CN104356508A - Antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film - Google Patents

Antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film Download PDF

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Publication number
CN104356508A
CN104356508A CN201410623718.6A CN201410623718A CN104356508A CN 104356508 A CN104356508 A CN 104356508A CN 201410623718 A CN201410623718 A CN 201410623718A CN 104356508 A CN104356508 A CN 104356508A
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China
Prior art keywords
temperature
flame
thin film
resistant polypropylene
agent
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Application number
CN201410623718.6A
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Chinese (zh)
Inventor
王举
孙益民
芮定文
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ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
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ANHUI RUIYAN NEW MATERIAL TECHNOLOGY RESEARCH INSTITUTE Co Ltd
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Priority to CN201410623718.6A priority Critical patent/CN104356508A/en
Publication of CN104356508A publication Critical patent/CN104356508A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses an antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film, belonging to the technical field of antiseptic plastics. The antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film comprises the following components in percentage by weight: 80-91% of substrates, 0.5-1% of flame-retardant, 0.1-0.5% of antioxidant, 0.05-0.1% of auxiliary antioxidant, 5-8% of flexibilizer, 0.8-1.2% of dispersing agent, 10-14% of disinfectant, and 1-2% of other auxiliaries. According to the antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film, raw materials of the components are easily available and low in cost, tourmaline can also release negative ions which can adjust ion balance of humans, enable the mind and body to be relaxed, activate cells, improve self-healing and the like, as well as inhibit the oxidization of a human body and remove peculiar smell; silver ions has the radiation-proof and sterilization functions; infrared ray emitted by nano silica and nano titanium dioxide has a health function.

Description

A kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film
Technical field
The present invention relates to a kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film, belong to antibiotic plastic technical field.
Background technology
Along with the widespread use of plastic prod, the performance requriements of people to plastic prod is also more and more higher.Negative ion is a kind of electronegative gaseous ion in air, human body can not only be facilitated to synthesize for negative ion and vitamin storage, strengthening and human activin physiological activity, there is very important impact to the activity of human body and other life, be therefore called as " air VITAMIN ".Negative ion can make brokenly the factors such as the acidity of ring life entity health, oxidation, active oxygen, lactic acid reduce gradually, the metabolism of activating cells tissue, to the environment that life entity internal invention is good, brings up healthy health.Thus strengthen the restorer of life entity self and naturally cure ability, and then overcome disease.Far-infrared engergy makes Marjoram Extract, accelerates blood circulation, is conducive to removing blood vessel and hoards objectionable impurities in thing and body, metabolic obstacle cleaning will be harmed, again make tissue bring back to life, promote that ferment generates, reach activation histocyte, prevent aging, strengthening immune system object.Far infrared rays is used in the assisting therapy of numerous disease, and such as muscles and bones sore muscle, tendinitis, bedsore, scald and wound such as not easily to heal at the disease, can utilize the characteristic that far infrared rays stimulates circulation, and reach the object of assisting therapy.Be no lack of high temperature resistant and antibacterial plastics in current plastic prod, but the plastic prod utilizing the characteristic of negative ion far-infrared and process is few.
Summary of the invention
In view of the defect that prior art exists, the object of this invention is to provide and a kind ofly can release negative ion far-infrared thus there is a kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film of nourishing function.
For achieving the above object, the technology used in the present invention solution is: a kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film, include matrix, fire retardant, oxidation inhibitor, auxiliary antioxidant, toughner, dispersion agent, sterilizing agent and other auxiliary agent, wherein the content of each composition is: matrix 80 ~ 91%, fire retardant 0.5 ~ 1%, oxidation inhibitor 0.1 ~ 0.5%, auxiliary antioxidant 0.05 ~ 0.1%, toughner 5 ~ 8%, dispersion agent 0.8 ~ 1.2%, sterilizing agent 10 ~ 14%, other auxiliary agent 1 ~ 2%.
Described matrix is: the one in polyethylene, polypropylene, polyvinylidene, nylon, polystyrene.
Described fire retardant selects the magnesium hydroxide in inorganic combustion inhibitor, the one in aluminium hydroxide.
Described oxidation inhibitor is at least one in 2,6-, tri-grades of butyl-4-methylphenols, two (3,5-, tri-grades of butyl-4-hydroxy phenyls) thioether, four (β-(3,5-, tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester.
Described auxiliary antioxidant is the one in thio-2 acid dibasic acid esters, phosphorous acid ester.
Described toughner is acrylic polymer.
Described dispersion agent is aliphatic amide type.
Described sterilizing agent is the mixture of tourmalinite, nano silicon, nano titanium oxide, Silver Nitrate, and proportioning is tourmalinite: nano silicon: nano titanium oxide: Silver Nitrate=5:3:4:3.
In the present invention, the raw material of each component is easy to get, and low price, tourmalinite can the micro-electric current of permanent generation, and the current capacity of this electric current and human nerve seemingly, can play and impel blood circulation, acts on smoothly, tourmalinite can also anion releasing in addition, these negative ions can regulate human body ionic equilibrium, and body and mind loosens, active cells, improve the effects such as immunizing power, and the oxidation that can suppress health and the effect eliminated the unusual smell; Silver ions has the function of radioprotective sterilization and disinfection; Nano silicon, nano titanium oxide can radiate its nourishing function of infrared rays.
Embodiment
A kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film, include matrix, fire retardant, oxidation inhibitor, auxiliary antioxidant, toughner, dispersion agent, sterilizing agent and other auxiliary agent, wherein the content of each composition is: matrix 80 ~ 91%, fire retardant 0.5 ~ 1%, oxidation inhibitor 0.1 ~ 0.5%, auxiliary antioxidant 0.05 ~ 0.1%, toughner 5 ~ 8%, dispersion agent 0.8 ~ 1.2%, sterilizing agent 10 ~ 14%, other auxiliary agent 1 ~ 2%.
Described matrix is: the one in polyethylene, polypropylene, polyvinylidene, nylon, polystyrene.
Described fire retardant selects the magnesium hydroxide in inorganic combustion inhibitor, the one in aluminium hydroxide.
Described oxidation inhibitor is at least one in 2,6-, tri-grades of butyl-4-methylphenols, two (3,5-, tri-grades of butyl-4-hydroxy phenyls) thioether, four (β-(3,5-, tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester.
Described auxiliary antioxidant is the one in thio-2 acid dibasic acid esters, phosphorous acid ester.
Described toughner is acrylic polymer.
Described dispersion agent is aliphatic amide type.
Described sterilizing agent is the mixture of tourmalinite, nano silicon, nano titanium oxide, Silver Nitrate, and proportioning is tourmalinite: nano silicon: nano titanium oxide: Silver Nitrate=5:3:4:3.

Claims (2)

1. an antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film, is characterized in that, includes matrix, fire retardant, oxidation inhibitor, auxiliary antioxidant, toughner, dispersion agent, sterilizing agent and other auxiliary agent, wherein the content of each composition is: matrix 80 ~ 91%, fire retardant 0.5 ~ 1%, oxidation inhibitor 0.1 ~ 0.5%, auxiliary antioxidant 0.05 ~ 0.1%, toughner 5 ~ 8%, dispersion agent 0.8 ~ 1.2%, sterilizing agent 10 ~ 14%, other auxiliary agent 1 ~ 2%, described matrix is: polyethylene, polypropylene, polyvinylidene, nylon, one in polystyrene, the magnesium hydroxide in inorganic combustion inhibitor selected by described fire retardant, one in aluminium hydroxide, described oxidation inhibitor is 2,6-, tri-grades of butyl-4-methylphenols, two (3,5-, tri-grades of butyl-4-hydroxy phenyls) thioether, at least one in four (β-(3,5-, tri-grades of butyl-4-hydroxy phenyls) propionic acid) pentaerythritol ester, described auxiliary antioxidant is thio-2 acid dibasic acid esters, one in phosphorous acid ester, described toughner is acrylic polymer, and described dispersion agent is aliphatic amide type.
2. a kind of antibacterial and mouldproof flame-resistant high-temperature-resistant polypropylene film according to claim 1, it is characterized in that, described sterilizing agent is the mixture of tourmalinite, nano silicon, nano titanium oxide, Silver Nitrate, and proportioning is tourmalinite: nano silicon: nano titanium oxide: Silver Nitrate=5:3:4:3.
CN201410623718.6A 2014-11-06 2014-11-06 Antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film Pending CN104356508A (en)

Priority Applications (1)

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CN201410623718.6A CN104356508A (en) 2014-11-06 2014-11-06 Antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film

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Application Number Priority Date Filing Date Title
CN201410623718.6A CN104356508A (en) 2014-11-06 2014-11-06 Antiseptic mildew-proof flame-retardant high-temperature-resistant polypropylene thin film

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104988625A (en) * 2015-06-23 2015-10-21 张家港市华阳针纺织品有限公司 High-strength composite yarn preparation method
CN104988626A (en) * 2015-06-24 2015-10-21 张家港市华阳针纺织品有限公司 Lengthened inflaming retarding spandex yarn preparation method
CN106188773A (en) * 2016-08-04 2016-12-07 安徽嘉木橡塑工业有限公司 A kind of nano packaging material and preparation method thereof
CN106243488A (en) * 2016-07-29 2016-12-21 王莹 A kind of flame-retardant polypropylene film formula
CN107674305A (en) * 2017-10-25 2018-02-09 安徽国泰印务有限公司 A kind of antimildew polyacrylic film
CN108948729A (en) * 2017-05-18 2018-12-07 无锡市银杏塑业科技有限公司 A kind of mould proof resin
CN111808364A (en) * 2020-07-21 2020-10-23 河北全成新能源汽车配件科技有限公司 Polypropylene capable of releasing negative oxygen ions and having environment-friendly and flame-retardant functions

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104988625A (en) * 2015-06-23 2015-10-21 张家港市华阳针纺织品有限公司 High-strength composite yarn preparation method
CN104988626A (en) * 2015-06-24 2015-10-21 张家港市华阳针纺织品有限公司 Lengthened inflaming retarding spandex yarn preparation method
CN106243488A (en) * 2016-07-29 2016-12-21 王莹 A kind of flame-retardant polypropylene film formula
CN106188773A (en) * 2016-08-04 2016-12-07 安徽嘉木橡塑工业有限公司 A kind of nano packaging material and preparation method thereof
CN108948729A (en) * 2017-05-18 2018-12-07 无锡市银杏塑业科技有限公司 A kind of mould proof resin
CN107674305A (en) * 2017-10-25 2018-02-09 安徽国泰印务有限公司 A kind of antimildew polyacrylic film
CN111808364A (en) * 2020-07-21 2020-10-23 河北全成新能源汽车配件科技有限公司 Polypropylene capable of releasing negative oxygen ions and having environment-friendly and flame-retardant functions

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