CN104452423A - Long-effective antiseptic and heat insulation type PVC (Polyvinyl Chloride) base wallpaper and preparation method thereof - Google Patents

Long-effective antiseptic and heat insulation type PVC (Polyvinyl Chloride) base wallpaper and preparation method thereof Download PDF

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Publication number
CN104452423A
CN104452423A CN201410672400.7A CN201410672400A CN104452423A CN 104452423 A CN104452423 A CN 104452423A CN 201410672400 A CN201410672400 A CN 201410672400A CN 104452423 A CN104452423 A CN 104452423A
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China
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parts
preparation
body paper
long
wallpaper
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CN201410672400.7A
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李华令
肖昌明
向凯
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Anhui Suoya Decorative Materials Co Ltd
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Anhui Suoya Decorative Materials Co Ltd
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Priority to CN201410672400.7A priority Critical patent/CN104452423A/en
Publication of CN104452423A publication Critical patent/CN104452423A/en
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Abstract

The invention relates to a wallpaper base, in particular to a long-effective antiseptic and heat insulation type PVC (Polyvinyl Chloride) base wallpaper and a preparation method thereof. The base wallpaper is prepared from the following raw materials in parts by weight: 4 to 6 parts of N-methylmorpholine-N-oxide, 40 to 50 parts of bleached chemical hardwood pulp, 12 to 15 parts of bamboo fiber, 20 to 30 parts of fully-bleached chemical softwood pulp, 1 to 2 parts of sodium carboxymethyl starch, 2 to 3 parts of menthol, 13 to 18 parts of 600-800-mesh porous mullite powder, 2 to 4 parts of soy isolate protein, 2 to 3 parts of polyvinyl butyral, 4 to 6 parts of a PAE wet strength agent, 12 to 16 parts of 800-1,250-mesh environmentally-friendly pigment, 10 to 15 parts of an adhesive, and 3 to 5 parts of an additive. The base wallpaper contains controlled-release menthol which can be dispersed and combined well in fiber pulp and is long-lasting; in addition, surface coating liquid prepared from the additive, the pigment and the adhesive by diluting and compounding is uniform and rich in color and luster, obvious in retention effect, easy to coat, and high in utilization rate; the glued base wallpaper has a flat and straight surface, is environmentally-friendly, nontoxic, heat-insulated, and outstanding in physical performance, so that a foundation is created for the production of quality wallpaper products.

Description

A kind of long-effective corrosion insulation PVC wallpaper body paper and preparation method thereof
Technical field
The present invention relates to a kind of hanging raw stock, be specifically related to a kind of long-effective corrosion insulation PVC wallpaper body paper and preparation method thereof.
Background technology
What wallpaper became many owners gradually as a kind of wall surfacing material is first-selected, the advantages such as its color is various, pattern abundant, environmental protection attractive in appearance, there is the advantage that many traditional wall coverings are incomparable, improve year by year in the utilization rate of China, PVC wallpaper is the common wallpaper of a class, it is mainly with pure paper as base material, and then at substrate surface coating polyvinyl chloride resin sizing material, then postmenstruation, ornamenting processing process obtained finished product.
Body paper directly has influence on operation effect and the service property (quality) in wallpaper later stage as base material, current body paper material ubiquity intensity, poor toughness, surface absorption are uneven, glue not easily applies, water resistant poor heat resistance, grow bacterium and the shortcoming such as to mildew, have a strong impact on the serviceability of finished product, therefore the composition and engineering improving traditional body paper is had very much, improve its adaptability, improve post-production performance, to realize High-efficient Production, obtain quality product.
Summary of the invention
The object of the invention is to provide a kind of long-effective corrosion to be incubated PVC wallpaper body paper and preparation method thereof, and to achieve these goals, the technical solution used in the present invention is as follows:
A kind of long-effective corrosion insulation PVC wallpaper body paper and preparation method thereof, it is characterized in that, this body paper is made up of the raw material of following weight portion: N-methylmorpholine-N-oxide 4-6, broad-leaved bleached wood pulp 40-50, bamboo fibre 12-15, needle float chemical wood pulp 20-30, sodium carboxymethyl starch 1-2, menthol 2-3,600-800 order porous mullite powder 13-18, soybean protein isolate 2-4, polyvinyl butyral resin 2-3, PAE wet strength agent 4-6,800-1250 order environmental-friendly pigment 12-16, adhesive 10-15, auxiliary agent 3-5 entirely;
Auxiliary agent is made up of the raw material of following weight portion: polymine 4-6, neopelex 0.2-0.5, poly-l-lysine (molecular weight 70000-150000) 2-3, sweet mellow wine 1-1.5, oxidized starch 6-8, water-based defoamer 0.1-0.2, atoleine 1-2, water 12-16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 30-40min, finally add other leftover materials again, continue insulated and stirred mixing 40-50min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
Described adhesive is aqueous non-toxic adhesive.
Described a kind of long-effective corrosion insulation PVC wallpaper body paper and preparation method thereof, its preparation method is:
(1) first broad-leaved bleached wood pulp, bamboo fibre, needle are floated full chemical wood pulp, the mixing of N-methylmorpholine-N-oxide drops into thin up in beater and pulls an oar, beating degree is 25-32 0sR;
(2) soybean protein isolate, sodium carboxymethyl starch are mixed with the water of 6-8 weight portion, after the dispersion of abundant stirring and dissolving, add menthol, continue dispersed with stirring evenly after, after gained mixed material bone dry removing moisture, it is for subsequent use to grind to form 600-800 order micro mist;
(3) step (1), (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1-2h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
Body paper advantage of the present invention is: utilize soybean protein isolate, carboxymethyl starch as wall material, by coated for the menthol with antisepsis and sterilization and delicate fragrance taste, make it can fine dispersion combine in fibre stuff, long-acting performance effect lastingly, makes full use of raw material; The surface coating liquid uniform color that auxiliary agent, pigment and adhesive dilute composite preparation is full, keep effective, easy coating, utilization rate is high, and the body paper surfacing after applying glue is well-pressed, environment-protecting asepsis, heat-insulation and heat-preservation, good physical properties, is easy to post-production, lays a good foundation for producing high-quality wallpaper finished product.
Detailed description of the invention
Embodiment
The body paper of the present embodiment is obtained by the raw material of following weight portion: N-methylmorpholine-N-oxide 5, broad-leaved bleached wood pulp 50, bamboo fibre 15, needle float chemical wood pulp 25, sodium carboxymethyl starch 2, menthol 3,800 order porous mullite powder 15, soybean protein isolate 3, polyvinyl butyral resin 3, PAE wet strength agent 5,1250 order environmental-friendly pigment 15, adhesive 13, auxiliary agent 4 entirely.
Auxiliary agent is made up of the raw material of following weight portion: polymine 5, neopelex 0.3, poly-l-lysine (molecular weight 70000-150000) 3, sweet mellow wine 1.2, oxidized starch 8, water-based defoamer 0.1, atoleine 1.5, water 16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 40min, finally add other leftover materials again, continue insulated and stirred mixing 45min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
Wherein adhesive to be solid content be 45 ± 1% phenylethylene-maleic anhydride polymer emulsion.
The preparation method of the present embodiment body paper is:
(1) first broad-leaved bleached wood pulp, bamboo fibre, needle are floated full chemical wood pulp, the mixing of N-methylmorpholine-N-oxide drops into thin up in beater and pulls an oar, beating degree is 30 0sR;
(2) soybean protein isolate, sodium carboxymethyl starch are mixed with the water of 6-8 weight portion, after the dispersion of abundant stirring and dissolving, add menthol, continue dispersed with stirring evenly after, after gained mixed material bone dry removing moisture, it is for subsequent use to grind to form 800 order micro mists;
(3) step (1), (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1.4h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
Body paper prepared by the present embodiment becomes each performance indications of paper as follows:
Presentation quality: uniform in color, surface smoothing, even tissue; Machine direction tensile strength: 3.8KN/m; Wet strength: 2.5KN/m; Tightness: 0.58g/m 3; Opacity: 95.4%; Air permeability: 1560ml/min; Surface absorption: 55g/m 2(60s); Expansion and contraction 0.2%; Killing fungus rate: 96.8%.

Claims (3)

1. long-effective corrosion insulation PVC wallpaper body paper and preparation method thereof, it is characterized in that, this body paper is made up of the raw material of following weight portion: N-methylmorpholine-N-oxide 4-6, broad-leaved bleached wood pulp 40-50, bamboo fibre 12-15, needle float chemical wood pulp 20-30, sodium carboxymethyl starch 1-2, menthol 2-3,600-800 order porous mullite powder 13-18, soybean protein isolate 2-4, polyvinyl butyral resin 2-3, PAE wet strength agent 4-6,800-1250 order environmental-friendly pigment 12-16, adhesive 10-15, auxiliary agent 3-5 entirely;
Auxiliary agent is made up of the raw material of following weight portion: polymine 4-6, neopelex 0.2-0.5, poly-l-lysine (molecular weight 70000-150000) 2-3, sweet mellow wine 1-1.5, oxidized starch 6-8, water-based defoamer 0.1-0.2, atoleine 1-2, water 12-16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 30-40min, finally add other leftover materials again, continue insulated and stirred mixing 40-50min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
2. a kind of long-effective corrosion insulation PVC wallpaper body paper as claimed in claim 1 and preparation method thereof, it is characterized in that, described adhesive is aqueous non-toxic adhesive.
3. a kind of long-effective corrosion insulation PVC wallpaper body paper as claimed in claim 1 and preparation method thereof, its preparation method is:
(1) first broad-leaved bleached wood pulp, bamboo fibre, needle are floated full chemical wood pulp, the mixing of N-methylmorpholine-N-oxide drops into thin up in beater and pulls an oar, beating degree is 25-32 0sR;
(2) soybean protein isolate, sodium carboxymethyl starch are mixed with the water of 6-8 weight portion, after the dispersion of abundant stirring and dissolving, add menthol, continue dispersed with stirring evenly after, after gained mixed material bone dry removing moisture, it is for subsequent use to grind to form 600-800 order micro mist;
(3) step (1), (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1-2h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
CN201410672400.7A 2014-11-22 2014-11-22 Long-effective antiseptic and heat insulation type PVC (Polyvinyl Chloride) base wallpaper and preparation method thereof Pending CN104452423A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105544310A (en) * 2015-12-03 2016-05-04 高大元 Modified bamboo pulp fiber wallpaper preparation method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974868A (en) * 2010-11-18 2011-02-16 浙江华邦特种纸业有限公司 Method for manufacturing high-breathability non-woven wallpaper body paper and product
CN104005260A (en) * 2013-02-21 2014-08-27 甘木林 Wallpaper base produced with recycled pulp

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974868A (en) * 2010-11-18 2011-02-16 浙江华邦特种纸业有限公司 Method for manufacturing high-breathability non-woven wallpaper body paper and product
CN104005260A (en) * 2013-02-21 2014-08-27 甘木林 Wallpaper base produced with recycled pulp

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105544310A (en) * 2015-12-03 2016-05-04 高大元 Modified bamboo pulp fiber wallpaper preparation method
CN105544310B (en) * 2015-12-03 2017-05-17 浙江方维装饰材料有限公司 Modified bamboo pulp fiber wallpaper preparation method

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Application publication date: 20150325