CN104432507A - Cigarette filter tip additive removing aldehydes in cigarette mainstream smoke and preparation method and application thereof - Google Patents
Cigarette filter tip additive removing aldehydes in cigarette mainstream smoke and preparation method and application thereof Download PDFInfo
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- CN104432507A CN104432507A CN201410779672.7A CN201410779672A CN104432507A CN 104432507 A CN104432507 A CN 104432507A CN 201410779672 A CN201410779672 A CN 201410779672A CN 104432507 A CN104432507 A CN 104432507A
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- Prior art keywords
- cigarette
- cigarette filter
- particle
- additive agent
- tip
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Abstract
The invention discloses a cigarette filter tip additive removing aldehydes in the cigarette mainstream smoke and a preparation method and application thereof. The cigarette filter tip additive is a compound material composed of tobacco material particles, carbon material and adhesive material in an adhered manner. The cigarette filter tip additive added into a cigarette filter tip is capable of reducing the aldehydes in the cigarette mainstream smoke effectively and selectively, and the cigarette taste is not influenced; the preparation method of the cigarette filter tip additive is easy and fast to implement, the cost is low, and the industrial production can be met.
Description
Technical field
The present invention relates to and a kind ofly remove cigarette filter-tip additive agent of aldehyde material in cigarette mainstream flue gas and its preparation method and application, belong to the preparing technical field of cigarette filter.
Background technology
Cigarette smoke is the chemical system that cigarette one of producing in aspiration procedure is very complicated, up to now identified chemical composition out has kind more than 4000, wherein there is some chemical properties to be all disadvantageous to human body and environment, mainly comprise carbon monoxide, hydrogen cyanide, volatile aldehyde, ammonia, nitrous ammonia, BaP and aldehydes matter etc.The aldehyde material found in components in cigarette smoke gas phase composition has reached more than 20 and has planted, what wherein content was the highest is formaldehyde, acetaldehyde, propionic aldehyde, methacrylaldehyde, crotonaldehyde and furfural, these volatile aldehyde materials especially formaldehyde, methacrylaldehyde and crotonaldehyde are the toxin of respiratory tract cilium, can cause PUD D.Wherein, crotonaldehyde was classified as one of seven kinds of harmful components in cigarette mainstream flue gas in 2008 by State Tobacco Monopoly Bureau especially.
In order to reduce the harm of cigarette to consumer health, improve the edible security of cigarette, a lot of experts of domestic and international tobacco business are devoted to the harm reduction research of cigarette always, wherein quite a few at the report removing aldehyde material in cigarette mainstream flue gas.Reporting maximum has active carbon for removing the additive of aldehyde material in cigarette mainstream flue gas, ion exchange resin, polymine etc., wherein the research of active carbon is the most comprehensive, the more external large tobacco companies such as BAT group, Blang Williamson company, Fei Mo company have all carried out large quantifier elimination and experimental demonstration, and have the product applying active carbon in the cigarette product of the U.S., Japan and other countries.Active carbon is very good to the Adsorption Filtration Properties of cigarette smoke, but poor selectivity, therefore direct activated carbon application will be brought negative effect to cigarette odor-absorbing in cigarette, easily causes product quality to reduce.Domestic exploratory development is in this respect quite a few, CN102058159 discloses the application of active carbon in cigarette filter rod with cuprous oxide modification, CN1692848 discloses and falls Ti-Pd-Cu based active carbon fiber and prepare composite tip stick, and CN9010729 discloses and active carbon is added the impact of mouth rod on cigarette smoke.The material with carbon element of major part research display active carbon both domestic and external and other modification is applied in cigarette filter, reduces successful to the tar of cigarette smoke, but selective not strong, and comparatively large on the suction taste impact of cigarette, causes its application to be limited to.
Summary of the invention
Directly apply to for absorbent charcoal material in prior art and reduce aldehyde compound in cigarette smoke to there is adsorption capacity excessive, poor selectivity, large defect is affected on cigarette odor-absorbing, the object of the invention is to be that providing a kind of can reduce aldehyde material in cigarette mainstream flue gas by efficient selective, and do not affect the cigarette filter-tip additive agent of cigarette odor-absorbing.
Another object of the present invention is to provide a kind of simple to operate, quick, and low cost prepares the method for described cigarette filter-tip additive agent.
3rd object of the present invention is to provide the application of a kind of described cigarette filter-tip additive agent in cigarette filter, is added on by cigarette filter-tip additive agent in cigarette filter and can reduces aldehyde material in cigarette mainstream flue gas by efficient selective, and do not affect cigarette odor-absorbing.
The invention provides a kind of cigarette filter-tip additive agent removing aldehyde material in cigarette mainstream flue gas, this additive to be bondd the compound additive particle formed by glutinous gelatin substance by tobacco-containing material particle and material with carbon element; Described material with carbon element is at least one in multi-walled carbon nano-tubes, amino functional multi-walled carbon nano-tube, carbon nanocoils, expanded graphite.
In preferred cigarette filter-tip additive agent, the mass ratio of tobacco-containing material particle, material with carbon element and glutinous gelatin substance is 60 ~ 90:38 ~ 5:2 ~ 5.Described material with carbon element is conventional commercially available prod.
Preferred tobacco-containing material particle is at least one in cabo particle, expanded cabo particle, offal particle.
The particle size of preferred tobacco-containing material particle is 20 ~ 60 orders.
Preferred glutinous gelatin substance is at least one in xanthans, guar gum, carob, CMC, hydroxymethyl-propyl cellulose, shitosan.
Present invention also offers a kind of preparation method of described cigarette filter-tip additive agent, the method is first by after material with carbon element ultrasonic disperse is in water, adds tobacco-containing material particle, ultrasonic disperse, then adds glutinous gelatin substance, further ultrasonic disperse; Filter, dry, obtain compound additive particle.
After adding tobacco-containing material particle in preferred preparation method, the time of ultrasonic disperse is 0.5 ~ 2h.
After adding glutinous gelatin substance in preferred preparation method, the time of further ultrasonic disperse is 10 ~ 30min.
Drying in preferred preparation method is under 80 ~ 200 DEG C of temperature conditions, toasts 12 ~ 48 hours.
Present invention also offers the application of described cigarette filter-tip additive agent, this application described cigarette filter-tip additive agent is added in cigarette filter the aldehyde compound be applied in selective reduction main flume.
In preferred application process, the addition of cigarette filter-tip additive agent in filter tip is that 30 ~ 70mg/ props up.
Preferred application process cigarette filter-tip additive agent is added on the close pipe tobacco end of filter tip.
Beneficial effect of the present invention: absorbent charcoal material wide material sources, of the prior art have employing active carbon or modified active Carbon Materials as the report of harmful components adsorbent for cigarette filter rod, but there is a general problem in the application of these Carbon Materials, all there is adsorption capacity to composition each in flue gas, cigarette odor-absorbing is caused to change, and can peculiar smell be brought, affect the quality of cigarette, cannot realize carrying out selective absorption to certain composition in flue gas, this technical bottleneck being difficult to capture having become Carbon Materials to apply in cigarette as sorbing material.The present patent application adopts glutinous gelatin substance by material with carbon element and tobacco-containing material compound, completely solve material with carbon element as the defect of falling harmful adsorbent and apply in cigarette existence, tobacco-containing material participates in the surface texture that compound effectively changes material with carbon element on the one hand, absorption property is changed, the function making it have selective absorption aldehyde compound (reduces obviously to aldehyde compound, particularly the selective reduced rate of PARA FORMALDEHYDE PRILLS(91,95) and crotonaldehyde is more than 30%), and the absorption properties such as tar, nicotine, water and carbon monoxide are not embodied substantially; Tobacco-containing material supplements appropriate tobacco flavor on the other hand, and makes cigarette sensory quality kept in balance.In addition, simply, cost is low, meets suitability for industrialized production for composite of the present invention and filter tip preparation method.
Detailed description of the invention
Following examples are intended to content of the present invention is described.Instead of the further restriction to scope.
Embodiment 1
15g multi-walled carbon nano-tubes is scattered in water uniformly, then slowly toward wherein adding 80g cabo particle (particle size 20 ~ 60 order), ultrasonic disperse is after 1 hour, add 5g xanthans, ultrasonic disperse 30 minutes, filter, particle is obtained corresponding additives of filter tip in dry 12 hours at 150 DEG C.
Embodiment 2
17g functional amido multi-walled carbon nano-tubes is scattered in water uniformly, then slowly toward wherein adding 80g expanded cabo particle (particle size 20 ~ 60 order), ultrasonic disperse is after 2 hours, add 3g shitosan, ultrasonic disperse 30 minutes, filter, particle is obtained corresponding additives of filter tip in dry 24 hours at 120 DEG C.
Embodiment 3
20g carbon nanocoils is scattered in water uniformly, then slowly toward wherein adding 75g expanded cabo particle (particle size 20 ~ 60 order), ultrasonic disperse is after 1 hour, add 5g shitosan, ultrasonic disperse 30 minutes, filter, particle is obtained corresponding additives of filter tip in dry 24 hours at 120 DEG C.
Embodiment 4
25g expanded graphite is scattered in water uniformly, then slowly toward wherein adding 70g offal particle (particle size 20 ~ 60 order), ultrasonic disperse is after 1 hour, add 5g melon glue, ultrasonic disperse 30 minutes, filter, particle is obtained corresponding additives of filter tip in dry 24 hours at 120 DEG C.
Embodiment 5
Be added in cigarette filter by the additives of filter tip of preparation in embodiment 1 ~ 4, the applied amount of often propping up the additive in filter tip is 50mg, simultaneously not add the cigarette filter of additives of filter tip as blank.After being balanced by cigarette, the content of aldehyde material in the test conventional smoke components of cigarette and main flume, testing result as shown in Table 1 and Table 2.
The conventional flue gas data of table 1 cigarette
Aldehyde material testing result in table 2 cigarette mainstream flue gas
Claims (12)
1. can remove a cigarette filter-tip additive agent for aldehyde material in cigarette mainstream flue gas, it is characterized in that, be to be bondd the composite particulate material formed by glutinous gelatin substance by tobacco-containing material particle and material with carbon element; Described material with carbon element is at least one in multi-walled carbon nano-tubes, amino functional multi-walled carbon nano-tube, carbon nanocoils, expanded graphite.
2. cigarette filter-tip additive agent as claimed in claim 1, it is characterized in that, the mass ratio of tobacco-containing material particle, material with carbon element and glutinous gelatin substance is 60 ~ 90:38 ~ 5:2 ~ 5.
3. cigarette filter-tip additive agent as claimed in claim 2, it is characterized in that, described tobacco-containing material particle is at least one in cabo particle, expanded cabo particle, offal particle.
4. cigarette filter-tip additive agent as claimed in claim 3, it is characterized in that, the particle size of described tobacco-containing material particle is 20 ~ 60 orders.
5. cigarette filter-tip additive agent as claimed in claim 2, it is characterized in that, described glutinous gelatin substance is at least one in xanthans, guar gum, carob, CMC, hydroxymethyl-propyl cellulose, shitosan.
6. the preparation method of the cigarette filter-tip additive agent described in any one of Claims 1 to 5, is characterized in that, first by after material with carbon element ultrasonic disperse is in water, adds tobacco-containing material particle, ultrasonic disperse, then adds glutinous gelatin substance, further ultrasonic disperse; Filter, dry, obtain compound additive particle.
7. as claim 6 preparation method, it is characterized in that, after adding tobacco-containing material particle, the time of ultrasonic disperse is 0.5 ~ 2h.
8. as claim 6 preparation method, it is characterized in that, after adding glutinous gelatin substance, the time of further ultrasonic disperse is 10 ~ 30min.
9. as claim 6 preparation method, it is characterized in that, described oven dry is under 80 ~ 200 DEG C of temperature conditions, toasts 12 ~ 48 hours.
10. the application of the cigarette filter-tip additive agent described in any one of Claims 1 to 5, is characterized in that, described cigarette filter-tip additive agent is added in cigarette filter the aldehyde compound be applied in selective reduction main flume.
11. apply as claimed in claim 10, it is characterized in that, the addition of described cigarette filter-tip additive agent in filter tip is that 30 ~ 70mg/ props up.
12. apply as claimed in claim 10, it is characterized in that, described cigarette filter-tip additive agent is added on the close pipe tobacco end of filter tip.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410779672.7A CN104432507B (en) | 2014-12-15 | 2014-12-15 | Cigarette filter-tip additive agent of aldehyde material and its preparation method and application in a kind of removable cigarette mainstream flue gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410779672.7A CN104432507B (en) | 2014-12-15 | 2014-12-15 | Cigarette filter-tip additive agent of aldehyde material and its preparation method and application in a kind of removable cigarette mainstream flue gas |
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| Publication Number | Publication Date |
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| CN104432507A true CN104432507A (en) | 2015-03-25 |
| CN104432507B CN104432507B (en) | 2017-11-14 |
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| CN201410779672.7A Active CN104432507B (en) | 2014-12-15 | 2014-12-15 | Cigarette filter-tip additive agent of aldehyde material and its preparation method and application in a kind of removable cigarette mainstream flue gas |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105768218A (en) * | 2016-03-25 | 2016-07-20 | 浙江海洋学院 | Cigarette purifying agent containing squid bones as well as preparation method and application of cigarette purifying agent |
| CN111227303A (en) * | 2020-03-20 | 2020-06-05 | 中国科学院宁波材料技术与工程研究所 | Cigarette filter tip additive material and preparation method and application thereof |
| CN114307953A (en) * | 2020-09-30 | 2022-04-12 | 湖南中烟工业有限责任公司 | Silicon dioxide/carbon composite aerogel for reducing harmful substances in smoke and preparation and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3353543A (en) * | 1964-12-02 | 1967-11-21 | American Filtrona Corp | Smoke filter |
| CN2872872Y (en) * | 2006-04-03 | 2007-02-28 | 洛阳深奥科技开发有限公司 | Expansion graphite composite cigarette filter tip |
| CN101128130A (en) * | 2005-02-24 | 2008-02-20 | 菲利普莫里斯生产公司 | Smoking article with tobacco beads |
| CN102342583A (en) * | 2010-08-02 | 2012-02-08 | 南通烟滤嘴有限责任公司 | Filter stick containing tobacco particles and preparation method thereof |
| CN103209606A (en) * | 2010-10-06 | 2013-07-17 | 塞拉尼斯醋酸纤维有限公司 | Smoke filters for smoking devices with porous masses having a carbon particle loading and an encapsulated pressure drop |
-
2014
- 2014-12-15 CN CN201410779672.7A patent/CN104432507B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3353543A (en) * | 1964-12-02 | 1967-11-21 | American Filtrona Corp | Smoke filter |
| CN101128130A (en) * | 2005-02-24 | 2008-02-20 | 菲利普莫里斯生产公司 | Smoking article with tobacco beads |
| CN2872872Y (en) * | 2006-04-03 | 2007-02-28 | 洛阳深奥科技开发有限公司 | Expansion graphite composite cigarette filter tip |
| CN102342583A (en) * | 2010-08-02 | 2012-02-08 | 南通烟滤嘴有限责任公司 | Filter stick containing tobacco particles and preparation method thereof |
| CN103209606A (en) * | 2010-10-06 | 2013-07-17 | 塞拉尼斯醋酸纤维有限公司 | Smoke filters for smoking devices with porous masses having a carbon particle loading and an encapsulated pressure drop |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105768218A (en) * | 2016-03-25 | 2016-07-20 | 浙江海洋学院 | Cigarette purifying agent containing squid bones as well as preparation method and application of cigarette purifying agent |
| CN111227303A (en) * | 2020-03-20 | 2020-06-05 | 中国科学院宁波材料技术与工程研究所 | Cigarette filter tip additive material and preparation method and application thereof |
| CN114307953A (en) * | 2020-09-30 | 2022-04-12 | 湖南中烟工业有限责任公司 | Silicon dioxide/carbon composite aerogel for reducing harmful substances in smoke and preparation and application thereof |
| CN114307953B (en) * | 2020-09-30 | 2024-03-08 | 湖南中烟工业有限责任公司 | Silica/carbon composite aerogel for reducing harmful substances in flue gas and preparation and application thereof |
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| Publication number | Publication date |
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| CN104432507B (en) | 2017-11-14 |
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