CN104356746A - Wear-resistant printing ink for plastic and glass - Google Patents

Wear-resistant printing ink for plastic and glass Download PDF

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Publication number
CN104356746A
CN104356746A CN201410541201.2A CN201410541201A CN104356746A CN 104356746 A CN104356746 A CN 104356746A CN 201410541201 A CN201410541201 A CN 201410541201A CN 104356746 A CN104356746 A CN 104356746A
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CN
China
Prior art keywords
ink
parts
dehydrated alcohol
cyanuric acid
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410541201.2A
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Chinese (zh)
Inventor
韩聂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI AOYA ALLOY Co Ltd
Original Assignee
ANHUI AOYA ALLOY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI AOYA ALLOY Co Ltd filed Critical ANHUI AOYA ALLOY Co Ltd
Priority to CN201410541201.2A priority Critical patent/CN104356746A/en
Publication of CN104356746A publication Critical patent/CN104356746A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention relates to the field of printing ink, in particular to wear-resistant printing ink for plastic and glass. The ink is prepared from raw materials in parts by weight as follows: 0.1-0.2 parts of molybdenum powder, 5-10 parts of 2-ethylhexyl acrylate, 0.01-0.02 parts of vitamin E, 10-15 parts of glycerol triacetate, 0.01-0.02 parts of cyanuric acid, 25-35 parts of polycarbonate resin, 10-13 parts of ethyl acetate, 5-8 parts of absolute ethyl alcohol, 8-15 parts of pigment, 1-2 parts of sodium lignin sulfonate and 1-2 parts of an additive. According to the ink, the polycarbonate resin is taken as a binder and has good bonding capacity, the vitamin E can promote the ultraviolet radiation aging yellowing resistance of the ink, the components such as the molybdenum powder, the cyanuric acid and the like can improve the wear resistance, the coating property and the like of an ink coating, the additive can improve the wettability of the ink and prevent coating bubbles from affecting the decoration effect, and during usage, the ink can be attached to surfaces of various plastic and glass base materials and is particularly applicable to the outdoor environment due to the good comprehensive performance.

Description

A kind of anti abrasive resin glass printing-ink
Technical field
The present invention relates to printing-ink field, be specifically related to a kind of anti abrasive resin glass printing-ink.
Background technology
Ink is a class coloured material very conventional in daily life, it is by the mode of the printing carrier as word and pattern, it is the gluey fluid of a kind of stickiness, be widely used in the various printings such as books and periodicals, packing and decorating, building decoration, along with social demand increases, ink kind and output is respective extension and growth also, improves the use properties of ink, and the production model reaching efficient energy-saving is the inevitable direction of following ink development all the time.
The factor affecting the use properties of ink is mainly the performance of the moietys such as pigment, low-melting ink vehicle, stopping composition and auxiliary agent, and such as pigment affects weather resistance and the tinting strength of ink; Low-melting ink vehicle directly affects set speed, the rate of drying and printing quality etc. of ink.Therefore, improve the use properties of ink, the performance from improving these compositions is needed to set about, improve the consistency between each raw material simultaneously, reach collaborative effect promoted, thus improve existing ink ubiquitous heap ink, fall the problems such as printing quality such as version, scumming, dirty version, set-off, to enhance productivity, avoid the waste of resource.
Summary of the invention
The object of the invention is to, provide a kind of anti abrasive resin glass printing-ink, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of anti abrasive resin glass printing-ink, it is characterized in that, this ink is made up of the raw material of following weight part: molybdenum powder 0.1-0.2, Isooctyl acrylate monomer 5-10, vitamin-E 0.01-0.02, Vanay 10-15, cyanuric acid 0.01-0.02, polycarbonate resin 25-35, vinyl acetic monomer 10-13, dehydrated alcohol 5-8, pigment 8-15, sodium lignosulfonate 1-2, auxiliary agent 1-2;
The raw material of following weight part is comprised: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4 in described auxiliary agent, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
The anti abrasive resin glass printing-ink of described one, its preparation method is: first cyanuric acid is dissolved in water-bath and is heated in the dehydrated alcohol of 40-50 DEG C, the solution of preparation mixes with other remaining component, be stirred to after material dissolves dispersion completely, drop into fully grinding in sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
Ink prepared by the present invention is using polycarbonate resin as low-melting ink vehicle, there is bonds well ability, there is the characteristic of abrasion resistant fire blocking, transparency is high, vitamin-E can promote the anti-ultraviolet aging xanthochromia ability of ink, the composition such as molybdenum powder, cyanuric acid can improve wear-resistant, coating of ink coating etc., and the auxiliary agent of interpolation can improve the wettability of ink, prevents coating bubbles and affects decorative effect; Ink low toxic and environment-friendly of the present invention, can in multiple plastics and glass substrate surface attachment, and printing adaptability is good, and excellent weather-proof, wear-resisting, ultraviolet aging resistance ability are especially applicable to outdoor environment and use.
Embodiment
Embodiment
Printing-ink prepared by the present embodiment is made up of the raw material of following weight part: molybdenum powder 0.1, Isooctyl acrylate monomer 8, vitamin-E 0.01, Vanay 12, cyanuric acid 0.01, polycarbonate resin 30, vinyl acetic monomer 10, dehydrated alcohol 8, pigment 12, sodium lignosulfonate 2, auxiliary agent 1.4; Wherein auxiliary agent is made up of the raw material of following weight part: trolamine 0.1, alumina sol 4, microfine diatomaceous 1, limonene 2, dehydrated alcohol 5, nano rare earth cerium colloidal sol 0.2, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
The preparation method of this printing-ink is: first cyanuric acid is dissolved in water-bath and is heated in the dehydrated alcohol of 40-50 DEG C, the solution of preparation mix with other remaining component, is stirred to after material dissolves dispersion completely, drops into abundant in sand mill grinding, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
By the ink printing obtained by the present embodiment on glass, after its complete drying, this ink in the performance test results of substrate surface is:
Above-mentioned test is all followed relevant criterion and is carried out.

Claims (2)

1. an anti abrasive resin glass printing-ink, it is characterized in that, this printing-ink is made up of the raw material of following weight part: molybdenum powder 0.1-0.2, Isooctyl acrylate monomer 5-10, vitamin-E 0.01-0.02, Vanay 10-15, cyanuric acid 0.01-0.02, polycarbonate resin 25-35, vinyl acetic monomer 10-13, dehydrated alcohol 5-8, pigment 8-15, sodium lignosulfonate 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: trolamine 0.1-0.2, alumina sol 4-6, microfine diatomaceous 1-2, limonene 1-2, dehydrated alcohol 3-5, nano rare earth cerium colloidal sol 0.2-0.4, preparation method is: first by trolamine, the abundant stirring and dissolving of limonene in dehydrated alcohol, add microfine diatomaceous subsequently, after ground and mixed 30-40min, gained pulp concentration is dry, the powder obtained mixes with alumina sol, nano rare earth cerium colloidal sol again, after complete dispersed with stirring is even.
2. a kind of anti abrasive resin glass printing-ink as claimed in claim 1, its preparation method is: first cyanuric acid is dissolved in water-bath and is heated in the dehydrated alcohol of 40-50 DEG C, the solution of preparation mixes with other remaining component, be stirred to after material dissolves dispersion completely, drop into fully grinding in sand mill, make the particle diameter of gained slurry be≤20 μm, to obtain final product.
CN201410541201.2A 2014-10-14 2014-10-14 Wear-resistant printing ink for plastic and glass Pending CN104356746A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410541201.2A CN104356746A (en) 2014-10-14 2014-10-14 Wear-resistant printing ink for plastic and glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410541201.2A CN104356746A (en) 2014-10-14 2014-10-14 Wear-resistant printing ink for plastic and glass

Publications (1)

Publication Number Publication Date
CN104356746A true CN104356746A (en) 2015-02-18

Family

ID=52524068

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410541201.2A Pending CN104356746A (en) 2014-10-14 2014-10-14 Wear-resistant printing ink for plastic and glass

Country Status (1)

Country Link
CN (1) CN104356746A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822707A (en) * 2018-06-05 2018-11-16 电子科技大学中山学院 Shielding film for outer wall decorative glass and preparation method thereof
CN112480741A (en) * 2020-11-27 2021-03-12 江苏唐彩新材料科技股份有限公司 High-resolution aqueous flexographic printing ink

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880485A (en) * 2010-07-09 2010-11-10 重庆航利实业有限责任公司 Rare-earth sol modified composite zinc-aluminum low-temperature sintered coating slurry
CN103666065A (en) * 2013-11-25 2014-03-26 铜陵方正塑业科技有限公司 Ultraviolet-curable printing ink for surface printing and preparation method of ultraviolet-curable printing ink
CN103865322A (en) * 2014-02-27 2014-06-18 安徽颍美彩印包装有限公司 Printing ink and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101880485A (en) * 2010-07-09 2010-11-10 重庆航利实业有限责任公司 Rare-earth sol modified composite zinc-aluminum low-temperature sintered coating slurry
CN103666065A (en) * 2013-11-25 2014-03-26 铜陵方正塑业科技有限公司 Ultraviolet-curable printing ink for surface printing and preparation method of ultraviolet-curable printing ink
CN103865322A (en) * 2014-02-27 2014-06-18 安徽颍美彩印包装有限公司 Printing ink and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822707A (en) * 2018-06-05 2018-11-16 电子科技大学中山学院 Shielding film for outer wall decorative glass and preparation method thereof
CN112480741A (en) * 2020-11-27 2021-03-12 江苏唐彩新材料科技股份有限公司 High-resolution aqueous flexographic printing ink

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Application publication date: 20150218