CN104370860A - 二环氧植物油酸乙酰甘油酯及其合成方法与应用 - Google Patents
二环氧植物油酸乙酰甘油酯及其合成方法与应用 Download PDFInfo
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- CN104370860A CN104370860A CN201410568201.1A CN201410568201A CN104370860A CN 104370860 A CN104370860 A CN 104370860A CN 201410568201 A CN201410568201 A CN 201410568201A CN 104370860 A CN104370860 A CN 104370860A
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- acid
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- vegetable oil
- glyceride
- aceto
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/48—Compounds containing oxirane rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms, e.g. ester or nitrile radicals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
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- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
3%醋酸水溶液 | 15%乙醇水溶液 | 葵花籽油 | |
对比例1(增塑剂DOTP) | 2.83 | 1.31 | 466 |
对比例2(增塑剂DINP) | / | / | 420 |
实施例1 | 0.0058 | 0.0055 | 368 |
Claims (10)
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CN201410568201.1A CN104370860B (zh) | 2014-10-22 | 2014-10-22 | 二环氧植物油酸乙酰甘油酯及其合成方法与应用 |
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CN201410568201.1A CN104370860B (zh) | 2014-10-22 | 2014-10-22 | 二环氧植物油酸乙酰甘油酯及其合成方法与应用 |
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CN104370860A true CN104370860A (zh) | 2015-02-25 |
CN104370860B CN104370860B (zh) | 2017-01-11 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104817521A (zh) * | 2015-03-03 | 2015-08-05 | 中国林业科学研究院林产化学工业研究所 | 一种环氧二聚脂肪酸甲酯及其制备方法和应用 |
CN105038261A (zh) * | 2015-06-18 | 2015-11-11 | 张家港市大能塑料制品有限公司 | 一种环保型增塑剂 |
CN105085442A (zh) * | 2015-07-23 | 2015-11-25 | 广州市海珥玛植物油脂有限公司 | 二元酸双一乙酰环氧植物油酯及其合成方法 |
CN106146431A (zh) * | 2016-06-30 | 2016-11-23 | 中国林业科学研究院林产化学工业研究所 | 一种环氧低热油脂增塑剂及其制备方法 |
CN106519081A (zh) * | 2016-09-22 | 2017-03-22 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
CN108530681A (zh) * | 2018-01-23 | 2018-09-14 | 四川大学 | 一种提高环氧乙酰蓖麻油酸甲酯增塑剂与pvc树脂相容性的方法 |
Citations (5)
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US3070608A (en) * | 1958-07-07 | 1962-12-25 | Swift & Co | Selective alcoholysis of epoxy fatty acid esters |
CN102285946A (zh) * | 2011-06-28 | 2011-12-21 | 广州市海珥玛植物油脂有限公司 | 二乙酰环氧植物油酸甘油酯及其合成方法 |
CN103483296A (zh) * | 2013-09-23 | 2014-01-01 | 广州市海珥玛植物油脂有限公司 | 二乙酰环氧油酸甘油酯的合成工艺 |
CN103889966A (zh) * | 2011-10-19 | 2014-06-25 | 阿彻丹尼尔斯米德兰德公司 | 从环氧化天然脂肪和油制造环氧化酯 |
CN104059032A (zh) * | 2014-04-29 | 2014-09-24 | 浙江嘉澳环保科技股份有限公司 | 己二酸酯环氧增塑剂的制备方法及产品 |
-
2014
- 2014-10-22 CN CN201410568201.1A patent/CN104370860B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3070608A (en) * | 1958-07-07 | 1962-12-25 | Swift & Co | Selective alcoholysis of epoxy fatty acid esters |
CN102285946A (zh) * | 2011-06-28 | 2011-12-21 | 广州市海珥玛植物油脂有限公司 | 二乙酰环氧植物油酸甘油酯及其合成方法 |
CN103889966A (zh) * | 2011-10-19 | 2014-06-25 | 阿彻丹尼尔斯米德兰德公司 | 从环氧化天然脂肪和油制造环氧化酯 |
CN103483296A (zh) * | 2013-09-23 | 2014-01-01 | 广州市海珥玛植物油脂有限公司 | 二乙酰环氧油酸甘油酯的合成工艺 |
CN104059032A (zh) * | 2014-04-29 | 2014-09-24 | 浙江嘉澳环保科技股份有限公司 | 己二酸酯环氧增塑剂的制备方法及产品 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104817521A (zh) * | 2015-03-03 | 2015-08-05 | 中国林业科学研究院林产化学工业研究所 | 一种环氧二聚脂肪酸甲酯及其制备方法和应用 |
CN105038261A (zh) * | 2015-06-18 | 2015-11-11 | 张家港市大能塑料制品有限公司 | 一种环保型增塑剂 |
CN105085442A (zh) * | 2015-07-23 | 2015-11-25 | 广州市海珥玛植物油脂有限公司 | 二元酸双一乙酰环氧植物油酯及其合成方法 |
CN106146431A (zh) * | 2016-06-30 | 2016-11-23 | 中国林业科学研究院林产化学工业研究所 | 一种环氧低热油脂增塑剂及其制备方法 |
CN106519081A (zh) * | 2016-09-22 | 2017-03-22 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
CN106519081B (zh) * | 2016-09-22 | 2018-06-26 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
CN108530681A (zh) * | 2018-01-23 | 2018-09-14 | 四川大学 | 一种提高环氧乙酰蓖麻油酸甲酯增塑剂与pvc树脂相容性的方法 |
CN108530681B (zh) * | 2018-01-23 | 2020-05-05 | 四川大学 | 一种提高环氧乙酰蓖麻油酸甲酯增塑剂与pvc树脂相容性的方法 |
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Application publication date: 20150225 Assignee: Guangzhou Baiyun District synthetic material plant Assignor: Hairma Chemicals (GZ) Ltd. Contract record no.: 2018440000003 Denomination of invention: Diepoxide vegetable oil acid acetyl glyceride and synthesis method and application thereof Granted publication date: 20170111 License type: Common License Record date: 20180119 |
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