CN104480315B - 电解金属锰、二氧化锰生产浸出压滤渣回收利用的方法 - Google Patents
电解金属锰、二氧化锰生产浸出压滤渣回收利用的方法 Download PDFInfo
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- CN104480315B CN104480315B CN201410787617.2A CN201410787617A CN104480315B CN 104480315 B CN104480315 B CN 104480315B CN 201410787617 A CN201410787617 A CN 201410787617A CN 104480315 B CN104480315 B CN 104480315B
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- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 29
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 238000001914 filtration Methods 0.000 claims abstract description 35
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 239000000463 material Substances 0.000 claims abstract description 20
- 238000000926 separation method Methods 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 15
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 claims abstract description 14
- -1 compound nitrogen phosphate Chemical class 0.000 claims abstract description 14
- 239000002686 phosphate fertilizer Substances 0.000 claims abstract description 13
- 239000002002 slurry Substances 0.000 claims abstract description 13
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000002386 leaching Methods 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 12
- 238000005516 engineering process Methods 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 238000006386 neutralization reaction Methods 0.000 claims description 26
- 239000000706 filtrate Substances 0.000 claims description 23
- 238000006243 chemical reaction Methods 0.000 claims description 21
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 13
- 238000001556 precipitation Methods 0.000 claims description 13
- 239000002585 base Substances 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 11
- 238000003825 pressing Methods 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 8
- 235000011149 sulphuric acid Nutrition 0.000 claims description 8
- 239000001117 sulphuric acid Substances 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 230000005070 ripening Effects 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 6
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- 239000012065 filter cake Substances 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 229910052587 fluorapatite Inorganic materials 0.000 claims description 5
- 229940077441 fluorapatite Drugs 0.000 claims description 5
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000011656 manganese carbonate Substances 0.000 claims description 3
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 238000010564 aerobic fermentation Methods 0.000 claims description 2
- 230000001351 cycling effect Effects 0.000 claims description 2
- MPNNOLHYOHFJKL-UHFFFAOYSA-N peroxyphosphoric acid Chemical compound OOP(O)(O)=O MPNNOLHYOHFJKL-UHFFFAOYSA-N 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- 239000001099 ammonium carbonate Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims 1
- 235000012501 ammonium carbonate Nutrition 0.000 claims 1
- 229940093474 manganese carbonate Drugs 0.000 claims 1
- 235000006748 manganese carbonate Nutrition 0.000 claims 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 claims 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 7
- 239000002351 wastewater Substances 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract 1
- 239000011572 manganese Substances 0.000 description 18
- 229910052748 manganese Inorganic materials 0.000 description 16
- 239000000126 substance Substances 0.000 description 11
- 239000000843 powder Substances 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 239000012085 test solution Substances 0.000 description 7
- 230000035800 maturation Effects 0.000 description 6
- 238000005070 sampling Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000001514 detection method Methods 0.000 description 5
- 239000003337 fertilizer Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 239000002367 phosphate rock Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 229940099596 manganese sulfate Drugs 0.000 description 3
- 235000007079 manganese sulphate Nutrition 0.000 description 3
- XZWYZXLIPXDOLR-UHFFFAOYSA-N metformin Chemical compound CN(C)C(=N)NC(N)=N XZWYZXLIPXDOLR-UHFFFAOYSA-N 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 description 2
- 229910003638 H2SiF6 Inorganic materials 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910004883 Na2SiF6 Inorganic materials 0.000 description 2
- 229910004014 SiF4 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 1
- 229910004074 SiF6 Inorganic materials 0.000 description 1
- 238000004176 ammonification Methods 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Fertilizers (AREA)
Abstract
Description
抽检样品 | 样品质量 | Fe含量% |
铁红矿粉 | 50 | 41 |
抽检样品 | 样品质量 | 锰含量% |
碳酸锰精矿 | 50 | 31.0 |
抽检样品 | 样品质量 | Fe含量% |
铁红矿粉 | 50 | 45 |
抽检样品 | 样品质量 | 锰含量% |
碳酸锰精矿 | 50 | 35 |
抽检样品 | 样品质量 | Fe含量% |
铁红矿粉 | 50 | 45 |
抽检样品 | 样品质量 | 锰含量% |
Mn(OH)2精矿 | 50 | 39 |
Claims (2)
Priority Applications (1)
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CN201410787617.2A CN104480315B (zh) | 2014-12-17 | 2014-12-17 | 电解金属锰、二氧化锰生产浸出压滤渣回收利用的方法 |
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CN201410787617.2A CN104480315B (zh) | 2014-12-17 | 2014-12-17 | 电解金属锰、二氧化锰生产浸出压滤渣回收利用的方法 |
Publications (2)
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CN104480315A CN104480315A (zh) | 2015-04-01 |
CN104480315B true CN104480315B (zh) | 2017-03-29 |
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CN201410787617.2A Expired - Fee Related CN104480315B (zh) | 2014-12-17 | 2014-12-17 | 电解金属锰、二氧化锰生产浸出压滤渣回收利用的方法 |
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Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105084421B (zh) * | 2015-09-22 | 2017-01-25 | 赵阳臣 | 中低品位软锰矿综合利用制备高纯碳酸锰的方法 |
CN105417584A (zh) * | 2015-12-09 | 2016-03-23 | 西南科技大学 | 电解锰矿渣回收锰的方法 |
CN110903046B (zh) * | 2019-11-12 | 2021-12-14 | 赵阳臣 | 一种用电解金属锰浸出渣制备建筑胶凝材料的方法 |
CN114772649A (zh) * | 2022-04-13 | 2022-07-22 | 贵州大龙汇成新材料有限公司 | 一种利用贫锰矿制备四氧化三锰的方法 |
CN114835167A (zh) * | 2022-04-13 | 2022-08-02 | 贵州大龙汇成新材料有限公司 | 一种利用贫锰矿生产硫酸锰的工艺 |
CN114855220B (zh) * | 2022-04-13 | 2024-02-13 | 贵州大龙汇成新材料有限公司 | 一种利用贫锰矿制取高纯锰的方法 |
WO2024138593A1 (zh) * | 2022-12-30 | 2024-07-04 | 耒阳市焱鑫有色金属有限公司 | 钽渣洗脱硫酸回收锡铁锰的工艺方法 |
CN117403055B (zh) * | 2023-10-17 | 2024-06-07 | 广东诚一环保科技有限公司 | 一种废渣中稀有金属回收处理的方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1085639C (zh) * | 1998-12-22 | 2002-05-29 | 郑州工业大学磷肥与复肥研究所 | 磷矿粉一步法制粒状过磷酸钙及其工艺 |
JP5802971B2 (ja) * | 2010-12-20 | 2015-11-04 | 日新製鋼株式会社 | 鉄鋼スラグ中の有価成分の回収方法 |
CN102605188A (zh) * | 2011-10-10 | 2012-07-25 | 云南建水锰矿有限责任公司 | 锰合金渣加压浸出生产硫酸锰的方法 |
WO2014045301A2 (en) * | 2012-08-30 | 2014-03-27 | Indo Gulf Fertilizers | A process for preparing phosphates from rock phosphate |
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Effective date of registration: 20170914 Address after: Xinxian County the Guangxi Zhuang Autonomous Region village 532315 Chongzuo City Lei Zhen Zhi Tun Da Ban under the letter of the Xinxian County Manganese Mining Co. Ltd. Patentee after: Xinxian County great faith Manganese Mining Co., Ltd. Address before: Xinxian County the Guangxi Zhuang Autonomous Region village 532315 Chongzuo City Lei Zhen Zhi Tun Da Ban under the letter of the Xinxian County Manganese Mining Co. Ltd. Patentee before: Zhao Yangchen |
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