CN104448693A - 环氧树脂组合物及其制备方法、应用 - Google Patents
环氧树脂组合物及其制备方法、应用 Download PDFInfo
- Publication number
- CN104448693A CN104448693A CN201410670021.4A CN201410670021A CN104448693A CN 104448693 A CN104448693 A CN 104448693A CN 201410670021 A CN201410670021 A CN 201410670021A CN 104448693 A CN104448693 A CN 104448693A
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- parts
- bisphenol
- composition
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 83
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 81
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims description 30
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 21
- 229920003987 resole Polymers 0.000 claims description 16
- 239000003054 catalyst Substances 0.000 claims description 12
- 229930185605 Bisphenol Natural products 0.000 claims description 11
- 230000001588 bifunctional effect Effects 0.000 claims description 8
- 229920003986 novolac Polymers 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 6
- -1 promotor ZDC Chemical compound 0.000 claims description 5
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 claims description 4
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims description 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 claims description 4
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 3
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 claims description 3
- YABOHEJSGUXUHX-UHFFFAOYSA-N CCCCCCN.CN(C)C Chemical compound CCCCCCN.CN(C)C YABOHEJSGUXUHX-UHFFFAOYSA-N 0.000 claims description 3
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 2
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 claims description 2
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 2
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- XUCHXOAWJMEFLF-UHFFFAOYSA-N bisphenol F diglycidyl ether Chemical compound C1OC1COC(C=C1)=CC=C1CC(C=C1)=CC=C1OCC1CO1 XUCHXOAWJMEFLF-UHFFFAOYSA-N 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- QOHMWDJIBGVPIF-UHFFFAOYSA-N n',n'-diethylpropane-1,3-diamine Chemical compound CCN(CC)CCCN QOHMWDJIBGVPIF-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 12
- 239000003063 flame retardant Substances 0.000 abstract description 7
- 239000011159 matrix material Substances 0.000 abstract description 7
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000012776 electronic material Substances 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 230000007704 transition Effects 0.000 description 6
- 238000007711 solidification Methods 0.000 description 5
- 230000008023 solidification Effects 0.000 description 5
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical group C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 3
- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- DLYLVPHSKJVGLG-UHFFFAOYSA-N 4-(cyclohexylmethyl)cyclohexane-1,1-diamine Chemical compound C1CC(N)(N)CCC1CC1CCCCC1 DLYLVPHSKJVGLG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410670021.4A CN104448693B (zh) | 2014-11-20 | 2014-11-20 | 环氧树脂组合物及其制备方法、应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410670021.4A CN104448693B (zh) | 2014-11-20 | 2014-11-20 | 环氧树脂组合物及其制备方法、应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN104448693A true CN104448693A (zh) | 2015-03-25 |
CN104448693B CN104448693B (zh) | 2020-04-10 |
Family
ID=52895484
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410670021.4A Active CN104448693B (zh) | 2014-11-20 | 2014-11-20 | 环氧树脂组合物及其制备方法、应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN104448693B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962040A (zh) * | 2015-07-13 | 2015-10-07 | 江苏中鹏新材料股份有限公司 | 一种提高环氧树脂组合物玻璃化转变温度的方法 |
CN106832752A (zh) * | 2017-01-05 | 2017-06-13 | 厦门复晟复合材料有限公司 | 一种碳纤维环氧树脂预浸料 |
CN112646322A (zh) * | 2020-12-21 | 2021-04-13 | 上海中化科技有限公司 | 树脂组合物、树脂材料及其制备方法 |
CN113480829A (zh) * | 2021-06-04 | 2021-10-08 | 牧世复合材料科技(苏州)有限公司 | 一种低粘度环氧/环硫树脂组合物及环氧/环硫基体树脂 |
CN115651579A (zh) * | 2022-11-02 | 2023-01-31 | 杭州之江有机硅化工有限公司 | 一种可快速固化的环氧胶及其制备方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87102696A (zh) * | 1986-04-14 | 1988-03-09 | 休斯航空公司 | 室温下可固化的结构型环氧糊状粘合剂及其制造方法 |
JPH1025333A (ja) * | 1996-07-10 | 1998-01-27 | Yuka Shell Epoxy Kk | 半導体封止用エポキシ樹脂組成物 |
CN101798438A (zh) * | 2009-02-06 | 2010-08-11 | 太阳油墨制造株式会社 | 热固化性树脂组合物、干膜和印刷线路板及其制造方法 |
CN101851386A (zh) * | 2009-04-01 | 2010-10-06 | 汉高(中国)投资有限公司 | 一种环氧树脂组合物 |
CN101864151A (zh) * | 2009-04-16 | 2010-10-20 | 三星电机株式会社 | 用于高剥离强化印刷电路板的阻燃树脂组合物、利用其的印刷电路板及其制造方法 |
CN103788576A (zh) * | 2013-12-02 | 2014-05-14 | 上海南亚覆铜箔板有限公司 | 环氧树脂组合物及其制备方法 |
-
2014
- 2014-11-20 CN CN201410670021.4A patent/CN104448693B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN87102696A (zh) * | 1986-04-14 | 1988-03-09 | 休斯航空公司 | 室温下可固化的结构型环氧糊状粘合剂及其制造方法 |
JPH1025333A (ja) * | 1996-07-10 | 1998-01-27 | Yuka Shell Epoxy Kk | 半導体封止用エポキシ樹脂組成物 |
CN101798438A (zh) * | 2009-02-06 | 2010-08-11 | 太阳油墨制造株式会社 | 热固化性树脂组合物、干膜和印刷线路板及其制造方法 |
CN101851386A (zh) * | 2009-04-01 | 2010-10-06 | 汉高(中国)投资有限公司 | 一种环氧树脂组合物 |
CN101864151A (zh) * | 2009-04-16 | 2010-10-20 | 三星电机株式会社 | 用于高剥离强化印刷电路板的阻燃树脂组合物、利用其的印刷电路板及其制造方法 |
CN103788576A (zh) * | 2013-12-02 | 2014-05-14 | 上海南亚覆铜箔板有限公司 | 环氧树脂组合物及其制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104962040A (zh) * | 2015-07-13 | 2015-10-07 | 江苏中鹏新材料股份有限公司 | 一种提高环氧树脂组合物玻璃化转变温度的方法 |
CN106832752A (zh) * | 2017-01-05 | 2017-06-13 | 厦门复晟复合材料有限公司 | 一种碳纤维环氧树脂预浸料 |
CN112646322A (zh) * | 2020-12-21 | 2021-04-13 | 上海中化科技有限公司 | 树脂组合物、树脂材料及其制备方法 |
CN113480829A (zh) * | 2021-06-04 | 2021-10-08 | 牧世复合材料科技(苏州)有限公司 | 一种低粘度环氧/环硫树脂组合物及环氧/环硫基体树脂 |
CN115651579A (zh) * | 2022-11-02 | 2023-01-31 | 杭州之江有机硅化工有限公司 | 一种可快速固化的环氧胶及其制备方法 |
CN115651579B (zh) * | 2022-11-02 | 2024-01-26 | 杭州之江有机硅化工有限公司 | 一种可快速固化的环氧胶及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN104448693B (zh) | 2020-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105849162B (zh) | 对基质添加剂的改进 | |
KR101542338B1 (ko) | 에폭시 수지 조성물 및 섬유 강화 복합 재료 | |
KR102345788B1 (ko) | 섬유 강화 수지 및 그의 제조 방법, 및 성형품 | |
CN104448693A (zh) | 环氧树脂组合物及其制备方法、应用 | |
TWI715759B (zh) | 聚醯胺粒子及其製造方法、樹脂組成物以及成形品 | |
JP2007016121A (ja) | 複合材料用プリプレグおよび複合材料 | |
TW201433600A (zh) | 包含層間韌化粒子之熱固性樹脂複合材料 | |
JPWO2011034040A1 (ja) | バインダー組成物、強化繊維基材、プリフォームおよび繊維強化複合材料とその製造方法 | |
TWI798298B (zh) | 預浸料及其製造方法及纖維強化複合材料之製造方法 | |
KR102261674B1 (ko) | 섬유 강화 수지 및 그의 제조 방법, 및 성형품 | |
JP2014227473A (ja) | 複合材料用エポキシ樹脂組成物、繊維強化複合材料およびそれらの製造方法 | |
CN106170387A (zh) | 复合材料 | |
CN109563289A (zh) | 具有热塑性增韧的线型酚醛基环氧树脂基质的复合材料 | |
JP6845141B2 (ja) | 樹脂組成物 | |
JP2013159618A (ja) | エポキシ樹脂組成物、繊維強化複合材料およびそれらの製造方法 | |
CN110337461B (zh) | 热塑性增韧的环氧复合材料在热和湿条件下保持压缩强度 | |
JP2007297549A (ja) | エポキシ樹脂組成物 | |
JP2010059300A (ja) | 炭素繊維強化複合材料およびその製造方法 | |
JP2018172609A (ja) | 繊維強化プラスチック成形用プリプレグの製造方法 | |
JP2011074223A (ja) | 繊維強化樹脂複合材料の製造法 | |
KR20230146005A (ko) | 섬유 강화 복합 재료용 에폭시 수지 조성물, 섬유 강화복합 재료, 및 섬유 강화 복합 재료의 제조 방법 | |
KR20100030469A (ko) | 경화형 프리프레그용 에폭시 수지조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
ASS | Succession or assignment of patent right |
Owner name: XU DONG Free format text: FORMER OWNER: SHENZHEN YATAIXING INDUSTRY LTD. Effective date: 20150310 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 518103 SHENZHEN, GUANGDONG PROVINCE TO: 518000 SHENZHEN, GUANGDONG PROVINCE |
|
TA01 | Transfer of patent application right |
Effective date of registration: 20150310 Address after: 518000 Baoan District, Shenzhen, Baoan District, the people of the first district of the square building, the first floor of the building on the ground floor, building 13, Applicant after: Xu Dong Address before: 518103, Guangdong Province, Shenzhen, Baoan District Baoan district nine District Road Plaza, building 13, building Applicant before: Shenzhen Yataixing Industry Ltd. |
|
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |