CN104371850A - Non-phosphorus environmental-friendly washing powder and preparation method thereof - Google Patents

Non-phosphorus environmental-friendly washing powder and preparation method thereof Download PDF

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Publication number
CN104371850A
CN104371850A CN201410663559.2A CN201410663559A CN104371850A CN 104371850 A CN104371850 A CN 104371850A CN 201410663559 A CN201410663559 A CN 201410663559A CN 104371850 A CN104371850 A CN 104371850A
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China
Prior art keywords
parts
sodium
washing powder
friendly washing
environmentally friendly
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CN201410663559.2A
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Chinese (zh)
Inventor
凌云
夏戊君
陆赛君
金可心
陈亮
程胜
凌天阳
陆鼎
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SUZHOU YOUJUN ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
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SUZHOU YOUJUN ENVIRONMENTAL SCIENCE AND TECHNOLOGY Co Ltd
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Priority to CN201410663559.2A priority Critical patent/CN104371850A/en
Publication of CN104371850A publication Critical patent/CN104371850A/en
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Abstract

The invention provides non-phosphorus environmental-friendly washing powder and a preparation method thereof. The non-phosphorus environmental-friendly washing powder comprises the following raw materials in parts by weight: 2-8 parts of tallow fatty alcohol polyoxyethylene ether, 15-28 parts of edetic acid, 0.8-2.2 parts of sodium dodecyl benzene sulfonate, 13-23 parts of sodium succinate, 5-14 parts of sodium silicate, 20-30 parts of zeolite, 1-3 parts of sodium perborate, 0.6-2 parts of dimethyl phthalate, 3-8 parts of sodium sulfafe decahydrate, 2-7 parts of sodium citrate, 1-5 parts of sodium sulfosuccinate diester and 4-11 parts of naphtha. The non-phosphorus environmental-friendly washing powder provided by the invention does not contain any environmentally harmful substance, is high in density and cleaning speed and good in effect.

Description

A kind of Phosphateless environmentally friendly washing powder and preparation method thereof
Technical field
The present invention relates to articles for washing field, particularly relate to a kind of Phosphateless environmentally friendly washing powder and preparation method thereof.
Background technology
Washing powder is the one of synthetic detergent, and be absolutely necessary household supplies.Washing powder in the market mainly contains following three kinds of classification, differs from one another.1. regular powder and concentrated detergent powder: regular powder, particle is large and loosen, and dissolve fast, foam comparatively horn of plenty, but detersive power is relatively weak, not easily rinsing, is generally suitable for hand washing; Concentrated detergent powder particle is little, and density is large, and foam is less, but strong detergency (being at least the twice of regular powder), be easy to cleaning, water saving, be generally suitable for machine washing.2. Powdered Detergent Containing Phosphate and non-phosphide detergent: Powdered Detergent Containing Phosphate is main auxiliary agent with phosphoric acid salt, and phosphoric easily causes environment water eutrophication, thus destroy water quality, contaminate environment.Non-phosphide detergent, then without this shortcoming, is conducive to water body environment protection.3. enzymatic laundry powder and aromatized washing powder: enzymatic laundry powder is exactly be added with enzyme in washing powder, aromatized washing powder is exactly be added with essence in washing powder.Enzymatic laundry powder has specific function to dispelling of specific dirt (as fruit juice, ink, bloodstain, milk stain, gravy, cow's milk, soy sauce etc.), and simultaneously some certain enzyme wherein can also play sterilization, brighten, protect look and increase the effects such as gorgeous.Aromatized washing powder allows clothing expire fragrance while meeting washing effect, makes people feel more comfortable.
Although there is non-phosphide detergent in the market, the composition still containing contaminate environment in its formula, and detersive power is limited, and density is low, and packed and transported cost is high.
Summary of the invention
the technical problem solved:for the shortcoming that existing non-phosphide detergent exists, the invention provides a kind of Phosphateless environmentally friendly washing powder and preparation method thereof, this washing powder is not containing any environmentally harmful material, and density is high, and the decontamination time is fast, effective.
technical scheme:a kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 2 ~ 8 parts, ethylenediamine tetraacetic acid (EDTA) 15 ~ 28 parts, Sodium dodecylbenzene sulfonate 0.8 ~ 2.2 part, Soduxin 13 ~ 23 parts, water glass 5 ~ 14 parts, 20 ~ 30 parts, zeolite, Sodium peroxoborate 1 ~ 3 part, dimethyl phthalate 0.6 ~ 2 part, sal glauberi 3 ~ 8 parts, Trisodium Citrate 2 ~ 7 parts, succinic diester sodium sulfonate 1 ~ 5 part, petroleum naphtha 4 ~ 11 parts.
A kind of Phosphateless environmentally friendly washing powder described above, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 3 ~ 7 parts, ethylenediamine tetraacetic acid (EDTA) 18 ~ 25 parts, Sodium dodecylbenzene sulfonate 1 ~ 2 part, Soduxin 16 ~ 21 parts, water glass 7 ~ 12 parts, 22 ~ 28 parts, zeolite, Sodium peroxoborate 1.5 ~ 2.5 parts, dimethyl phthalate 1 ~ 1.8 part, sal glauberi 4 ~ 7 parts, Trisodium Citrate 3 ~ 6 parts, succinic diester sodium sulfonate 2 ~ 4 parts, petroleum naphtha 5 ~ 10 parts.
A kind of Phosphateless environmentally friendly washing powder described above, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 4 parts, ethylenediamine tetraacetic acid (EDTA) 20 parts, Sodium dodecylbenzene sulfonate 1.2 parts, Soduxin 17 parts, water glass 8 parts, 24 parts, zeolite, Sodium peroxoborate 1.8 parts, dimethyl phthalate 1.3 parts, sal glauberi 5 parts, Trisodium Citrate 4 parts, succinic diester sodium sulfonate 2.5 parts, petroleum naphtha 6 parts.
A kind of Phosphateless environmentally friendly washing powder described above, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 5 parts, ethylenediamine tetraacetic acid (EDTA) 21 parts, Sodium dodecylbenzene sulfonate 1.5 parts, Soduxin 18 parts, water glass 10 parts, 25 parts, zeolite, Sodium peroxoborate 2 parts, dimethyl phthalate 1.4 parts, sal glauberi 5.5 parts, Trisodium Citrate 4.5 parts, succinic diester sodium sulfonate 3 parts, petroleum naphtha 7.5 parts.
The preparation method of a kind of Phosphateless environmentally friendly washing powder described above; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 30 ~ 60s in super mixer; then granulation in tablets press, gets product after dry cooling.
Described above mixes 45s by mixture in super mixer.
beneficial effect:compared with prior art, a kind of Phosphateless environmentally friendly washing powder provided by the invention and preparation method thereof, this washing powder is not containing any environmentally harmful material, and density is high, packaging and transportation cost low, do not damage clothing and HUMAN HEALTH, the decontamination time is soon, effective.
Embodiment
embodiment 1
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 2 parts, ethylenediamine tetraacetic acid (EDTA) 15 parts, Sodium dodecylbenzene sulfonate 0.8 part, Soduxin 13 parts, water glass 5 parts, 20 parts, zeolite, Sodium peroxoborate 1 part, dimethyl phthalate 0.6 part, sal glauberi 3 parts, Trisodium Citrate 2 parts, succinic diester sodium sulfonate 1 part, petroleum naphtha 4 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 30s in super mixer; then granulation in tablets press, gets product after dry cooling.
embodiment 2
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 8 parts, ethylenediamine tetraacetic acid (EDTA) 28 parts, Sodium dodecylbenzene sulfonate 2.2 parts, Soduxin 23 parts, water glass 14 parts, 30 parts, zeolite, Sodium peroxoborate 3 parts, dimethyl phthalate 2 parts, sal glauberi 8 parts, Trisodium Citrate 7 parts, succinic diester sodium sulfonate 5 parts, petroleum naphtha 11 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 60s in super mixer; then granulation in tablets press, gets product after dry cooling.
embodiment 3
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 3 parts, ethylenediamine tetraacetic acid (EDTA) 18 parts, Sodium dodecylbenzene sulfonate 1 part, Soduxin 16 parts, water glass 7 parts, 22 parts, zeolite, Sodium peroxoborate 1.5 parts, dimethyl phthalate 1 part, sal glauberi 4 parts, Trisodium Citrate 3 parts, succinic diester sodium sulfonate 2 parts, petroleum naphtha 5 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 30s in super mixer; then granulation in tablets press, gets product after dry cooling.
embodiment 4
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 7 parts, ethylenediamine tetraacetic acid (EDTA) 25 parts, Sodium dodecylbenzene sulfonate 2 parts, Soduxin 21 parts, water glass 12 parts, 28 parts, zeolite, Sodium peroxoborate 2.5 parts, dimethyl phthalate 1.8 parts, sal glauberi 7 parts, Trisodium Citrate 6 parts, succinic diester sodium sulfonate 4 parts, petroleum naphtha 10 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 60s in super mixer; then granulation in tablets press, gets product after dry cooling.
embodiment 5
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 4 parts, ethylenediamine tetraacetic acid (EDTA) 20 parts, Sodium dodecylbenzene sulfonate 1.2 parts, Soduxin 17 parts, water glass 8 parts, 24 parts, zeolite, Sodium peroxoborate 1.8 parts, dimethyl phthalate 1.3 parts, sal glauberi 5 parts, Trisodium Citrate 4 parts, succinic diester sodium sulfonate 2.5 parts, petroleum naphtha 6 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 45s in super mixer; then granulation in tablets press, gets product after dry cooling.
embodiment 6
A kind of Phosphateless environmentally friendly washing powder, comprises the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 5 parts, ethylenediamine tetraacetic acid (EDTA) 21 parts, Sodium dodecylbenzene sulfonate 1.5 parts, Soduxin 18 parts, water glass 10 parts, 25 parts, zeolite, Sodium peroxoborate 2 parts, dimethyl phthalate 1.4 parts, sal glauberi 5.5 parts, Trisodium Citrate 4.5 parts, succinic diester sodium sulfonate 3 parts, petroleum naphtha 7.5 parts.
A kind of preparation method of Phosphateless environmentally friendly washing powder; comprise the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 45s in super mixer; then granulation in tablets press, gets product after dry cooling.
performance test
Test the performance of the embodiment of the present invention 1 ~ 6 product, test result is in table 1.
Table 1 product performance test data
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6
Density (kg/ dm 3 0.835 0.846 0.853 0.864 0.875 0.881
To dirt clearance (%) 98.2 98.5 98.7 98.5 99.3 99.7
Above to invention has been detailed introduction, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.

Claims (6)

1. a Phosphateless environmentally friendly washing powder, is characterized in that comprising the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 2 ~ 8 parts, ethylenediamine tetraacetic acid (EDTA) 15 ~ 28 parts, Sodium dodecylbenzene sulfonate 0.8 ~ 2.2 part, Soduxin 13 ~ 23 parts, water glass 5 ~ 14 parts, 20 ~ 30 parts, zeolite, Sodium peroxoborate 1 ~ 3 part, dimethyl phthalate 0.6 ~ 2 part, sal glauberi 3 ~ 8 parts, Trisodium Citrate 2 ~ 7 parts, succinic diester sodium sulfonate 1 ~ 5 part, petroleum naphtha 4 ~ 11 parts.
2. a kind of Phosphateless environmentally friendly washing powder according to claim 1, it is characterized in that comprising the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 3 ~ 7 parts, ethylenediamine tetraacetic acid (EDTA) 18 ~ 25 parts, Sodium dodecylbenzene sulfonate 1 ~ 2 part, Soduxin 16 ~ 21 parts, water glass 7 ~ 12 parts, 22 ~ 28 parts, zeolite, Sodium peroxoborate 1.5 ~ 2.5 parts, dimethyl phthalate 1 ~ 1.8 part, sal glauberi 4 ~ 7 parts, Trisodium Citrate 3 ~ 6 parts, succinic diester sodium sulfonate 2 ~ 4 parts, petroleum naphtha 5 ~ 10 parts.
3. a kind of Phosphateless environmentally friendly washing powder according to claim 1, is characterized in that comprising the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 4 parts, ethylenediamine tetraacetic acid (EDTA) 20 parts, Sodium dodecylbenzene sulfonate 1.2 parts, Soduxin 17 parts, water glass 8 parts, 24 parts, zeolite, Sodium peroxoborate 1.8 parts, dimethyl phthalate 1.3 parts, sal glauberi 5 parts, Trisodium Citrate 4 parts, succinic diester sodium sulfonate 2.5 parts, petroleum naphtha 6 parts.
4. a kind of Phosphateless environmentally friendly washing powder according to claim 1, is characterized in that comprising the following raw material according to mass fraction meter: tallow fatty alcohol Soxylat A 25-7 5 parts, ethylenediamine tetraacetic acid (EDTA) 21 parts, Sodium dodecylbenzene sulfonate 1.5 parts, Soduxin 18 parts, water glass 10 parts, 25 parts, zeolite, Sodium peroxoborate 2 parts, dimethyl phthalate 1.4 parts, sal glauberi 5.5 parts, Trisodium Citrate 4.5 parts, succinic diester sodium sulfonate 3 parts, petroleum naphtha 7.5 parts.
5. the preparation method of a kind of Phosphateless environmentally friendly washing powder as claimed in claim 1; it is characterized in that comprising the steps: first tallow fatty alcohol Soxylat A 25-7, ethylenediamine tetraacetic acid (EDTA), Sodium dodecylbenzene sulfonate and Soduxin to be mixed; then mix with water glass, zeolite, Sodium peroxoborate, dimethyl phthalate, sal glauberi, Trisodium Citrate, succinic diester sodium sulfonate, petroleum naphtha; obtain mixture; mixture is mixed 30 ~ 60s in super mixer; then granulation in tablets press, gets product after dry cooling.
6. the preparation method of a kind of Phosphateless environmentally friendly washing powder according to claim 5, is characterized in that described mixture being mixed 45s in super mixer.
CN201410663559.2A 2014-11-19 2014-11-19 Non-phosphorus environmental-friendly washing powder and preparation method thereof Pending CN104371850A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877840A (en) * 2015-06-15 2015-09-02 马建剑 Novel high-density washing powder for yarns and preparation method of washing powder
CN106867688A (en) * 2017-03-13 2017-06-20 中山市绿浪助剂有限公司 A kind of phosphate-free synthesized detergent Builder

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064885A (en) * 1992-03-18 1992-09-30 李潜德 Scouring powder and xeraphium remove the formula spraying dry-cleaning cream
US20040147189A1 (en) * 1999-08-02 2004-07-29 The Procter & Gamble Company Personal care articles comprising batting
US6773625B2 (en) * 2002-08-26 2004-08-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dry bleach compositions
CN102453618A (en) * 2010-10-25 2012-05-16 陈文冬 Pre-cleaning agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1064885A (en) * 1992-03-18 1992-09-30 李潜德 Scouring powder and xeraphium remove the formula spraying dry-cleaning cream
US20040147189A1 (en) * 1999-08-02 2004-07-29 The Procter & Gamble Company Personal care articles comprising batting
US6773625B2 (en) * 2002-08-26 2004-08-10 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Dry bleach compositions
CN102453618A (en) * 2010-10-25 2012-05-16 陈文冬 Pre-cleaning agent

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* Cited by examiner, † Cited by third party
Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877840A (en) * 2015-06-15 2015-09-02 马建剑 Novel high-density washing powder for yarns and preparation method of washing powder
CN106867688A (en) * 2017-03-13 2017-06-20 中山市绿浪助剂有限公司 A kind of phosphate-free synthesized detergent Builder

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