CN104369120B - A kind of diamond implanted based on grinding unit or CBN grinding tool preparation method - Google Patents

A kind of diamond implanted based on grinding unit or CBN grinding tool preparation method Download PDF

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Publication number
CN104369120B
CN104369120B CN201410468484.2A CN201410468484A CN104369120B CN 104369120 B CN104369120 B CN 104369120B CN 201410468484 A CN201410468484 A CN 201410468484A CN 104369120 B CN104369120 B CN 104369120B
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grinding
grinding unit
flexible material
diamond
implanted
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CN104369120A (en
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黄曦
郭阳生
吕伟利
刘政航
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Huzhou You Yan Intellectual Property Service Co.,Ltd.
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Xi'an New Material Technology Development Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/001Manufacture of flexible abrasive materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The invention discloses a kind of diamond implanted based on grinding unit or CBN grinding tool preparation method, abrasive material, filler, bonding agent and various auxiliary agent mix homogeneously, scratch on treated base material with the grinding tool designed, base material can be the fiber paper base of flexibility, fabricbase, it can also be the hybrid substrate of the Metal Substrate of rigidity or cloth and metal, material after blade coating, after placing certain time, enter baking oven, solidifying under certain temperature and time, material after solidification just becomes novel removing material through pruning, shaping, bonding, gluing, lettering, packaging.The feature of this removing material is to have good adhesive strength, high toughness, ablation high temperature resistant, resistance to, life-span length, grinding efficiency height, applicable various metals and nonmetallic grinding.

Description

A kind of diamond implanted based on grinding unit or CBN grinding tool preparation method
Technical field
The invention belongs to removing material technical field, relate to a kind of based on grinding unit implant diamond or CBN grinding tool preparation method.
Background technology
The removing material industry of China is grown out of nothing, and changes from small to big, and develops through over half a century, especially After being reform and opening-up, in eighties of last century the nineties, China's removing material industry is with world-class Gap was once substantially reduced.But, due to world's material science and technology, mechanical processing technique and modern times The fast development of science and technology, external removing material industry development is rapid, new technique, new product, new work Skill continues to bring out.And the removing material industry of China in this in period be in the system of industrial management change, enterprise In the stage that industry changes direction, industrial organization structure adjusts, original industrial pattern is disturbed, new market Order is being explored foundation, industry development and technological progress and is being stayed cool for the moment so that already The gap reduced is widened rapidly again.
In recent ten years, removing material manufacturing enterprise of China achieves significant progress, has gradually formed product Product A wide selection of colours and designs, there is the removing material production system of certain comprehensive strength.And then define with transnational public affairs Department and co-partnership company and several domestic corporation are main high-end removing material manufacturing enterprise, with state-owned or Large and medium-sized enterprise that state-run assets are holding and the big private developed rapidly in recent years and characteristic private enterprise are Main middle and high end removing material manufacturing enterprise;And the low and middle-end removing material based on minor private enterprises Three levels of manufacturing enterprise.Whole nation year removing material production capacity has had sizable scale at present, permissible Say it is the big producing country of removing material.But not being the power of removing material, removing material top with the world is looked forward to Industry is compared, the most certain gap.It is mainly manifested in (1) overall craft and equipment also has certain gap. Removing material manufacturing enterprise of China has had very through development in recent years, the equipment of some leading enterprises Big improving, some processes and equipment have reached first-class level of modernization in line with international standards, but totally Technique and equipment also certain gap compared with international removing material advanced enterprises, particularly produces new Product research and development, automatization and equipment application aspect.(2) there are mainly some skills of international competitiveness in the past The product that art content is low, added value is less, and there is the high-tech product shortcoming of independent core technology.But In recent years, though situation has change, but in the exploitation application progress of new type abrasive, function removing material Slowly.(3) low in economic efficiency.The Industrial added value of removing material manufacturing enterprise of advanced country is substantially Between 50% to 150%, minimum also more than 30%, removing material manufacturing enterprise of China but only has 5~20%, have a long way to go.(4) not enough, at Product Process, the height of removing material due to theory innovation End properties of product and research and development of new product aspect, also have sizable gap (5) enterprise pair with Foreign Advanced Lerel The quick-reaction capability in market is poor.China's removing material new product average construction cycle is 18 months, produces The life cycle of product is 10~15 years.And abroad realize " three three ", i.e. the life cycle of product Being 3 years, the trial-production cycle of product is 3 months, and the design cycle of product was 3 week.(6) enterprise The structure of size is unreasonable.From the point of view of industrial organization structure, China's removing material manufacturing enterprise scale pole does not conforms to Reason, large enterprise is strong greatly and not, and small business is little and special, and enterprise has been absorbed in deadlocked in the market competition State.The particularly strength of large enterprise still can not realize appropriate scale of operation and collectivized operation, it is difficult to Multinational corporations contends with.In general, though China's removing material industry achieves significant progress.But Owing to product independent research and development capacity is weak, entry threshold is relatively low, and the nearly more than ten years are imitating always, plagiarize On the basis of develop and expansion, inefficient consumes a large amount of valuable resource and the energy, first intakes with the world Flat compare the biggest gap, be mainly manifested in: high-tech product can not meet the market demand, rely on into Mouthful;There is structural surplus in the low-grade universal product, cause overstocked, be in arrears with payment for goods and price war.The whole industry Production capacity has reached certain scale, but actual production capacity is relatively decentralized, and scope of the enterprise is little, economic effect Benefit is poor.Technology development capability is weak, and product and the technology of own intellectual property are few, do not grasp product development Initiative.Product variety is few, with low content of technology.Removing material industry domestic famous brand gold content is low, more Rare international famous brand.
This technique of grinding the most at home and abroad develops very rapidly and is widely available application, along with the modern times Developing rapidly of industry and being gradually improved of coated abrasive tool manufacturing technology, it is as a kind of unconventional grinding Technology, with the processing characteristic of its uniqueness, impact car, milling, dig, traditional manufacturing technology such as mill.It was both Can grinding metal (including difficult-to-machine metal), again can grinding be nonmetal (includes glass, leather, timber, treasured Stone).From space flight and aviation industry, car industry to building materials industry, the table of floor furniture in life from light industry to people Facing sand light, grinding technique is obtained for extensively application in all trades and professions.Americanized Engineering society (S, M, Z) Think: grinding is that one is widely used, in high precision, high efficiency, the process technology of low cost, its working (machining) efficiency Exceed car, milling, plane processing.
External Grinding Technology development is very fast, has currently reached at a relatively high level.Particularly Europe, The industrially developed country such as beautiful and Japanese, is engaged in grinding technique research, the research institution of exploitation and manufacturing firm (or group) quantity is a lot of and fully reinforced, and its achievement and product represent world today's grinding technique Top level.
Domestic Grinding Technology is just to start to be able to true development in late 1970s, along with Domestic reform and opening-up, Sand Band Grinding Technique causes every profession and trade, each research unit and each enterprise day by day Pay attention to, in addition the development of the manufacturing technology of removing material and the increase of kind so that the research of equipment for grinding Bigger development is have also been obtained with producing.Grinding just towards strength, at a high speed, efficient and high-precision direction develops. Due to distinctive processing characteristics and the high material removing rate of grinding, grinding has been also introduced into domestic Many new applications, solve many processing difficult problems.Grinding not only can realize traditional material Processing and also can realize the big surplus precision rubbing down to the difficult-to-machine material such as rustless steel, titanium alloy processing, Efficiency is high, good processing accuracy, and surface roughness is low, and abrasion is few, and service life is long, and processing cost is low.
Although domestic Grinding Technology is being caught up with rapidly, but with abroad compare from quantity the most also It is that quality has bigger gap.In terms of high-speed grinding, the U.S. has succeeded in developing the high speed of 100m/s Abrasive belt grinding machine.High efficient grinding aspect, Westinghouse Electrical Corp. centreless abrasive belt grinding machine 60 horsepowers of rotors of processing, Per hour up to thousand;Concentricity requirement 0.005mm of Wu Lusen lathe company, error exist The rotor of 0.012mm can reach 200 per hour, the every cm width of abrasive belt surface grinder of 3m company 650cm can be excised3/min。
Owing to the power utilization of grinding is high, material removing rate is high, and this external abrasive machine also has processing model Enclosing wide, integrated cost is low, simple in construction, and small investment is simple to operate, produces non-cutting time few, work The advantage such as safe and reliable, grinding application rapidly be development at home.Therefore, new abrasive material, new base are developed Material, new binding agent and coating material improve the configuration of abrasive particle, improve the performance of removing material And quality, improve the key issue that service life is removing material application.
Summary of the invention
Present invention solves the problem in that offer one at high temperature has preferable adhesive strength, have simultaneously There are high tenacity, high temperature resistant, ablation resistance, use time length, high the planting based on grinding unit of grinding efficiency The diamond entered or CBN grinding tool preparation method.
For reaching above-mentioned purpose, the diamond implanted based on grinding unit of the present invention or CBN mill Tool preparation method comprises the following steps:
1) filler A, 40-60 part bonding of the abrasive material of 30-80 part, 60-80 part is weighed by mass fraction Agent A and the additive of 0.5-5 part, then abrasive material and filler A are placed into mix homogeneously in mixing container, It is subsequently adding adhesive A, adds additive and adjust denseness, after mix homogeneously, obtain compound;
2) flexible material is carried out impregnation and preservative treatment, then the mould of removing material is routed to flexible material On material, then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, Make compound according to shape molding on flexible material of grinding unit die cavity, the mould of described removing material Including the grinding unit die cavity of the some hollow structures being arranged in array, disengage the mould of removing material the most again Tool, makes compound be implanted on flexible material according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound flexible material stand 10-30 minute, the most again Solidification;
4) by step 3) flexible material being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Described additive is polyacrylamide;
Described abrasive material is diamond or CBN.
Step 3) in the concrete operations that carry out solidifying be: the flexible material being first just implanted with compound is put Put and the environment of 30~50 DEG C solidify 8~12h, then in the environment of 60~80 DEG C, solidify 8~12h, In the environment of 90-100 DEG C, solidify 5~10h the most again, solidify in the environment of 100-120 DEG C the most again 3~8h.
Described flexible material is paper, cotton, blended cloth, chemical fabric, flaxen fiber fabric, tinsel One in net and cotton fiber.
Step 2) in the concrete operations of dipping process for flexible material being placed into dipping solution or gluing solution Middle immersion treatment 0.1-2h;
Described dipping solution is by filler B, the 0.5-1 by bonding agent B, 10-30 part that mass fraction is 30-80 part The coupling agent A of toughener A, 0.3-3 part of wetting agent A, 0.5-5 part of part and dividing of 0.2-1.0 part Powder A forms;
Described gluing solution is by filler C, the 0.5-1 by bonding agent C, 0-15 part that mass fraction is 30-80 part The coupling agent B of toughener B, 0.3-3 part of wetting agent B, 0.5-5 part of part and dividing of 0.2-1.0 part Powder B forms.
Described adhesive A, bonding agent B and bonding agent C are phenolic resin, epoxy resin, urea One in urea formaldehyde, melamine formaldehyde resin, acrylic resin and polyurethane;
Described coupling agent A and coupling agent B is silane coupler, titanate coupling agent, Aluminate coupling One in agent, bimetallic coupling agent and stannum coupling agent;
Described wetting agent A and wetting agent B be azone, dodecylbenzene sodium sulfonate, Nekal BX, One in the condensation substance of sodium lauryl sulphate and fatty alcohol and oxirane;
Described toughener A and toughener B is carboxy terminated nitrile rubber, LNBR, PVOH contracting Butyraldehyde, polyether sulfone, polyphenylene oxide ketone, carboxylic acrylonitrile butadiene rubber latex, polyvinyl alcohol, polyacrylamide, liquid silicon One in rubber and polyethers;
Described filler A, filler B and filler C are corundum.
Step 2) in flexible material is carried out impregnation and preservative treatment before further comprising the steps of:
1a) flexible material described in cutting, then the flexible material cut is placed into mass concentration is 5% Sodium hydroxide solution be rinsed, rinse out the fat liquid on flexible material surface;
2b) by step 1a) flexible material that obtains ironing and being dried, remove the fine hair on flexible material surface.
In the mould of described removing material, grinding unit die cavity is shaped as triangular form, bar shaped, circle, Pedicellus et Pericarpium Trapae Shape, square, oval or trapezoidal in one.
Described removing material is the one in abrasive band, sand paper, dry grinding disc, cutting sheet and emery wheel.
Compared with prior art, the present invention has a following useful technique effect:
The diamond implanted based on grinding unit of present invention offer or CBN grinding tool preparation method molding side Method is simple, convenient and swift, it is not necessary to too much equipment;Rely on grinding tool abrasive material, filler, bonding agent And the mixture of additive composition is coated on flexible material, through overcuring, thus formed based on grinding list The diamond of unit's implantation or CBN grinding tool, simple to operate, solve other method and produce super-hard abrasive tool pair The problem of environmental pollution, it addition, the highest to temperature requirement, to super hard abrasive itself particularly when solidification Grinding sword does not has any trauma, makes the abrasive particle of grinding unit can keep good sharp state, and sbrasive belt grinding is imitated Fruit is more preferably;Realize mixing the molding of material by the mould of removing material so that each grinding unit simultaneously Between leave bigger space, during use, flexible material rotate time drive air flow at high speed, make grinding Time temperature be substantially reduced, it addition, in manufacturing process, flexible material has been carried out at impregnation and anticorrosion Reason, thus prepare based on grinding unit implant diamond or CBN grinding tool have use time length, High tenacity and the high feature of adhesive strength.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of mould;
Fig. 2 is the grinding unit schematic diagram after implanting;
Fig. 3 is that low-temperature setting avoids the carbonization at high temperature sintering of diamond or CBN grinding tool and burn Phenomenon.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, described in be to the present invention Explanation rather than restriction.
With reference to Fig. 1, Fig. 2 and Fig. 3, described dispersant A, dispersant B are fatty acid, fat Race's amide-type and esters, paraffin class, metal soap, low-molecular-weight wax class and HPMA, wherein fatty acid, Aliphatic amide type and esters are vinyl bis-stearamides, and paraffin class is microcrystalline wax, and metal soap is Barium stearate, low-molecular-weight wax class is Tissuemat E.
Embodiment one
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) by mass fraction weigh the diamond of 30 parts, the corundum of 60 parts, the phenolic resin of 40 parts and The polyacrylamide of 0.5 part, then diamond and corundum are placed into mix homogeneously in mixing container, then add Enter phenolic resin, add polyacrylamide and adjust denseness, after mix homogeneously, obtain compound;
2) paper is carried out impregnation and preservative treatment, then the mould of removing material is routed on paper, then will Step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, make compound by According to shape molding on paper of grinding unit die cavity, the mould of described removing material includes being arranged in array The grinding unit die cavity of some hollow structures, disengages the mould of removing material the most again, make compound according to The shape of grinding unit die cavity is implanted on flexible material;
3) by step 2) obtain be implanted with compound paper stand 10 minutes, then resolidification;
4) by step 3) paper being implanted with compound after the solidification that obtains carries out cutting and finishing, obtains base Diamond or CBN grinding tool in grinding unit implantation.
Step 3) in the concrete operations that carry out solidifying be: the paper being first just implanted with compound is placed into 30 DEG C Environment in solidify 8h, then in the environment of 60 DEG C solidify 8h, the most again in the environment of 90 DEG C solidify 5h, solidifies 3h the most again in the environment of 100 DEG C.
Step 2) in the concrete operations of dipping process for paper being placed in dipping solution or gluing solution immersion Process 0.1h;
Described dipping solution by by the polyurethane that mass fraction is 30 parts, the corundum of 10 parts, the azone of 0.5 part, The vinyl bis-stearamides of the carboxy terminated nitrile rubber of 0.5 part, the silane coupler of 0.3 part and 0.2 part Composition;
Described gluing solution is by by the phenolic resin that mass fraction is 30 parts, the azone of 0.5 part, 0.5 part poly- The vinyl bis-stearamides composition of vinyl alcohol, the silane coupler of 0.3 part and 0.2 part.
Embodiment two
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) by mass fraction weigh the diamond of 80 parts, the corundum of 80 parts, the epoxy resin of 60 parts and The polyacrylamide of 5 parts, then diamond and corundum are placed into mix homogeneously in mixing container, then add Enter epoxy resin, add polyacrylamide and adjust denseness, after mix homogeneously, obtain compound;
2) cotton is carried out impregnation and preservative treatment, then the mould of removing material is routed on cotton, so After by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, makes mixing Expecting the shape molding on cotton according to grinding unit die cavity, the mould of described removing material includes in array The grinding unit die cavity of some hollow structures of arrangement, disengages the mould of removing material the most again, makes mixing Material is implanted on cotton according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound cotton stand 30 minutes, then resolidification;
4) by step 3) cotton being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: the cotton being first just implanted with compound is placed into The environment of 50 DEG C solidifies 12h, then in the environment of 80 DEG C, solidifies 12h, the most again at the environment of 100 DEG C Middle solidification 10h, solidifies 8h the most again in the environment of 120 DEG C.
Step 2) in the concrete operations of dipping process for cotton being placed in dipping solution or gluing solution leaching Bubble processes 2h;
Described dipping solution by by the acrylic resin that mass fraction is 80 parts, the corundum of 30 parts, the ten of 1 part Dialkyl benzene sulfonic acids sodium, the LNBR of 5 parts, the stannum coupling agent of 3 parts and the microlite of 1.0 parts Wax forms;
Described gluing solution by by the epoxy resin that mass fraction is 80 parts, the corundum of 15 parts, the 12 of 1 part Sodium alkyl benzene sulfonate, the carboxylic acrylonitrile butadiene rubber latex of 5 parts, the titanate coupling agent of 3 parts and the ethylene of 1.0 parts Base bis-stearamides forms.
Embodiment three
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) by mass fraction weigh the diamond of 40 parts, the corundum of 65 parts, the Lauxite of 45 parts and The polyacrylamide of 1 part, then diamond and corundum are placed into mix homogeneously in mixing container, then add Enter Lauxite, add polyacrylamide and adjust denseness, after mix homogeneously, obtain compound;
2) blended cloth is carried out impregnation and preservative treatment, then the mould of removing material is routed on blended cloth, Then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, make to mix Close material according to shape molding on blended cloth of grinding unit die cavity, the mould of described removing material include in The grinding unit die cavity of some hollow structures of array arrangement, disengages the mould of removing material the most again, makes Compound is implanted on blended cloth according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound blended cloth stand 15 minutes, then resolidification;
4) by step 3) blended cloth being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: the blended cloth being first just implanted with compound is placed In the environment of 35 DEG C, solidify 8.5h, then in the environment of 65 DEG C, solidify 8.5h, the most again at 91 DEG C Environment solidifies 6h, in the environment of 105 DEG C, solidifies 3.5h the most again.
Step 2) in the concrete operations of dipping process for blended cloth is placed in dipping solution or gluing solution Immersion treatment 0.5h;
Described dipping solution by by the melamine formaldehyde resin that mass fraction is 35 parts, the corundum of 15 parts, The Nekal BX of 0.6 part, the PVOH butyral of 1 part, the bimetallic coupling agent of 0.8 part and 0.4 part Barium stearate composition;
Described gluing solution by by the Lauxite that mass fraction is 40 parts, the Nekal BX of 0.6 part, 1 The vinyl bis-stearamides composition of polyphenylene oxide ketone, the aluminate coupling agent of 0.8 part and 0.4 part of part.
Embodiment four
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) CBN of 50 parts, the corundum of 70 parts, the carbamide of 50 parts are weighed by mass fraction Resin and the polyacrylamide of 2 parts, then CBN and corundum are placed into mix homogeneously in mixing container, It is subsequently adding melamine formaldehyde resin, adds polyacrylamide and adjust denseness, after mix homogeneously, Compound;
2) chemical fabric is carried out impregnation and preservative treatment, then the mould of removing material is routed on chemical fabric, Then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, make to mix Close material according to shape molding on chemical fabric of grinding unit die cavity, the mould of described removing material include in The grinding unit die cavity of some hollow structures of array arrangement, disengages the mould of removing material the most again, makes Compound is implanted on chemical fabric according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound chemical fabric stand 20 minutes, then resolidification;
4) by step 3) chemical fabric being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: the chemical fabric being first just implanted with compound is placed In the environment of 40 DEG C, solidify 9h, then in the environment of 69 DEG C, solidify 9h, the most again at the environment of 95 DEG C Middle solidification 7h, solidifies 5h the most again in the environment of 110 DEG C.
Step 2) in the concrete operations of dipping process for chemical fabric is placed in dipping solution or gluing solution Immersion treatment 1h;
Described dipping solution by by the Lauxite that mass fraction is 50 parts, the corundum of 20 parts, the ten of 0.8 part Sodium dialkyl sulfate, the PVOH butyral of 2.5 parts, the aluminate coupling agent of 1.5 parts and 0.5 part Tissuemat E forms;
Described gluing solution by by the melamine formaldehyde resin that mass fraction is 50 parts, the corundum of 2 parts, The dodecylbenzene sodium sulfonate of 0.7 part, the polyether sulfone of 2 parts, the bimetallic coupling agent and 0.6 of 1.5 parts The microcrystalline wax composition of part.
Embodiment five
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) by mass fraction weigh the CBN of 60 parts, the corundum of 72 parts, 53 parts acrylic resin with And the polyacrylamide of 4 parts, then CBN and corundum are placed into mix homogeneously in mixing container, then Add acrylic resin, add polyacrylamide and adjust denseness, after mix homogeneously, obtain compound;
2) flaxen fiber fabric is carried out impregnation and preservative treatment, then the mould of removing material is routed to fiber crops On fibrous braid, then by step 1) compound that obtains is placed in the mould of removing material, and Blade coating uniformly, make compound according to shape molding on flaxen fiber fabric of grinding unit die cavity, described The mould of removing material includes the grinding unit die cavity of the some hollow structures being arranged in array, and takes off the most again Open the mould of removing material, make compound be implanted to flaxen fiber fabric according to the shape of grinding unit die cavity On;
3) by step 2) obtain be implanted with compound flaxen fiber fabric stand 25 minutes, then Resolidification;
4) by step 3) flexible material being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: be first just implanted with the flaxen fiber braiding of compound Thing is placed in the environment of 45 DEG C solidification 10h, then solidifies 10h in the environment of 75 DEG C, the most again at 97 DEG C Environment in solidify 8h, the most again in the environment of 115 DEG C solidify 6.5h.
Step 2) in the concrete operations of dipping process for flaxen fiber fabric is placed into dipping solution or painting Immersion treatment 0.7h in glue;
Described dipping solution is by by the epoxy resin that mass fraction is 70 parts, the corundum of 25 parts, the fat of 0.8 part Fat alcohol and the condensation substance of oxirane, the polyether sulfone of 4 parts, the titanate coupling agent of 2.5 parts and 0.8 part Tissuemat E composition;
Described gluing solution by by acrylic resin that mass fraction is 70 parts, the corundum of 10 parts, 0.8 part Nekal BX, the PVOH butyral of 4 parts, the stannum coupling agent of 2.5 parts and the barium stearate of 0.8 part Composition.
Embodiment six
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) CBN of 75 parts, the corundum of 75 parts, the polyurethane of 58 parts and 4.5 are weighed by mass fraction The polyacrylamide of part, then CBN and corundum are placed into mix homogeneously in mixing container, it is subsequently adding Polyurethane, adds polyacrylamide and adjusts denseness, after mix homogeneously, obtain compound;
2) metal gauze is carried out impregnation and preservative treatment, then the mould of removing material is routed to tinsel On the net, then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, Make compound according to the shape molding on a wire mesh of grinding unit die cavity, the mould of described removing material Including the grinding unit die cavity of the some hollow structures being arranged in array, disengage the mould of removing material the most again Tool, makes compound be implanted on metal gauze according to the shape of grinding unit die cavity;
3) by step 2) metal gauze being implanted with compound that obtains stands 28 minutes, the most solid Change;
4) by step 3) metal gauze being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: the metal gauze being first just implanted with compound is put Put solidification 11h in the environment of 48 DEG C, then in the environment of 78 DEG C, solidify 11h, the most again at 99 DEG C Environment solidifies 9h, in the environment of 118 DEG C, solidifies 7h the most again.
Step 2) in the concrete operations of dipping process for metal gauze being placed into dipping solution or gluing solution Middle immersion treatment 0.9h;
Described dipping solution by by the phenolic resin that mass fraction is 75 parts, the corundum of 25 parts, the ten of 0.9 part Dialkyl benzene sulfonic acids sodium, the polyphenylene oxide ketone of 4.5 parts, the silane coupler of 2.7 parts and the poly-second of 0.8 part Alkene wax forms;
Described gluing solution by by the polyurethane that mass fraction is 75 parts, the corundum of 13 parts, the 12 of 0.9 part Alkyl sodium sulfate, the LNBR of 4.5 parts, the stannum coupling agent of 2.7 parts and the polyethylene of 0.9 part Wax forms.
Embodiment seven
Of the present invention based on grinding unit implant diamond or CBN grinding tool preparation method include with Lower step:
1) by mass fraction weigh the CBN of 60 parts, the corundum of 62 parts, the phenolic resin of 43 parts and The polyacrylamide of 1.2 parts, then CBN and corundum are placed into mix homogeneously in mixing container, then add Enter phenolic resin, add polyacrylamide and adjust denseness, after mix homogeneously, obtain compound;
2) cotton fiber is carried out impregnation and preservative treatment, then the mould of removing material is routed on cotton fiber, Then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, make to mix Close material according to shape molding on cotton fiber of grinding unit die cavity, the mould of described removing material include in The grinding unit die cavity of some hollow structures of array arrangement, disengages the mould of removing material the most again, makes Compound is implanted on cotton fiber according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound cotton fiber stand 13 minutes, then resolidification;
4) by step 3) cotton fiber being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
Step 3) in the concrete operations that carry out solidifying be: the cotton fiber being first just implanted with compound is placed In the environment of 33 DEG C, solidify 8.5h, then in the environment of 64 DEG C, solidify 8.5h, the most again at 94 DEG C Environment solidifies 5.5h, in the environment of 106 DEG C, solidifies 4h the most again.
Step 2) in the concrete operations of dipping process for cotton fiber is placed in dipping solution or gluing solution Immersion treatment 0.2h;
Described dipping solution by by the polyurethane that mass fraction is 35 parts, the corundum of 12 parts, the 12 of 0.8 part Gathering of sodium alkyl benzene sulfonate, the carboxylic acrylonitrile butadiene rubber latex of 1 part, the bimetallic coupling agent of 1.2 parts and 0.4 part Ethylene waxes forms;
Described gluing solution by by the polyurethane that mass fraction is 35 parts, the corundum of 8 parts, the 12 of 0.6 part Sodium alkyl benzene sulfonate, the carboxy terminated nitrile rubber of 0.8 part, the bimetallic coupling agent of 0.9 part and 0.3 part Barium stearate forms.
Described toughener A and toughener B can also be polyvinyl alcohol, polyacrylamide, liquid silicon rubber One in glue and polyethers;
The removing material produced by this technique is compared with conventionally produced removing material has good gluing Connect intensity, high toughness, ablation high temperature resistant, resistance to, life-span length, grinding efficiency height.Described removing material Mould in grinding unit die cavity be shaped as triangular form, bar shaped, circle, rhombus, square, ellipse Or the one in trapezoidal.Described removing material is in abrasive band, sand paper, dry grinding disc, cutting sheet and emery wheel One.

Claims (8)

1. the diamond implanted based on grinding unit or CBN grinding tool preparation method, it is characterised in that Comprise the following steps:
1) filler A, 40-60 part bonding of the abrasive material of 30-80 part, 60-80 part is weighed by mass fraction Agent A and the additive of 0.5-5 part, then abrasive material and filler A are placed into mix homogeneously in mixing container, It is subsequently adding adhesive A, adds additive and adjust denseness, after mix homogeneously, obtain compound;
2) flexible material is carried out impregnation and preservative treatment, then the mould of removing material is routed to flexible material On material, then by step 1) compound that obtains is placed in the mould of removing material, and scratches uniformly, Make compound according to shape molding on flexible material of grinding unit die cavity, the mould of described removing material Including the grinding unit die cavity of the some hollow structures being arranged in array, disengage the mould of removing material the most again Tool, makes compound be implanted on flexible material according to the shape of grinding unit die cavity;
3) by step 2) obtain be implanted with compound flexible material stand 10-30 minute, the most again Solidification;
4) by step 3) flexible material being implanted with compound after the solidification that obtains carries out cutting and finishing, The diamond must implanted based on grinding unit or CBN grinding tool.
2. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that
Described additive is polyacrylamide;
Described abrasive material is diamond or CBN.
3. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that step 3) in the concrete operations that carry out solidifying be: be first just implanted with compound Flexible material be placed in the environment of 30~50 DEG C solidification 8~12h, then in the environment of 60~80 DEG C Solidification 8~12h, solidifies 5~10h, more again at 100-120 DEG C in the environment of 90-100 DEG C Environment in solidify 3~8h.
4. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that described flexible material is paper, cotton, blended cloth, chemical fabric, flaxen fiber volume One in fabric, metal gauze and cotton fiber.
5. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that step 2) in the concrete operations of dipping process for flexible material is placed into leaching Immersion treatment 0.1-2h in glue or gluing solution;
Described dipping solution is by filler B, the 0.5-1 by bonding agent B, 10-30 part that mass fraction is 30-80 part The coupling agent A of toughener A, 0.3-3 part of wetting agent A, 0.5-5 part of part and dividing of 0.2-1.0 part Powder A forms;
Described gluing solution is by filler C, the 0.5-1 by bonding agent C, 0-15 part that mass fraction is 30-80 part The coupling agent B of toughener B, 0.3-3 part of wetting agent B, 0.5-5 part of part and dividing of 0.2-1.0 part Powder B forms.
6. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that step 2) in flexible material is carried out impregnation and preservative treatment before also include with Lower step:
1a) flexible material described in cutting, then the flexible material cut is placed into mass concentration is 5% Sodium hydroxide solution be rinsed, rinse out the fat liquid on flexible material surface;
2b) by step 1a) flexible material that obtains ironing and being dried, remove the fine hair on flexible material surface.
7. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that in the mould of described removing material, grinding unit die cavity is shaped as triangle, circle Shape, rhombus, square, oval or trapezoidal in one.
8. the diamond implanted based on grinding unit as claimed in claim 1 or CBN grinding tool preparation side Method, it is characterised in that described removing material is in abrasive band, sand paper, dry grinding disc, cutting sheet and emery wheel One.
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CN105252436A (en) * 2015-10-09 2016-01-20 芜湖市鸿坤汽车零部件有限公司 Cerium and silicon composite oxidization resin grinding wheel and preparation method thereof
CN105364730A (en) * 2015-10-09 2016-03-02 芜湖市鸿坤汽车零部件有限公司 Anti-washout resin grinding wheel and manufacturing method thereof
CN105234842B (en) * 2015-10-12 2019-01-08 长沙岱勒新材料科技股份有限公司 A kind of diamond resin grinding tool material and diamond-resin grinding wheel
CN110449576B (en) * 2019-09-12 2020-06-09 兰州理工大学 Preparation method of iron-based magnetic grinding powder

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US3874126A (en) * 1971-10-15 1975-04-01 Remington Arms Co Inc Flexible hand held abrading tool
US5441549A (en) * 1993-04-19 1995-08-15 Minnesota Mining And Manufacturing Company Abrasive articles comprising a grinding aid dispersed in a polymeric blend binder
US5645471A (en) * 1995-08-11 1997-07-08 Minnesota Mining And Manufacturing Company Method of texturing a substrate using an abrasive article having multiple abrasive natures
US6458018B1 (en) * 1999-04-23 2002-10-01 3M Innovative Properties Company Abrasive article suitable for abrading glass and glass ceramic workpieces
US20050060942A1 (en) * 2003-09-23 2005-03-24 3M Innovative Properties Company Structured abrasive article
US7661247B2 (en) * 2005-06-30 2010-02-16 3M Innovative Properties Company Abrasive article packaging and method of making same
JP2014508650A (en) * 2011-01-26 2014-04-10 スリーエム イノベイティブ プロパティズ カンパニー Abrasive article comprising a backing having a replicated microstructure and method of using the same
CN103492126B (en) * 2011-04-18 2017-03-29 3M创新有限公司 Method for grinding and abrasive product

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