CN104362411B - Aluminium alloy air battery system - Google Patents
Aluminium alloy air battery system Download PDFInfo
- Publication number
- CN104362411B CN104362411B CN201410690605.8A CN201410690605A CN104362411B CN 104362411 B CN104362411 B CN 104362411B CN 201410690605 A CN201410690605 A CN 201410690605A CN 104362411 B CN104362411 B CN 104362411B
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- Prior art keywords
- aluminium
- anode
- cathode
- shell
- sodium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
- H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
Abstract
A kind of aluminium alloy air battery system, including shell, anode and cathode is equipped in shell, anode is equipped with anode extraction electrode, cathode is equipped with cathode extraction electrode, electrolyte solution is additionally provided in shell, the anode is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution is correspondingly sodium hydroxide or potassium hydroxide.It is additionally provided with fluid reservoir, fluid reservoir is by pipeline and shell, and pipeline is equipped with electrolyte pump, so that electrolyte solution flows between fluid reservoir and shell.A kind of aluminium alloy air battery system provided by the invention, anode use aluminium sodium alloy or aluminium potassium-sodium alloy, decline sodium hydroxide or potassium hydroxide content in electrolyte solution will not.The specific energy and specific power of battery can be improved, the velocity of discharge is fast.The present invention has efficiently, practical, low from rotten reactivity, the controllable feature of the operation is stable.
Description
Technical field
The present invention relates to the technical field of metal-air battery, especially a kind of aluminium alloy air battery system.
Background technique
In known metal-air chemical cell, aluminium-air cell principle and the present invention are the most close.Aluminium-air cell
Using aluminium as the anode of battery, catalytic oxygen does cathode, and strong alkali solution is as electrolyte solution, when aluminium and oxygen exist respectively
When the two poles of the earth chemically react, battery discharge.Using electrolyte as sodium hydroxide (the very close electrolyte of the chemical property of potassium and sodium
Solution can also use potassium hydroxide solution to replace sodium hydroxide potassium solution) chemical reaction that occurs in battery for solution at this time has:
Anode: 4Al-12e=4Al3+
Cathode: 3O2+6H2O+12e=12OH-
Net reaction: 4Al+3O2+6H2O+4NaOH=4NaAl (OH) 4+E (electricity) ↑+H (heat) ↑
4NaAl (OH) 4=4NaOH+4Al (OH) 3
Anode surface can occur from rotten reaction simultaneously:
2Al+6H2O+2NaOH=2NaAl (OH) 4+3H2↑
Aluminium-air cell biggest advantage continues for that can provide the continuation of the journey of ultra-long time for various electrical equipments for automobile
Boat power supply aspect, preferably record is to change an aluminium-air cell course continuation mileage to have reached 1600 kilometers at present.2014 on the books
The practical specific energy of aluminium-air cell has reached 350wh/kg, is 8 times of lead-acid battery, 5.8 times of nickel-metal hydride battery, lithium battery
2.3 again.But the theoretical energy values of aluminium-air cell are 8100wh/kg, it means that aluminium-air cell has largely at present
Energy be wasted, the specific energy of battery needs to be greatly improved.It is aluminium-air cell energy by being reacted known to analysis from corruption
Measure the biggest factor of reactive power consumption, at the same battery stop working after the self discharge effect that occurs be also that energy content of battery reactive power consumption is another
One factor.It is another the reason is that discharge rate is excessively slow that aluminium-air cell large-scale application is restricted at present, voltage delay, due to mesh
Preceding aluminium-air cell mostly uses greatly 99.99% pure aluminum plate to do anode and is immersed in electrolyte solution, molten with electrolyte in this way
Liquid contact surface sizes values are certain, and this value is little, so the aluminium atom quantity for participating in chemical reaction is certain and numerical value is smaller makes
It is slow at battery discharge, and the velocity of discharge is uncontrollable.When aluminium-air cell work, chemistry occurs for aluminium and oxygen instead
Also create a large amount of heat while electric energy should be generated, excluded not in time if amount of heat is assembled in battery, gently if can
Cause battery job insecurity, it is heavy then cause cell damage, or even can explode, generate safety problem.Current aluminium air
There is no a set of simple and effective heat-extraction system and methods for battery.Therefore, only by the above-mentioned bottleneck problem of aluminium-air cell into
Row effectively solves, and aluminium-air cell can just be used widely.
Summary of the invention
Technical problem to be solved by the invention is to provide a kind of aluminium alloy air battery systems, and the ratio of battery can be improved
Energy and specific power, the velocity of discharge are fast.In preferred scheme, the velocity of discharge of battery is controllable, and concentration of electrolyte solutions is not at any time
Between it is elongated and reduce, less from rotten reaction, self discharge reaction reactive power consumption aluminium, electrolyte solution can be automatically entered, is discharged, air
It can automatically enter, be discharged, and convenient for heat dissipation, reduce the security risk generated by heat.
In order to solve the above technical problems, the technical scheme adopted by the invention is that: a kind of aluminium alloy air battery system, packet
Shell is included, anode and cathode is equipped in shell, anode is equipped with anode extraction electrode, and cathode is equipped with cathode extraction electrode, shell
It is additionally provided with electrolyte solution in vivo, the anode is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution is correspondingly hydroxide
Sodium or potassium hydroxide.
Preferably, the volume ratio of sodium is 0.1~30% in aluminium sodium alloy；
The volume ratio of potassium is 0.1~30% in aluminium potassium-sodium alloy.
It is further preferred that the volume ratio of sodium is 4% in aluminium sodium alloy；
The volume ratio of potassium is 4% in aluminium potassium-sodium alloy.
The anode is equipped with multiple vertical columnar gaps.
Preferably, it is additionally provided with fluid reservoir, fluid reservoir is connect by pipeline with enclosure interior, and pipeline is equipped with electrolyte pump,
So that electrolyte solution flows between fluid reservoir and shell.
Preferably, the cathode is porous silver-based catalytic cathode plate, and cathode is located at the lower section of anode, and cathode top is set
There is gas gathering mask, exhaust pipe upper end opening is located at close to the position of gas gathering mask inner top；
Exhaust pipe is connected to exhaust pump, and porous silver-based catalytic cathode board bottom portion is connect with air inlet pipe, air inlet pipe and air inlet
Pump connection；
The first liquid level sensor and the second liquid level sensor are additionally provided in gas gathering mask.
Preferably, the cathode is slidably supported in insulated enclosure shell by multiple support wheels, and can be floated up and down.
Preferably, it is additionally provided with heat-pipe radiating apparatus, heat pipe evaporation ends are located in shell, and condensation end is connect with radiating fin,
Temperature sensor is additionally provided in shell.
Preferably, case top is additionally provided with hydrogen discharge pipe, and hydrogen discharge pipe is equipped with hydrogen waste cock valve, in shell
Equipped with hydrogen gas concentration sensor.
Preferably, case top at least diagonal position, which is equipped with, is inverted electrolyte discharge liquid pipe, is inverted electrolyte and liquid pipe is discharged
Equipped with the first inversion-prevention valve and the second inversion-prevention valve, it is inverted in electrolyte discharge liquid pipe and is additionally provided with inversion-prevention pump, also set in shell
There is inversion-prevention switch.
A kind of aluminium alloy air battery system provided by the invention, has the advantage that as follows:
1, by by galvanic anode use aluminium sodium alloy or aluminium potassium-sodium alloy, correspondingly the sodium hydroxide in electrolyte solution or
Potassium hydroxide is slowly supplemented always, and concentration of electrolyte solutions is not elongated gradually by the trace acidic gas in air at any time
It consumes and reduces, because battery discharge is also related with concentration of electrolyte solutions, therefore the structure can increase cell discharge performance
Stability.Its principle is when battery work, since the metal active character of sodium or potassium is better than aluminium, in the sodium or potassium of anode surface
Atom can be chemically reacted prior to aluminium, and reactional equation is as follows by taking sodium as an example:
Anode: 4Na-4e=4Na+
Cathode: O2+2H2O+4e=4OH-
Net reaction: 4Na+O2+2H2O=4NaOH
Reacting end product is sodium hydroxide or potassium hydroxide, is supplemented in electrolyte solution.
Anode uses aluminium sodium alloy or aluminium potassium-sodium alloy, and sodium or potassium proportional amount are between 0.1%-30%, to make electrolyte
Sodium hydroxide or potassium hydroxide content will not decline in solution.And after sodium or potassium formerly react, there is spot corrosion effect for anode,
It can also accelerate subsequent reaction rate.
2, as shown in Figure 1, by be by the structure setting of anode have from bottom to top surface multiple columnar gaps bulk or
Column Al alloy block or aluminum alloy sheet, come make anode increase can with the contact area of electrolyte solution contacts, with same volume
Simple aluminium sheet, which is compared, can increase substantially battery discharge.Anode uses this structure also to realize that the velocity of discharge can for the present invention
Control provides necessary condition.Battery discharge control principle is: by rising or reducing the electrolyte solution liquid in battery
Face, to change the contact area size of anode and electrolyte solution, to control the electric speed that battery is put.
After the present invention does anode and anode structure containing columnar gap collective effect by using aluminium sodium alloy or aluminium potassium-sodium alloy,
The velocity of discharge greatly improves compared with existing monomer-type pure aluminum plate air cell.
3, as shown in Figure 1, passing through the external fluid reservoir of setting electrolyte solution, cooperate liquid level sensor and electrolyte pump,
Realize the liquid surface lifting control system of electrolyte solution.That is, control anode immerses the depth of electrolyte solution, to come
Control the velocity of discharge of battery.When battery does not need work, electrolyte solution liquid surface lifting control system can be molten by electrolyte
Liquid liquid level is down to anode bottom face hereinafter, anode is made to be detached from electrolyte solution, has not only prevented battery in this way because sending out when not used
Raw self discharge reaction, and reacting from corruption for a large amount of reactive power consumption anodes is also prevented at this time, avoids the aluminium quilt in anode
A large amount of wastes, to greatly improve the specific energy of aluminium sodium alloy air cell.
After electrolyte solution liquid surface lifting control system cooperates jointly, it is greatly decreased from the anode of rotten reaction consumption, than energy
Amount greatly improves compared with existing monomer-type pure aluminum plate air cell.
And after electrolyte solution liquid surface lifting control system cooperates jointly, the velocity of discharge is realized controllable.
4, as shown in Figure 1, the cathode made of porous silver-based catalytic air cathode plate is by the oxygen catalytic in air,
To chemically react in cathode after so that oxygen is obtained the electronics that anode electrode conveying comes.By in porous silver-based catalytic air
The both sides side-lower of cathode plate installs the float of enough buoyancy additional, and multiple support wheels and top setting limit grid are respectively installed in two sides
The mode of plate achievees the purpose that cathode is kept fixed distance and attitude stabilization with anode always, to keep battery discharge more steady
It is fixed.The surplus air for having consumed oxygen is collected by installing gas gathering mask additional in the top of cathode.It avoids remaining in surplus air
Oxygen loss everywhere in the battery, directly chemically reacted with the aluminium in anode and sodium, to avoid reactive power consumption battery
Energy.Oxygen is provided to porous silver-based catalytic air cathode plate by air inlet pipe.It is discharged by the exhaust pipe in gas gathering mask
Air in gas gathering mask, it is preferred that the top of exhaust pipe is located at the top in gas gathering mask.Make air by air inlet, gas exhaust inspecting
Timely it can input and be discharged automatically, guarantee the normal work of battery.The automatic defeated, row of cathode construction and respective air of the invention
System keeps discharge performance more stable.
5, as shown in Figure 1, the heat conducting pipe made of using heat pipe principle, the structure of heat exchanger fin and cooling fin, cooperation temperature
It spends sensor and control device forms battery automatic radiating system, the heat generated when battery of the present invention is worked is constantly expelled to
Outside battery, internal temperature of battery is excessively high caused by avoiding inside battery from assembling because of heat, and generates adverse consequences.Automatic radiating system
Battery is set to realize high efficiency and heat radiation.
6, the row's hydrogen device and inversion-prevention device being arranged, can have the safety for ensuring battery, when density of hydrogen is higher
It waits, extra hydrogen is discharged from hydrogen discharge pipe, when battery is inverted, to avoid safety accident, by electrolyte
Solution is discharged in fluid reservoir by inversion-prevention pump, and inversion-prevention pump is powered by additional battery.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples:
Fig. 1 is overall structure diagram of the invention.
In figure: anode 1, metal sealing shell 2, insulating materials capsul 3, column hole 4, electrolyte solution 5, collection
Gas hood 6, support wheel 7, float 8, porous silver-based catalytic cathode plate 9, the first liquid level sensor 10, air inlet pipe 11, row
Tracheae 12, cathode extraction electrode 13, the second liquid level sensor 14, third liquid level sensor 15, temperature sensor 16, into
Air pump 17, exhaust pump 18, inversion-prevention switch 19, control device 20, rechargeable battery 21, fan 22, the electrolysis of storage
Matter solution 23, fluid reservoir 24, positive displacement pump 25, infusion pump 26, liquid pipe 27, heat pipe 28, radiating fin 29, inversion-prevention pump
30, the second inversion-prevention valve 31, anode extraction electrode 32, hydrogen gas concentration sensor 33, hydrogen waste cock valve 34, hydrogen row
Outlet pipe 35 is inverted electrolyte and liquid pipe 36, the first inversion-prevention valve 37, limit screen 38, cathode 39 is discharged.
Specific embodiment
As shown in fig. 1, a kind of aluminium alloy air battery system, including shell, the shell in this example is using double-deck knot
Structure, internal layer use corrosion resistant plastics, and outer layer uses metal material, anode 1 and cathode 39 are equipped in shell, and anode is equipped with sun
Pole extraction electrode 32, cathode are equipped with cathode extraction electrode 13 and outwardly provide the cathode and anode of power supply respectively by conducting wire,
It is loaded for connecting, electrolyte solution 5 is additionally provided in shell, the anode 1 is that aluminium sodium alloy or aluminium potassium-sodium alloy, electrolyte are molten
Liquid 5 is correspondingly sodium hydroxide or potassium hydroxide.
Preferably, the volume ratio of sodium is 0.1~30% in aluminium sodium alloy；
The volume ratio of potassium is 0.1~30% in aluminium potassium-sodium alloy.
Preferably, the volume ratio of sodium is 3~12% in aluminium sodium alloy；
The volume ratio of potassium is 3~12% in aluminium potassium-sodium alloy.
It is further preferred that the volume ratio of sodium is 4% in aluminium sodium alloy；
The volume ratio of potassium is 4% in aluminium potassium-sodium alloy.Make in electrolyte solution sodium hydroxide or potassium hydroxide content will not under
Drop.Improve the stability of battery discharge.
The anode 1 is equipped with multiple vertical columnar gaps 104.To increase the contact area with electrolyte solution.
Linear relationship is kept as liquid level is gone up and down to ensure that area increases and reduces, therefore, this example uses vertical columnar gap
104 structures.
Preferably as shown in figure 1, it is additionally provided with fluid reservoir 24, fluid reservoir 24 is connect with enclosure interior by pipeline, set on pipeline
There is electrolyte pump, so that electrolyte solution flows between fluid reservoir 24 and shell.When needing to increase generated energy, infusion pump 26
Starting, electrolyte solution is input in shell, and when needing to reduce generated energy, electrolyte solution is drained by positive displacement pump 25
In fluid reservoir 24.Individual battery driving can also can be set by spontaneous electric drive in infusion pump 26 and positive displacement pump 25.
When the present invention needs to stop working, control device 20 drive positive displacement pump 25 by electrolyte solution by liquid pipe 27 from
It is discharged in the shell of battery in fluid reservoir 24, stops when third liquid level sensor 15 provides the signal of electrolyte solution liquid level
Only.So that anode is detached from electrolyte solution at this time, not only prevents battery in this way because the self discharge that occurs when not used is reacted, Er Qie great
Amount reactive power consumption anode is also prevented at this time from rotten reaction, and the aluminium avoided in anode is largely wasted, to greatly improve
The specific energy of aluminium sodium alloy air cell.According to the voltage or electric current of output, the height of electrolyte solution submergence anode 1 is controlled,
The size of i.e. controllable output voltage or electric current.
It is preferred that in this example, being located at the structure below anode using cathode, the cathode is porous silver such as Fig. 1
Base catalytic cathode plate 9, cathode top are equipped with gas gathering mask 6, and 12 upper end opening of exhaust pipe is located at close to the position of 6 inner top of gas gathering mask
It sets；
Exhaust pipe 12 is connected to exhaust pump 18, and porous 9 bottom of silver-based catalytic cathode plate is connect with air inlet pipe 11, air inlet pipe
11 are connected to air intake pump 17；
The first liquid level sensor 10 and the second liquid level sensor 14 are additionally provided in gas gathering mask 6.In use, air intake pump
17 continue working, and gas enters porous silver-based catalytic cathode plate 9 by air inlet pipe 11, and the oxygen in air is in silver-based material
Catalysis issue biochemical reaction, and be consumed.The air for consuming oxygen passes through crinosity pore silver-based catalytic air cathode plate 6
Upward loss covers whole collections by gas collection 4, when the gas generated in reaction process keeps the gas in gas gathering mask 6 excessive, at this time
Second liquid level sensor 14 obtains liquid level signal, drive dynamic control device, such as single-chip microcontroller, starts the exhaust pump on exhaust pipe 12
18, extra gas is discharged, until the first liquid level sensor 10 stops when obtaining liquid level signal.
Preferably, the cathode is slidably supported in insulated enclosure shell 3 by multiple support wheels 7, and is floated up and down.?
Cathode is equipped with multiple floats, so that cathode floats, limit screen 38 is equipped at the top of cathode, so that between cathode and anode
Suitable distance is kept, under the driving of float, entire cathode tends to float up, until limit screen 38 touches anode 1
Lower end, so that the distance between cathode and anode are limited, to obtain optimal generating efficiency.Since anode is in power generation process
In can constantly be lost, cathode can continue to float after anode loss, remain between cathode and anode to be most preferably to generate electricity
Spacing.Support wheel 7 is for keeping cathode more steady in location free procedure.
Preferably, it is additionally provided with radiator, 28 evaporation ends of heat pipe are located in shell, and condensation end is connect with radiating fin 29,
29 side of radiating fin is equipped with fan 22, and temperature sensor 16 is additionally provided in shell.Heat is directed to radiating fin by heat pipe 28
Piece 29, is then radiated by fan.Fan in this example is preferably powered by independent battery.
Preferably, case top is additionally provided with hydrogen discharge pipe 35, and hydrogen discharge pipe 35 is equipped with hydrogen waste cock valve 34,
Hydrogen gas concentration sensor 33 is equipped in shell.When detecting that density of hydrogen is higher than setting value, control device 20 controls hydrogen
Waste cock valve 34 is opened, and hydrogen is discharged, it is ensured that cell safety.
Preferably, case top at least diagonal position, which is equipped with, is inverted electrolyte discharge liquid pipe 36, is inverted electrolyte discharge liquor
Pipe 36 is equipped with the first inversion-prevention valve 37 and the second inversion-prevention valve 31, is inverted in electrolyte discharge liquid pipe 36 and is additionally provided with inversion-prevention pump
30, inversion-prevention switch 19 is additionally provided in shell.Thus structure, when battery topples, inversion-prevention switch 19 issues signal, control
Device 20 processed controls a underlying inversion-prevention valve among the first inversion-prevention valve 37 at this time and the second inversion-prevention valve 31 and opens,
30 starting of inversion-prevention pump simultaneously, is discharged into fluid reservoir 24 for electrolyte solution, to ensure safety.It is further preferred that inversion-prevention
It pumps the 30, first inversion-prevention valve 37 and the second inversion-prevention valve 31 to drive using additional battery, to avoid in aluminium alloy air cell
Power supply can not be obtained in the case where failure.It is further preferred that being additionally provided with security solenoid valve, security solenoid valve is obtaining electric shape
State is closed, and is opened under power failure state, and the electrolyte solution emptying in air cell is enabled aluminum alloy to.
The above embodiments are only the preferred technical solution of the present invention, and are not construed as limitation of the invention, this hair
Bright protection scope should be with the technical solution of claim record, technical characteristic in the technical solution recorded including claim
Equivalents are protection scope.Equivalent replacement i.e. within this range is improved, also within protection scope of the present invention.
Claims (9)
1. a kind of aluminium alloy air battery system, including shell, shell is interior to be equipped with anode (1) and cathode (39), and anode is equipped with
Anode extraction electrode (32), cathode are equipped with cathode extraction electrode (13), are additionally provided with electrolyte solution (5), feature in shell
Be: the anode (1) is aluminium sodium alloy or aluminium potassium-sodium alloy, and electrolyte solution (5) is correspondingly sodium hydroxide or potassium hydroxide；
The cathode is porous silver-based catalytic cathode plate (9), and cathode is located at the lower section of anode (1), and cathode top is equipped with collection
Gas hood (6), exhaust pipe (12) upper end opening are located at close to the position of gas gathering mask (6) inner top；
Exhaust pipe (12) is connected to exhaust pump (18), and porous silver-based catalytic cathode plate (9) bottom is connect with air inlet pipe (11), into
Tracheae (11) is connected to air intake pump (17)；
The first liquid level sensor (10) and the second liquid level sensor (14) are additionally provided in gas gathering mask (6).
2. a kind of aluminium alloy air battery system according to claim 1, it is characterized in that: in aluminium sodium alloy sodium volume ratio
It is 0.1~30%；
The volume ratio of potassium is 0.1~30% in aluminium potassium-sodium alloy.
3. a kind of aluminium alloy air battery system according to claim 2, it is characterized in that: in aluminium sodium alloy sodium volume ratio
It is 4%；
The volume ratio of potassium is 4% in aluminium potassium-sodium alloy.
4. a kind of aluminium alloy air battery system according to claim 1, it is characterized in that: the anode (1) is equipped with
Multiple vertical columnar gaps (104).
5. a kind of aluminium alloy air battery system according to claim 1 stores up it is characterized in that: being additionally provided with fluid reservoir (24)
Flow container (24) is connect by pipeline with enclosure interior, and pipeline is equipped with electrolyte pump, so that electrolyte solution is in fluid reservoir (24)
It is flowed between shell.
6. a kind of aluminium alloy air battery system according to claim 1, it is characterized in that: the cathode passes through multiple
Support wheel (7) is slidably supported in insulated enclosure shell (3), and is floated up and down.
7. a kind of aluminium alloy air battery system according to claim 1, it is characterized in that: it is additionally provided with radiator, heat pipe
(28) evaporation ends are located in shell, and condensation end is connect with radiating fin (29), and temperature sensor (16) are additionally provided in shell.
8. a kind of aluminium alloy air battery system according to claim 1 or 5, it is characterized in that: case top is additionally provided with hydrogen
Gas discharge pipe (35), hydrogen discharge pipe (35) are equipped with hydrogen waste cock valve (34), are equipped with hydrogen gas concentration sensor in shell
(33)。
9. a kind of aluminium alloy air battery system according to claim 1 or 5, it is characterized in that: case top is at least diagonal
Position, which is equipped with, is inverted electrolyte discharge liquid pipe (36), is inverted electrolyte discharge liquid pipe (36) and is equipped with the first inversion-prevention valve (37) and the
Two inversion-prevention valves (31) are inverted in electrolyte discharge liquid pipe (36) and are additionally provided with inversion-prevention pump (30), are additionally provided with inversion-prevention in shell
It switchs (19).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690605.8A CN104362411B (en) | 2014-11-18 | 2014-11-18 | Aluminium alloy air battery system |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410690605.8A CN104362411B (en) | 2014-11-18 | 2014-11-18 | Aluminium alloy air battery system |
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| CN104362411A CN104362411A (en) | 2015-02-18 |
| CN104362411B true CN104362411B (en) | 2018-12-07 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114335759B (en) * | 2020-09-25 | 2023-07-25 | 包头昊明稀土新电源科技有限公司 | Chaotropic long-life water system power battery and preparation method thereof |
| CN113690469B (en) * | 2021-08-25 | 2022-12-06 | 浙江大学 | Aluminum-water electrochemical cell system |
| CN115939450B (en) * | 2022-12-20 | 2024-04-12 | 河南科技大学 | Aluminum-potassium ferricyanide energy-saving battery circulating device |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202737061U (en) * | 2012-04-10 | 2013-02-13 | 德阳东深新能源科技有限公司 | High-power aluminum-air battery system |
| CN103125047A (en) * | 2010-10-07 | 2013-05-29 | 住友化学株式会社 | Air battery |
| JP2014203552A (en) * | 2013-04-02 | 2014-10-27 | 冨士色素株式会社 | Metal air battery |
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2014
- 2014-11-18 CN CN201410690605.8A patent/CN104362411B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103125047A (en) * | 2010-10-07 | 2013-05-29 | 住友化学株式会社 | Air battery |
| CN202737061U (en) * | 2012-04-10 | 2013-02-13 | 德阳东深新能源科技有限公司 | High-power aluminum-air battery system |
| JP2014203552A (en) * | 2013-04-02 | 2014-10-27 | 冨士色素株式会社 | Metal air battery |
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