CN104385713A - Temperature control fenestrated membrane and making method thereof - Google Patents

Temperature control fenestrated membrane and making method thereof Download PDF

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Publication number
CN104385713A
CN104385713A CN201410568704.9A CN201410568704A CN104385713A CN 104385713 A CN104385713 A CN 104385713A CN 201410568704 A CN201410568704 A CN 201410568704A CN 104385713 A CN104385713 A CN 104385713A
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China
Prior art keywords
film
fenestrated membrane
temperature control
doping
membrane
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CN201410568704.9A
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Chinese (zh)
Inventor
于甄
高建聪
解金库
胡坤
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Zhangjiagang Kangdexin Optronics Material Co Ltd
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Zhangjiagang Kangdexin Optronics Material Co Ltd
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Priority to CN201410568704.9A priority Critical patent/CN104385713A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/02Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent

Abstract

The invention discloses a temperature control fenestrated membrane and a making method thereof. The temperature control fenestrated membrane comprises a spectrum-selective membrane, doped membranes and a flexible basal membrane, wherein the doped membranes are arranged on the two side surfaces of the spectrum-selective membrane; the flexible basal membrane is arranged on the VO2 doped membrane on one side of the spectrum-selective membrane. According to the temperature control fenestrated membrane and the making method thereof, the VO2 membranes are formed on the two side surfaces of the spectrum-selective membrane, the property that the VO2 membranes in the metallographic phase under high temperature reflect infrared rays while in the semiconductor phase under low temperature enable the infrared rays to penetrate through is utilized, and through the doping technology, the phase-transition temperature of the VO2 doped membranes is reduced to room temperature, so that the purpose of automatically regulating the infrared transmission according to the indoor temperatures is achieved, and the control precision of the intelligent fenestrated membrane on the transmittance of the infrared rays is further improved.

Description

The preparation method of temperature control fenestrated membrane and temperature control fenestrated membrane
Technical field
The present invention relates to fenestrated membrane technical field, in particular to the preparation method of a kind of temperature control fenestrated membrane and temperature control fenestrated membrane.
Background technology
At present, energy-saving and emission-reduction become one of important channel of reply greenhouse effects and Global climate change.Regulate required energy consumption to be huge in automobile and building field temperature, incide indoor heat have 70% by forms through.Paste one deck fenestrated membrane at automobile or building glass inner surface, can effectively intercept infrared ray and ultraviolet, keep visible light-transmissive, reduce air conditioning energy consumption.In addition, the damage that fenestrated membrane also can reduce in car or indoor article and personnel cause because of Ultraviolet radiation.
The method preparing fenestrated membrane comprises wet and dry type coating.Wherein, wet comprises dipping formula, roller type and scraper type coating etc.Such as, application number be CN201110125866.1 Chinese patent by wet technique define a kind of can the effectively heat insulation fenestrated membrane having again high transmission rate.Again such as, application number be 201210285669.0 Chinese patent define a kind of fenestrated membrane with effects such as high printing opacity height are heat insulation, anti-scratch by wet technique.The Heat insulation UV-resistant principle of this kind of fenestrated membrane is in fenestrated membrane, add material infrared ray, ultraviolet being had to absorption.But fenestrated membrane absorbs after heat reaches capacity and no longer absorbs heat, makes too much heat storage in fenestrated membrane, and then easily causes rete old.Generally, this kind of fenestrated membrane General Life was lower than 5 years.
Dry type coating process comprises chemical vapour deposition (CVD), molecular beam epitaxy, vacuum evaporation and magnetron sputtering etc.Such as, abroad some fenestrated membrane manufacturing enterprises magnetron sputtering technique is prepared into a kind of high printing opacity and the heat insulation fenestrated membrane of height, and its heat insulation rate can reach 90%, and light transmittance can reach 80%.This kind of window film insulation principle is: in fenestrated membrane, sputter layer of metal or metal oxide, this metal or metal oxide can to light carry out selective through, namely through visible ray, uv reflectance and infrared ray.This type of fenestrated membrane can not only realize high printing opacity, height is heat insulation, high every ultraviolet effect, and long service life, generally can use 5 ~ 10 years.
Above-mentioned traditional fenestrated membrane owing to just cannot change its physical property once formed product, thus cannot regulate heat insulation rate according to external condition automatically.Such as, need more heat to incide indoor the people in winter of cold, and traditional fenestrated membrane cannot reach such effect.In order to obtain the better fenestrated membrane of energy-saving effect, researcher turns to intelligent fenestrated membrane sight, namely can be regulated the fenestrated membrane of its light transmittance by the change of ambient temperature.Application number be 201310611551.7 Chinese patent disclose a kind of co-extruding biaxial stretched functional polyester intelligent light modulation film and preparation method thereof, this intelligent light modulation film has the function that environmentally variations in temperature automatically adjusts to the saturating reflection characteristic of photo-thermal.Application number is that the Chinese patent of 201210019446.X discloses the energy-conservation composite film-stuck of a kind of intelligent temperature control, and the energy-conservation composite film-stuck of this intelligent temperature control can realize cold and hot bidirectional modulation, thus reaches the effect that winter is warming, summer is heat insulation.Application number be 201310360653.6 Chinese patent disclose a kind of fenestrated membrane of automatic adjustment light transmittance, this fenestrated membrane automatically reduces light transmittance under strong light environment, and becomes coloured from colourless, and automatically recovers under low light environment.
But; the transmitance control accuracy of above-mentioned intelligent fenestrated membrane to IR is not high; thermoregulation effect not obvious (data display is about 20%); and its production technology (such as magnetron sputtering etc.) is complicated; its correlative study concentrates on laboratory stage, yet there are no the manufacturing enterprise of scale.In addition, above-mentioned intelligent fenestrated membrane, at the light transmittance of visible region low (visible ray mean transmissivity is less than 50%), does not meet relevant industries standard.For these problems, also there is no effective solution at present.
Summary of the invention
The present invention aims to provide the preparation method of a kind of temperature control fenestrated membrane and temperature control fenestrated membrane, to improve the control accuracy of intelligent fenestrated membrane to the transmitance of IR.
For this reason, the invention provides a kind of temperature control fenestrated membrane, this temperature control fenestrated membrane comprises: optical electivity film; Doping VO 2film, is arranged on two sides of optical electivity film; And flexible base film, be arranged at the doping VO of the side of optical electivity film 2on film.
Further, adulterate VO 2doped chemical in film is any one or more in W, Mo, Er, Nb, Ce and Mg.
Further, adulterate VO 2the doping percentage of the doped chemical in film is 1% ~ 10%.
Further, adulterate VO 2the gross thickness of film is 120 ~ 150nm.
Further, optical electivity film is made up of metal level and the Seed Layer be arranged on two sides of metal level.
Further, the material of metal level is Ag, Au, Rh or Pt; The material of Seed Layer is zinc or titanium.
Further, the thickness of metal level is 1 ~ 20nm; The thickness being positioned at the Seed Layer of the side of metal level is 1 ~ 20nm.
Further, the material of flexible base film is transparent flexible polyester, and mist degree≤2 of flexible base film.
Further, the thickness of flexible base film is 10 ~ 50 μm.
Meanwhile, present invention also offers a kind of preparation method of temperature control fenestrated membrane, be included in step flexible base film being formed optical electivity film, two sides that this preparation method is also included in optical electivity film form doping VO 2the step of film.
Further, in the step forming optical electivity film, formed by metal level and be positioned at the optical electivity film that the Seed Layer on two sides of metal level forms.
Further, in the step forming Seed Layer, the oxidized formation oxide layer of material of Some Species sublayer.
Further, doping VO is formed 2the technique of film, Seed Layer and metal level is magnetron sputtering technique.
The present invention by forming doping VO on two sides of optical electivity film 2film, and utilize doping VO 2film when high temperature due in Metal Phase and reflected infrared ray, cold state due in semiconductor phase through ultrared character, and by doping techniques make forms the VO that adulterates 2the phase transition temperature of film is down to room temperature, thus achieves the object automatically regulating infrared light transmission according to indoor temperature, and then improves the control accuracy of intelligent fenestrated membrane to the transmitance of IR.
Accompanying drawing explanation
The accompanying drawing forming a part of the present invention is used to provide a further understanding of the present invention, and schematic description and description of the present invention, for explaining the present invention, does not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 shows the cross-sectional view of the temperature control fenestrated membrane that embodiment of the present invention provides; And
Fig. 2 shows the temperature control fenestrated membrane transmission spectrum at different temperatures that the application's embodiment provides.
Detailed description of the invention
It should be noted that, when not conflicting, the embodiment in the application and the feature in embodiment can combine mutually.Below with reference to the accompanying drawings and describe the application in detail in conjunction with the embodiments.
It should be noted that used term is only to describe detailed description of the invention here, and be not intended to the illustrative embodiments of restricted root according to the application.As used herein, unless the context clearly indicates otherwise, otherwise singulative is also intended to comprise plural form, in addition, it is to be further understood that, " comprise " when using term in this manual and/or " comprising " time, it indicates existing characteristics, step, operation, device, assembly and/or their combination.
For convenience of description, here can usage space relative terms, as " ... on ", " in ... top ", " at ... upper surface ", " above " etc., be used for the spatial relation described as a device shown in the figure or feature and other devices or feature.Should be understood that, space relative terms is intended to comprise the different azimuth in use or operation except the described in the drawings orientation of device.Such as, " in other devices or structure below " or " under other devices or structure " will be positioned as after if the device in accompanying drawing is squeezed, being then described as the device of " above other devices or structure " or " on other devices or structure ".Thus, exemplary term " in ... top " can comprise " in ... top " and " in ... below " two kinds of orientation.This device also can other different modes location (90-degree rotation or be in other orientation), and relatively describe space used here and make respective explanations.
From background technology, the transmitance control accuracy of existing intelligent fenestrated membrane to IR is not high, and thermoregulation effect is not obvious.The present inventor studies for the problems referred to above, proposes a kind of temperature control fenestrated membrane.As shown in Figure 1, this temperature control fenestrated membrane comprises: optical electivity film 30; Doping VO 2film 20, is arranged on two sides of optical electivity film 30; And flexible base film 10, be arranged at the doping VO of the side of optical electivity film 30 2on film 20.
The present invention by forming doping VO on two sides of optical electivity film 30 2film 20, and utilize doping VO 2film 20 when high temperature due in Metal Phase and reflected infrared ray, cold state due in semiconductor phase through ultrared character, and by doping techniques make forms the VO that adulterates 2the phase transition temperature of film 20 is down to room temperature, thus achieves the object automatically regulating infrared light transmission according to indoor temperature, and then improves the control accuracy of intelligent fenestrated membrane to the transmitance of IR.
When winter temperature is lower, infrared light temperature control fenestrated membrane enters indoor to improve indoor temperature.When summer temperature height, temperature control fenestrated membrane reduces the transmitance of infrared light automatically, stops indoor temperature to raise, thus serves effect cool in summer and warm in winter.
Illustrative embodiments according to temperature control fenestrated membrane provided by the invention will be described in more detail below.But these illustrative embodiments can be implemented by multiple different form, and should not be interpreted as being only limited to embodiment set forth herein.Should be understood that, provide these embodiments be in order to make the application open thorough and complete, and the design of these illustrative embodiments is fully conveyed to those of ordinary skill in the art.
In order to reduce VO 2the phase transition temperature of film, the present invention passes through VO 2film carries out adulterating to form above-mentioned doping VO 2film 20, these Doped ions can make the VO that adulterates 2the phase transition temperature of film 20 is down to room temperature (such as 20 ~ 38 DEG C).In order to realize this object, the present inventor obtains doping VO by lot of experiments 2the key process parameters such as the doped chemical in film 20 and doping content, its preferred processing condition is: doping VO 2doped chemical in film 20 is any one or more in W, Mo, Er, Nb, Ce and Mg; Doping VO 2the doping percentage of the doped chemical in film 20 is 1% ~ 10%.
Meanwhile, inventor also finds the VO that adulterates 2the thickness of film 20 also can affect the performance of temperature control fenestrated membrane.Preferably, adulterate VO 2the gross thickness of film 20 is 120 ~ 150nm.If doping VO 2the gross thickness of film 20 is too thick (being greater than 150nm), doping VO 2the visible light transmissivity of film 20 can reduce; If doping VO 2the gross thickness of film 20 is too thin (being less than 120nm), doping VO 2the phase transition performance of film 20 can be affected.
The film with optical electivity function that above-mentioned optical electivity film 30 can adopt this area common.In a preferred embodiment, optical electivity film 30 is made up of metal level 33 and the Seed Layer 31 be arranged on two sides of metal level 33.Wherein, the material of metal level 33 can be Ag, Au, Rh or Pt, and the material of Seed Layer 31 can be zinc or titanium.Certainly, the material of metal level 33 and Seed Layer 31 is not limited to above-mentioned example.
The thickness of metal level 33 also can affect the performance of temperature control fenestrated membrane.Preferably, the thickness of metal level 33 is 1 ~ 20nm.If the thickness of metal level 33 too thick (being greater than 20nm), the light transmittance of temperature control fenestrated membrane can reduce; If the thickness of metal level 33 is too thin, in metal level 33, easily there is gap, thus affect the electric conductivity of metal level 33.
The oxonium ion in dielectric layer " can be caught " in Seed Layer 31 1 aspect, makes dielectric layer be oxygen debt state, and then forms so-called tunneling effect raising electric conductivity; Conductive metal layer 33 can be prevented to be oxidized by intelligent temperature control layer and to lose efficacy on the other hand, fill when gap appears in conductive metal layer 33 because thickness is too small simultaneously, thus increase electric conductivity.Preferably, the thickness being positioned at the Seed Layer 31 of the side of metal level 33 is 1 ~ 20nm.
The material of above-mentioned flexible base film 10 can be transparent flexible polyester (such as PET etc.), and the mist degree of flexible base film 10 have≤2.Preferably, the thickness of flexible base film 10 is 10 ~ 50 μm.
Meanwhile, present invention also offers a kind of preparation method of temperature control fenestrated membrane, be included in step flexible base film being formed optical electivity film, two sides that this preparation method is also included in optical electivity film form doping VO 2the step of film.This making by forming doping VO in flexible base film 2film and optical electivity film, achieve takeup type plated film, thus improve film forming face sum rate of film build, provides a kind of new method for temperature control fenestrated membrane moves towards industrialization.
The illustrative embodiments of the preparation method of the temperature control fenestrated membrane provided according to one embodiment of the present invention will be described in more detail below.But these illustrative embodiments can be implemented by multiple different form, and should not be interpreted as being only limited to embodiment set forth herein.Should be understood that, provide these embodiments be in order to make the application open thorough and complete, and the design of these illustrative embodiments is fully conveyed to those of ordinary skill in the art.
First, plating one deck doping VO is formed in flexible base film 2film.Form doping VO 2the equipment of film can adopt at winding magnetic control sputtering coating machine, specifically comprises the following steps: winding magnetic control sputtering coating machine installs flexible base film and doping VO 2the target of film, then sputtering forms doping VO 2film.The material of flexible base film can be transparent flexible polyester (such as PET etc.), and the mist degree of flexible base film have≤2.Preferably, the thickness of flexible base film is 10 ~ 50 μm.
Then, at doping VO 2light-plated spectrum selective membrane on film.In a preferred embodiment, the technique of light-plated spectrum selective membrane comprises the following steps: first, at doping VO 2film is formed one deck Seed Layer, such as Ti layer; Then, sputtering forms metal level, such as Ag layer on the seed layer; Finally, one deck Seed Layer is formed again at metal level.Upper and lower two-layer Seed Layer, except playing index matching effect, greatly can also improve non-oxidizability, increases the service life of fenestrated membrane.In this step, the oxidized formation oxide layer of material of Some Species sublayer 31, is doped VO to avoid metal level 2film is oxidized.
Finally, another layer of doping VO is formed again at optical electivity film 2film.Form doping VO 2the equipment of film can adopt at winding magnetic control sputtering coating machine.This two-layer doping VO 2film has the covert character of thermic, automatically can adjust infrared light transmission according to ambient temperature, in temperature higher than having lower infrared light transmission during phase transition temperature, in temperature lower than having higher infrared light transmission during phase transition temperature.
After this step, in single resonator, the physical thickness of whole film system (temperature control fenestrated membrane) can control within 200nm, thus makes the thickness of temperature control fenestrated membrane of the present invention thinner compared with other fenestrated membrane existing.In addition, adulterate VO 2after film, can also at doping VO 2film forms ionic membrane.
Temperature control fenestrated membrane provided by the invention and preparation method thereof is further illustrated below in conjunction with embodiment.
The preparation method of temperature control fenestrated membrane provided by the invention specifically comprises the following steps:
First, plating one deck doping VO is formed in PET film 2film, wherein the mist degree of PET film is 1.2, and the thickness of PET film is 50 μm, doping VO 2doped chemical in film is W, and the doping percentage of doped chemical is 1%, doping VO 2the thickness of film 20 is 70nm;
Then, at doping VO 2light-plated spectrum selective membrane on film, comprises the following steps: at doping VO 2film is formed the Ti Seed Layer that a layer thickness is 18nm, then in Ti Seed Layer, sputtering forms the Ag metal level that thickness is 20nm, finally, forms at Ag metal level the Ti Seed Layer that a layer thickness is 18nm again;
Finally, another layer of doping VO is formed at optical electivity film 2film, wherein, doping VO 2doped chemical in film is W, and the doping percentage of doped chemical is 1%, doping VO 2the thickness of film is 70nm.
Test: the transmission spectrum (as shown in Figure 2) utilizing sample under Lambda950 spectrophotometer measurement different temperatures, draws ultraviolet, visible ray, infrared transmittivity according to transmission spectrum.Can analyze from Fig. 2, form temperature control fenestrated membrane visible light transmissivity reach 85%; Ultraviolet isolating rate reaches more than 99%; 10% is less than at the above wave band infrared light transmission of high temperature state 1200nm; Being less than 10% higher than infrared light transmission during room temperature, is 60% lower than infrared light transmission during room temperature.
As can be seen from the above embodiments, the example that the present invention is above-mentioned achieves following technique effect:
(1) the present invention by forming doping VO on two sides of optical electivity film 2film, and utilize doping VO 2film when high temperature due in Metal Phase and reflected infrared ray, cold state due in semiconductor phase through ultrared character, and by doping techniques make forms the VO that adulterates 2the phase transition temperature of film is down to room temperature, thus achieves the object automatically regulating infrared light transmission according to indoor temperature, and then improves the control accuracy of intelligent fenestrated membrane to the transmitance of IR.
(2) by forming doping VO in flexible base film 2film and optical electivity film, achieve takeup type plated film, thus improve film forming face sum rate of film build, provides a kind of new method for temperature control fenestrated membrane moves towards industrialization.
(3) form temperature control fenestrated membrane visible light transmissivity reach 85%; Ultraviolet isolating rate reaches more than 99%; 10% is less than at the above wave band infrared light transmission of high temperature state 1200nm; Being less than 10% higher than infrared light transmission during room temperature, is 60% lower than infrared light transmission during room temperature.
These are only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (13)

1. a temperature control fenestrated membrane, is characterized in that, described temperature control fenestrated membrane comprises:
Optical electivity film (30);
Doping VO 2film (20), is arranged on two sides of described optical electivity film (30); And
Flexible base film (10), is arranged at the described doping VO of the side of described optical electivity film (30) 2on film (20).
2. temperature control fenestrated membrane according to claim 1, is characterized in that, described doping VO 2doped chemical in film (20) is any one or more in W, Mo, Er, Nb, Ce and Mg.
3. temperature control fenestrated membrane according to claim 2, is characterized in that, described doping VO 2the doping percentage of the doped chemical in film (20) is 1% ~ 10%.
4. temperature control fenestrated membrane according to claim 1, is characterized in that, described doping VO 2the gross thickness of film (20) is 120 ~ 150nm.
5. temperature control fenestrated membrane according to claim 1, is characterized in that, described optical electivity film (30) is made up of metal level (33) and the Seed Layer (31) be arranged on two sides of described metal level (33).
6. temperature control fenestrated membrane according to claim 5, is characterized in that, the material of described metal level (33) is Ag, Au, Rh or Pt; The material of described Seed Layer (31) is zinc or titanium.
7. temperature control fenestrated membrane according to claim 5, is characterized in that, the thickness of described metal level (33) is 1 ~ 20nm; The thickness being positioned at the described Seed Layer (31) of the side of described metal level (33) is 1 ~ 20nm.
8. temperature control fenestrated membrane according to claim 1, is characterized in that, the material of described flexible base film (10) is transparent flexible polyester, and mist degree≤2 of described flexible base film (10).
9. temperature control fenestrated membrane according to claim 8, is characterized in that, the thickness of described flexible base film (10) is 10 ~ 50 μm.
10. a preparation method for temperature control fenestrated membrane, is included in the upper step forming optical electivity film (30) of flexible base film (10), it is characterized in that, two sides that described preparation method is also included in described optical electivity film 30 form doping VO 2the step of film (20).
11. preparation methods according to claim 10, it is characterized in that, in the step forming described optical electivity film (30), form the described optical electivity film (30) be made up of metal level (33) and the Seed Layer (31) be positioned on two sides of described metal level (33).
12. preparation methods according to claim 11, is characterized in that, in the step forming described Seed Layer (31), and the oxidized formation oxide layer of material of the described Seed Layer of part (31).
13. preparation methods according to claim 11, is characterized in that, form described doping VO 2the technique of film (20), described Seed Layer (31) and described metal level (33) is magnetron sputtering technique.
CN201410568704.9A 2014-10-22 2014-10-22 Temperature control fenestrated membrane and making method thereof Pending CN104385713A (en)

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CN107219581A (en) * 2016-03-21 2017-09-29 张家港康得新光电材料有限公司 Intelligent temperature control film and its application
CN107338415A (en) * 2016-05-03 2017-11-10 上海大学 A kind of preparation method of the laminated film of metal nano gauze and vanadium dioxide
JP2018025745A (en) * 2016-07-27 2018-02-15 株式会社リコー Multilayer film, multilayer film composite, optical component, and window
CN107933033A (en) * 2017-12-29 2018-04-20 常州山由帝杉防护材料制造有限公司 With heat-insulating and energy-saving effect fenestrated membrane and include its glassware
CN111204987A (en) * 2018-11-21 2020-05-29 中国建筑材料科学研究总院有限公司 Glass type thermal control coating and preparation method thereof
CN111204988A (en) * 2018-11-21 2020-05-29 中国建筑材料科学研究总院有限公司 Flexible film type thermal control coating and preparation method thereof
CN111378189A (en) * 2020-01-19 2020-07-07 天津大学 Intelligent temperature adjusting material based on radiation cooling and preparation method thereof

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CN103254664A (en) * 2013-05-14 2013-08-21 四川大学 Method for preparing intelligent temperature control type powder with mica coated by vanadium dioxide
CN103744132A (en) * 2014-01-28 2014-04-23 张家港康得新光电材料有限公司 Anti-reflection structure and anti-reflection film

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CN107219581A (en) * 2016-03-21 2017-09-29 张家港康得新光电材料有限公司 Intelligent temperature control film and its application
CN107338415A (en) * 2016-05-03 2017-11-10 上海大学 A kind of preparation method of the laminated film of metal nano gauze and vanadium dioxide
CN107338415B (en) * 2016-05-03 2022-02-25 上海大学 Preparation method of composite film of metal nanowire network and vanadium dioxide
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