CN104449032A - White printing ink for printing tipping paper for cigarettes and preparation method - Google Patents

White printing ink for printing tipping paper for cigarettes and preparation method Download PDF

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Publication number
CN104449032A
CN104449032A CN201510023425.9A CN201510023425A CN104449032A CN 104449032 A CN104449032 A CN 104449032A CN 201510023425 A CN201510023425 A CN 201510023425A CN 104449032 A CN104449032 A CN 104449032A
Authority
CN
China
Prior art keywords
tipping paper
weight
binder
preparation
printing ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510023425.9A
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Chinese (zh)
Inventor
喻睿
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QUJING KIRIN FUPAI PRINTING Co Ltd
Original Assignee
QUJING KIRIN FUPAI PRINTING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QUJING KIRIN FUPAI PRINTING Co Ltd filed Critical QUJING KIRIN FUPAI PRINTING Co Ltd
Priority to CN201510023425.9A priority Critical patent/CN104449032A/en
Publication of CN104449032A publication Critical patent/CN104449032A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to the technical field of printing ink, in particular to white printing ink for printing tipping paper for cigarettes and a preparation method. The white printing ink comprises, by weight, 36%-44% of light calcium, 25%-35% of connecting materials and 27%-35% of ethyl alcohol; the connecting materials comprise, by weight, 8%-15% of polyvinyl butyral and 85%-92% of ethyl alcohol. The white printing ink is simple in formula, the preparation method is simple and convenient, the produced product thoroughly meets security indexes, and the product production process requirement is met. The contents and the types of volatile substance are reduced to the maximum degree, the security indexes of the produced printing tipping paper for the cigarettes reach the security indexes of environment-friendly products, and the quality standard requirement is met. In addition, as the formula is simple, the production cost of an enterprise can be reduced; the types of the volatile substance in the connecting materials are fewer, contents of the volatile substance are low, injuries to the human body are avoided, and the daily-strict environment-friendly requirements can be met.

Description

The white ink of printing cigarette tipping paper and preparation method
Technical field
The present invention relates to printing-ink technical field, specifically a kind of white ink and preparation method printing cigarette tipping paper.
Background technology
Cigarette tipping paper is that filter tip and Cigarette are hinged with the dedicated paper got up, it forms primarily of the subsidiary material such as paper, ink, ink is the important component part of tipping paper, and the quality of ink directly determines the sanitary index attractive in appearance and various of product, the tipping paper packaging majority of most cigarette is yellow background color, arrange in pairs or groups various gold stamping, radium-shine and other process combination form, and ink occupies very important effect in cigarette tipping paper.
Along with the proposition of GB YC171-2009, higher requirement has been had to the VOC of cigarette tipping paper and heavy metal content, on October 8th, 2010, being organized in a Tobacco Control meeting of international Tobacco use control Assessment of Policy project (ITC) discloses a scientific research report, data presentation 13 domestic cigarette brands of China detect containing heavy metal, compared with its content produces cigarette with Canada, the highlyest exceed more than three times.Therefore, just propose the nontoxic water color ink do not fired is improved to cigarette tipping paper ink again.
Summary of the invention
The object of the invention is for the problems referred to above, a kind of white ink and the preparation method that print cigarette tipping paper are provided.
For achieving the above object, the technical solution used in the present invention is: a kind of white ink printing cigarette tipping paper, it is characterized in that: be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 36 ~ 44%, binder 25 ~ 35% and ethanol 27 ~ 35%, the weight of described each raw material and be 100%; Described binder by weight part be 8 ~ 15% polyvinyl butyral acetal and weight part be 85 ~ 92% ethanol form.
Further, be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 39.1%, binder 29.7% and ethanol 31.2%, described binder by weight part be 10.1% polyvinyl butyral acetal and weight part be 89.9% ethanol form.
Another object of the present invention is to provide a kind of preparation method printing the white ink of cigarette tipping paper, and step comprises:
(1) fine particle calcium carbonate, binder and ethanol is taken by weight;
(2) fine particle calcium carbonate is put into sand mill and carry out sand milling more than 7.5 hours, then add binder and continue grind and stir 3 ~ 4 hours, make that the fineness of ink is not more than 5 μm, viscosity is 22.5 ~ 23.5 " be finished product.
Advantageous Effects of the present invention is: the present invention formula only with fine particle calcium carbonate, polyvinyl butyral acetal and ethanol for raw material, preparation method is easy, the problem of thorough solution safety indexes, meet again the process requirements of products production, reduce content and the kind of volatile matter to greatest extent, the cigarette tipping paper safety indexes of producing reaches Green Product, meets quality criteria requirements; In addition because raw material dosage is simple, the production cost of enterprise is greatly reduced; In ink of the present invention, volatile species is few, content is low, harmless, meets the environmental requirement of increasingly stringent.
Binder Product checking data of the present invention are as following table 1, table 2 and table 3:
Table 1 invention product inorganic elements detected result
Table 2 invention product volatile organic compounds detected result
Table 3 invention product volatile organic compounds detected result
Embodiment
Below in conjunction with the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Print a white ink for cigarette tipping paper, be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 44%, binder 25% and ethanol 31%, binder by weight part be 15% polyvinyl butyral acetal and weight part be 85% ethanol form.
Preparation method, step comprises:
(1) fine particle calcium carbonate, binder and ethanol is taken by weight;
(2) fine particle calcium carbonate is put into sand mill and carry out sand milling 8 hours, then add binder and continue grind and stir 3.5 hours, make the fineness 4 μm of ink, viscosity is 23 " be finished product.
Embodiment 2
Print a white ink for cigarette tipping paper, be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 36%, binder 35% and ethanol 29%, binder by weight part be 8% polyvinyl butyral acetal and weight part be 92% ethanol form.
Preparation method, step comprises:
(1) fine particle calcium carbonate, binder and ethanol is taken by weight;
(2) fine particle calcium carbonate is put into sand mill and carry out sand milling more than 7.5 hours, then add binder and continue grind and stir 3 hours, make the fineness 5 μm of ink, viscosity is 22.5 " be finished product.
Embodiment 3
A kind of white ink printing cigarette tipping paper, be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 39.1%, binder 29.7% and ethanol 31.2%, binder by weight part be 10.1% polyvinyl butyral acetal and weight part be 89.9% ethanol form.
Preparation method, step comprises:
(1) fine particle calcium carbonate, binder and ethanol is taken by weight;
(2) fine particle calcium carbonate is put into sand mill and carry out sand milling more than 9 hours, then add binder and continue grind and stir 4 hours, make the fineness 5 μm of ink, viscosity is 23.5 " be finished product.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (3)

1. print the white ink of cigarette tipping paper, it is characterized in that: be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 36 ~ 44%, binder 25 ~ 35% and ethanol 27 ~ 35%, the weight of described each raw material and be 100%; Described binder by weight part be 8 ~ 15% polyvinyl butyral acetal and weight part be 85 ~ 92% ethanol form.
2. print the white ink of cigarette tipping paper according to claim 1, it is characterized in that: be prepared from by the raw material of following parts by weight: fine particle calcium carbonate 39.1%, binder 29.7% and ethanol 31.2%, described binder by weight part be 10.1% polyvinyl butyral acetal and weight part be 89.9% ethanol form.
3. according to any one of claim 1 ~ 2, print the preparation method of the white ink of cigarette tipping paper, it is characterized in that, step comprises:
(1) fine particle calcium carbonate, binder and ethanol is taken by weight;
(2) fine particle calcium carbonate is put into sand mill and carry out sand milling more than 7.5 hours, then add binder and continue grind and stir 3 ~ 4 hours, make that the fineness of ink is not more than 5 μm, viscosity is 22.5 ~ 23.5 " be finished product.
CN201510023425.9A 2015-01-17 2015-01-17 White printing ink for printing tipping paper for cigarettes and preparation method Pending CN104449032A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510023425.9A CN104449032A (en) 2015-01-17 2015-01-17 White printing ink for printing tipping paper for cigarettes and preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510023425.9A CN104449032A (en) 2015-01-17 2015-01-17 White printing ink for printing tipping paper for cigarettes and preparation method

Publications (1)

Publication Number Publication Date
CN104449032A true CN104449032A (en) 2015-03-25

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Family Applications (1)

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CN201510023425.9A Pending CN104449032A (en) 2015-01-17 2015-01-17 White printing ink for printing tipping paper for cigarettes and preparation method

Country Status (1)

Country Link
CN (1) CN104449032A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105200863A (en) * 2015-09-10 2015-12-30 玉溪接装纸制造有限公司 Low-temperature-hot-stamped gold-stamped type tipping paper for cigarettes and preparation method of tipping paper
CN106480778A (en) * 2016-10-12 2017-03-08 安徽集友纸业包装有限公司 Cigarette tipping paper and preparation method thereof
CN106638128A (en) * 2016-10-12 2017-05-10 安徽集友纸业包装有限公司 Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof
CN110079149A (en) * 2019-05-28 2019-08-02 福建中烟工业有限责任公司 Ink, standard substance, preparation method and application
CN110698913A (en) * 2019-09-25 2020-01-17 云南中烟工业有限责任公司 Lip adhesion-preventing alcohol-soluble ink for tipping paper for cigarettes

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429360A (en) * 2008-11-17 2009-05-13 青岛喜盈门集团有限公司 Formula of inorganic red printing ink for tipping paper and producing process therefor
CN101445687A (en) * 2008-12-23 2009-06-03 周贤永 Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof
KR100932722B1 (en) * 2009-05-11 2009-12-21 오리엔트화학 (주) Composition for paint markerpen and method of preparing the same
CN103666090A (en) * 2012-08-30 2014-03-26 广东广乐包装材料股份有限公司 Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101429360A (en) * 2008-11-17 2009-05-13 青岛喜盈门集团有限公司 Formula of inorganic red printing ink for tipping paper and producing process therefor
CN101445687A (en) * 2008-12-23 2009-06-03 周贤永 Alcohol solution printing ink for wrapping paper of intaglio plate cigarette and preparation method thereof
KR100932722B1 (en) * 2009-05-11 2009-12-21 오리엔트화학 (주) Composition for paint markerpen and method of preparing the same
CN103666090A (en) * 2012-08-30 2014-03-26 广东广乐包装材料股份有限公司 Alcohol-soluble environment-friendly printing ink for tipping paper and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
袁继祖: "《非金属矿物填料与加工技术》", 31 January 2007, 化学工业出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105200863A (en) * 2015-09-10 2015-12-30 玉溪接装纸制造有限公司 Low-temperature-hot-stamped gold-stamped type tipping paper for cigarettes and preparation method of tipping paper
CN106480778A (en) * 2016-10-12 2017-03-08 安徽集友纸业包装有限公司 Cigarette tipping paper and preparation method thereof
CN106638128A (en) * 2016-10-12 2017-05-10 安徽集友纸业包装有限公司 Oleophobic and hydrophilic coating for tipping paper for cigarettes and preparation method thereof
CN106638128B (en) * 2016-10-12 2018-12-04 安徽集友纸业包装有限公司 Oleophobic hydrophilic coating and preparation method thereof for cigarette tipping paper
CN110079149A (en) * 2019-05-28 2019-08-02 福建中烟工业有限责任公司 Ink, standard substance, preparation method and application
CN110079149B (en) * 2019-05-28 2022-02-11 福建中烟工业有限责任公司 Printing ink, standard substance, preparation method and application thereof
CN110698913A (en) * 2019-09-25 2020-01-17 云南中烟工业有限责任公司 Lip adhesion-preventing alcohol-soluble ink for tipping paper for cigarettes

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SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20150325

RJ01 Rejection of invention patent application after publication