CN104356788A - Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof - Google Patents

Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof Download PDF

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Publication number
CN104356788A
CN104356788A CN201410667855.XA CN201410667855A CN104356788A CN 104356788 A CN104356788 A CN 104356788A CN 201410667855 A CN201410667855 A CN 201410667855A CN 104356788 A CN104356788 A CN 104356788A
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China
Prior art keywords
paint
agent
tangerine line
line effect
weight
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Pending
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CN201410667855.XA
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Chinese (zh)
Inventor
胡基如
张志宏
丁力
宋梓琪
王红梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN GRANDLAND ENVIRONMENT PROTECTION PAINT CO Ltd
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SHENZHEN GRANDLAND ENVIRONMENT PROTECTION PAINT CO Ltd
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Publication date
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Priority to CN201410667855.XA priority Critical patent/CN104356788A/en
Publication of CN104356788A publication Critical patent/CN104356788A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to an orange-peel-effect fluorocarbon paint, and a preparation method and application method thereof. The main agent is composed of the following components in parts by weight: 50.0-60.0 parts of fluororesin, 0.5-1.5 parts of dispersing agent, 0.6-1.0 part of anti-settling agent, 20.0-30.0 parts of rutile titanium white, 0.2-0.4 part of defoaming agent, 15.0-25.0 parts of mixed solvent, 0-6 parts of matting powder and 0.4-0.8 part of orange peel agent. The curing agent is composed of the following components in parts by weight: 80.0 parts of HDI (hexamethylene diisocyanate) curing agent and 20.0 parts of butyl acetate. The weight ratio of the hydroxyl value of the fluororesin to the NCO content of the curing agent (OH:NCO) is 1:(1.05-1.15). The fluorocarbon paint can directly display the realistic orange peel effect, and can select the thickness, brightness and matting degree of the orange peel according to needs, thereby omitting the galling paint in the prior art and saving the material cost and procedure.

Description

A kind of tangerine line effect F-C paint and preparation method thereof and using method
Technical field
The present invention relates to a kind of F-C paint, especially relate to a kind of cold cross-linking type tangerine line effect F-C paint and preparation method thereof and using method.
Background technology
Cold cross-linking type F-C paint is in the application of external wall, experienced by extreme imitation aluminium plate effect coating process, due to China's painting site construction management present situation, be difficult to strict implement construction proportioning and construction technology, generally there is coating cracking phenomenon in imitative aluminium sheet application, causes very large puzzlement to F-C paint industry.People are one after another from change construction technology, and application fluorine carbon finishing paint on various texture coating, to obtain the texture effect of various personalization, to solve the problem of coating cracking simultaneously, keeps the advantage of F-C paint excellent weather resistance again.But prior art is for realizing tangerine line effect, and need to be coated with one deck elastomeric gigging paint on priming paint, then paint spray paint at elastic napping, so cause cost to increase, operation also increases thereupon, finish paint unstable properties simultaneously, weakens tangerine line effect greatly.Based on the consideration of texture effect and cost, now need badly after F-C paint is constructed and directly present tangerine line effect, direct application F-C paint on traditional priming paint, to obtain tangerine line effect paint film true to nature.
Summary of the invention
After the technical problem to be solved in the present invention is to provide a kind of construction, paint film directly presents the cold cross-linking type F-C paint of tangerine line effect true to nature.Meanwhile, the present invention also provides preparation method and the using method of this tangerine line effect F-C paint.
For solving the problems of the technologies described above, the invention provides a kind of tangerine line effect F-C paint, its host is made up of the component of following parts by weight:
The solidifying agent of described tangerine line effect F-C paint is made up of the component of following parts by weight:
HDI solidifying agent 80.0
Butylacetate 20.0
The weight proportion of described host and solidifying agent calculates according to the hydroxyl value of fluoro-resin and the NCO content of solidifying agent and their parts by weight in formula, gets OH:NCO=1:(1.05-1.15).
As optimal way, described fluoro-resin is the quarternary copolymerized resin of trifluorochloroethylene or tetrafluoroethylene and vinyl monomer, carboxylic monomer and carboxylic monomer, and its Oil repellent is more than or equal to 20%.
As optimal way, described dispersion agent is the high molecular weight block copolymer solution containing affine pigment group.
As optimal way, described anti-settling agent is organobentonite, and described flatting silica is silicon-dioxide flatting silica.
As optimal way, described defoamer is broken bubble polysiloxane solution.
As optimal way, described mixed solvent is the mixture of propylene glycol methyl ether acetate, butylacetate, valeric acid dimethyl ester.
As optimal way, the agent of described tangerine line is high molecular weight silicone or its solution.
As optimal way, described fluoro-resin is large King Company GK570 or middle vast and boundless JF-2X or Asahi Glass LF200;
Described dispersion agent is BYK-163;
Described anti-settling agent is this SD-1 of hamming;
Described defoamer is BYK-066N;
Described titanium dioxide is U.S. gift connection RCL-595 or Du Pont R-706 or peaceful titanium NTR-606;
The agent of described tangerine line is Zhong Shan Yongfeng chemical industry GHDY-1800;
Described flatting silica is SY7000.
The present invention also provides the preparation method of tangerine line effect F-C paint described in a kind of claim 1, comprises the steps:
Step one, colo(u)rant dispersion, taking fluoro-resin by about 80% of titanium dioxide weight in formula adds in dispersion cylinder, then dispersion agent is added, 3 minutes are disperseed with the rotating speed of 600-800RMP, add defoamer again, 5 minutes are disperseed with the rotating speed of 600-800RMP, then anti-settling agent is added, 5 minutes are disperseed with the rotating speed of 1200-1500RMP, then under the stirring of about 400RMP rotating speed, slowly add titanium dioxide, after adding titanium dioxide, within 15-20 minute, be less than or equal to 25 μm to fineness with the dispersion of the rotating speed of 1200-1500RMP;
The preparation of step 2, F-C paint, adds remaining fluoro-resin and mixed solvent, and stir 10-15 minute under the rotating speed of about 400RMP in the titanium dioxide slurry of step one gained, obtains light white F-C paint; Add the flatting silica of the component of specifying, high speed dispersion 15 minutes, namely obtain the dumb light white F-C paint of corresponding gloss.
The preparation of step 3, tangerine line F-C paint, the white F-C paint that step 2 obtains stirs and adds the agent of tangerine line under the rotating speed of 400-600RMP, then stirs under the rotating speed of about 400RMP and within about 5 minutes, namely obtains tangerine line effect F-C paint.
The present invention also provides the using method of tangerine line effect F-C paint described in a kind of claim 1, tangerine line effect F-C paint host is mixed by proportioning with solidifying agent, and add the thinner of host weight 20 ~ 30%, mix, make viscosity reach 30 ~ 40s/ and be coated with 4# cup, then carry out spraying application, sprayed seasoning, namely obtain tangerine line effect F-C paint paint film;
Wherein, described thinner is made up of the component of following weight ratio:
Dimethylbenzene 30
Butylacetate 40
1-Methoxy-2-propyl acetate 30.
Tangerine line effect F-C paint tool of the present invention has the following advantages:
1, outward appearance directly presents tangerine line effect true to nature, can select tangerine line thickness and light, dumb light degree as required, meets the different demands of market to F-C paint outward appearance.Be painted on priming paint, eliminate plucking paint of the prior art, save material cost and operation, improve operating efficiency, be conducive to keeping the performances such as its weathering resistance simultaneously, be conducive to increasing the service life.
2, functional, after testing, the finish paint such as weathering resistance, resistance to acids and bases performance all meets the requirements.
3, prepare, easy construction, tangerine line effect F-C paint of the present invention only needs cold cross-linking to solidify, can site operation, is widely used in the application of construction exterior paint and various building and ornament materials.
Embodiment
Below by embodiment, technical scheme of the present invention is described further.
Each component of the present invention all adopts currently available products.Wherein, dispersion agent is the high molecular weight block copolymer solution containing affine pigment group.Fluoro-resin is the quarternary copolymerized resin of trifluorochloroethylene or tetrafluoroethylene and vinyl monomer, carboxylic monomer and carboxylic monomer, and its Oil repellent is more than or equal to 20%.Anti-settling agent is organobentonite.Defoamer is broken bubble polysiloxane solution.Flatting silica is silicon-dioxide flatting silica.The agent of tangerine line is high molecular weight silicone or its solution.Mixed solvent can be selected strong to fluoro-resin solvency power and belong to environmentally friendly solvent, as the mixture of propylene glycol methyl ether acetate (PMA), butylacetate, valeric acid dimethyl ester etc.
Embodiment 1
Get each component by weight shown in embodiment in table one 1, prepare in accordance with the following steps:
Step one: take 16kgGK570 fluoro-resin and add in dispersion cylinder, then 0.5kgBYK-163 dispersion agent is added, middling speed (600-800RMP) disperses 3 minutes, add 0.2kgBYK-066N defoamer again, middling speed disperses 5 minutes, then 0.6kgSD-1 anti-settling agent is added, (1200-1500RMP) disperses 5 minutes at a high speed, then under low speed (about 400RMP) stirs, slowly add 20kgRCL-595 titanium dioxide, add high speed dispersion 15-20 minute and be less than or equal to 25 μm to fineness.
Step 2: add remaining 34kgGK570 fluoro-resin and 5kg butylacetate, 7kg propylene glycol methyl ether acetate, 3kg valeric acid dimethyl ester in the titanium dioxide slurry of step one, and low speed (about 400RMP) stirs 10-15 minute.Then add 2kgSY7000 flatting silica, (1200-1500RMP) disperses 15 minutes at a high speed, namely obtains half dumb light white F-C paint.
Step 3: low speed (400-600RMP) adds 0.4kg tangerine line agent GHDY-1800 under stirring in the half dumb light white F-C paint that step 2 obtains, add rear continuation low speed (about 400RMP) and stir 5 minutes, namely obtain tangerine line effect F-C paint by 120 order filter screen filtration.
Prepare solidifying agent of the present invention: fully mixed by anhydrous for TKA-75B9.4kg and 2.4kg butyl ester by weight proportion in formula, filter and package and obtain the solidifying agent of the present embodiment with 200 mesh filter screens.
The thinner that preparation the present invention is supporting: 30kg dimethylbenzene, 40kg butylacetate, 30kg 1-Methoxy-2-propyl acetate are added in production container, low speed (about 400RMP) stirs 5-10 minute, and 200 mesh filter screens filter and package the diluent namely obtaining described tangerine line effect F-C paint.
Tangerine line effect F-C paint host of the present invention, solidifying agent, thinner are mixed by weight 88.7:11.8:18, makes viscosity reach 37s/ and be coated with 4# cup, then carry out spraying application, spraying air pressure 2 ~ 2.5kg/cm 2.Spray seasoning and namely obtained tangerine line effect F-C paint paint film, do solid work 24 hours under normal temperature, complete drying 7 days.The performance index that can reach are as shown in embodiment in table two 1 corresponding data.
Embodiment 2
Get each component according to weight shown in embodiment in table one 2, repeat the method described in embodiment 1, prepare tangerine line effect F-C paint host, solidifying agent and thinner.According to host: solidifying agent: the weight ratio of thinner=106.7:8.7:25 mixes, viscosity 34s, then to construct according to the method for embodiment 1, dry.Performance test results is as shown in embodiment in table two 2 corresponding data.
Embodiment 3
Get each component according to weight shown in embodiment in table one 3, repeat the method described in embodiment 1, prepare tangerine line effect F-C paint host, solidifying agent and thinner.According to host: solidifying agent: the weight ratio of thinner=124.7:12.4:35 mixes, viscosity 32s, then to construct according to the method for embodiment 1, dry.Performance test results is as shown in embodiment in table two 3 corresponding data.
The tangerine line effect F-C paint more than obtained also can be mixed colours, and adds appropriate F-C paint special-used colour starch, can obtain the tangerine line effect F-C paint of various required color.Matting agent can be selected to add as required, if do not add matting agent, then will obtain light white F-C paint.
Tangerine line effect F-C paint of the present invention only needs cold cross-linking to solidify, can site operation, is widely used in the application of construction exterior paint and various building and ornament materials.
The component that embodiment 1 ~ 3 is selected and weight part and each component model be as shown in Table 1:
Table one
The performance index of embodiment 1 ~ 3 are as shown in Table 2:
Table two

Claims (10)

1. a tangerine line effect F-C paint, is characterized in that, its host is made up of the component of following parts by weight:
The solidifying agent of described tangerine line effect F-C paint is made up of the component of following parts by weight:
HDI solidifying agent 80.0
Butylacetate 20.0
The weight proportion of described host and solidifying agent calculates according to the hydroxyl value of fluoro-resin and the NCO content of solidifying agent and their parts by weight in formula, gets OH:NCO=1:(1.05-1.15).
2. a kind of tangerine line effect F-C paint according to claim 1, it is characterized in that, described fluoro-resin is the quarternary copolymerized resin of trifluorochloroethylene or tetrafluoroethylene and vinyl monomer, carboxylic monomer and carboxylic monomer, and its Oil repellent is more than or equal to 20%.
3. a kind of tangerine line effect F-C paint according to claim 1, is characterized in that, described dispersion agent is the high molecular weight block copolymer solution containing affine pigment group.
4. a kind of tangerine line effect F-C paint according to claim 1, it is characterized in that, described anti-settling agent is organobentonite, and described flatting silica is silicon-dioxide flatting silica.
5. a kind of tangerine line effect F-C paint according to claim 1, is characterized in that, described defoamer is broken bubble polysiloxane solution.
6. a kind of tangerine line effect F-C paint according to claim 1, it is characterized in that, described mixed solvent is the mixture of propylene glycol methyl ether acetate, butylacetate, valeric acid dimethyl ester.
7. a kind of tangerine line effect F-C paint according to claim 1, it is characterized in that, the agent of described tangerine line is high molecular weight silicone or its solution.
8. a kind of tangerine line effect F-C paint according to claim 1, is characterized in that, described fluoro-resin is large King Company GK570 or middle vast and boundless JF-2X or Asahi Glass LF200;
Described dispersion agent is BYK-163;
Described anti-settling agent is this SD-1 of hamming;
Described defoamer is BYK-066N;
Described titanium dioxide is U.S. gift connection RCL-595 or Du Pont R-706 or peaceful titanium NTR-606;
The agent of described tangerine line is Zhong Shan Yongfeng chemical industry GHDY-1800;
Described flatting silica is SY7000.
9. a preparation method for tangerine line effect F-C paint described in claim 1, is characterized in that, comprise the steps:
Step one, colo(u)rant dispersion, taking fluoro-resin by about 80% of titanium dioxide weight in formula adds in dispersion cylinder, then dispersion agent is added, 3 minutes are disperseed with the rotating speed of 600-800RMP, add defoamer again, 5 minutes are disperseed with the rotating speed of 600-800RMP, then anti-settling agent is added, 5 minutes are disperseed with the rotating speed of 1200-1500RMP, then under the stirring of about 400RMP rotating speed, slowly add titanium dioxide, after adding titanium dioxide, within 15-20 minute, be less than or equal to 25 μm to fineness with the dispersion of the rotating speed of 1200-1500RMP;
The preparation of step 2, F-C paint, adds remaining fluoro-resin and mixed solvent, and stir 10-15 minute under the rotating speed of about 400RMP in the titanium dioxide slurry of step one gained, obtains light white F-C paint; Add the flatting silica of the component of specifying, high speed dispersion 15 minutes, namely obtain the dumb light white F-C paint of corresponding gloss.
The preparation of step 3, tangerine line F-C paint, the white F-C paint that step 2 obtains stirs and adds the agent of tangerine line under the rotating speed of 400-600RMP, then stirs under the rotating speed of about 400RMP and within about 5 minutes, namely obtains tangerine line effect F-C paint.
10. the using method of tangerine line effect F-C paint described in a claim 1, it is characterized in that, tangerine line effect F-C paint host is mixed by proportioning with solidifying agent, and add the thinner of host weight 20 ~ 30%, mix, make viscosity reach 30 ~ 40s/ and be coated with 4# cup, then carry out spraying application, spray seasoning, namely obtain tangerine line effect F-C paint paint film;
Wherein, described thinner is made up of the component of following weight ratio:
Dimethylbenzene 30
Butylacetate 40
1-Methoxy-2-propyl acetate 30.
CN201410667855.XA 2014-11-20 2014-11-20 Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof Pending CN104356788A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410667855.XA CN104356788A (en) 2014-11-20 2014-11-20 Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof

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Application Number Priority Date Filing Date Title
CN201410667855.XA CN104356788A (en) 2014-11-20 2014-11-20 Orange-peel-effect fluorocarbon paint, and preparation method and application method thereof

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Publication Number Publication Date
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603361A (en) * 2017-10-22 2018-01-19 惠州市阿斯顿涂料有限公司 A kind of long-acting weather resistance fluorocarbon coating
CN109337429A (en) * 2018-08-03 2019-02-15 广东中星科技股份有限公司 A kind of aqueous mallear stria agent and the aqueous polyurethane paint using mallear stria agent
CN111218191A (en) * 2020-03-02 2020-06-02 佛山市顺德区千之彩实业有限公司 Metal powder coating and preparation process thereof

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603361A (en) * 2017-10-22 2018-01-19 惠州市阿斯顿涂料有限公司 A kind of long-acting weather resistance fluorocarbon coating
CN109337429A (en) * 2018-08-03 2019-02-15 广东中星科技股份有限公司 A kind of aqueous mallear stria agent and the aqueous polyurethane paint using mallear stria agent
CN111218191A (en) * 2020-03-02 2020-06-02 佛山市顺德区千之彩实业有限公司 Metal powder coating and preparation process thereof

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