CN104356922A - Waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware - Google Patents

Waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware Download PDF

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Publication number
CN104356922A
CN104356922A CN201410583477.7A CN201410583477A CN104356922A CN 104356922 A CN104356922 A CN 104356922A CN 201410583477 A CN201410583477 A CN 201410583477A CN 104356922 A CN104356922 A CN 104356922A
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CN
China
Prior art keywords
flexibility
percent
fast
water
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410583477.7A
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Chinese (zh)
Inventor
习小山
王军
黄波
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Chengdu Nashuo Technology Co Ltd
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Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201410583477.7A priority Critical patent/CN104356922A/en
Publication of CN104356922A publication Critical patent/CN104356922A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention relates to the field of coatings, in particular to a waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware. The waterproof and high-flexibility ultraviolet-curable luminescent coating for the wooden ware is prepared from the following raw materials in percentage by mass: 20 to 35 percent of mixture of standard bisphenol A epoxy diacrylic ester and aliphatic polyurethane hexaacrylate, 5 to 10 percent of polyester acrylate resin, 5 to 12 percent of an initiator, 1 to 3 percent of a surface auxiliary, 5 to 10 percent of a co-solvent, 10 to 20 percent of a reactive diluent, 10 to 20 percent of long-acting luminescent powder and 10 to 20 percent of ethanol. According to the waterproof and high-flexibility ultraviolet-curable luminescent coating for the wooden ware, requirements for beautifying and protection functions of the coating can completely be met, a novel decoration method is provided; meanwhile, the coating has low chromatic number, high gloss and high hardness performance, and has the properties such as waterproofness and high flexibility, the wooden ware is further protected, and the service life of the wooden ware is prolonged.

Description

A kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware
Technical field
The present invention relates to paint field, particularly relate to a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware.
Background technology
Ultraviolet-curing paint is since appearance, because it has the feature of 5E, i.e. efficient (Efficient), applicable wide (Enabling), economic (Economical), energy-conservation (Energy Saying), environmental friendliness (Environmental-friendly).In the prior art, ultraviolet-curing paint is widely used in and closely bound up field of living by people, to play the effect beautifying object and protection object.
Coating can not be corroded by the wooden appliances of available protecting, thus extends the work-ing life of wooden appliances, and wooden appliances seems more attractive in appearance under the covering with paint of coating in addition.But along with era development, people are for the diversification more of decoration demand, and traditional woodwork coating only has change in color and color and luster, and the mode lacking a kind of innovation meets the demand of people.
Summary of the invention
The object of the invention is to address the deficiencies of the prior art, a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is provided, while the present invention possesses background color number, high gloss, performance, possesses a kind of luminous effect, a kind of artistry technique of expression of novelty is provided, also possesses the features such as water-fast, high-flexibility.
For realizing the object of the invention, the technical solution used in the present invention is as follows:
For water-fast, the UV light solidified luminous coating of high-flexibility of woodenware, it is characterized in that: be prepared from by the raw material of following mass percent: standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20% ~ 35%; Polyester acrylate resin: 5% ~ 10%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Long-acting noctilucent powder: 10% ~ 20%; Ethanol: 10 ~ 20%.
Further, described a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is prepared from by the raw material of following mass percent: standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20%; Polyester acrylate resin: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 7.5%; Reactive thinner: 18%; Long-acting noctilucent powder: 20%; Ethanol: 20%.
Further, described standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture, both mass ratioes are 1:3 ~ 5.
Further, described reactive thinner is ethyl acetate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
Further, described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
Further, described surface modifier is silicone based, organic fluorine class or said mixture.
Further, described solubility promoter is alcohol ether solvents.
The invention provides a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware, beneficial effect is as follows:
What a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware of the present invention not only can meet that coating has completely beautifies and defencive function; additionally provide a kind of decoration technique of expression of novelty; possess low chromatic number, high gloss, high rigidity performance simultaneously; also there is the performances such as good water-fast, high-flexibility; further protect woodenware, increase the service life.
Accepted standard bisphenol A epoxy diacrylate of the present invention and aliphatic polyurethane six acrylate mixture, there is the advantage that cost is low, hardness is high, chemical-resistant is good, surface cure performance is good, to the luminescent properties of long-acting noctilucent powder, there is good synergy again.
Embodiment
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1:
Described a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is prepared from by the raw material of following mass percent:
Standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20%; Polyester acrylate resin: 5%; Benzophenone: 8%; Organic fluorine class: 1.5%; Glycol ether: 7.5%; Ethyl acetate, diacrylate ester mixture: 18%; Long-acting noctilucent powder: 20%; Ethanol: 20%.
Wherein, standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture mass ratio are 1:3.5; Ethyl acetate, diacrylate mixture quality are than being 2:1.
Embodiment 2:
Described a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is prepared from by the raw material of following mass percent:
Standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20%; Polyester acrylate resin: 6%; 1-hydroxycyclohexyl phenyl ketone: 12%; Silicone based: 2%; Glycol ether: 7%; Ethyl acetate, diacrylate ester mixture: 18%; Long-acting noctilucent powder: 20%; Ethanol: 15%.
Wherein, standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture mass ratio are 1:4; Ethyl acetate, diacrylate mixture quality are than being 2.5:1.
Embodiment 3:
Described a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is prepared from by the raw material of following mass percent:
Standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 30%; Polyester acrylate resin: 6%; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture: 12%; Silicone based, organic fluorine class mixture: 3%; Glycol ether: 10%; Ethyl acetate, diacrylate ester mixture: 9%; Long-acting noctilucent powder: 10%; Ethanol: 20%.
Wherein, standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture mass ratio are 1:4.5; Benzophenone, 1-hydroxycyclohexyl phenyl ketone mixture quality are than being 2.2:1; Ethyl acetate, diacrylate mixture quality are than being 1.8:1.

Claims (7)

1. for water-fast, the UV light solidified luminous coating of high-flexibility of woodenware, it is characterized in that: be prepared from by the raw material of following mass percent: standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20% ~ 35%; Polyester acrylate resin: 5% ~ 10%; Initiator: 5% ~ 12%; Surface modifier: 1% ~ 3%; Solubility promoter: 5% ~ 10%; Reactive thinner: 10% ~ 20%; Long-acting noctilucent powder: 10% ~ 20%; Ethanol: 10 ~ 20%.
2. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1, is characterized in that: described a kind of water-fast, UV light solidified luminous coating of high-flexibility for woodenware is prepared from by the raw material of following mass percent: standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture: 20%; Polyester acrylate resin: 5%; Initiator: 8%; Surface modifier: 1.5%; Solubility promoter: 7.5%; Reactive thinner: 18%; Long-acting noctilucent powder: 20%; Ethanol: 20%.
3. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1 and 2, it is characterized in that: described standard Bisphenol-A epoxy diacrylate and aliphatic polyurethane six acrylate mixture, both mass ratioes are 1:3 ~ 5.
4. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1 and 2, is characterized in that: described reactive thinner is ethyl acetate and diacrylate ester mixture, and both mass ratioes are 1.5 ~ 2.5:1.
5. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1 and 2, is characterized in that: described initiator is benzophenone, 1-hydroxycyclohexyl phenyl ketone or said mixture.
6. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1 and 2, is characterized in that: described surface modifier is silicone based, organic fluorine class or said mixture.
7. a kind of water-fast, the UV light solidified luminous coating of high-flexibility for woodenware according to claim 1 and 2, is characterized in that: described solubility promoter is alcohol ether solvents.
CN201410583477.7A 2014-10-28 2014-10-28 Waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware Pending CN104356922A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410583477.7A CN104356922A (en) 2014-10-28 2014-10-28 Waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410583477.7A CN104356922A (en) 2014-10-28 2014-10-28 Waterproof and high-flexibility ultraviolet-curable luminescent coating for wooden ware

Publications (1)

Publication Number Publication Date
CN104356922A true CN104356922A (en) 2015-02-18

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700854A (en) * 2015-11-15 2017-05-24 惠州市长润发涂料有限公司 Ultraviolet light curing anti-yellowing spray bright top-coat paint
CN112852283A (en) * 2021-02-24 2021-05-28 东莞大宝化工制品有限公司 Self-extinction UV wood coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101045833A (en) * 2007-04-11 2007-10-03 江苏工业学院 Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method
CN101693809A (en) * 2009-10-08 2010-04-14 广东三和化工科技有限公司 Long-acting noctilucent polyurethane hammer paint and preparation method thereof
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof
CN102993908A (en) * 2012-11-30 2013-03-27 上海长润发涂料有限公司 UV (Ultraviolet) white primer for electrostatic spraying
CN103044996A (en) * 2012-12-24 2013-04-17 东莞上海大学纳米技术研究院 Solvent-free ultraviolet (UV) curing photodiffusion coating material, preparation method and application of solvent-free UV curing photodiffusion coating material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101045833A (en) * 2007-04-11 2007-10-03 江苏工业学院 Preparation metod of modified ultroviolet light solidified wooden articles paint by in-situ method
CN101693809A (en) * 2009-10-08 2010-04-14 广东三和化工科技有限公司 Long-acting noctilucent polyurethane hammer paint and preparation method thereof
CN101967338A (en) * 2010-11-03 2011-02-09 苏州凯康化工科技有限公司 High gloss high abrasion resistance ultra-violet curing overprinting varnish of mobile phone and preparation method thereof
CN102993908A (en) * 2012-11-30 2013-03-27 上海长润发涂料有限公司 UV (Ultraviolet) white primer for electrostatic spraying
CN103044996A (en) * 2012-12-24 2013-04-17 东莞上海大学纳米技术研究院 Solvent-free ultraviolet (UV) curing photodiffusion coating material, preparation method and application of solvent-free UV curing photodiffusion coating material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106700854A (en) * 2015-11-15 2017-05-24 惠州市长润发涂料有限公司 Ultraviolet light curing anti-yellowing spray bright top-coat paint
CN112852283A (en) * 2021-02-24 2021-05-28 东莞大宝化工制品有限公司 Self-extinction UV wood coating and preparation method thereof
CN112852283B (en) * 2021-02-24 2022-04-19 东莞大宝化工制品有限公司 Self-extinction UV wood coating and preparation method thereof

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Application publication date: 20150218

RJ01 Rejection of invention patent application after publication