CN104445528A - Device for purifying polluted water by using uniform dielectric barrier discharging plasma - Google Patents

Device for purifying polluted water by using uniform dielectric barrier discharging plasma Download PDF

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Publication number
CN104445528A
CN104445528A CN201410748878.3A CN201410748878A CN104445528A CN 104445528 A CN104445528 A CN 104445528A CN 201410748878 A CN201410748878 A CN 201410748878A CN 104445528 A CN104445528 A CN 104445528A
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electrode
water
plasma
reaction
dielectric barrier
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CN104445528B (en
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孙亚兵
彭园慧
张梦怡
辛路
蒋浩
汪健
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Nanjing University
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Nanjing University
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/4608Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • C02F1/325Irradiation devices or lamp constructions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/78Treatment of water, waste water, or sewage by oxidation with ozone
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention discloses a device for purifying polluted water by using uniform dielectric barrier discharging plasma. The device comprises a plasma reaction kettle and a reaction table, wherein the plasma reaction kettle comprises a reaction container and a cover plate used for closing the reaction container; the reaction container has a dual-loop structure; the reaction table comprises an insulation plate, a conductive base, a support rod, a high-voltage electrode and a grounding electrode; the high-voltage electrode and the grounding electrode are respectively connected with an anode and a cathode of a high-voltage high-frequency electric source; and the plasma reaction kettle is arranged between the high-voltage electrode and the grounding electrode. The device has the advantages of stable and reliable performance, fast speed, simple structure, strong practicability, and no secondary pollution and the like. The device especially has obvious effect on difficultly decomposed organic pollutants and pollutants with special treatment demands, has considerable potential application prospect and is hopeful to be widely popularized and applied in future water body pollution treatment process.

Description

A kind of device of homogeneous dielectric barrier discharge plasma for purification polluted-water
Technical field
The invention belongs to polluted water purification technical field, be specifically related to a kind of device of homogeneous dielectric barrier discharge plasma for purification water body.
Background technology
Along with expanding economy, China is faced with shortage of water resources and the serious environmental problem of water pollutions at present.Traditional biologic treating technique is difficult to meet day by day complicated water conditioning requirement, as waste water from dyestuff, agricultural chemicals waste water, process containing persistence organic pollutant waste water etc.
Plasma technique is the high-level oxidation technology in a kind of comparatively forward position occurred in recent years, and is first applied in environmental improvement.It act as one with ozone oxidation, ultraviolet degradation, free-radical oxidn, pyrolysis and high energy electron irradiation etc. are multiple, effectively can remove the various pollutents in waste water, electric discharge is the main method that low-temperature plasma produces, oxidizing extremely strong OH, H, O, O in discharge plasma 3isoreactivity particle, and along with effects such as high temperature oxidation, uv-radiation, shockwave, organism, under the effect of these combined effects, is degraded to CO the most at last 2, H 2o or other organic substance.Have that treatment cycle is short, efficiency is high, non-secondary pollution, the advantage such as applied widely.Be applied in the process field of water environment pollution gradually at present, but plasma technique still comes with some shortcomings at present, as efficiency is not high, processing cost ways and means specific aim that is relatively high and degradation effect is not strong.
The human hairs such as CN 203281600U Luo Yongming understand a kind of apparatus for low-temperature plasma treatment of soil persistent organic pollutant, its reaction unit mainly comprises reactor and reaction bench, the object mainly persistence organic pollutant of process, show by experiment, this reaction unit has good removal effect to the pollution soil body, but the handling object of this experimental installation is only for contaminated soil, limitation is large, and experiment can not be reacted by continuous circulation, determines this invention and can only be used for small scale experiments and theoretical investigation.
As can be seen here, find a kind of efficient, simple, avoid the waste disposal plant of secondary pollution or method extremely urgent.
Summary of the invention
The object of the invention is on the basis of existing technology, a kind of device of homogeneous dielectric barrier discharge plasma for purification polluted-water is provided.The advantages such as this apparatus design is simple, it is low to invest, treatment effect good, reaction efficiency is high, non-secondary pollution, can be applied to the continuous circulation process in organic polluting water field.
Object of the present invention is achieved through the following technical solutions:
A kind of device of homogeneous dielectric barrier discharge plasma for purification polluted-water, it comprises plasma reaction still and reaction bench, described plasma reaction still comprises reaction vessel and the cover plate for closed reaction vessel, described reaction vessel is twin nuclei, by interior annulus and outer toroid, reaction vessel is divided into circular reactive tank and annular aerator tank, the height of described outer toroid is higher than interior annulus, described outer toroid is provided with water-in and inlet mouth is respectively used to pass into gas and water filling in annular aerator tank, described interior annulus is provided with water outlet, micro-pore aeration plate is provided with for disperseing the gas passed into by inlet mouth in annular aerator tank in described annular aerator tank, described reaction bench comprises insulcrete, conductive seat, support bar, the high voltage electrode connecting high voltagehigh frequency power positive cathode respectively and ground-electrode, described insulcrete is arranged on the top of conductive seat by support bar, described high voltage electrode and ground-electrode are oppositely arranged on insulcrete and conductive seat respectively, and described plasma reaction still is arranged between high voltage electrode and ground-electrode.
Described cover plate is detachable.The material of described reactor is silica glass or stainless steel.
Described micro-pore aeration plate is even porous structure and the shape of shape and annular aerator tank matches, and the plate face of described micro-pore aeration plate is parallel with the bottom surface of reaction vessel and be separated with a segment distance.
Described inlet mouth is arranged on the below in micro-pore aeration plate face, and described water-in is arranged on the top in micro-pore aeration plate face.Described inlet mouth is connected with pneumatic pump with air flowmeter, and the large I of air flow arbitrarily regulates.
Described high voltage electrode and ground-electrode are cylindric, the diameter of described high voltage electrode and ground-electrode with in described reaction vessel in annulus diameter identical.
Described support bar is provided with insulcrete arrangement for adjusting height.The structure of this arrangement for adjusting height is known to the skilled person.
Voltage, the electric current of described high voltagehigh frequency power supply are all adjustable.
Under described water outlet, interface is a little more than interface on tank-top plate, and its height adjustable.
The device process organic polluting water of described homogeneous dielectric barrier discharge plasma for purification polluted-water, has that process range is wide, effective, non-secondary pollution, can to carry out at normal temperatures and pressures.Effective way and the developing direction of nowadays high-concentration hardly-degradable pollutant effluents process are become.
Beneficial effect of the present invention:
Device of the present invention has that practicality is wide, processing efficiency is high, equipment cost is low, working cost is low, utilization ratio is high, continuity is strong, economic environmental protection and the advantage such as stable, solve that the treatment effect existed in current treatment technology is low, treatment capacity is few and the problem such as discharge instability, the process field of organic polluting water can be widely used in.
Accompanying drawing explanation
Fig. 1 is the structure iron of plasma reaction still.
Fig. 2 is the structure iron of homogeneous dielectric barrier discharge plasma for purification polluted-water device of the present invention.
Embodiment
Below in conjunction with accompanying drawing, this working of an invention process is made an explanation and is analyzed:
As depicted in figs. 1 and 2, a kind of device of homogeneous dielectric barrier discharge plasma for purification polluted-water, it comprises plasma reaction still and reaction bench, described plasma reaction still comprises reaction vessel 1 and the cover plate 2 for closed reaction vessel, described reaction vessel 1 is twin nuclei, by interior annulus 3 and outer toroid 4, reaction vessel is divided into circular reactive tank and annular aerator tank, the height of described outer toroid 4 is higher than interior annulus 3, described outer toroid 4 is provided with water-in 5 and inlet mouth 6 is respectively used to pass into gas and water filling in annular aerator tank, described interior annulus 3 is provided with water outlet 7, micro-pore aeration plate 8 is provided with for disperseing the gas passed into by inlet mouth 6 in annular aerator tank in described annular aerator tank, described reaction bench comprises insulcrete 11, conductive seat 12, support bar 13, the high voltage electrode 9 connecting high voltagehigh frequency power positive cathode respectively and ground-electrode 10, described insulcrete 11 is arranged on the top of conductive seat 12 by support bar 13, described high voltage electrode 9 and ground-electrode 10 are oppositely arranged on insulcrete 11 and conductive seat 12 respectively, and described plasma reaction still is arranged between high voltage electrode 9 and ground-electrode 10.
Described cover plate 2 is detachable.The material of described plasma reaction still is silica glass or stainless steel.
Described micro-pore aeration plate 8 is even porous structure and the shape of shape and annular aerator tank matches, and the plate face of described micro-pore aeration plate 8 is parallel with the bottom surface of reaction vessel and be separated with a segment distance.
Described inlet mouth 6 is arranged on the below in micro-pore aeration plate 8 plate face, and described water-in 5 is arranged on the top in micro-pore aeration plate 8 plate face.Described inlet mouth 6 is connected with pneumatic pump with air flowmeter, and the large I of air flow arbitrarily regulates.
Described high voltage electrode 9 and ground-electrode 10 are cylindric, the diameter of described high voltage electrode 9 and ground-electrode 10 with in described reaction vessel 1 in annulus 3 diameter identical.
Described support bar 13 is provided with insulcrete 11 arrangement for adjusting height.
Described high voltagehigh frequency voltage of supply, electric current are all adjustable.
Under described water outlet, interface is a little more than interface on tank-top plate, and its height adjustable.
Adopt the process of device purifying treatment polluted-water of the present invention as follows: pretreated water body is injected in the annular aerator tank of reaction vessel 1 by the water-in 5 of reaction vessel 1, before injecting at sewage, a certain amount of air is imported by inlet mouth 6, and by the dispersed gas of micro-pore aeration plate 8, the water body imported carries out aeration pre-treatment on micro-pore aeration plate 8, oxygen in air is fully dissolved in water body, water body to overflow in circular reactive tank through interior annulus 3 gap and forms certain thickness liquid level, after vapor liquid equilibrium, close cover plate 2 whole plasma reaction still is placed in reaction bench reserved location, after adjusting height and position, the positive and negative electrode of high voltagehigh frequency power supply is connected to high voltage electrode 9 and the ground-electrode 10 of reaction bench, adjustment electric current and voltage are after suitable numerical value, produce evenly between electrode, plasma discharge significantly, put a region and just in time cover whole circular reactive tank scope.
In high voltagehigh frequency corona discharge process, the air passed into can be ionized in a large number, and forms a large amount of high-energy electron and OH, e eq -, O, HO 2deng the O that free-radical oxidn is extremely strong 3and H 2o 2, because these materials have strong oxidisability, advanced treatment can be carried out to water quality; Meanwhile, also with effects such as localized hyperthermia, strong shock wave, stronger UV-light, thus the organic content in waste water can effectively be removed.Electric current in reaction, voltage and air flow and reaction solution face thickness all adjustable, can adjust flexibly according to effluent quality, also can carry out circulating according to the effluent quality of tail water simultaneously and repeatedly process, thus can effectively be decomposed organic waste water by the chemistry of plasma discharge, physical action and remove, reach the object of purification.Water body after purification is discharged through water outlet 7.Prove by experiment, the tsiklomitsin standardized solution of the 100mg/L of 100L is passed through reactor with the flow velocity of 50mL/min, and air flow is 0.1m 3h -1, output rating is 80.0W, and the reaction times is 20min, and the clearance of tsiklomitsin can reach 91.5%.
This treatment unit have simple to operate, remove that pollutent efficiency is high, facility investment is little, can continuous catalysis, applied widely, at a high speed, efficiently, the advantage such as non-secondary pollution, especially to the organic pollutant of difficult degradation and the pollutent effect that has special processing to require comparatively remarkable, there is considerable potential application foreground, be expected to be promoted widely in water pollution treatment process from now on and use.

Claims (6)

1. the device of a homogeneous dielectric barrier discharge plasma for purification polluted-water, it is characterized in that it comprises plasma reaction still and reaction bench, described plasma reaction still comprises reaction vessel and the cover plate for closed reaction vessel, described reaction vessel is twin nuclei, by interior annulus and outer toroid, reaction vessel is divided into circular reactive tank and annular aerator tank, the height of described outer toroid is higher than interior annulus, described outer toroid is provided with water-in and inlet mouth is respectively used to pass into gas and water filling in annular aerator tank, described interior annulus is provided with water outlet, micro-pore aeration plate is provided with for disperseing the gas passed into by inlet mouth in annular aerator tank in described annular aerator tank, described reaction bench comprises insulcrete, conductive seat, support bar, the high voltage electrode connecting high voltagehigh frequency power positive cathode respectively and ground-electrode, described insulcrete is arranged on the top of conductive seat by support bar, described high voltage electrode and ground-electrode are oppositely arranged on insulcrete and conductive seat respectively, and described plasma reaction still is arranged between high voltage electrode and ground-electrode.
2. the device of homogeneous dielectric barrier discharge plasma for purification polluted-water according to claim 1, is characterized in that described cover plate is detachable.
3. the device of homogeneous dielectric barrier discharge plasma for purification polluted-water according to claim 1, it is characterized in that described micro-pore aeration plate is even porous structure and the shape of shape and annular aerator tank matches, the plate face of described micro-pore aeration plate is parallel with the bottom surface of reaction vessel and be separated with a segment distance.
4. the device of the homogeneous dielectric barrier discharge plasma for purification polluted-water according to claim 1 or 3, it is characterized in that described inlet mouth is arranged on the below in micro-pore aeration plate face, described water-in is arranged on the top in micro-pore aeration plate face.
5. the device of homogeneous dielectric barrier discharge plasma for purification polluted-water according to claim 1, it is characterized in that described high voltage electrode and ground-electrode are cylindric, the diameter of described high voltage electrode and ground-electrode with in described reaction vessel in annulus diameter identical.
6. the device of homogeneous dielectric barrier discharge plasma for purification polluted-water according to claim 1, is characterized in that described support bar is provided with insulcrete arrangement for adjusting height.
CN201410748878.3A 2014-12-09 2014-12-09 A kind of device of homogeneous dielectric barrier discharge plasma for purification polluted-water Active CN104445528B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104787939A (en) * 2015-03-31 2015-07-22 南京大学 Method and device for treating triclosan-containing wastewater by adopting double-dielectric barrier discharge
CN105858988A (en) * 2016-06-08 2016-08-17 南京大学 Method and device for treating triclocarban-containing wastewater through cooperation of plasma and TiO2-ACFs composite catalyst
CN106587251A (en) * 2016-12-29 2017-04-26 南京西普环保科技有限公司 Method and equipment for controlling urban black and odorous water body by using solar energy-plasmas
CN108101159A (en) * 2018-01-15 2018-06-01 重庆工商大学 A kind of high-pressure medium barrier discharge plasma wastewater treatment equipment

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107445284A (en) * 2017-09-04 2017-12-08 南京大学 A kind of device of dielectric barrier discharge plasma processing sewage

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202542925U (en) * 2012-03-15 2012-11-21 大连海事大学 Gas-liquid mixed dielectric barrier discharge generating device
CN103272839A (en) * 2013-04-28 2013-09-04 中国科学院南京土壤研究所 Low-temperature plasma processing device and method for persistent organic pollutants in soil
US20140246364A1 (en) * 2013-03-01 2014-09-04 Eon Labs Llc Systems and methods for non-thermal plasma over liquid direct ion injection

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202542925U (en) * 2012-03-15 2012-11-21 大连海事大学 Gas-liquid mixed dielectric barrier discharge generating device
US20140246364A1 (en) * 2013-03-01 2014-09-04 Eon Labs Llc Systems and methods for non-thermal plasma over liquid direct ion injection
CN103272839A (en) * 2013-04-28 2013-09-04 中国科学院南京土壤研究所 Low-temperature plasma processing device and method for persistent organic pollutants in soil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104787939A (en) * 2015-03-31 2015-07-22 南京大学 Method and device for treating triclosan-containing wastewater by adopting double-dielectric barrier discharge
CN105858988A (en) * 2016-06-08 2016-08-17 南京大学 Method and device for treating triclocarban-containing wastewater through cooperation of plasma and TiO2-ACFs composite catalyst
CN106587251A (en) * 2016-12-29 2017-04-26 南京西普环保科技有限公司 Method and equipment for controlling urban black and odorous water body by using solar energy-plasmas
CN108101159A (en) * 2018-01-15 2018-06-01 重庆工商大学 A kind of high-pressure medium barrier discharge plasma wastewater treatment equipment

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