497640 A CN104497640 A CN 104497640A
- Authority
- CN
- China
- Prior art keywords
- phthalocyanine blue
- iron oxide
- composite pigment
- coated iron
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention relates to a preparation method of a phthalocyanine blue-coated iron oxide yellow composite pigment. The method comprises the following steps of rinsing phthalocyanine blue with ethanol and then rinsing with deionized water, repeating for many times, drying for later use, mixing iron oxide yellow and treated phthalocyanine blue, adding deionized water and sodium chloride to prepare a suspension, adjusting the pH, carrying out rolling stirring for 30-60 minutes at room temperature, filtering, washing and drying at 100-110 DEG C to obtain the phthalocyanine blue-coated iron oxide yellow composite pigment. According to the preparation method of the phthalocyanine blue-coated iron oxide yellow composite pigment, by the rolling-stirring method and controlling the mass ratio of iron oxide yellow to phthalocyanine blue, the composite pigment having different colors can be prepared.
Description
Technical field
The invention belongs to pigment technology field, relate to the preparation method of the yellow composite pigment of a kind of phthalocyanine blue coated iron oxide.
Background technology
Mineral dye has excellent resistance to acids and bases and weather resistance, is widely used in the painted of material of construction, coating, plastics and rubber etc.Since the forties in 20th century, for problems such as mineral dye color are dull, color is bright-coloured not, abroad carry out and chemically coating has been carried out to prepare the research of novel inorganic composite pigment to mineral dye, the multiple composite bead delustering pigment that to occur with white lead carbonate, subchloride of mercury, lead hydrogen arsenate, alkali formula lead phosphate etc. be Material synthesis.But its major part, because of containing heavy metal element, is prohibited from using in succession.1963, E.I.Du Pont Company, first using mica as core, at its Surface coating 1 layer or the different metal oxide of multilayer, successfully synthesized the composite pigment such as mica titanium, mica iron.Occur again subsequently a series of with silicon-dioxide, calcium carbonate and titanium dioxide for core, carry out the NEW TYPE OF COMPOSITE pigment of coating compound with inorganic color or organic dye, thus enriched the kind of mineral dye.
Summary of the invention
In view of this, the object of the present invention is to provide the preparation method of the yellow composite pigment of a kind of phthalocyanine blue coated iron oxide.
For achieving the above object, the invention provides following technical scheme:
A preparation method for the yellow composite pigment of phthalocyanine blue coated iron oxide, comprises the steps:
Use ethanol rinse phthalocyanine blue, then rinsed with deionized water is used, repeated multiple times, dry for standby, iron oxide yellow is mixed with treated phthalocyanine blue, add deionized water and sodium-chlor makes suspension liquid, adjust ph, roll under room temperature stirring 30 ~ 60min, filter, washing, dry at 100 ~ 110 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
Preferably, iron oxide yellow mixes with treated phthalocyanine blue, and the mass fraction of wherein said phthalocyanine blue is 2 ~ 18%.
Preferably, adjust ph, rolls under room temperature and stirs 50min.
Preferably, filter, washing, dry at 105 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
The preparation method of the yellow composite pigment of phthalocyanine blue coated iron oxide of the present invention, by the method stirred of rolling, the mass ratio of controlled oxidization iron oxide yellow and phthalocyanine blue can prepare the composite pigment of different color.
Embodiment
Be described in detail to the technical scheme in the embodiment of the present invention below, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under the prerequisite not making creative work, all belongs to the scope of protection of the invention.
Embodiment 1
Use ethanol rinse phthalocyanine blue, then rinsed with deionized water is used, repeated multiple times, dry for standby, iron oxide yellow (98wt%) is mixed with treated phthalocyanine blue (2wt%), add deionized water and sodium-chlor makes suspension liquid, adjust ph, roll under room temperature and stir 30min, filter, washing, dry at 100 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
Embodiment 2
Use ethanol rinse phthalocyanine blue, then rinsed with deionized water is used, repeated multiple times, dry for standby, iron oxide yellow (82wt%) is mixed with treated phthalocyanine blue (18wt%), add deionized water and sodium-chlor makes suspension liquid, adjust ph, roll under room temperature and stir 60min, filter, washing, dry at 110 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
Embodiment 3
Use ethanol rinse phthalocyanine blue, then rinsed with deionized water is used, repeated multiple times, dry for standby, iron oxide yellow (88wt%) is mixed with treated phthalocyanine blue (12wt%), add deionized water and sodium-chlor makes suspension liquid, adjust ph, roll under room temperature and stir 50min, filter, washing, dry at 105 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
In those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. a preparation method for the yellow composite pigment of phthalocyanine blue coated iron oxide, is characterized in that, comprise the steps:
Use ethanol rinse phthalocyanine blue, then rinsed with deionized water is used, repeated multiple times, dry for standby, iron oxide yellow is mixed with treated phthalocyanine blue, add deionized water and sodium-chlor makes suspension liquid, adjust ph, roll under room temperature stirring 30 ~ 60min, filter, washing, dry at 100 ~ 110 DEG C, obtain the yellow composite pigment of phthalocyanine blue coated iron oxide.
2. the preparation method of the yellow composite pigment of phthalocyanine blue coated iron oxide according to claim 1, it is characterized in that: iron oxide yellow mixes with treated phthalocyanine blue, the mass fraction of wherein said phthalocyanine blue is 2 ~ 18%.
3. the preparation method of the yellow composite pigment of phthalocyanine blue coated iron oxide according to claim 1, is characterized in that: adjust ph, rolls and stir 50min under room temperature.
4. the preparation method of the yellow composite pigment of phthalocyanine blue coated iron oxide according to claim 1, is characterized in that: filter, washing, dry at 105 DEG C, obtains the yellow composite pigment of phthalocyanine blue coated iron oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410822024.5A CN104497640A (en) | 2014-12-26 | 2014-12-26 | Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410822024.5A CN104497640A (en) | 2014-12-26 | 2014-12-26 | Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104497640A true CN104497640A (en) | 2015-04-08 |
Family
ID=52939102
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410822024.5A Pending CN104497640A (en) | 2014-12-26 | 2014-12-26 | Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104497640A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108997787A (en) * | 2018-08-10 | 2018-12-14 | 天津城建大学 | High near infrared reflectivity rutile TiO2/ phthalocyanine blue composite pigment and preparation method thereof |
| CN109233412A (en) * | 2018-08-10 | 2019-01-18 | 天津城建大学 | Core/shell structure phthalocyanine blue/rutile TiO2Composite pigment and preparation method thereof |
| CN110643203A (en) * | 2019-10-15 | 2020-01-03 | 湖州师范学院 | Easily-dispersible iron oxide green pigment and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4798856A (en) * | 1987-11-06 | 1989-01-17 | Columbian Chemicals Co. | Pigment dispersion in resin |
| CN101275038A (en) * | 2007-03-26 | 2008-10-01 | 上海涂料有限公司上海长风化工厂 | Special dispersant compound for iron phthalein green and preparation thereof |
| CN103502545A (en) * | 2011-05-16 | 2014-01-08 | 阿克佐诺贝尔国际涂料股份有限公司 | Solar infra red reflective paints |
-
2014
- 2014-12-26 CN CN201410822024.5A patent/CN104497640A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4798856A (en) * | 1987-11-06 | 1989-01-17 | Columbian Chemicals Co. | Pigment dispersion in resin |
| CN101275038A (en) * | 2007-03-26 | 2008-10-01 | 上海涂料有限公司上海长风化工厂 | Special dispersant compound for iron phthalein green and preparation thereof |
| CN103502545A (en) * | 2011-05-16 | 2014-01-08 | 阿克佐诺贝尔国际涂料股份有限公司 | Solar infra red reflective paints |
Non-Patent Citations (1)
| Title |
|---|
| 郭丽萍等: "酞菁蓝包覆氧化铁黄复合颜料的制备及其机理研究", 《新型建筑材料》, vol. 38, no. 10, 30 October 2011 (2011-10-30) * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108997787A (en) * | 2018-08-10 | 2018-12-14 | 天津城建大学 | High near infrared reflectivity rutile TiO2/ phthalocyanine blue composite pigment and preparation method thereof |
| CN109233412A (en) * | 2018-08-10 | 2019-01-18 | 天津城建大学 | Core/shell structure phthalocyanine blue/rutile TiO2Composite pigment and preparation method thereof |
| CN110643203A (en) * | 2019-10-15 | 2020-01-03 | 湖州师范学院 | Easily-dispersible iron oxide green pigment and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104530874B (en) | A kind of high abrasion resistance multicolor finish and preparation method thereof | |
| CN103849280B (en) | Preparation method of ultra-stable high-weather-resistance water-in-water granite-like multicolor paint | |
| CN105601166B (en) | A kind of lacquer of temperature variation resistant construction and preparation method thereof | |
| CN102408220A (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN104194456A (en) | Water-in-water colorful reflective insulating stone-like coating and preparation method thereof | |
| CN104445429A (en) | Method for preparing iron oxide red pigment by using pyrite cinder residue-firing hydrothermal process | |
| CN101343436A (en) | Novel water-covering water gorgeous paint and preparation thereof | |
| CN104497640A (en) | Preparation method of phthalocyanine blue-coated iron oxide yellow composite pigment | |
| CN101967324A (en) | Luminous antibacterial aqueous inner wall coating and preparation method and application thereof | |
| CN105086554A (en) | Artistic pigment and preparation method thereof | |
| CN104386761A (en) | Preparation method of high-tinting-strength iron oxide black paint | |
| CN104018349B (en) | Curtain transparent coatings and using method thereof | |
| CN105670345A (en) | Preparation method of flame retardant medium temperature resistant iron oxide yellow pigment | |
| CN102086310A (en) | Preparation method of weather-resistance environmental-friendly synthetic mica pearlescent pigment | |
| CN108455681A (en) | A method of preparing iron oxide yellow using iron content, aluminum i ndustry waste water | |
| CN104559591A (en) | Environment-friendly water-based paint for aluminum profile production and preparation method thereof | |
| CN106046963A (en) | Preparation method of latex paint | |
| CN101864235B (en) | Method for preparing exterior wall coating | |
| CN104629555A (en) | Novel low-carbon flexible water-based coating and preparation method thereof | |
| CN104109408A (en) | Building roof waterproof coating | |
| CN110305548A (en) | A kind of preparation method of aqueous artistic pearl simulation wall cloth paint | |
| CN105342878A (en) | Waterborne 3D magnetic nail polish and preparation method thereof | |
| CN104263123A (en) | High-glossiness decorative latex paint | |
| CN104263121A (en) | Polyvinyl acetate latex paint | |
| CN102786848A (en) | Preparation method for interior wall nanometer emulsion paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20150408 |