CN104449568A - High-yield energy-saving type slag grinding aid - Google Patents

High-yield energy-saving type slag grinding aid Download PDF

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Publication number
CN104449568A
CN104449568A CN201410658094.1A CN201410658094A CN104449568A CN 104449568 A CN104449568 A CN 104449568A CN 201410658094 A CN201410658094 A CN 201410658094A CN 104449568 A CN104449568 A CN 104449568A
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China
Prior art keywords
grinding aid
type slag
slag grinding
saving type
slag
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CN201410658094.1A
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CN104449568B (en
Inventor
尹丹
黄煌
陈威
王恒
阮长泰
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GUILIN HUAYUE ENVIRONMENTAL PROTECTION CO Ltd
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GUILIN HUAYUE ENVIRONMENTAL PROTECTION CO Ltd
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Publication of CN104449568A publication Critical patent/CN104449568A/en
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Abstract

The invention belongs to an additive in the mineral powder preparation field and particularly relates to a high-yield energy-saving type slag grinding aid. The high-yield energy-saving type slag grinding aid is prepared from the following raw materials in percentage by weight: 10-20% of diethanolisopropanolamine, 10-18% of propylene glycol, 2-7% of sodium tripolyphosphate, 8-15% of polyacrylamide, 15-20% of polyether, 2-7% of sodium gluconate, 10-15% of a stabilizer and the balance of water. By adding the grinding aid into slag grinding, the output per machine is improved by 30.22% at most, the yield amplitude is greatly improved, and the energy consumption is obviously reduced.

Description

A kind of high yield and saving energy type slag grinding aid
Technical field
The invention belongs to breeze admixture technical field, particularly a kind of high yield and saving energy type slag grinding aid.
Background technology
Slag is a kind of byproduct that steel smelting procedure produces, and in order to efficent use of resources, uses after usually being worn into fine powder as slag micropowder.Slag micropowder is new green environment protection product, effectively can not only utilize blast-furnace metallurgical slag, turn waste into wealth, and also plays promoter action to the occupation of land of reduction slag, minimizing environmental pollution.Slag micropowder has become one of production high-quality cement, configuration high-performance, long lifetime concrete first-selected material.The concrete being mixed with slag micropowder has that hydration heat is low, corrosion-resistant, high, the anti-micro of good fluidity, later strength, can make the features such as concrete interface adhesive property improvement, is defined as one of construction industry ten new technologies by Minstry of Housing and Urban-Rural Development of People Republic of China (MOHURD).
Because slag is stone, need in fine grinding process to consume a large amount of energy and production time.Main ethylene glycol or the mixture containing ethylene glycol of adopting of the formula composition of existing liquid slag grinding aid is as grinding aid.But due to the vitreous structure reason of slag, grinding aid of the prior art joins in slag milling process, although the agglomeration around slag particle can be removed, the grindability of slag particle itself can not be improved, so grinding-aid effect or not ideal enough.And along with the minimizing day by day of Mineral resources, and large-lot producer is serious to the consumption of the energy, how to improve the difficult problem that unit-hour output and save energy also become this area.For this reason, seeking a kind of high yield and saving energy type slag grinding aid product is domestic grinding aid industry problem in urgent need to solve.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of high yield and saving energy type slag grinding aid, and in slag milling, mix this grinding aid, unit-hour output improves greatly, and energy consumption significantly reduces.
For achieving the above object, the present invention adopts following technical scheme:
A kind of high yield and saving energy type slag grinding aid, be made up of the raw material of following weight percent:
Above-mentioned one package stabilizer can be dispersion agent NNO (methylene-bis bitter edible plant sodium sulfonate) and/or Dispersant MF (dispersing agent MF), be preferably dispersion agent NNO and Dispersant MF is composite forms, the weight ratio of dispersion agent NNO and Dispersant MF is (2 ~ 4): 1.
Preferably, the weight ratio of above-mentioned dispersion agent NNO and Dispersant MF is 3:1.
Preferably, high yield and saving energy type slag grinding aid of the present invention, be made up of the raw material of following weight percent:
In formula material of the present invention, di-alcohol monoisopropanolamine, as hardening accelerator, ensures the intensity of slag, has good grinding-aid effect simultaneously; The end group of propylene glycol is an aliphatic group, has good dispersiveness, is conducive to the mobility of powder, and comparatively di-alcohol monoisopropanolamine is strong for the grinding-aid effect of propylene glycol, substitutes di-alcohol monoisopropanolamine, make grinding-aid effect more with propylene glycol; Tripoly phosphate sodium STPP has good dispersiveness, can prevent slag powder bag ball, stick with paste ball, attached integrated group, improve mill efficiency, reduce energy consumption; Polyacrylamide has lubrication, reduces the resistance of grinding, improves the mill efficiency of powder; Polyethers can lubricate powder, improves the mobility of powder, thus improves the efficiency of powder, improves unit-hour output, reduces energy consumption; Sunmorl N 60S has unusual effect to the mobility improving powder; Add stablizer, the permanent stability of grinding aid can be ensured, also there is powerful dissemination simultaneously, effectively promote mill efficiency.
Beneficial effect of the present invention is:
1, in formula of the present invention, each raw material plays synergistic effect, can improve 30.22% unit-hour output, reduces energy consumption, accomplishes high yield and saving energy.
2, grinding aid of the present invention is watery thing, makes each component more even, more can strengthen grinding effect, improve mill efficiency, reduce energy consumption.
3, needed for grinding aid of the present invention, output is few, only need mix 0.02 ~ 0.05%, just can have good high yield and saving energy effect.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited to these embodiments.
Embodiment 1
Take following raw material by weight percentage: di-alcohol monoisopropanolamine 10%, propylene glycol 18%, tripoly phosphate sodium STPP 2%, polyacrylamide 15%, polyethers 15%, Sunmorl N 60S 7%, dispersion agent NNO 8%, Dispersant MF 2%, water 23%, mixing, positive mechanical formula stirs, and obtains product.
Embodiment 2
Take following raw material by weight percentage: di-alcohol monoisopropanolamine 13%, propylene glycol 16%, tripoly phosphate sodium STPP 3%, polyacrylamide 13%, polyethers 16%, Sunmorl N 60S 5%, dispersion agent NNO 8.25%, Dispersant MF 2.75%, water 23%, mixing, positive mechanical formula stirs, and obtains product.
Embodiment 3
Take following raw material by weight percentage: di-alcohol monoisopropanolamine 15%, propylene glycol 14%, tripoly phosphate sodium STPP 5%, polyacrylamide 12%, polyethers 17%, Sunmorl N 60S 4%, dispersion agent NNO 9%, Dispersant MF 3%, water 21%, mixing, positive mechanical formula stirs, and obtains product.
Embodiment 4
Take following raw material by weight percentage: di-alcohol monoisopropanolamine 18%, propylene glycol 12%, tripoly phosphate sodium STPP 6%, polyacrylamide 10%, polyethers 18%, Sunmorl N 60S 3%, dispersion agent NNO 10.4%, Dispersant MF 2.6%, water 20%, mixing, positive mechanical formula stirs, and obtains product.
Embodiment 5
Take following raw material by weight percentage: di-alcohol monoisopropanolamine 20%, propylene glycol 10%, tripoly phosphate sodium STPP 7%, polyacrylamide 8%, polyethers 20%, Sunmorl N 60S 2%, dispersion agent NNO 10%, Dispersant MF 5%, water 18%, mixing, positive mechanical formula stirs, and obtains product.
Grinding-aid effect simultaneous test
The grinding aid adopting the embodiment of the present invention 1 ~ 5 to be prepared into and commercially available grinding aid (model: GA-100) mix in cement raw material grinding process, and test each grinding aid, test result is in table 1:
Table 1 cement test result
Note: the whole of above-mentioned cement grinding are tuber grinders.

Claims (3)

1. a high yield and saving energy type slag grinding aid, is characterized in that, is made up of the raw material of following weight percent:
Described stablizer is dispersion agent NNO and Dispersant MF is composite forms, and the weight ratio of dispersion agent NNO and Dispersant MF is (2 ~ 4): 1.
2. high yield and saving energy type slag grinding aid according to claim 1, is characterized in that: the weight ratio of described dispersion agent NNO and Dispersant MF is 3:1.
3. high yield and saving energy type slag grinding aid according to claim 1, is characterized in that, be made up of the raw material of following weight percent:
CN201410658094.1A 2014-11-18 2014-11-18 High-yield energy-saving type slag grinding aid Active CN104449568B (en)

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CN104449568B CN104449568B (en) 2017-01-11

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105152576A (en) * 2015-09-30 2015-12-16 王璐 Slag grinding aid
CN105152567A (en) * 2015-09-18 2015-12-16 南京荣丰环保科技有限公司 Slag grinding aid for vertical grinding
CN105733508A (en) * 2016-03-17 2016-07-06 安徽颖达锌业发展有限公司 Zinc concentrate grinding aid and production process thereof
CN109111150A (en) * 2017-06-23 2019-01-01 武汉华轩高新技术有限公司 A kind of grinding aid material and its application method improving flyash mobility
CN110734744A (en) * 2018-07-18 2020-01-31 盱眙县江淮建材科技有限公司 mineral powder grinding aid based on physical and chemical twinning

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584079A (en) * 2012-03-13 2012-07-18 济南高新区工业废弃物利用研发中心 Cement grinding aid for preventing crystallization and salt particle precipitation at low temperature
CN103833257A (en) * 2014-03-26 2014-06-04 山东宏艺科技股份有限公司 Coagulating enhanced cement grinding aid
CN103964732A (en) * 2014-05-05 2014-08-06 宁夏青铜峡市西夏科润建材有限公司 Liquid cement grinding aid for improving adaptability of cement and concrete and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584079A (en) * 2012-03-13 2012-07-18 济南高新区工业废弃物利用研发中心 Cement grinding aid for preventing crystallization and salt particle precipitation at low temperature
CN103833257A (en) * 2014-03-26 2014-06-04 山东宏艺科技股份有限公司 Coagulating enhanced cement grinding aid
CN103964732A (en) * 2014-05-05 2014-08-06 宁夏青铜峡市西夏科润建材有限公司 Liquid cement grinding aid for improving adaptability of cement and concrete and preparing method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105152567A (en) * 2015-09-18 2015-12-16 南京荣丰环保科技有限公司 Slag grinding aid for vertical grinding
CN105152567B (en) * 2015-09-18 2017-03-29 南京荣丰环保科技有限公司 A kind of Vertical Mill slag grinding aid
CN105152576A (en) * 2015-09-30 2015-12-16 王璐 Slag grinding aid
CN105152576B (en) * 2015-09-30 2017-12-22 桂林融通科技有限公司 A kind of slag grinding aid
CN105733508A (en) * 2016-03-17 2016-07-06 安徽颖达锌业发展有限公司 Zinc concentrate grinding aid and production process thereof
CN109111150A (en) * 2017-06-23 2019-01-01 武汉华轩高新技术有限公司 A kind of grinding aid material and its application method improving flyash mobility
CN110734744A (en) * 2018-07-18 2020-01-31 盱眙县江淮建材科技有限公司 mineral powder grinding aid based on physical and chemical twinning

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