CN104379688A - 涂料及近红外线吸收滤波器 - Google Patents
涂料及近红外线吸收滤波器 Download PDFInfo
- Publication number
- CN104379688A CN104379688A CN201380033258.5A CN201380033258A CN104379688A CN 104379688 A CN104379688 A CN 104379688A CN 201380033258 A CN201380033258 A CN 201380033258A CN 104379688 A CN104379688 A CN 104379688A
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- China
- Prior art keywords
- methyl
- acid
- acrylate
- coating
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 31
- 239000003973 paint Substances 0.000 title abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 35
- 239000002904 solvent Substances 0.000 claims abstract description 34
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 6
- 125000005843 halogen group Chemical group 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 43
- 239000011248 coating agent Substances 0.000 claims description 36
- 239000000049 pigment Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 13
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 7
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 150000001450 anions Chemical class 0.000 abstract description 4
- 125000001424 substituent group Chemical group 0.000 abstract 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 abstract 1
- -1 cyanine compound Chemical class 0.000 description 90
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 22
- 239000002253 acid Substances 0.000 description 14
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 150000002500 ions Chemical class 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 6
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert-Butyl hydroperoxide Substances CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 230000000176 photostabilization Effects 0.000 description 5
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 4
- 239000012965 benzophenone Substances 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000019439 ethyl acetate Nutrition 0.000 description 4
- 238000003384 imaging method Methods 0.000 description 4
- 229920003986 novolac Polymers 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000010835 comparative analysis Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 3
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 150000007518 monoprotic acids Chemical class 0.000 description 3
- 229920000647 polyepoxide Polymers 0.000 description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 description 3
- 235000013824 polyphenols Nutrition 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- FDSUVTROAWLVJA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)COCC(CO)(CO)CO FDSUVTROAWLVJA-UHFFFAOYSA-N 0.000 description 2
- JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical compound OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 2
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 2
- FUGYGGDSWSUORM-UHFFFAOYSA-N 4-hydroxystyrene Chemical compound OC1=CC=C(C=C)C=C1 FUGYGGDSWSUORM-UHFFFAOYSA-N 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- VVJKKWFAADXIJK-UHFFFAOYSA-N Allylamine Chemical compound NCC=C VVJKKWFAADXIJK-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical class COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
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- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- SJNALLRHIVGIBI-UHFFFAOYSA-N allyl cyanide Chemical compound C=CCC#N SJNALLRHIVGIBI-UHFFFAOYSA-N 0.000 description 2
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- 150000008064 anhydrides Chemical class 0.000 description 2
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- 239000004566 building material Substances 0.000 description 2
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- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
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- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
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- WGYZMNBUZFHYRX-UHFFFAOYSA-N 1-(1-methoxypropan-2-yloxy)propan-2-ol Chemical compound COCC(C)OCC(C)O WGYZMNBUZFHYRX-UHFFFAOYSA-N 0.000 description 1
- FQCJGOFQLJELIV-UHFFFAOYSA-N 1-(azetidin-1-yl)prop-2-en-1-one Chemical compound C=CC(=O)N1CCC1 FQCJGOFQLJELIV-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B53/00—Quinone imides
- C09B53/02—Indamines; Indophenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- G—PHYSICS
- G02—OPTICS
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Abstract
本发明提供一种含有红外线吸收色素(A)、树脂(B)及溶剂(C)且作为溶剂(C)成分以二丙酮醇为必须成分的涂料以及使用该涂料形成的近红外线吸收滤波器。红外线吸收色素(A)优选为二亚铵化合物、特别是下述通式(I)表示的二亚铵化合物。式中,R11、R12、R13、R14、R15、R16、R17及R18表示氢原子或可以具有取代基的C1~10的烷基,R19、R20、R21及R22表示氢原子、卤素原子、可以具有取代基的C1~10的烷基或可以具有取代基的氨基,上述烷基中的亚甲基可以被-O-或-CH=CH-取代,t表示1~4的数,Anq-表示q价的阴离子。
Description
技术领域
本发明涉及含有红外线吸收色素、树脂及作为溶剂的二丙酮醇的涂料以及使用该涂料形成的近红外线吸收滤波器。
背景技术
近红外线吸收滤波器由于可见光线区域的透射率高且能够高效地屏蔽红外线,所以被用于等离子体显示面板、CRT、荧光显示管、场致发射型显示器等的显示面板;照相机、摄像机等光学设备的受光元件、摄像元件中使用的光电二极管、CCD、C-MOS;光学透镜、汽车用玻璃、建材用玻璃、太阳能电池模块等的热射线屏蔽滤波器;摄像机等光学设备的受光元件、摄像元件等中。
专利文献1中公开了含有二丙酮醇作为溶剂的正型感光性树脂组合物,专利文献2中公开了含有着色剂及溶剂的含着色剂固化性组合物,并作为溶剂例示了二丙酮醇。专利文献3中公开了含有二丙酮醇作为溶剂的正型感光性树脂组合物,专利文献4中公开了含有酸性染料和醇系有机溶剂的油墨,专利文献5中公开了使用二亚铵化合物得到的近红外线吸收滤波器。
但是,在上述专利文献1~5中既没有记载也没有暗示通过使用二丙酮醇作为溶剂,将涂料涂布到基板上而得到的薄膜的耐光性提高。
现有技术文献
专利文献
专利文献1:日本特开平10-123700号公报
专利文献2:US2007049650A1
专利文献3:日本特开2010-128065号公报
专利文献4:日本专利4199580号公报
专利文献5:日本专利4403473号公报
发明内容
发明所要解决的问题
因此,本发明的目的在于提供一种耐光性高的近红外线吸收滤波器。
用于解决问题的方法
本发明人反复进行了深入研究,结果发现,使用含有红外线吸收色素(A)、树脂(B)及溶剂(C)且作为溶剂(C)成分以二丙酮醇为必须成分的涂料形成的近红外线吸收滤波器的耐光性高,从而完成了本发明。
本发明提供一种含有红外线吸收色素(A)、树脂(B)及溶剂(C)且作为溶剂(C)成分以二丙酮醇为必须成分的涂料。
另外,本发明还提供一种使用上述涂料形成的近红外线吸收滤波器。
发明效果
本发明的近红外线吸收滤波器在耐光性高这方面优异。
具体实施方式
以下,基于优选的实施方式对本发明的涂料及近红外线吸收滤波器进行说明。
本发明的涂料中,作为红外线吸收色素(A),可以使用在红外区域具有特性吸收且以往作为(近)红外线吸收色素使用的物质,可列举出例如以往的花青化合物、方酸内鎓化合物、卟啉化合物、金属二硫醇络合物、铬、钴金属络合盐化合物、蒽醌类、酞菁化合物、萘酞菁化合物、二亚铵化合物、无机氧化物粒子等,其中,二亚铵化合物由于红外线的吸收能力高且在可见光区域中的透明性高,所以优选。
上述二亚铵化合物中,下述通式(I)表示的化合物由于耐湿热性优异,所以进一步优选。
(式中,R11、R12、R13、R14、R15、R16、R17及R18分别独立地表示氢原子或可以具有取代基的碳原子数为1~10的烷基,R19、R20、R21及R22分别独立地表示氢原子、卤素原子、可以具有取代基的碳原子数为1~10的烷基或可以具有取代基的氨基,上述烷基中的亚甲基也可以被-O-或-CH=CH-取代,t表示1~4的数,Anq-表示q价的阴离子,q表示1或2,p表示将电荷保持在中性的系数。)
上述通式(I)中,作为R11、R12、R13、R14、R15、R16、R17、R18、R19、R20、R21及R22表示的可以具有取代基的碳原子数为1~10的烷基,可列举出甲基、乙基、丙基、异丙基、丁基、仲丁基、叔丁基、异丁基、戊基、异戊基、叔戊基、己基、环己基、环己基甲基、环己基乙基、庚基、异庚基、叔庚基、正辛基、异辛基、叔辛基、2-乙基己基、三氟甲基、三氯甲基、三溴甲基、1,2-二氯乙基、3,3,3-三氟丙基、丙-1-烯-1-基等,
作为R19、R20、R21及R22表示的卤素原子,可列举出氟原子、氯原子、溴原子、碘原子等,
作为R19、R20、R21及R22表示的可以具有取代基的氨基,可列举出氨基、乙基氨基、二甲基氨基、二乙基氨基、丁基氨基、环戊基氨基、2-乙基己基氨基、十二烷基氨基、苯胺基、氯苯基氨基、甲苯氨基、茴香氨基、N-甲基-苯胺基、二苯基氨基、萘基氨基、2-吡啶基氨基、甲氧基羰基氨基、苯氧基羰基氨基、乙酰基氨基、苯甲酰基氨基、甲酰基氨基、新戊酰基氨基、月桂酰基氨基、氨基甲酰基氨基、N,N-二甲基氨基羰基氨基、N,N-二乙基氨基羰基氨基、吗啉代羰基氨基、甲氧基羰基氨基、乙氧基羰基氨基、叔丁氧基羰基氨基、正十八烷氧基羰基氨基、N-甲基-甲氧基羰基氨基、苯氧基羰基氨基、氨磺酰基氨基、N,N-二甲基氨基磺酰基氨基、甲基磺酰基氨基、丁基磺酰基氨基、苯基磺酰基氨基等。
作为上述通式(I)中的pAnq-表示的q价的阴离子,除了甲磺酸根阴离子、十二烷基磺酸根阴离子、苯磺酸根阴离子、甲苯磺酸根阴离子、三氟甲磺酸根阴离子、萘磺酸根阴离子、二苯基胺-4-磺酸根阴离子、2-氨基-4-甲基-5-氯苯磺酸根阴离子、2-氨基-5-硝基苯磺酸根阴离子、日本特开平10-235999号公报、日本特开平10-337959号公报、日本特开平11-102088号公报、日本特开2000-108510号公报、日本特开2000-168223号公报、日本特开2001-209969号公报、日本特开2001-322354号公报、日本特开2006-248180号公报、日本特开2006-297907号公报、日本特开平8-253705号公报、日本特表2004-503379号公报、日本特开2005-336150号公报、国际公开2006/28006号公报等中记载的磺酸根阴离子等有机磺酸根阴离子以外,还可列举出氯化物离子、溴化物离子、碘化物离子、氟化物离子、氯酸根离子、硫氰酸根离子、高氯酸根离子、六氟磷酸根离子、六氟锑酸根离子、四氟硼酸根离子、辛基磷酸根离子、十二烷基磷酸根离子、十八烷基磷酸根离子、苯基磷酸根离子、壬基苯基磷酸根离子、2,2’-亚甲基双(4,6-二-叔丁基苯基)膦酸根离子、四(五氟苯基)硼酸根离子、具有使处于激发状态的活性分子脱激发(猝灭)的功能的猝灭剂阴离子、在环戊二烯基环上具有羧基、膦酸基、磺酸基等阴离子性基团的二茂铁、二茂钌等茂金属化合物阴离子等。
作为本发明的上述通式(I)表示的二亚铵化合物的阳离子的具体例子,可列举出下述化合物No.1~8。
上述红外线吸收色素(A)可以单独使用或将多种组合使用。
上述红外线吸收色素(A)中,上述通式(I)表示的化合物的含量优选为50~100质量%,更优选为70~100质量%。若上述通式(I)表示的化合物的含量小于50质量%,则有在溶剂中的溶解性降低或耐热性降低的情况。
上述红外线吸收色素(A)优选涂膜的最大吸收波长(λmax)为700nm以上,进一步优选为780~850nm。若涂膜的最大吸收波长(λmax)低于700nm,则不会吸收目标波长的光,所以不优选。
本发明的涂料中,上述红外线吸收色素(A)的含量在本发明的涂料中,优选为0.01~50质量%,更优选为0.1~10质量%。若红外线吸收色素(A)的含量小于0.01质量%,则有在使用本发明的涂料形成的近红外线吸收滤波器中不会吸收目标波长的情况,若大于50质量%,则有在涂料中发生红外线吸收色素(A)析出的情况。
本发明的涂料中,作为树脂(B),只要是能够将上述红外线吸收色素(A)均匀地分散的物质就没有特别限定,可优选使用聚酯系、聚丙烯酸系、聚酰胺系、聚氨酯系、聚烯烃系、聚碳酸酯系等树脂、进一步将这些树脂通过有机过氧化物、交联剂、光交联引发剂等交联而成的树脂。此外,优选树脂的玻璃化转变温度及通过将含有该树脂的涂料涂布到基板上而得到的固化膜(近红外线吸收滤波器)的玻璃化转变温度为所用设备的使用保证温度以上。
上述树脂(B)中,从与红外线吸收色素(A)的相容性的角度出发,优选聚丙烯酸系树脂,进一步优选使具有烯键式不饱和键的聚合性化合物单独或多种聚合而得到的物质。
作为上述具有烯键式不饱和键的聚合性化合物,没有特别限定,可以使用以往公知的化合物,可列举出例如乙烯、丙烯、丁烯、异丁烯、氯乙烯、偏氯乙烯、偏氟乙烯、四氟乙烯等不饱和脂肪族烃;(甲基)丙烯酸、α―氯丙烯酸、衣康酸、马来酸、柠康酸、富马酸、腐植酸、巴豆酸、异巴豆酸、乙烯基醋酸、烯丙基醋酸、肉桂酸、山梨酸、中康酸、琥珀酸单[2-(甲基)丙烯酰氧基乙基]酯、邻苯二甲酸单[2-(甲基)丙烯酰氧基乙基]酯、ω-羧基聚己内酯单(甲基)丙烯酸酯等两末端具有羧基和羟基的聚合物的单(甲基)丙烯酸酯、(甲基)丙烯酸·马来酸羟基乙酯、(甲基)丙烯酸·马来酸羟基丙酯、二环戊二烯·马来酸酯或具有1个羧基和2个以上的(甲基)丙烯酰基的多官能(甲基)丙烯酸酯等不饱和多元酸;(甲基)丙烯酸-2-羟基乙酯、(甲基)丙烯酸-2-羟基丙酯、(甲基)丙烯酸缩水甘油酯、下述化合物No.A1~No.A4、(甲基)丙烯酸甲酯、(甲基)丙烯酸丁酯、(甲基)丙烯酸异丁酯、(甲基)丙烯酸-叔丁酯、(甲基)丙烯酸环己酯、(甲基)丙烯酸正辛酯、(甲基)丙烯酸异辛酯、(甲基)丙烯酸异壬酯、(甲基)丙烯酸硬脂酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸甲氧基乙酯、(甲基)丙烯酸二甲基氨基甲酯、(甲基)丙烯酸二甲基氨基乙酯、(甲基)丙烯酸氨基丙酯、(甲基)丙烯酸二甲基氨基丙酯、(甲基)丙烯酸乙氧基乙酯、(甲基)丙烯酸聚(乙氧基)乙酯、(甲基)丙烯酸丁氧基乙氧基乙酯、(甲基)丙烯酸乙基己酯、(甲基)丙烯酸苯氧基乙酯、(甲基)丙烯酸四氢呋喃酯、(甲基)丙烯酸乙烯酯、(甲基)丙烯酸烯丙酯、(甲基)丙烯酸苄基酯、乙二醇二(甲基)丙烯酸酯、二乙二醇二(甲基)丙烯酸酯、三乙二醇二(甲基)丙烯酸酯、聚乙二醇二(甲基)丙烯酸酯、丙二醇二(甲基)丙烯酸酯、1,4-丁二醇二(甲基)丙烯酸酯、1,6-己二醇二(甲基)丙烯酸酯、三羟甲基乙烷三(甲基)丙烯酸酯、三羟甲基丙烷三(甲基)丙烯酸酯、二季戊四醇五(甲基)丙烯酸酯、二季戊四醇六(甲基)丙烯酸酯、季戊四醇四(甲基)丙烯酸酯、季戊四醇三(甲基)丙烯酸酯、三环癸烷二羟甲基二(甲基)丙烯酸酯、三[(甲基)丙烯酰基乙基]异氰脲酸酯、聚酯(甲基)丙烯酸酯低聚物等不饱和一元酸及多元醇或多元酚的酯;(甲基)丙烯酸锌、(甲基)丙烯酸镁等不饱和多元酸的金属盐;马来酸酐、衣康酸酐、柠康酸酐、甲基四氢邻苯二甲酸酐、四氢邻苯二甲酸酐、三烷基四氢邻苯二甲酸酐、5-(2,5-二氧代四氢呋喃基)-3-甲基-3-环己烯-1,2-二羧酸酐、三烷基四氢邻苯二甲酸酐-马来酸酐加成物、十二碳烯基琥珀酸酐、甲基腐植酸酐等不饱和多元酸的酸酐;(甲基)丙烯酰胺、亚甲基双-(甲基)丙烯酰胺、二亚乙基三胺三(甲基)丙烯酰胺、亚二甲苯基双(甲基)丙烯酰胺、α-氯丙烯酰胺、N-2-羟基乙基(甲基)丙烯酰胺等不饱和一元酸及多元胺的酰胺;丙烯醛等不饱和醛;(甲基)丙烯腈、α-氯丙烯腈、偏二氰乙烯、烯丙基腈等不饱和腈;苯乙烯、4-甲基苯乙烯、4-乙基苯乙烯、4-甲氧基苯乙烯、4-羟基苯乙烯、4-氯苯乙烯、二乙烯基苯、乙烯基甲苯、乙烯基苯甲酸、乙烯基苯酚、乙烯基磺酸、4-乙烯基苯磺酸、乙烯基苄基甲基醚、乙烯基苄基缩水甘油醚等不饱和芳香族化合物;甲基乙烯基酮等不饱和酮;乙烯基胺、烯丙基胺、N-乙烯基吡咯烷酮、乙烯基哌啶等不饱和胺化合物;烯丙基醇、巴豆醇等乙烯基醇;乙烯基甲基醚、乙烯基乙基醚、正丁基乙烯基醚、异丁基乙烯基醚、烯丙基缩水甘油醚等乙烯基醚;马来酰亚胺、N-苯基马来酰亚胺、N-环己基马来酰亚胺等不饱和酰亚胺类;茚、1-甲基茚等茚类;1,3-丁二烯、异戊二烯、氯丁二烯等脂肪族共轭二烯类;聚苯乙烯、聚(甲基)丙烯酸甲酯、聚(甲基)丙烯酸正丁酯、聚硅氧烷等聚合物分子链的末端具有单(甲基)丙烯酰基的大分子单体类;氯乙烯、偏氯乙烯、琥珀酸二乙烯酯、邻苯二甲酸二烯丙酯、磷酸三烯丙酯、异氰脲酸三烯丙酯、乙烯基硫醚、乙烯基咪唑、乙烯基噁唑啉、乙烯基咔唑、乙烯基吡咯烷酮、乙烯基吡啶、含羟基的乙烯基单体及聚异氰酸酯化合物的乙烯基氨基甲酸酯化合物、含羟基的乙烯基单体及聚环氧化合物的乙烯基环氧化合物、季戊四醇三丙烯酸酯、二季戊四醇五丙烯酸酯等含羟基的多官能丙烯酸酯与甲苯撑二异氰酸酯、六亚甲基二异氰酸酯等多官能异氰酸酯的反应物、季戊四醇三丙烯酸酯、二季戊四醇五丙烯酸酯等含羟基的多官能丙烯酸酯与琥珀酸酐、邻苯二甲酸酐、四氢邻苯二甲酸酐等二元酸酐的反应物即具有酸值的多官能丙烯酸酯;使(甲基)丙烯酸-2-羟基乙酯、(甲基)丙烯酸-2-羟基丙酯、(甲基)丙烯酸缩水甘油酯等具有羟基的丙烯酸酯与二异氰酸酯化合物的反应产物即烯键式不饱和单异氰酸酯与多元醇或多元酚反应而得到的氨基甲酸酯丙烯酸酯;使丙烯酸多元醇与二异氰酸酯化合物反应而得到的氨基甲酸酯丙烯酸酯;苯酚和/或甲酚酚醛清漆环氧树脂、具有联苯骨架、萘骨架的酚醛清漆环氧树脂、双酚A酚醛清漆型环氧化合物、二环戊二烯酚醛清漆型环氧化合物等酚醛清漆型环氧化合物、具有多官能环氧基的聚苯基甲烷型环氧树脂、双酚A型环氧树脂等使环氧基与不饱和一元酸作用并进一步与多元酸酐作用而得到的环氧丙烯酸酯;不饱和多元酸的酐与多元醇或多元酚的酯。
通过将这些聚合性化合物单独或2种以上进行聚合,可以得到聚丙烯酸系树脂。
作为为了得到上述树脂而使用的有机过氧化物,在热、氧化还原体系的存在下容易地产生过氧化自由基的物质较佳,可列举出例如1,1-双(叔丁基过氧化)-3,5,5-三甲基环己烷、2,5-二甲基己烷-2,5-二羟基过氧化物、二叔丁基过氧化物、叔丁基枯基过氧化物、二枯基过氧化物、α,α'-双(叔丁基过氧化)-对二异丙基苯、2,5-二甲基-2,5-二(叔丁基过氧化)己烷、2,5-二甲基-2,5-二(叔丁基过氧化)己炔-3、苯甲酰过氧化物、叔丁基过氧化苯、2,5-二甲基-2,5-二(苯甲酰过氧化)己烷、叔丁基过氧化马来酸、叔丁基过氧化异丙基碳酸酯等,其为采取在由过氧化物产生的自由基作用下通过聚合物主链的脱氢反应在聚合物主链中产生自由基并进行交联这样的交联形态,聚合物主链整体被纳入交联结构中并均匀地交联而成的。
作为为了得到上述树脂而使用的交联剂,可列举出多官能环氧化合物、多官能异氰酸酯、二酸酐、苯乙酮、二苯甲酮、蒽醌、三嗪、氮丙啶、三聚氰胺化合物、金属盐、金属螯合物化合物等;多官能丙烯酸酯、烯烃性不饱和化合物、共聚性二苯甲酮等紫外线交联剂;羟基酮类、苯偶酰双甲醚类、氨基酮类、酰基氧化膦系、二苯甲酮系、含三氯甲基的三嗪衍生物、多官能二苯甲酮、将丙烯酸化二苯甲酮聚合而成的低聚物、1-〔4-(2-羟基乙氧基)苯基〕-2-羟基-2-甲基-1-丙烷-1-酮的伯羟基与2-异氰酸酯甲基丙烯酸乙酯的反应物聚合而成的低聚物、2-羟基-2-甲基-〔4-(1-甲基乙烯基)苯基〕丙醇低聚物等后添加光交联剂等。
作为为了得到上述树脂而使用的光交联引发剂,可列举出2-甲基-1[4-(甲硫基)苯基]-2-吗啉代丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)-丁酮-1等α-氨基酮系、1-羟基-环己基-苯基-酮、2-羟基-2-甲基-1-苯基-丙烷-1-酮等α-羟基酮系、2,2-二甲氧基-1,2-二苯基乙烷-1-酮等苯偶酰双甲醚系。
本发明的涂料中,上述树脂(B)的含量在本发明的涂料的固体成分中优选为30~99质量%,特别优选为60~95质量%。若上述树脂(B)的含量小于30质量%,则有涂布到基板上后的近红外线吸收滤波器与基板的密合性降低的情况,若大于99质量%,则有近红外线吸收滤波器的强度降低的情况。
本发明的涂料中,作为溶剂(C),以二丙酮醇为必须成分,另外还可以与通常根据需要的可溶解或分散上述各成分(本发明的红外线吸收色素(A)等)的溶剂混合使用。作为其他溶剂,可列举出例如甲乙酮、甲基戊基酮、二乙基酮、丙酮、甲基异丙基酮、甲基异丁基酮、环己酮、2-庚酮等酮类;乙基醚、二噁烷、四氢呋喃、1,2-二甲氧基乙烷、1,2-二乙氧基乙烷、二丙二醇二甲基醚等醚系溶剂;醋酸甲酯、醋酸乙酯、醋酸正丙酯、醋酸异丙酯、醋酸正丁酯、醋酸环己酯、乳酸乙酯、琥珀酸二甲酯、Texanol(2,2,4-三甲基-1.3戊二醇单异丁酸酯)等酯系溶剂;乙二醇单甲基醚、乙二醇单乙基醚等溶纤剂系溶剂;甲醇、乙醇、异丙醇或正丙醇、异丁醇或正丁醇、戊醇等醇系溶剂;乙二醇单甲基醋酸酯、乙二醇单乙基醋酸酯、丙二醇-1-单甲基醚-2-醋酸酯(PGMEA)、二丙二醇单甲基醚醋酸酯、3-甲氧基丁基醋酸酯、乙氧基乙基丙酸酯等醚酯系溶剂;苯、甲苯、二甲苯等BTX系溶剂;己烷、庚烷、辛烷、环己烷等脂肪族烃系溶剂;松节油、D-柠檬烯、蒎烯等萜烯系烃油;矿油精、Swasol#310(COSMO松山石油)、Solvesso#100(Exon化学)等石蜡系溶剂;四氯化碳、氯仿、三氯乙烯、二氯甲烷、1,2-二氯乙烷等卤代脂肪族烃系溶剂;氯苯等卤代芳香族烃系溶剂;卡必醇系溶剂、苯胺、三乙胺、吡啶、醋酸、乙腈、二硫化碳、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺、N-甲基吡咯烷酮、二甲基亚砜、水等,这些溶剂可以使用1种或作为2种以上的混合溶剂使用。其中,酮类、醚酯系溶剂等、特别是丙二醇-1-单甲基醚-2-醋酸酯、二甲基乙酰胺、环己酮等由于在本发明的涂料中与红外线吸收色素(A)或树脂(B)的相容性良好,所以优选。
本发明的涂料中,相对于上述溶剂(C)的合计量,二丙酮醇为30~100质量%、特别是为50~95质量%由于溶液稳定性良好,所以优选。
本发明的涂料中,上述溶剂(C)的用量优选使除溶剂(C)以外的组合物的浓度达到5~30质量%,当小于5质量%时,由于难以增大膜厚,无法充分吸收所期望的波长光,所以不优选,当超过30质量%时,由于因组合物的析出所导致的组合物的保存性降低或粘度提高,所以处理性降低,因此不优选。
本发明的涂料中可以进一步含有无机化合物。作为该无机化合物,可列举出例如氧化镍、氧化铁、氧化铱、氧化钛、氧化锌、氧化镁、氧化钙、氧化钾、二氧化硅、氧化铝等金属氧化物;层状粘土矿物、米洛丽蓝、碳酸钙、碳酸镁、钴系、锰系、玻璃粉末、云母、滑石、高岭土、亚铁氰化物、各种金属硫酸盐、硫化物、硒化物、硅酸铝、硅酸钙、氢氧化铝、铂、金、银、铜等,其中,优选氧化钛、二氧化硅、层状粘土矿物、银等。本发明的涂料中,无机化合物的含量相对于上述丙烯酸树脂100质量份优选为0.1~50质量份,更优选为0.5~20质量份,这些无机化合物可以使用1种或2种以上。
这些无机化合物例如作为填充剂、防反射剂、导电剂、稳定剂、阻燃剂、机械强度提高剂、特殊波长吸收剂、防油墨剂等使用。
另外,本发明的涂料中根据需要还可以添加除本发明的红外线吸收色素以外的色素,对茴香醚、氢醌、焦儿茶酚、叔丁基儿茶酚、吩噻嗪等热聚合抑制剂,热聚合引发剂,光聚合引发剂,增塑剂,粘接促进剂,填充剂,消泡剂,流平剂,表面调节剂,抗氧化剂,紫外线吸收剂,分散助剂,抗凝聚剂,催化剂,效果促进剂,交联剂,增稠剂,表面活性剂,硅烷偶联剂,三聚氰胺等惯用的添加物。
本发明的涂料中,除红外线吸收色素(A)、树脂(B)以外的任意成分(其中除外溶剂(C))的含量根据其使用目的来适当选择,没有特别限制,但优选相对于上述树脂(B)100质量份合计为50质量份以下。
接着,对本发明的近红外线吸收滤波器进行说明。
本发明的近红外线吸收滤波器通过将本发明的涂料涂布到基板上而获得。
上述基板没有特别限定,作为其优选的例子,可列举出玻璃板、聚对苯二甲酸乙二醇酯板、聚碳酸酯板、聚酰亚胺板、聚酰胺板、聚甲基丙烯酸甲酯板、聚苯乙烯板、聚氯乙烯板、聚烯烃板、环烯烃聚合物板、聚四氟乙烯板、三乙酰基纤维素板、降冰片烯板、聚乙烯醇板、醋酸纤维素板、聚芳酯板、聚砜板、聚醚砜板、硅片、反射板、方解石板、石英板、玻璃板、纸、木材、金属板等。
该基板也可以实施利用电晕放电处理、火焰处理、等离子体处理、辉光放电处理、粗面化处理、药品处理等以往公知的方法的表面处理、增粘涂剂或底漆等的涂布。
作为涂布到上述基板上的方法,可以采用公知的方法,例如可以采用帘式涂布法、挤出涂布法、辊涂法、旋涂法、浸渍涂布法、棒涂法、喷涂法、滑动涂布法、刮刀涂布法、凹版涂布法、印刷涂布法等。
本发明的近红外线吸收滤波器在800~1100nm的(近)红外线区域中的透射率显示10%以下,优选显示8%以下。
本发明的近红外线吸收滤波器可以用于等离子体显示面板、CRT、荧光显示管、场致发射型显示器等的显示面板,照相机、摄像机等光学设备的受光元件、摄像元件中使用的光电二极管、CCD、C-MOS,光学透镜、汽车用玻璃、建材用玻璃、太阳能电池模块等的热射线屏蔽滤波器,摄像机等光学设备的受光元件、摄像元件,红外线吸收油墨、调色剂用途,红外线吸收材料以红外感光性的感材用安全灯滤波器、红外区域的半导体激光等作为光源的感光材料、光盘用记录材料等,现金卡、ID卡等的防伪造用途,太阳光线中包含的红外线吸收的调光材料,植物培育的控制等的农业用材料,保护眼镜等视觉保护医疗材料等各种用途,对其用途没有特别限制。
实施例
以下,列举出实施例等对本发明更详细地进行说明,但本发明并不限定于这些实施例等。
[实施例1]涂料No.1的制备
加入作为(A)成分的化合物No.1的双(三氟甲磺酰基)亚胺盐0.05g、和作为(C)成分的二丙酮醇2.75g,搅拌、使其溶解。之后,混合作为(B)成分的SPC-2000(昭和电工公司制)5g,搅拌至不溶物消失,得到涂料No.1。
[实施例2~6及比较例1~2]涂料No.2~No.6及比较涂料No.1~No.2的制备
通过与实施例1同样的步骤,以表1中所示的配方将各成分混合,得到涂料No.2~No.6及比较涂料No.1~No.2。
表1
*1:SPC-1000:昭和电工公司制
*2:Z-250:Daicel Cytec公司制
*3:Sumipex LG:住友化学公司制
*4:DAA:二丙酮醇
*5:DMAc:二甲基乙酰胺
[实施例7~12及比较例3~4]近红外线吸收滤波器No.1~No.6及比较近红外线吸收滤波器No.1~No.2的制造
在Toray公司制PET薄膜即Lumirror U98上滴加实施例1~6中得到的涂料No.1~No.6及比较例1~2中得到的比较涂料No.1~No.2的2.5mL,使用#14棒涂器进行涂布。之后,在100℃下干燥15分钟,制造了近红外线吸收滤波器No.1~No.6及比较近红外线吸收滤波器No.1~No.2。
[评价例1~6及比较评价例1~2]近红外线吸收滤波器No.1~No.6及比较近红外线吸收滤波器No.1~No.2的耐光性试验
对实施例1~6中得到的近红外线吸收滤波器No.1~No.6及比较例1~2中得到的比较近红外线吸收滤波器No.1~No.2利用Suga试验机制氙耐光性试验机Table Sun XT-1500L实施耐光性试验25小时,评价1000nm下的吸光度残留率。算出试验后的吸光度相对于试验前的吸光度的比率作为吸光度残留率。将评价结果示于表2中。
表2
近红外线吸收滤波器 | 1000nm下的吸光度残留率 | |
评价例1 | No.1 | 90.7% |
评价例2 | No.2 | 89.2% |
评价例3 | No.3 | 90.8% |
评价例4 | No.4 | 94.0% |
评价例5 | No.5 | 96.5% |
评价例6 | No.6 | 96.1% |
比较评价例1 | 比较No.1 | 85.6% |
比较评价例2 | 比较No.2 | 60.6% |
由上述表2的结果可知,本发明的近红外线吸收滤波器的耐光性高。
Claims (4)
1.一种涂料,其含有红外线吸收色素(A)、树脂(B)及溶剂(C),且作为溶剂(C)成分以二丙酮醇为必须成分。
2.根据权利要求1所述的涂料,其特征在于,所述红外线吸收色素(A)为二亚铵化合物。
3.根据权利要求2所述的涂料,其特征在于,所述二亚铵化合物为下述通式(I)表示的二亚铵化合物,
通式(I)中,R11、R12、R13、R14、R15、R16、R17及R18分别独立地表示氢原子或可以具有取代基的碳原子数为1~10的烷基,R19、R20、R21及R22分别独立地表示氢原子、卤素原子、可以具有取代基的碳原子数为1~10的烷基或可以具有取代基的氨基,所述烷基中的亚甲基可以被-O-或-CH=CH-取代,t表示1~4的数,Anq-表示q价的阴离子,q表示1或2,p表示将电荷保持在中性的系数。
4.一种近红外线吸收滤波器,其是使用权利要求1~3中任一项所述的涂料形成的。
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CN105207576A (zh) * | 2015-10-28 | 2015-12-30 | 蒋安为 | 一种红外线发电器 |
CN108474884A (zh) * | 2016-01-29 | 2018-08-31 | 富士胶片株式会社 | 组合物、膜、近红外线截止滤波器、层叠体、图案形成方法、固体成像元件、图像显示装置、红外线传感器及滤色器 |
CN109923447A (zh) * | 2016-11-14 | 2019-06-21 | 日本板硝子株式会社 | 光吸收性组合物及滤光器 |
CN113337170A (zh) * | 2020-02-18 | 2021-09-03 | 东京应化工业株式会社 | 固化性组合物、固化物、近红外线吸收滤光器及其制造方法 |
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WO2015198782A1 (ja) * | 2014-06-25 | 2015-12-30 | ソニー株式会社 | 赤外光カットフィルタ、固体撮像素子及び撮像装置 |
JP6796443B2 (ja) * | 2016-09-27 | 2020-12-09 | 株式会社日本触媒 | 光選択吸収樹脂積層体 |
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JPH06256754A (ja) * | 1993-03-04 | 1994-09-13 | Canon Inc | 赤外吸収化合物及びそれを用いた光記録媒体 |
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US7524619B2 (en) * | 2002-11-22 | 2009-04-28 | Japan Carlit Co., Ltd. | Coloring matter absorbing near-infrared ray and filter for cutting off near-infrared ray |
US7332257B2 (en) * | 2003-07-11 | 2008-02-19 | Asahi Glass Company, Limited | Composition for optical film, and optical film |
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CN105207576A (zh) * | 2015-10-28 | 2015-12-30 | 蒋安为 | 一种红外线发电器 |
CN108474884A (zh) * | 2016-01-29 | 2018-08-31 | 富士胶片株式会社 | 组合物、膜、近红外线截止滤波器、层叠体、图案形成方法、固体成像元件、图像显示装置、红外线传感器及滤色器 |
US10947389B2 (en) | 2016-01-29 | 2021-03-16 | Fujifilm Corporation | Composition, film, near infrared cut filter, laminate, pattern forming method, solid image pickup element, image display device, infrared sensor, and color filter |
US11518833B2 (en) | 2016-01-29 | 2022-12-06 | Fujifilm Corporation | Composition, film, near infrared cut filter, laminate, pattern forming method, solid image pickup element, image display device, infrared sensor, and color filter |
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CN113337170A (zh) * | 2020-02-18 | 2021-09-03 | 东京应化工业株式会社 | 固化性组合物、固化物、近红外线吸收滤光器及其制造方法 |
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