CN104385716B - Metal resin composite material and preparing method thereof - Google Patents
Metal resin composite material and preparing method thereof Download PDFInfo
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- CN104385716B CN104385716B CN201410597572.2A CN201410597572A CN104385716B CN 104385716 B CN104385716 B CN 104385716B CN 201410597572 A CN201410597572 A CN 201410597572A CN 104385716 B CN104385716 B CN 104385716B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
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- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/10—Silicon-containing compounds
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- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
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- C08K2003/2296—Oxides; Hydroxides of metals of zinc
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention relates to a metal resin composite material and a preparing method thereof, relating to the technical field of materials. The composite material comprises a metal base material and a surface coating, namely a Al-Ti alloy and a resin coating respectively, wherein the resin coating comprises the following components by mass: 30-50 parts of modified organic silicon resin, 3-12 parts of aluminum silicate fibers, 4-9 parts of nano-stannic oxide, 3-8 parts of nano-zinc oxide, 4-10 parts of reinforced fibers, 3-9 parts of a silane coupling agent, and 5-10 parts of a curing agent. The metal resin composite material provided by the invention is an aluminum titanium alloy-organic silicon resin composite material, and a resin layer is formed on the surface of the aluminum titanium alloy by mold pressing, so that tenacity of the material is effectively ensured, the defects that aluminum titanium alloy is easy to oxidize and low in strength are overcome, and the composite material has both high tenacity and high strength, and can be applied to the field of mechanical manufacture, aerospace and the like.
Description
Technical field
The invention belongs to field of material technology, the preparation of more particularly to a kind of metal matrix composite materials and the composite
Method.
Background technology
Metal resin composite material, is the material based on metal, is covered with answering for one layer of resin bed in substrate material surface
Condensation material.The property and performance of composite is directly related with the property of matrix material and resin bed.
Aluminium alloy is most widely used class non-ferrous metal structural material in industry, in Aeronautics and Astronautics, automobile, machinery
Widely applied in manufacture, ship and chemical industry.Industrial economy is developed rapidly, demand day to Welded structural member
Benefit increases, and the Research on Weldability for enabling aluminum alloy to is also therewith deeply.
According to the difference of alloy material, aluminium alloy can be divided into alfer, alusil alloy, almag and aluminium copper
Deng the performance of various alloys is also not quite similar, and aluminum titanium alloy is a kind of more rare alloy, because with aluminum and titanium as main component
Alloy, its ductility preferably but intensity is poor, therefore, its use range is less, not extensively.In view of aluminum titanium alloy is excellent
Good ductility and toughness, it is to improve aluminum titanium alloy application prospect to have efficacious prescriptions to be improved by the intensity to aluminum titanium alloy
Formula.
At present, there are two kinds to the mode that the intensity of aluminum titanium alloy is improved：
First kind of way is to add other alloy materials, improves the strong of material by other metallic elements or compound
Degree.This improved procedure can effectively improve the intensity of material, but deposit problem both ways：On the one hand, the intensity of material is obtained
To raising, but the consistency of alloy material is reduced, and the toughness of material is also reduced；Second, aluminum titanium alloy when aluminium content is higher,
Aluminum in alloy is easily oxidized by oxygen, and generates pellumina, reduces the performance of material.
The second way is that aluminum titanium alloy surface is processed, to improve its intensity, including the place for carrying out alloy coat
Reason, this coating way can be while the intensity of alloy material be improved, it is to avoid the aluminum in alloy is oxidized, so as to affect which
Performance.
For the second way, the different coating of selection is processed, and effect is also not quite similar, and composite coating wants root
Selected according to the property of matrix material, it is also desirable to improve its performance as far as possible.
The content of the invention
Present invention solves the technical problem that：For above-mentioned deficiency, the defect of prior art is overcome, the purpose of the present invention is to carry
For a kind of metal resin composite material and preparation method thereof.
Technical scheme：A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 3-9:1；
Face coat is resinous coat, and thickness is 1-200um, and which includes each component of following mass content：It is modified to have
Machine silicones 30-50 parts；Alumina silicate fibre 3-12 parts；Nano tin dioxide 4-9 parts；Nano zine oxide 3-8 parts；Reinforcing fiber 4-10
Part；Silane coupler 3-9 parts；Firming agent 5-10 parts.
Preferably, the one kind of reinforcing fiber for carbon fiber, glass fibre or aramid fiber.
Preferably, firming agent is cumyl peroxide or vinyl triamine.
Preferably, firming agent is cumyl peroxide.
A kind of preparation method of metal resin composite material, preparation process are as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 25-80MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, temperature 95-110 DEG C, pressure 5-20MPa, time 20-40min take out after cooling, that is, are prepared into
To metal resin composite material.
Preferably, step（4）The temperature of compression molding is 105 DEG C, pressure 10MPa.
Beneficial effect：The metal resin composite material that the present invention is provided, is the material based on aluminum titanium alloy, by adjustment
The ratio of aluminum and titanium so that alloy material reaches preferable toughness and ductility, beneficial to processing and use.Meanwhile, it is effectively to change
The intensity of kind material and antioxygenic property, are molded one layer of resin bed on aluminum titanium alloy surface, and wherein, resin with organic siliconresin is
Matrix resin, adds aluminium silicate fiber peacekeeping reinforcing fiber, improves the intensity of resin bed；Nano zine oxide and nano tin dioxide plus
Enter, the particle of nano shape can be effectively improved the consistency and performance of resin bed, while by the collaboration of Zinc Oxide and firming agent
Effect, can effectively improve the curing performance of resin.Therefore, the metal resin composite material that the present invention is provided, is aluminum titanium alloy-have
Machine silicone resin composite material, by being molded one layer of resin bed on aluminum titanium alloy surface, can not only be effectively ensured the tough of material
Property, and also overcome that aluminum titanium alloy is oxidizable and the defect of low intensity so that composite has high tenacity and high-strength simultaneously
The performance of degree, can be applied to the fields such as machine-building, Aero-Space.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, but
It should be appreciated that these descriptions are simply for further illustrating the features and advantages of the present invention, rather than to the claims in the present invention
Limit.
Embodiment 1：
A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 9:1；
Face coat is resinous coat, and which includes each component of following mass content：30 parts of modified organic silicone resin；Silicon
3 parts of sour aluminum fiber；4 parts of nano tin dioxide；3 parts of nano zine oxide；4 parts of carbon fiber；3 parts of silane coupler；Peroxidating diisopropyl
Benzene firming agent 5-10 parts.
Above-mentioned metal resin composite material is prepared according to the preparation method that the present invention is provided, step is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 60MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with 1000# sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, 105 DEG C of temperature, pressure 10MPa, time 20min take out after cooling, that is, prepare Metal tree
Resin composite material.
After testing, the thickness of resin bed is 50um.
Embodiment 2：
A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 8:1；
Face coat is resinous coat, and which includes each component of following mass content：50 parts of modified organic silicone resin；Silicon
12 parts of sour aluminum fiber；9 parts of nano tin dioxide；8 parts of nano zine oxide；10 parts of carbon fiber；9 parts of silane coupler；Peroxidating two is different
10 parts of propyl benzene firming agent.
Above-mentioned metal resin composite material is prepared according to the preparation method that the present invention is provided, step is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 60MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with 1000# sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, 105 DEG C of temperature, pressure 10MPa, time 25min take out after cooling, that is, prepare Metal tree
Resin composite material.
After testing, the thickness of resin bed is 70um.
Embodiment 3：
A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 6:1；
Face coat is resinous coat, and which includes each component of following mass content：42 parts of modified organic silicone resin；Silicon
9 parts of sour aluminum fiber；5 parts of nano tin dioxide；5 parts of nano zine oxide；7 parts of glass fibre；6 parts of silane coupler；Vinyl triamine
7 parts of firming agent.
Above-mentioned metal resin composite material is prepared according to the preparation method that the present invention is provided, step is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 60MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with 1000# sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, 105 DEG C of temperature, pressure 5-20MPa, time 25min take out after cooling, that is, prepare metal
Resin composite materials.
After testing, the thickness of resin bed is 65um.
Embodiment 4：
A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 3:1；
Face coat is resinous coat, and which includes each component of following mass content：40 parts of modified organic silicone resin；Silicon
8 parts of sour aluminum fiber；6 parts of nano tin dioxide；5 parts of nano zine oxide；7 parts of aramid fiber；8 parts of silane coupler；Peroxidating two is different
6 parts of propyl benzene firming agent.
Above-mentioned metal resin composite material is prepared according to the preparation method that the present invention is provided, step is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 60MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with 1000# sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, 105 DEG C of temperature, pressure 10MPa, time 30min take out after cooling, that is, prepare Metal tree
Resin composite material.
After testing, the thickness of resin bed is 95um.
Embodiment 5：
A kind of metal resin composite material, including metal matrix material and face coat,
Wherein metal matrix material is Al-Ti alloys, and the atomic ratio of wherein Al and Ti is 7:1；
Face coat is resinous coat, and which includes each component of following mass content：45 parts of modified organic silicone resin；Silicon
10 parts of sour aluminum fiber；6 parts of nano tin dioxide；7 parts of nano zine oxide；6 parts of reinforcing fiber；6 parts of silane coupler；Firming agent 5-10
Part.
Preferably, the one kind of reinforcing fiber for carbon fiber, glass fibre or aramid fiber.
Preferably, firming agent is cumyl peroxide or vinyl triamine.
Preferably, firming agent is cumyl peroxide.
Above-mentioned metal resin composite material is prepared according to the preparation method that the present invention is provided, step is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast to aluminium alloy, pressure
Power 25-80MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with 1000# sand paper；
（3）Prepare coating material, add each component of coating material in a reservoir, ultrasonic agitation it is uniform it
Afterwards, pour alloy base material surface into, pave；
（4）Compression molding, 110 DEG C of temperature, pressure 20MPa, time 30min take out after cooling, that is, prepare Metal tree
Resin composite material.
After testing, the thickness of resin bed is 90um.
The performance test of intensity and toughness is carried out to the composite that above-mentioned specific embodiment is obtained, as a result such as 1 institute of table
Show：
1 metal resin composite material intensity of table and toughness properties are determined
As seen from the above table, the intensity and toughness of embodiment 1-5 is subject to the double influence of aluminum titanium atom ratio and resin layer thickness,
When atomic ratio is relatively low higher with resin layer thickness, intensity and toughness are presented higher level, are 7 in atomic ratio:1, resin bed
When thickness is 90um, intensity and toughness reach highest.
In sum, the metal resin composite material that the present invention is provided has good toughness and intensity.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using the present invention.
Various modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention
The embodiments shown herein is not intended to be limited to, and is to fit to and principles disclosed herein and features of novelty phase one
The most wide scope for causing.
Claims (5)
1. a kind of preparation method of metal resin composite material, it is characterised in that preparation process is as follows：
（1）Al powder and Ti powder are positioned in foundry furnace carries out high melt, then carries out die cast, pressure to aluminium alloy
25-80MPa, cools down after molding, that is, prepares Al-Ti alloy base materials；
Wherein, the atomic ratio of Al and Ti is 3-9:1；
（2）Al-Ti alloy base materials are put in mould, alloy surface are refined with sand paper；
（3）Surface resin coating material is prepared, including each component of following mass fraction：Modified organic silicone resin 30-50 parts,
Alumina silicate fibre 3-12 parts, nano tin dioxide 4-9 parts, nano zine oxide 3-8 parts, reinforcing fiber 4-10 part, silane coupler 3-9
Part and firming agent 5-10 parts, add each component of coating material in a reservoir, after ultrasonic agitation is uniform, pour alloy into
Substrate material surface, paves；
（4）Compression molding, temperature 95-110 DEG C, pressure 5-20MPa, time 20-40min are taken out after cooling, resinous coat thickness
For 1-200 μm, that is, prepare metal resin composite material.
2. the preparation method of metal resin composite material according to claim 1, it is characterised in that：Step（4）It is molded into
The temperature of type is 105 DEG C, pressure 10MPa.
3. the preparation method of metal resin composite material according to claim 1, it is characterised in that：Step（3）Middle enhancing
The one kind of fiber for carbon fiber, glass fibre or aramid fiber.
4. the preparation method of metal resin composite material according to claim 1, it is characterised in that：Step（3）Middle solidification
Agent is cumyl peroxide or vinyl triamine.
5. the preparation method of metal resin composite material according to claim 4, it is characterised in that：Step（3）Middle solidification
Agent is cumyl peroxide.
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| CN111534724B (en) * | 2020-06-04 | 2021-07-06 | 浙江华电器材检测研究所有限公司 | High-strength high-dispersion nano modified aluminum alloy, and preparation method and application thereof |
| CN112251105B (en) * | 2020-09-27 | 2021-09-24 | 广东求精电气有限公司 | Composite material and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1080590A (en) * | 1992-07-03 | 1994-01-12 | 中国科学院金属研究所 | Vinylon strengthened aluminium alloy laminated composited material and preparation method |
| CN1286146A (en) * | 2000-09-25 | 2001-03-07 | 成都宏亿复合材料工程技术有限公司 | Anticorrosion process for metallic surface |
| CN1912161A (en) * | 2006-08-22 | 2007-02-14 | 哈尔滨工业大学 | Preparation method of fine-grained TiAl intermetallic compound material |
| CN103468130A (en) * | 2013-09-03 | 2013-12-25 | 吴江市冰心文教用品有限公司 | High temperature resistant anticorrosive paint |
| CN103602859A (en) * | 2013-11-16 | 2014-02-26 | 袁辉 | Aluminum titanium alloy foil |
-
2014
- 2014-10-30 CN CN201410597572.2A patent/CN104385716B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1080590A (en) * | 1992-07-03 | 1994-01-12 | 中国科学院金属研究所 | Vinylon strengthened aluminium alloy laminated composited material and preparation method |
| CN1286146A (en) * | 2000-09-25 | 2001-03-07 | 成都宏亿复合材料工程技术有限公司 | Anticorrosion process for metallic surface |
| CN1912161A (en) * | 2006-08-22 | 2007-02-14 | 哈尔滨工业大学 | Preparation method of fine-grained TiAl intermetallic compound material |
| CN103468130A (en) * | 2013-09-03 | 2013-12-25 | 吴江市冰心文教用品有限公司 | High temperature resistant anticorrosive paint |
| CN103602859A (en) * | 2013-11-16 | 2014-02-26 | 袁辉 | Aluminum titanium alloy foil |
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