CN104372681A - Cold-pressed pull-up embossed PU leather - Google Patents

Cold-pressed pull-up embossed PU leather Download PDF

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Publication number
CN104372681A
CN104372681A CN201410629051.0A CN201410629051A CN104372681A CN 104372681 A CN104372681 A CN 104372681A CN 201410629051 A CN201410629051 A CN 201410629051A CN 104372681 A CN104372681 A CN 104372681A
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CN
China
Prior art keywords
layer
leather
water repellent
micro
capsule
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410629051.0A
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Chinese (zh)
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CN104372681B (en
Inventor
田树松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG JINSHANG SYNTHETIC LEATHER Co Ltd
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ZHEJIANG JINSHANG SYNTHETIC LEATHER Co Ltd
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Priority to CN201410629051.0A priority Critical patent/CN104372681B/en
Publication of CN104372681A publication Critical patent/CN104372681A/en
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Publication of CN104372681B publication Critical patent/CN104372681B/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0004Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using ultra-fine two-component fibres, e.g. island/sea, or ultra-fine one component fibres (< 1 denier)
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0034Polyamide fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00Condition, form or state of the materials
    • D06N2205/08Microballoons, microcapsules
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/08Properties of the materials having optical properties
    • D06N2209/0807Coloured
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • D06N2209/128Non-permeable
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/28Artificial leather

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention discloses cold-pressed pull-up embossed PU leather. The cold-pressed pull-up embossed PU leather comprises a base cloth layer, wherein a polyurethane bonding layer is compounded on the base cloth layer, a water repellent layer is arranged on the polyurethane bonding layer, a color-change layer is compounded on the water repellent layer, a polyurethane surface layer is compounded on the color-change layer, a plurality of cavities are formed between the color-change layer and the water repellent layer, micro-capsules which are ruptured automatically under extrusion are formed in the cavity, and the micro-capsules are filled with sympathetic ink. According to the cold-pressed pull-up embossed PU leather, the loss of the sympathetic ink is reduced and the service life of the pull-up PU leather is prolonged.

Description

One cold pressing burnt discoloration PU leather
Technical field
The present invention relates to a kind of PU to remove from office.
Technical background
Variable color PU is also referred to as the general leather in pula, and it is that a kind of crying in the general oil injection in pula leather is made, because the diffusion of the general oil in pula makes leather color when stressed can produce the effect of a gradual change with diffusion recovery, therefore must be called variable color PU.There is certain transparency on the top layer of variable color PU, and after receiving force-extension effect, the general oil in the pula wherein injected is stressed transfers, use stressed leather to show and lose oiliness, color shoals gradually, and neighbouring varying in size because of active force, the degree losing oiliness is different, forms a kind of aberration.But variable color PU removes from office after being repeatedly subject to force-extension, and color shifting ink wherein easily runs off, thus affects effect and the service life of variable color PU.
Summary of the invention
Technical problem to be solved by this invention is just to provide one and colds pressing burnt discoloration PU leather, can alleviate the loss of color shifting ink, improve the service life of variable color PU leather.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
One cold pressing burnt discoloration PU leather, comprise base cloth layer, on described base cloth layer, compound is provided with polyurethane adhesive layer, on described polyurethane adhesive layer, conjunction is provided with water repellent layer, on described water repellent layer, compound is provided with photochromic layer, and on described photochromic layer, compound is provided with polyurethane cover, is provided with several cavitys between described photochromic layer and water repellent layer, be provided with the micro-capsule of the automatic ulceration that is squeezed in described cavity, in described micro-capsule, be filled with color shifting ink.
Preferably, described micro-capsule comprises the body with spherical inner chamber, and described color shifting ink is filled in intrinsic spherical inner chamber, and the outer surface of described body is provided with has flexible shell fragment, the two ends of described shell fragment are respectively equipped with tartar, and the thorn point of described tartar is arranged towards body surface.
Preferably, described cavity is arranged at the lower surface of photochromic layer or the upper surface of water repellent layer.
Preferably, described cavity is the hemispherical cavity formed between photochromic layer and water repellent layer.
Preferably, described base cloth layer is that the fabric of island-in-sea type nylon ultrafine fiber at 5 ~ 7 dawn is made through polyurethane slurry impregnation by fiber number.
Beneficial effect of the present invention is:
When variable color PU removes from office by force-extension, cavity between water repellent layer and photochromic layer can be squeezed, thus the micro-capsule in cavity is squeezed and ulceration, color shifting ink in micro-capsule flows out colour changes on impregnation layer automatically, thus supplement color shifting ink for photochromic layer is lasting, variable color PU leather can not lose color changeable effect fast because of the loss of color shifting ink, thus extends the service life of variable color PU leather.
Accompanying drawing explanation
Below in conjunction with the drawings and specific embodiments, the present invention is described further:
Fig. 1 is structural representation of the present invention;
Fig. 2 is the structural representation of micro-capsule in the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is elaborated.
As shown in Figure 1, the present invention includes base cloth layer 1, on described base cloth layer, compound is provided with polyurethane adhesive layer 2, on described polyurethane adhesive layer, conjunction is provided with water repellent layer 3, on described water repellent layer, compound is provided with photochromic layer 4, and on described photochromic layer, compound is provided with polyurethane cover 5, is provided with several cavitys 401 between described photochromic layer and water repellent layer, be provided with the micro-capsule 402 of the automatic ulceration that is squeezed in described cavity, in described micro-capsule, be filled with color shifting ink 4022.Described cavity 401 is arranged at the lower surface of photochromic layer 4 or the upper surface of water repellent layer.Described cavity 401 is the hemispherical cavity formed between photochromic layer and water repellent layer.Described base cloth layer 1 is that the fabric of island-in-sea type nylon ultrafine fiber at 5 ~ 7 dawn is made through polyurethane slurry impregnation by fiber number.
As shown in Figure 2, described micro-capsule 402 comprises the body 4021 with spherical inner chamber, described color shifting ink 4022 is filled in intrinsic spherical inner chamber, the outer surface of described body is provided with has flexible shell fragment 4023, the two ends of described shell fragment are respectively equipped with tartar 4024, and the thorn point of described tartar is arranged towards body surface.
Principle of the present invention is:
When variable color PU removes from office by force-extension, cavity between water repellent layer and photochromic layer can be squeezed, the inwall moving contact shell fragment of cavity, the body surface making tartar stab micro-capsule is moved at shell fragment two ends, micro-capsule is thrust and ulceration by tartar, color shifting ink in micro-capsule body flows out colour changes on impregnation layer automatically, thus supplement color shifting ink for photochromic layer is lasting, and the inner chamber of micro-capsule body is spherical, when color shifting ink liquid level to micro-capsule body surface is subject to below the ulceration mouth of tartar's puncture, color shifting ink will no longer flow out, when variable color PU removes from office and stretches by next time, micro-capsule is squeezed impact, color shifting ink will spill on a small quantity, thus long-term colour changes on impregnation layer, variable color PU leather can not lose color changeable effect fast because of the loss of color shifting ink, thus extend the service life of variable color PU leather.
Just preferred embodiment of the present invention is described above, but can not be interpreted as it is restriction to claim.The present invention is not only confined to above embodiment, and its concrete structure allows to change, and those skilled in the art can make various change and distortion according to the present invention, only otherwise depart from spirit of the present invention, all belongs to the scope that claims of the present invention define.

Claims (5)

1. a burnt discoloration PU leather of colding pressing, comprise base cloth layer (1), on described base cloth layer, compound is provided with polyurethane adhesive layer (2), it is characterized in that: on described polyurethane adhesive layer, conjunction is provided with water repellent layer (3), on described water repellent layer, compound is provided with photochromic layer (4), on described photochromic layer, compound is provided with polyurethane cover (5), several cavitys (401) are provided with between described photochromic layer and water repellent layer, be provided with the micro-capsule (402) of the automatic ulceration that is squeezed in described cavity, in described micro-capsule, be filled with color shifting ink (4022).
2. one according to claim 1 cold pressing burnt discoloration PU leather, it is characterized in that: described micro-capsule (402) comprises the body (4021) with spherical inner chamber, described color shifting ink (4022) is filled in intrinsic spherical inner chamber, the outer surface of described body is provided with has flexible shell fragment (4023), the two ends of described shell fragment are respectively equipped with tartar (4024), and the thorn point of described tartar is arranged towards body surface.
3. one according to claim 2 cold pressing burnt discoloration PU leather, it is characterized in that: described cavity (401) is arranged at the lower surface of photochromic layer (4) or the upper surface of water repellent layer.
4. one according to claim 3 cold pressing burnt discoloration PU leather, it is characterized in that: described cavity (401) hemispherical cavity for forming between photochromic layer and water repellent layer.
5. one according to claim 1 is colded pressing burnt discoloration PU leather, it is characterized in that: described base cloth layer (1) is that the fabric of island-in-sea type nylon ultrafine fiber at 5 ~ 7 dawn is made through polyurethane slurry impregnation by fiber number.
CN201410629051.0A 2014-11-10 2014-11-10 Cold pressing branding variable color PU leather of one Active CN104372681B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410629051.0A CN104372681B (en) 2014-11-10 2014-11-10 Cold pressing branding variable color PU leather of one

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410629051.0A CN104372681B (en) 2014-11-10 2014-11-10 Cold pressing branding variable color PU leather of one

Publications (2)

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CN104372681A true CN104372681A (en) 2015-02-25
CN104372681B CN104372681B (en) 2016-05-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107672085A (en) * 2016-08-01 2018-02-09 波音公司 Force-responsive pre-preg complex method, system and device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807409A (en) * 1996-10-30 1998-09-15 Rohm And Haas Company Method of improving pull-up characteristic of leather substrate and modified finishing oil used therein
TW589427B (en) * 2003-01-29 2004-06-01 San Fang Chemical Industry Co Pull-up ultra-fine fiber artificial leather and method for producing the same
CN101736599A (en) * 2008-11-25 2010-06-16 苏州宝泽高分子材料有限公司 Embossed two-colour leather
CN102166108A (en) * 2011-05-15 2011-08-31 赵德政 Press-contact type wetted sandwich tissue
CN102650103A (en) * 2012-05-23 2012-08-29 安徽安利合成革股份有限公司 Preparation method for polyurethane synthetic leather with water repellent performance
CN204185710U (en) * 2014-11-10 2015-03-04 浙江锦尚合成革有限公司 One cold pressing burnt discoloration PU leather

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5807409A (en) * 1996-10-30 1998-09-15 Rohm And Haas Company Method of improving pull-up characteristic of leather substrate and modified finishing oil used therein
TW589427B (en) * 2003-01-29 2004-06-01 San Fang Chemical Industry Co Pull-up ultra-fine fiber artificial leather and method for producing the same
CN101736599A (en) * 2008-11-25 2010-06-16 苏州宝泽高分子材料有限公司 Embossed two-colour leather
CN102166108A (en) * 2011-05-15 2011-08-31 赵德政 Press-contact type wetted sandwich tissue
CN102650103A (en) * 2012-05-23 2012-08-29 安徽安利合成革股份有限公司 Preparation method for polyurethane synthetic leather with water repellent performance
CN204185710U (en) * 2014-11-10 2015-03-04 浙江锦尚合成革有限公司 One cold pressing burnt discoloration PU leather

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107672085A (en) * 2016-08-01 2018-02-09 波音公司 Force-responsive pre-preg complex method, system and device
CN107672085B (en) * 2016-08-01 2021-06-15 波音公司 Force responsive prepreg composite method, system and apparatus

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SE01 Entry into force of request for substantive examination
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PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Cold-pressed pull-up embossed PU leather

Effective date of registration: 20160608

Granted publication date: 20160525

Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd

Pledgor: Zhejiang Jinshang Synthetic Leather Co., Ltd.

Registration number: 2016990000486

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PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20180530

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Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd

Pledgor: Zhejiang Jinshang Synthetic Leather Co., Ltd.

Registration number: 2016990000486

PC01 Cancellation of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Cold-pressed pull-up embossed PU leather

Effective date of registration: 20180530

Granted publication date: 20160525

Pledgee: Changxin Zhejiang rural commercial bank Limited by Share Ltd

Pledgor: Zhejiang Jinshang Synthetic Leather Co., Ltd.

Registration number: 2018990000421

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Registration number: 2018990000421

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Denomination of invention: A cold embossed discolored PU leather

Effective date of registration: 20220414

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