CN104496273A - Artificial quartzite plate and manufacturing method thereof - Google Patents
Artificial quartzite plate and manufacturing method thereof Download PDFInfo
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- CN104496273A CN104496273A CN201410775578.4A CN201410775578A CN104496273A CN 104496273 A CN104496273 A CN 104496273A CN 201410775578 A CN201410775578 A CN 201410775578A CN 104496273 A CN104496273 A CN 104496273A
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Abstract
The invention discloses an artificial quartzite plate and a manufacturing method thereof. The artificial quartzite plate is composed of the following components in parts by weight: 30-90 parts of 3-80-mesh quartzite, 30-70 parts of 325-mesh quartz powder, 5-15 parts of cullet, 3-10 parts of 30-50-mesh tourmaline, 3-12 parts of 50-100-mesh sillimanite powder, 3-12 parts of 100-200-mesh zirconium silicate powder, 0.1-2 parts of antioxidant, 5-10 parts of unsaturated resin, 0.3-2 parts of silane coupling agent, 0.3-2 parts of curing agent and 0.1-1 part of pigment. The antioxidant is added to the raw materials, thereby enhancing the oxidation resistance and ultraviolet resistance of the artificial quartzite plate. The tourmaline is added to the raw materials to effectively enhance the antibacterial property of the artificial quartzite plate, and thus, the artificial quartzite plate has long antimicrobial effect. The sillimanite powder and zirconium silicate powder, which are favorable refractory materials with very high melting point and hardness, can enhance the refractory temperature of the artificial quartzite plate, prolong the refractory time and increase the compression strength.
Description
Technical field
The invention belongs to material of construction preparing technical field, specifically, refer to a kind of artificial quartz stone plate and manufacture method thereof.
Background technology
Artificial quartz in lump is as the substitute of lithotome, have high strength, high rigidity, high temperature resistant, protection against corrosion, anti-aging, easy to clean, wear-resisting, material is consummate, the unrivaled advantage of lithotome such as radiationless, now be widely used in the daily life of industrial production and the people, as the decorative material material of floor tile, metope etc.
But the artificial quartz in lump that prior art manufactures, exist density unevenness, hardness low, easily tie powder ball, yielding, easily aging, easily enter look, color and pattern single, not there is the defects such as anti-microbial effect, limit its larger application on a large scale, urgently to be resolved hurrily.
Summary of the invention
Technical problem to be solved by this invention is not enough for prior art, a kind of artificial quartz stone plate and preparation method thereof is provided, the artificial quartz stone plate adopting the present invention to prepare is anti-aging, has antibacterial and fire-proof function, expands the range of application of artificial quartz in lump.
The technical scheme that the present invention solves the problems of the technologies described above is as follows: artificial quartz stone plate, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 30 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, 30 ~ 50 3 ~ 10 parts, order tourmalinite, 50 ~ 100 3 ~ 12 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 3 ~ 12 parts, 0.1 ~ 2 part, oxidation inhibitor, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the component of following parts by weight: 3 ~ 80 order quartzites 70 parts, 325 order silica powders 40 parts, glass cullet 10 parts, 30 ~ 50 5 parts, order tourmalinite, 50 ~ 100 5 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 5 parts, 1 part, oxidation inhibitor, unsaturated polyester 8 parts, silane coupling agent 1 part, 0.5 part, solidifying agent, pigment 0.5 part.
Further, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
Further, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
Further, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
Further, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
Further, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
The manufacture method of artificial quartz stone plate, comprise following processing step: the component taking following parts by weight: 3 ~ 80 order quartzites 30 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, 30 ~ 50 3 ~ 10 parts, order tourmalinite, 50 ~ 100 3 ~ 12 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 3 ~ 12 parts, 0.1 ~ 2 part, oxidation inhibitor, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
The invention has the beneficial effects as follows:
(1) anti-aging: in raw material of the present invention, to the addition of oxidation inhibitor, improve the oxidation-resistance of artificial quartz stone plate of the present invention and the ability of antiultraviolet, there is use widely.
(2) antibacterial: tourmalinite is ring texture silicate minerals, there is the special performances such as piezoelectricity, pyroelectric, far-infrared radiation and anion releasing, the present invention with the addition of tourmalinite in the feed, effectively can increase the germ resistance of artificial quartz stone plate, and antibiotic effect is for a long time special.
(3) prevent fires: sillimanite powder and zirconium silicate powder are good refractory materialss, and fusing point and hardness are very high, and they can improve the refractory temperature of artificial quartz stone plate of the present invention, extend fire resistance period, increase ultimate compression strength.
(4) manufacture method of the present invention is simple, is suitable for suitability for industrialized production.
Embodiment
Be described principle of the present invention and feature below in conjunction with specific embodiment, example, only for explaining the present invention, is not intended to limit scope of the present invention.
Embodiment 1:
Take 3 ~ 80 order quartzite 30kg, 325 order silica powder 70kg, glass cullet 5kg, 30 ~ 50 order tourmalinite 10kg, 50 ~ 100 order sillimanite powder 3kg, 100 ~ 200 order zirconium silicate powder 12kg, oxidation inhibitor 1222:0.1kg, epoxy resin 10kg, silane coupling agent γ-methacryloxypropyl trimethoxy silane (KH570) 0.3kg, peroxide-2-ethyl hexanoic acid tert-butyl 2kg, pigment 0.1kg, described pigment is made up of according to mass ratio 15:1 titanium dioxide and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " white board " artificial quartz in lump can be obtained.
Embodiment 2:
Take 3 ~ 80 order quartzite 90kg, 325 order silica powder 30kg, glass cullet 15kg, 30 ~ 50 order tourmalinite 3kg, 50 ~ 100 order sillimanite powder 12kg, 100 ~ 200 order zirconium silicate powder 3kg, oxidation inhibitor 1098:2kg, resol 5kg, silane coupling agent γ-aminopropyl triethoxysilane (KH550) 2kg, peroxidized t-butyl perbenzoate 0.3kg, pigment 1kg, described pigment is made up of according to mass ratio 312:6:25:1:28 titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, " shallow steel gray plate " artificial quartz in lump after surface finish polished finish, can be obtained.
Embodiment 3:
Take 3 ~ 80 order quartzite 70kg, 325 order silica powder 40kg, glass cullet 10kg, 30 ~ 50 order tourmalinite 5kg, 50 ~ 100 order sillimanite powder 5kg, 100 ~ 200 order zirconium silicate powder 5kg, oxidation inhibitor 245:1kg, urethane resin 8kg, silane coupling agent γ-glycidyl ether oxygen propyl trimethoxy silicane 1kg, benzoyl peroxide 0.5kg, pigment 0.5kg, described pigment is made up of according to mass ratio 980:1:2:3:118 titanium dioxide, iron oxide yellow powder, iron black powder, chrome green powder and Lan Shui; By above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, when when vacuumizing, air pressure reaches-0.1MPa, under 2.5 ~ 3.5MPa pressure vibrate 2 ~ 3 minutes shaping, then send into curing oven solidification, solidification value 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivers to surely thick polishing machine and carries out surely thick, after surface finish polished finish, " spring's colours fill the garden " artificial quartz in lump can be obtained.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. artificial quartz stone plate, is characterized in that, is made up of the component of following parts by weight: 3 ~ 80 order quartzites 30 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, 30 ~ 50 3 ~ 10 parts, order tourmalinite, 50 ~ 100 3 ~ 12 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 3 ~ 12 parts, 0.1 ~ 2 part, oxidation inhibitor, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part.
2. artificial quartz stone plate according to claim 1, is characterized in that, is made up of the component of following parts by weight: 3 ~ 80 order quartzites 70 parts, 325 order silica powders 40 parts, glass cullet 10 parts, 30 ~ 50 5 parts, order tourmalinite, 50 ~ 100 5 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 5 parts, 1 part, oxidation inhibitor, unsaturated polyester 8 parts, silane coupling agent 1 part, 0.5 part, solidifying agent, pigment 0.5 part.
3. artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described oxidation inhibitor is one or more in oxidation inhibitor 1222, AT-76, antioxidant 2246-S, AT-59, oxidation inhibitor 1035, oxidation inhibitor 1098, oxidation inhibitor 3125, TPP, TNPP, AT-168, oxidation inhibitor 245, GA-80, oxidation inhibitor 858, antioxidant 1010.
4. artificial quartz stone plate according to claim 1 and 2, is characterized in that, described unsaturated polyester is one or more in epoxy resin, resol, acryl resin and urethane resin.
5. artificial quartz stone plate according to claim 1 and 2, it is characterized in that, described silane coupling agent is the one in γ-methacryloxypropyl trimethoxy silane, γ-aminopropyl triethoxysilane, γ-glycidyl ether oxygen propyl trimethoxy silicane, vinyl three ('beta '-methoxy oxyethyl group) silane, vinyltriethoxysilane or γ-divinyl triammonium base propyl-triethoxysilicane.
6. artificial quartz stone plate according to claim 1 and 2, is characterized in that, described solidifying agent is the one in peroxide-2-ethyl hexanoic acid tert-butyl, peroxidized t-butyl perbenzoate or benzoyl peroxide.
7. artificial quartz stone plate according to claim 1 and 2, is characterized in that, described pigment be titanium dioxide, iron oxide yellow powder, iron oxide red, iron black powder, chrome green powder, Lan Shuizhong one or more.
8. the manufacture method of artificial quartz stone plate, it is characterized in that, comprise following processing step: the component taking following parts by weight:: 3 ~ 80 order quartzites 30 ~ 90 parts, 325 order silica powders 30 ~ 70 parts, glass cullet 5 ~ 15 parts, 30 ~ 50 3 ~ 10 parts, order tourmalinite, 50 ~ 100 3 ~ 12 parts, order sillimanite powder, 100 ~ 200 order zirconium silicate powders 3 ~ 12 parts, 0.1 ~ 2 part, oxidation inhibitor, unsaturated polyester 5 ~ 10 parts, silane coupling agent 0.3 ~ 2 part, 0.3 ~ 2 part, solidifying agent, pigment 0.1 ~ 1 part, by above-mentioned each component Homogeneous phase mixing, the material mixed evenly is tiled on making sheet mould, then making sheet mould is sent into vacuum chamber, vacuumize, vibratory compaction, pressure during vibratory compaction is 2.5 ~ 3.5MPa, molding time is 2 ~ 3 minutes, send into curing oven solidification again, the temperature of solidification is 85 ~ 95 DEG C, time is 30 ~ 45 minutes, sheet material after solidification is come out of the stove the demoulding, after stacking cooling, delivering to surely thick polishing machine carries out surely thick, after surface finish polished finish, artificial quartz in lump can be obtained.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105801004A (en) * | 2016-04-21 | 2016-07-27 | 太仓市建兴石英玻璃厂 | Preparation method of health-care man-made quartz stone plate |
| CN106630748A (en) * | 2016-12-01 | 2017-05-10 | 安徽星元环保科技有限公司 | Temperature-resistant quartz pot with low water absorption |
| CN106630755A (en) * | 2016-12-01 | 2017-05-10 | 安徽星元环保科技有限公司 | Wear-resistant and impact-resistant jade basin for bathroom accessories |
| CN106810115A (en) * | 2015-12-01 | 2017-06-09 | 衡阳双雁运输机械有限公司 | Fire resisting quartzite slate and its manufacture method |
| CN106810114A (en) * | 2015-11-30 | 2017-06-09 | 衡阳市雅典娜石英石有限公司 | A kind of quartz and preparation method thereof |
| CN107739176A (en) * | 2017-10-09 | 2018-02-27 | 上海前引科技有限公司 | A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN112374803A (en) * | 2020-11-17 | 2021-02-19 | 广东河源住方高分子材料有限公司 | Health-care quartz stone plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106810115A (en) * | 2015-12-01 | 2017-06-09 | 衡阳双雁运输机械有限公司 | Fire resisting quartzite slate and its manufacture method |
| CN105801004A (en) * | 2016-04-21 | 2016-07-27 | 太仓市建兴石英玻璃厂 | Preparation method of health-care man-made quartz stone plate |
| CN106630748A (en) * | 2016-12-01 | 2017-05-10 | 安徽星元环保科技有限公司 | Temperature-resistant quartz pot with low water absorption |
| CN106630755A (en) * | 2016-12-01 | 2017-05-10 | 安徽星元环保科技有限公司 | Wear-resistant and impact-resistant jade basin for bathroom accessories |
| CN107739176A (en) * | 2017-10-09 | 2018-02-27 | 上海前引科技有限公司 | A kind of antibacterial and mouldproof anion artificial slabstone and preparation method thereof |
| CN111548052A (en) * | 2020-05-06 | 2020-08-18 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN111548052B (en) * | 2020-05-06 | 2021-05-04 | 广东河源住方高分子材料有限公司 | Artificial quartz stone plate and preparation method thereof |
| CN112374803A (en) * | 2020-11-17 | 2021-02-19 | 广东河源住方高分子材料有限公司 | Health-care quartz stone plate and preparation method thereof |
| CN112573861A (en) * | 2021-02-03 | 2021-03-30 | 湖北钊晟新材料科技有限公司 | Quartz stone plate with low expansion coefficient and preparation method thereof |
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Application publication date: 20150408 |
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