CN104356837B - A kind of metallic paint compositions and preparation method thereof - Google Patents

A kind of metallic paint compositions and preparation method thereof Download PDF

Info

Publication number
CN104356837B
CN104356837B CN201410714931.8A CN201410714931A CN104356837B CN 104356837 B CN104356837 B CN 104356837B CN 201410714931 A CN201410714931 A CN 201410714931A CN 104356837 B CN104356837 B CN 104356837B
Authority
CN
China
Prior art keywords
weight portion
paint compositions
metallic paint
zinc oxide
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410714931.8A
Other languages
Chinese (zh)
Other versions
CN104356837A (en
Inventor
李冰心
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUZHOU BINGXIN STATIONERY Co Ltd
Original Assignee
SUZHOU BINGXIN STATIONERY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUZHOU BINGXIN STATIONERY Co Ltd filed Critical SUZHOU BINGXIN STATIONERY Co Ltd
Priority to CN201410714931.8A priority Critical patent/CN104356837B/en
Publication of CN104356837A publication Critical patent/CN104356837A/en
Application granted granted Critical
Publication of CN104356837B publication Critical patent/CN104356837B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0856—Iron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of metallic paint compositions and preparation method thereof.This metallic paint compositions, is made up of the component comprising following weight portion: polymethyl acrylate 20 30 parts, 8 12 parts of water, zinc oxide 58 parts, lauryl alcohol 58 parts, metallic pigments 58 parts, propylene glycol monomethyl ether 23 parts and methyl triacetoxysilane 12 parts.Present invention also offers the preparation method of a kind of metallic paint compositions, comprise the following steps: (1) weighs polymethyl acrylate 20 30 weight portion, lauryl alcohol 58 weight portion, zinc oxide 58 weight portion, metallic pigments 58 weight portion and methyl triacetoxysilane 12 weight portion；(2) said components is added in homogenizer mix homogeneously at 60 75 DEG C, sequentially add water 8 12 weight portion, oil with hydrogenated soybean 02 weight portion and propylene glycol monomethyl ether 23 weight portion, high-speed stirred 10 15 minutes, under vacuum deaeration 12 hours, obtain metallic paint compositions.

Description

A kind of metallic paint compositions and preparation method thereof
Technical field
The present invention relates to a kind of metallic paint Material Field, particularly a kind of metallic paint compositions and preparation method thereof.
Background technology
Metallic pigments have metallic luster, mainly by metal, the granule of alloy or thin slice through levigate and prepared, by extensively General make decorative paint for coatings industry.
In recent years, metallic paint is mainly used in material surface, on the one hand plays good decorative effect, on the other hand also functions to Protection material surface is from infringements such as corrosion and scratches.Conventional corrosion resistant coating mainly has epoxy zinc-rich paint, owing to its color is close Metal true qualities, and the effect of protection metal surface can be played.But owing to the density of metal zinc is bigger, free settling, thus need To add a certain amount of sagging inhibitor in paint, due to the addition of anti-settling agent, the viscosity of paint is consequently increased, so that add Substantial amounts of toxic solvent, and lacquer coat is along with the change of environmental condition, and after solidification, the fragility of paint film becomes big, and metal becomes in temperature Expand with heat and contract with cold during change, easily cause alligatoring or come off.
Summary of the invention
For above-mentioned demand, invention especially provides a kind of metallic paint compositions and preparation method thereof.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of metallic paint compositions, is made up of the component comprising following weight portion:
The mixing of one or more in aluminium powder, copper powder, zinc powder and stainless steel powder of the described metallic pigments.
Described zinc oxide is nano-zinc oxide powder.
Described component also includes oil with hydrogenated soybean 0-2 weight portion.
The preparation method of a kind of metallic paint compositions, comprises the following steps:
(1) polymethyl acrylate 20-30 weight portion, lauryl alcohol 5-8 weight portion, zinc oxide 5-8 weight portion, metal face are weighed Material 5-8 weight portion and methyl triacetoxysilane 1-2 weight portion；
(2) said components is added in homogenizer mix homogeneously at 60-75 DEG C, sequentially add water 8-12 weight portion, Oil with hydrogenated soybean 0-2 weight portion and propylene glycol monomethyl ether 2-3 weight portion, high-speed stirred 10-15 minute, under vacuum deaeration 1- 2 hours, obtain metallic paint compositions.
The stir speed (S.S.) of described high-speed stirred is 1100-1250 rev/min.
Compared with prior art, it has the beneficial effect that the present invention
(1) the metallic paint compositions that the present invention prepares has excellent protective and binding ability, easy to use, and has Good dicoration.
(2) the metallic paint compositions of the present invention is in preparation process while need not add substantial amounts of solvent, still may be used Make the dispersive property that metallic pigments holding is good, and the ductility of the metallic paint compositions of the present invention is preferable, is not likely to produce crisp Property and obscission.
(3) the metallic paint compositions of the present invention, adhesive force is good, and service life is long, has good weatherability.
(4) preparation method of the metallic paint compositions of the present invention is simple, low cost, is suitable for large-scale production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) polymethyl acrylate 20kg, lauryl alcohol 8kg, nano-zinc oxide powder 6kg, aluminium powder 5kg and methyl three second are weighed Acyloxy silane 1kg；
(2) said components is added in homogenizer mix homogeneously at 60 DEG C, sequentially adds water 8kg, oil with hydrogenated soybean 2kg and propylene glycol monomethyl ether 2kg, stirs 15 minutes with the stir speed (S.S.)s of 1100 revs/min, deaeration 1 hour under vacuum, To metallic paint compositions.
The performance test results preparing metallic paint compositions is as shown in table 1.
Embodiment 2
(1) polymethyl acrylate 25kg, lauryl alcohol 5kg, nano-zinc oxide powder 8kg, copper powder 7kg and methyl three second are weighed Acyloxy silane 1kg；
(2) said components is added in homogenizer mix homogeneously at 75 DEG C, sequentially adds water 12kg, oil with hydrogenated soybean 1kg and propylene glycol monomethyl ether 3kg, stirs 10 minutes with the stir speed (S.S.)s of 1250 revs/min, deaeration 2 hours under vacuum, To metallic paint compositions.
The performance test results preparing metallic paint compositions is as shown in table 1.
Embodiment 3
(1) polymethyl acrylate 30kg, lauryl alcohol 7kg, nano-zinc oxide powder 5kg, stainless steel powder 8kg and methyl are weighed Triacetoxysilane 2kg；
(2) said components is added in homogenizer mix homogeneously at 70 DEG C, sequentially adds water 10kg and propylene glycol first Ether 2kg, stirs 10 minutes with the stir speed (S.S.)s of 1100 revs/min, deaeration 1 hour under vacuum, obtains metallic paint combination Thing.
The performance test results preparing metallic paint compositions is as shown in table 1.
Embodiment 4
(1) polymethyl acrylate 28kg, lauryl alcohol 5kg, nano-zinc oxide powder 8kg, zinc powder 5kg and methyl three second are weighed Acyloxy silane 1kg；
(2) said components is added in homogenizer mix homogeneously at 75 DEG C, sequentially adds water 12kg and propylene glycol first Ether 2kg, stirs 12 minutes with the stir speed (S.S.)s of 1200 revs/min, deaeration 2 hours under vacuum, obtains metallic paint combination Thing.
The performance test results preparing metallic paint compositions is as shown in table 1.
Table 1
Test event Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Free formaldehyde (g/kg) Do not detect Do not detect Do not detect Do not detect
Bond strength (MPa) 21.5 22.8 19.2 18.9

Claims (1)

1. a metallic paint compositions, it is characterised in that be made up of the component comprising following weight portion:
Polymethyl acrylate 20-30 part,
Water 8-12 part,
Zinc oxide 5-8 part,
Lauryl alcohol 5-8 part,
Metallic pigments 5-8 part,
Propylene glycol monomethyl ether 2-3 part,
Methyl triacetoxysilane 1-2 part；
The mixing of one or more in aluminium powder, copper powder, zinc powder and stainless steel powder of the described metallic pigments；
Described zinc oxide is nano-zinc oxide powder；
Described component also includes oil with hydrogenated soybean 0-2 weight portion；
Described a kind of metallic paint compositions is prepared by following preparation method:
(1) polymethyl acrylate 20-30 weight portion, lauryl alcohol 5-8 weight portion, zinc oxide 5-8 weight portion, metallic pigments 5-are weighed 8 weight portions and methyl triacetoxysilane 1-2 weight portion；
(2) said components is added in homogenizer mix homogeneously at 60-75 DEG C, sequentially adds water 8-12 weight portion, hydrogenation Soybean oil 0-2 weight portion and propylene glycol monomethyl ether 2-3 weight portion, high-speed stirred 10-15 minute, deaeration 1-2 is little under vacuum Time, obtain metallic paint compositions；
The stir speed (S.S.) of described high-speed stirred is 1100-1250 rev/min.
CN201410714931.8A 2014-12-01 2014-12-01 A kind of metallic paint compositions and preparation method thereof Expired - Fee Related CN104356837B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410714931.8A CN104356837B (en) 2014-12-01 2014-12-01 A kind of metallic paint compositions and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410714931.8A CN104356837B (en) 2014-12-01 2014-12-01 A kind of metallic paint compositions and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104356837A CN104356837A (en) 2015-02-18
CN104356837B true CN104356837B (en) 2016-08-31

Family

ID=52524159

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410714931.8A Expired - Fee Related CN104356837B (en) 2014-12-01 2014-12-01 A kind of metallic paint compositions and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104356837B (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106752649A (en) * 2016-12-30 2017-05-31 芜湖天鸿汽车零部件有限公司 A kind of automobile metal paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0883654A1 (en) * 1996-02-27 1998-12-16 BASF Coatings Aktiengesellschaft Colored metallic paint compositions and painted objects
CN1405246A (en) * 2002-07-10 2003-03-26 刘长源 Water-based metal paint
CN1439681A (en) * 2003-02-26 2003-09-03 广州市涂易得涂料制造有限公司 Aqueous metal paints preparation and paints therefrom
CN1648184A (en) * 2004-12-30 2005-08-03 肖海波 Nano fluorescent elastic water soluble metal lacquer
CN102911571A (en) * 2011-08-06 2013-02-06 郑修余 Aluminum powder paint and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0883654A1 (en) * 1996-02-27 1998-12-16 BASF Coatings Aktiengesellschaft Colored metallic paint compositions and painted objects
CN1405246A (en) * 2002-07-10 2003-03-26 刘长源 Water-based metal paint
CN1439681A (en) * 2003-02-26 2003-09-03 广州市涂易得涂料制造有限公司 Aqueous metal paints preparation and paints therefrom
CN1648184A (en) * 2004-12-30 2005-08-03 肖海波 Nano fluorescent elastic water soluble metal lacquer
CN102911571A (en) * 2011-08-06 2013-02-06 郑修余 Aluminum powder paint and preparation method thereof

Also Published As

Publication number Publication date
CN104356837A (en) 2015-02-18

Similar Documents

Publication Publication Date Title
CN102382550B (en) Solvent-free epoxy anticorrosion paint with corrosion restoration function and preparation method thereof
CN108047834B (en) Easily-oriented high-performance fluorine-silicon composite water-based aluminum powder paint and preparation method thereof
CN102604535A (en) High-temperature-resisting aluminum paint used on steel surface, and preparation method thereof
CN103483983B (en) A kind of epoxy zinc rich primer and preparation method thereof
CN104119470B (en) Anticorrosive paint is by acrylic resin modified, the preparation method of copper surface anticorrosion coating
CA2906317A1 (en) Ambient curable corrosion resistant sol-gel coating and composition and process for making the same
CN102993859A (en) Zinc powder-free shop primer and preparation method thereof
CN107446480A (en) Has cohesive coating and preparation method thereof to ground
CN105419569A (en) Humidity-heat-resistant long-acting anticorrosion coating
CN104356837B (en) A kind of metallic paint compositions and preparation method thereof
CN115651537A (en) High-temperature-resistant anticorrosive paint and preparation method and application thereof
CN110791197A (en) Formula and preparation method of low-VOC (volatile organic compound) water-based silver powder baking paint
CN105855457A (en) Mold release agent for casting of mobile phone magnesium alloy middle plate and preparation method of mold release agent for casting of mobile phone magnesium alloy middle plate
CN105419409A (en) High-temperature-fuel-gas-washing-resistant coating and preparation method and application thereof
CN104131293A (en) Polishing fluid for polishing metal surfaces and preparation method thereof
CN103484193A (en) Hard film rust preventive
CN104212332B (en) A kind of epoxy aluminum-rich coatings and preparation method thereof
CN101117513A (en) Method for preparing metal surface anticorrosive paint
CN101875796A (en) Paint remover formula
CN109161316B (en) Coating with good surface adhesion and preparation method and application thereof
CN103965751B (en) A kind of super organic solvent-resistant type baked paint and preparation method thereof
CN107573456B (en) High-adhesion benzene-free hydroxyl acrylic resin and preparation method thereof
CN102312130A (en) Quinary alloy hot-dip coating raw material preparation and application method
CN104673044B (en) Ageing resistant steel surface coating material and preparation method thereof
CN105294136A (en) Coating for sintering of hard alloy

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160831

Termination date: 20161201