CN104356816B - A kind of anticorrosive paint - Google Patents
A kind of anticorrosive paint Download PDFInfo
- Publication number
- CN104356816B CN104356816B CN201410751549.4A CN201410751549A CN104356816B CN 104356816 B CN104356816 B CN 104356816B CN 201410751549 A CN201410751549 A CN 201410751549A CN 104356816 B CN104356816 B CN 104356816B
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- parts
- anticorrosive paint
- agent
- coalescents
- coating
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- 239000003973 paint Substances 0.000 title claims abstract description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- -1 phenolic aldehyde amine Chemical class 0.000 claims abstract description 12
- 239000000375 suspending agent Substances 0.000 claims abstract description 12
- 239000007767 bonding agent Substances 0.000 claims abstract description 10
- 239000013530 defoamer Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 9
- 150000001298 alcohols Chemical class 0.000 claims abstract description 9
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 7
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 9
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 9
- 239000000440 bentonite Substances 0.000 claims description 9
- 229910000278 bentonite Inorganic materials 0.000 claims description 9
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 9
- 229920001568 phenolic resin Polymers 0.000 claims description 9
- 239000005011 phenolic resin Substances 0.000 claims description 9
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 claims description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 230000004048 modification Effects 0.000 claims description 5
- 238000012986 modification Methods 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 abstract description 22
- 238000000576 coating method Methods 0.000 abstract description 22
- 230000002421 anti-septic effect Effects 0.000 abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 5
- 239000011593 sulfur Substances 0.000 abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 4
- 150000007513 acids Chemical class 0.000 abstract description 4
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003643 water by type Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 description 14
- 238000003756 stirring Methods 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 4
- 238000005987 sulfurization reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of anticorrosive paint, count by weight, be made up of 50 60 parts of zinc acrylate resin, 10 15 parts of coalescents, 10 20 parts of magnesium oxide, 12 22 parts of silicon oxides, 12 parts of ferrum oxides, 58 parts of toluenesulfonic acids, 58 parts of calcium carbonate, 23 parts of suspending agents, 35 parts of alcohols solvents, 12 parts of bonding agents, 46 parts of phenolic aldehyde amine, 12 parts of nitrile rubbers, 0.7 1.2 parts of thickening agents, 0.5 1 parts of defoamer, 0.4 0.8 parts of levelling agents and 20 30 parts of deionized waters.The sulfur resistance of the coating of the present invention is good, antiseptic property is good.
Description
Technical field
The present invention relates to a kind of anticorrosive paint.
Background technology
For some base material, when its exposed outside time, because being corroded by the material in air, base material is easy to cure, thus affects the mechanics of base material, heat-resisting, weather-proof, wear-resisting and decay resistance etc..For this technical problem, how to reduce the sulfuration to base material now with a lot of people in research.One way in which is sprayed coating on base material, and as disclosed a kind of sulfuration resistant coating in the patent documentation of Application No. 200610078245.1, although studying the coating of this aspect now with a lot of people, but the sulfuration resistant of coating could be improved at present.For coating, if antiseptic property is poor, then the effect duration of coating is difficult to ensure that.
Summary of the invention
In order to improve sulfuration resistant performance, improve antiseptic property, the invention provides a kind of anticorrosive paint.
For reaching above-mentioned purpose, a kind of anticorrosive paint, count by weight, be made up of 50-60 part zinc acrylate resin, 10-15 part coalescents, 10-20 part magnesium oxide, 12-22 part silicon oxide, 1-2 part ferrum oxide, 5-8 part toluenesulfonic acid, 5-8 part calcium carbonate, 2-3 part suspending agent, 3-5 part alcohols solvent, 1-2 part bonding agent, 4-6 part phenolic aldehyde amine, 1-2 part nitrile rubber, 0.7-1.2 part thickening agent, 0.5-1 part defoamer, 0.4-0.8 part levelling agent and 20-30 part deionized water.
Further, described coalescents is butyl glycol ether.
Further, described suspending agent is lithium bentonite.
Further, described bonding agent be ratio of weight and number be phenolic resin and the Colophonium of 3:1.
Further, described thickening agent is polyvinyl butyral.
Further, described defoamer is broken bubble polysiloxane solution.
Further, described levelling agent is terminal groups modification organosilicon.
The invention has the beneficial effects as follows: after coating is sprayed onto on base material, when the sulfur in air touches paint film, under the effect of toluenesulfonic acid, the product that zinc acrylate resin, magnesium oxide generate after reacting with sulfurous gas remains in coating, prevents sulfurous gas directly to contact with substrate interface.It is suspending agent with lithium bentonite, this bentonite is with natural calcium base bentonite as raw material, through a kind of mineral material that artificial lithiumation modification is prepared, it can form colloidal material with alcohols solvent under the initiation of deionized water, the expansion thickening ability obtained, phenolic resin and Colophonium is selected to make binding agent, phenolic resin room temperature cohesive force is strong, coating can be made to obtain high normal temperature surface intensity, but gas forming amount is bigger, addition big coating when lighting easy to crack and easily cause base material produce gas hole defect, Colophonium is the most easy to crack after coating is lighted.Therefore, use phenolic resin and a small amount of Colophonium with the use of, be possible not only to reduce the addition of binding agent, improve the adhesion strength of coating, and carrier viscosity can be improved so that it is sulfur resistance is more preferable.Phenolic aldehyde amine as firming agent, can fast setting at low ambient temperatures, and there is good antiseptic property.The membership that adds of a small amount of nitrile rubber improves antiseptic property further, improves impact resistance.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further elaborated.
Anticorrosive paint, count by weight, be made up of 50-60 part zinc acrylate resin, 10-15 part coalescents, 10-20 part magnesium oxide, 12-22 part silicon oxide, 1-2 part ferrum oxide, 5-8 part toluenesulfonic acid, 5-8 part calcium carbonate, 2-3 part suspending agent, 3-5 part alcohols solvent, 1-2 part bonding agent, 4-6 part phenolic aldehyde amine, 1-2 part nitrile rubber, 0.7-1.2 part thickening agent, 0.5-1 part defoamer, 0.4-0.8 part levelling agent and 20-30 part deionization.Described coalescents is butyl glycol ether.Described suspending agent is lithium bentonite.Described bonding agent be ratio of weight and number be phenolic resin and the Colophonium of 3:1.Described thickening agent is polyvinyl butyral.Described defoamer is broken bubble polysiloxane solution.Described levelling agent is terminal groups modification organosilicon.
Embodiment 1.
(1) weigh 10 parts of coalescents, 10 parts of magnesium oxide, 12 parts of silicon oxides, 1 part of ferrum oxide, 5 parts of toluenesulfonic acids, 5 parts of calcium carbonate, 2 parts of suspending agents, 3 parts of alcohols solvents, 1 part of bonding agent and 20 parts of deionized waters to stir under the rotating speed of the temperature 400 ~ 800r/min of 60-70 DEG C.
(2) weigh 50 parts of zinc acrylate resin, 4 parts of phenolic aldehyde amine, 1 part of nitrile rubber, joined in step (1), and in the water-bath of 90-110 DEG C, react 25-35min while stirring.
(3) weigh 0.7 part of thickening agent, 0.5 part of defoamer, 0.4 part of levelling agent join in step (2), under 200 ~ 400r/min speed conditions, stir 10 ~ 13 minutes；Through being filtrated to get coating.
Embodiment 2.
(1) weigh 15 parts of coalescents, 20 parts of magnesium oxide, 22 parts of silicon oxides, 2 parts of ferrum oxides, 8 parts of toluenesulfonic acids, 8 parts of calcium carbonate, 3 parts of suspending agents, 5 parts of alcohols solvents, 2 parts of bonding agents and 30 parts of deionized waters to stir under the rotating speed of the temperature 400 ~ 800r/min of 60-70 DEG C.
(2) weigh 60 parts of zinc acrylate resin, 6 parts of phenolic aldehyde amine, 2 parts of nitrile rubbers, joined in step (1), and in the water-bath of 90-110 DEG C, react 25-35min while stirring.
(3) weigh 1.2 parts of thickening agents, 1 part of defoamer, 0.8 part of levelling agent join in step (2), under 200 ~ 400r/min speed conditions, stir 10 ~ 13 minutes；Through being filtrated to get coating.
Embodiment 3.
(1) weigh 12 parts of coalescents, 15 parts of magnesium oxide, 17 parts of silicon oxides, 1.5 parts of ferrum oxides, 6.5 parts of toluenesulfonic acids, 7 parts of calcium carbonate, 4 parts of alcohols solvents of 2.5 parts of suspending agents, 1.5 parts of bonding agents and 25 parts of deionized waters to stir under the rotating speed of the temperature 400 ~ 800r/min of 60-70 DEG C.
(2) weigh 55 parts of zinc acrylate resin, 5 parts of phenolic aldehyde amine, 1.5 parts of nitrile rubbers, joined in step (1), and in the water-bath of 90-110 DEG C, react 25-35min while stirring.
(3) weigh 0.9 part of thickening agent, 0.8 part of defoamer, 0.6 part of levelling agent join in step (2), under 200 ~ 400r/min speed conditions, stir 10 ~ 13 minutes；Through being filtrated to get coating.
In the present invention, after coating is sprayed onto on base material, when the sulfur in air touches paint film, under the effect of toluenesulfonic acid, the product that zinc acrylate resin, magnesium oxide generate after reacting with sulfurous gas remains in coating, prevents sulfurous gas directly to contact with substrate interface.It is suspending agent with lithium bentonite, this bentonite is with natural calcium base bentonite as raw material, through a kind of mineral material that artificial lithiumation modification is prepared, it can form colloidal material with alcohols solvent under the initiation of deionized water, the expansion thickening ability obtained, phenolic resin and Colophonium is selected to make binding agent, phenolic resin room temperature cohesive force is strong, coating can be made to obtain high normal temperature surface intensity, but gas forming amount is bigger, addition big coating when lighting easy to crack and easily cause base material produce gas hole defect, Colophonium is the most easy to crack after coating is lighted.Therefore, use phenolic resin and a small amount of Colophonium with the use of, be possible not only to reduce the addition of binding agent, improve the adhesion strength of coating, and carrier viscosity can be improved so that it is sulfur resistance is more preferable.Phenolic aldehyde amine as firming agent, can fast setting at low ambient temperatures, and there is good antiseptic property.The membership that adds of a small amount of nitrile rubber improves antiseptic property further, improves impact resistance.
Claims (6)
1. an anticorrosive paint, it is characterized in that: count by weight, be made up of 50-60 part zinc acrylate resin, 10-15 part coalescents, 10-20 part magnesium oxide, 12-22 part silicon oxide, 1-2 part ferrum oxide, 5-8 part toluenesulfonic acid, 5-8 part calcium carbonate, 2-3 part suspending agent, 3-5 part alcohols solvent, 1-2 part bonding agent, 4-6 part phenolic aldehyde amine, 1-2 part nitrile rubber, 0.7-1.2 part thickening agent, 0.5-1 part defoamer, 0.4-0.8 part levelling agent and 20-30 part deionized water；Described bonding agent be ratio of weight and number be phenolic resin and the Colophonium of 3:1.
Anticorrosive paint the most according to claim 1, it is characterised in that: described coalescents is butyl glycol ether.
Anticorrosive paint the most according to claim 1, it is characterised in that: described suspending agent is lithium bentonite.
Anticorrosive paint the most according to claim 1, it is characterised in that: described thickening agent is polyvinyl butyral.
Anticorrosive paint the most according to claim 1, it is characterised in that: described defoamer is broken bubble polysiloxane solution.
Anticorrosive paint the most according to claim 1, it is characterised in that: described levelling agent is terminal groups modification organosilicon.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410751549.4A CN104356816B (en) | 2014-12-10 | 2014-12-10 | A kind of anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410751549.4A CN104356816B (en) | 2014-12-10 | 2014-12-10 | A kind of anticorrosive paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104356816A CN104356816A (en) | 2015-02-18 |
| CN104356816B true CN104356816B (en) | 2016-09-14 |
Family
ID=52524138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410751549.4A Active CN104356816B (en) | 2014-12-10 | 2014-12-10 | A kind of anticorrosive paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104356816B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107439260A (en) * | 2017-06-30 | 2017-12-08 | 中山诺顿科研技术服务有限公司 | Do benefit to planting of dragon fruit growth and use support |
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| CN106978015A (en) * | 2017-05-04 | 2017-07-25 | 冯志容 | A kind of anticorrosive paint |
| CN107158870A (en) * | 2017-06-30 | 2017-09-15 | 陈伟景 | A kind of novel deduster for Feed Manufacturing |
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Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2468825A1 (en) * | 2010-12-21 | 2012-06-27 | Akzo Nobel Coatings International B.V. | Antifouling coating composition |
| CN103289007B (en) * | 2013-04-12 | 2015-09-30 | 中国科学院烟台海岸带研究所 | A kind of zinc acrylate resin/resin of copper preparation method of improvement |
| CN103897092B (en) * | 2014-03-24 | 2017-01-04 | 海洋化工研究院有限公司 | The preparation of acrylic acid zinc-type self polishing copolymer antifouling paint matrix resin and application |
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2014
- 2014-12-10 CN CN201410751549.4A patent/CN104356816B/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107439260A (en) * | 2017-06-30 | 2017-12-08 | 中山诺顿科研技术服务有限公司 | Do benefit to planting of dragon fruit growth and use support |
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| Publication number | Publication date |
|---|---|
| CN104356816A (en) | 2015-02-18 |
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Effective date of registration: 20170522 Address after: 510800 East Village, North Hing town, Huadu District, Guangdong, Guangzhou Patentee after: Guangzhou advance new material development Co., Ltd. Address before: Huadu Village No. 57 Xinhua Town Huadu District 510800 road construction in Guangdong province Guangzhou city 9-508 Patentee before: Li Yongzhi |
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