CN104496802A - Esterification reaction method and device for production of fatty acid triglyceride - Google Patents
Esterification reaction method and device for production of fatty acid triglyceride Download PDFInfo
- Publication number
- CN104496802A CN104496802A CN201410707822.3A CN201410707822A CN104496802A CN 104496802 A CN104496802 A CN 104496802A CN 201410707822 A CN201410707822 A CN 201410707822A CN 104496802 A CN104496802 A CN 104496802A
- Authority
- CN
- China
- Prior art keywords
- fatty acid
- esterifying kettle
- reaction
- esterifying
- esterification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005886 esterification reaction Methods 0.000 title claims abstract description 38
- 239000000194 fatty acid Substances 0.000 title claims abstract description 37
- 235000014113 dietary fatty acids Nutrition 0.000 title claims abstract description 36
- 229930195729 fatty acid Natural products 0.000 title claims abstract description 36
- 150000004665 fatty acids Chemical class 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 title abstract description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000006243 chemical reaction Methods 0.000 claims abstract description 40
- 230000032050 esterification Effects 0.000 claims abstract description 31
- 235000011187 glycerol Nutrition 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 25
- 230000005587 bubbling Effects 0.000 claims abstract description 14
- 239000003054 catalyst Substances 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims description 52
- 150000002632 lipids Chemical class 0.000 claims description 38
- 238000002309 gasification Methods 0.000 claims description 9
- 238000005507 spraying Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000003595 mist Substances 0.000 claims description 6
- 238000004891 communication Methods 0.000 claims description 5
- 239000000376 reactant Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- -1 fatty acid ester Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 abstract description 6
- 238000007599 discharging Methods 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 14
- 238000009835 boiling Methods 0.000 description 10
- 239000005639 Lauric acid Substances 0.000 description 7
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 4
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 3
- 235000009508 confectionery Nutrition 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000004667 medium chain fatty acids Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 150000004666 short chain fatty acids Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 125000005908 glyceryl ester group Chemical group 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000199 molecular distillation Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00761—Details of the reactor
- B01J2219/00763—Baffles
- B01J2219/00765—Baffles attached to the reactor wall
- B01J2219/00777—Baffles attached to the reactor wall horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/192—Details relating to the geometry of the reactor polygonal
- B01J2219/1923—Details relating to the geometry of the reactor polygonal square or square-derived
- B01J2219/1925—Details relating to the geometry of the reactor polygonal square or square-derived prismatic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410707822.3A CN104496802B (en) | 2014-11-28 | 2014-11-28 | A kind of esterifying reaction method and esterification device of producing fatty acid triglycercide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410707822.3A CN104496802B (en) | 2014-11-28 | 2014-11-28 | A kind of esterifying reaction method and esterification device of producing fatty acid triglycercide |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104496802A true CN104496802A (en) | 2015-04-08 |
CN104496802B CN104496802B (en) | 2016-05-04 |
Family
ID=52938277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410707822.3A Active CN104496802B (en) | 2014-11-28 | 2014-11-28 | A kind of esterifying reaction method and esterification device of producing fatty acid triglycercide |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104496802B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109836328A (en) * | 2019-03-16 | 2019-06-04 | 广州隽沐生物科技股份有限公司 | The synthetic method of median chain triglyceride oil |
CN111495276A (en) * | 2019-01-30 | 2020-08-07 | 宁波富理电池材料科技有限公司 | High-temperature high-pressure gas-solid reaction kettle |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101198677A (en) * | 2006-04-28 | 2008-06-11 | Sk化学股份有限公司 | Method and equipment for producing fatty acid alkyl-ester by using fatty acid |
CN101305763A (en) * | 2008-06-10 | 2008-11-19 | 无锡市双惠化工有限公司 | Granulation method of granulating food additive rosin glyceride |
US20090099380A1 (en) * | 2007-10-12 | 2009-04-16 | Aiken John E | Fatty acid alkyl ester production from oleaginous seeds |
CN101638610A (en) * | 2009-08-13 | 2010-02-03 | 铁岭北亚药用油有限公司 | Medicinal medium-chain triglyceride esterification reaction tank |
CN102153465A (en) * | 2011-02-15 | 2011-08-17 | 浙江赞宇科技股份有限公司 | Method for preparing low acid-value fatty acid methyl ester |
CN204281647U (en) * | 2014-11-28 | 2015-04-22 | 浙江赞宇科技股份有限公司 | A kind of esterification device producing fatty acid triglycercide |
-
2014
- 2014-11-28 CN CN201410707822.3A patent/CN104496802B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101198677A (en) * | 2006-04-28 | 2008-06-11 | Sk化学股份有限公司 | Method and equipment for producing fatty acid alkyl-ester by using fatty acid |
US20090099380A1 (en) * | 2007-10-12 | 2009-04-16 | Aiken John E | Fatty acid alkyl ester production from oleaginous seeds |
CN101305763A (en) * | 2008-06-10 | 2008-11-19 | 无锡市双惠化工有限公司 | Granulation method of granulating food additive rosin glyceride |
CN101638610A (en) * | 2009-08-13 | 2010-02-03 | 铁岭北亚药用油有限公司 | Medicinal medium-chain triglyceride esterification reaction tank |
CN102153465A (en) * | 2011-02-15 | 2011-08-17 | 浙江赞宇科技股份有限公司 | Method for preparing low acid-value fatty acid methyl ester |
CN204281647U (en) * | 2014-11-28 | 2015-04-22 | 浙江赞宇科技股份有限公司 | A kind of esterification device producing fatty acid triglycercide |
Non-Patent Citations (2)
Title |
---|
刘兴艳等: "中碳链脂肪酸甘油酯的研究进展", 《食品工业科技》, vol. 34, no. 12, 31 December 2013 (2013-12-31), pages 366 - 370 * |
孟橘等: "长短链甘油三酯生产工艺及应用研究进展", 《中国油脂》, vol. 36, no. 5, 31 December 2011 (2011-12-31), pages 31 - 35 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111495276A (en) * | 2019-01-30 | 2020-08-07 | 宁波富理电池材料科技有限公司 | High-temperature high-pressure gas-solid reaction kettle |
CN111495276B (en) * | 2019-01-30 | 2022-09-23 | 宁波富理电池材料科技有限公司 | High-temperature high-pressure gas-solid reaction kettle |
CN109836328A (en) * | 2019-03-16 | 2019-06-04 | 广州隽沐生物科技股份有限公司 | The synthetic method of median chain triglyceride oil |
Also Published As
Publication number | Publication date |
---|---|
CN104496802B (en) | 2016-05-04 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee after: ZANYU TECHNOLOGY GROUP CO.,LTD. Patentee after: HANGZHOU OLEOCHEMICALS CO.,LTD. Address before: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee before: ZHEJIANG ZANYU TECHNOLOGY Co.,Ltd. Patentee before: HANGZHOU OLEOCHEMICALS CO.,LTD. |
|
CP01 | Change in the name or title of a patent holder |
Address after: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee after: ZANYU TECHNOLOGY GROUP CO.,LTD. Patentee after: Hangzhou Zanyu Oil Technology Co.,Ltd. Address before: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee before: ZANYU TECHNOLOGY GROUP CO.,LTD. Patentee before: HANGZHOU OLEOCHEMICALS CO.,LTD. |
|
CP01 | Change in the name or title of a patent holder | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231120 Address after: Room C706, No. 198 Qidi Road, Economic and Technological Development Zone, Xiaoshan District, Hangzhou City, Zhejiang Province, 310000 Patentee after: Hangzhou Zanyu Chemical Co.,Ltd. Address before: Hangzhou City, Zhejiang province 310009 City Shangcheng District No. 128 Lane Patentee before: ZANYU TECHNOLOGY GROUP CO.,LTD. Patentee before: Hangzhou Zanyu Oil Technology Co.,Ltd. |
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TR01 | Transfer of patent right |