CN104342223A - Anti-attrition lubricating material - Google Patents

Anti-attrition lubricating material Download PDF

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Publication number
CN104342223A
CN104342223A CN201410512999.8A CN201410512999A CN104342223A CN 104342223 A CN104342223 A CN 104342223A CN 201410512999 A CN201410512999 A CN 201410512999A CN 104342223 A CN104342223 A CN 104342223A
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China
Prior art keywords
attrition
graphene
graphite
molybdenumdisulphide
mnznfe
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CN201410512999.8A
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Chinese (zh)
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殷国忠
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Individual
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Individual
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Priority to CN201410512999.8A priority Critical patent/CN104342223A/en
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Abstract

The invention relates to an anti-attrition lubricating material, which comprises the following components in percentage by weight: 10-20% of molybdenum disulfide, 50-60% of graphite, 10-20% of graphene, 5-10% of MnZnFe2O4, and 5-10% of titanium dioxide. The anti-attrition lubricating material has the beneficial effects that the graphite fills and remedies a rough metal surface so as to play an anti-attrition role; the bearing capacity of the base oil can be greatly improved and the diameter of an attrition mark and the furrow of the attrition surface can be reduced through the MnZnFe2O4 nanoparticles; molybdenum disulfide is suspended in oil under the action of graphene to form a covering film on the metal surface, and has extreme pressure resistance property, and suspended molybdenum disulfide can be continuously supplemented onto the worn metal surface even if the generated film is worn, so as to play anti-attrition lubricating roles, as well as the energy-saving, environment-friendly, accelerating, extreme pressure-resistant, anti-oxidization and other roles.

Description

A kind of anti-attrition lubricant
Technical field
The present invention relates to a kind of anti-attrition lubricant.
Background technology
Current frictional wear is the major cause that the destruction of material and mechanical means are scrapped, and lubrication technology is the effective means reducing friction, reduce wearing and tearing, and the important means of lubrication technology makes with lubricator.Lubricant can be divided into liquid lubricant and solid lubricant etc. again, it is the lubricator by adhering to or be coated on surface of friction pair, on friction surface, form lubrication transfer film by means of process of friction and wear, improve the contact condition between friction pair, thus play the wear-resistant effect of effective anti-attrition.
Its anti-attrition lubricant effect of more existing antifriction materials is poor, can not meet the anti-attrition requirement of the extreme environments such as high temperature, high pressure or corrosion.
Summary of the invention
The technical problem to be solved in the present invention is: based on the problems referred to above, the invention provides a kind of anti-attrition lubricant.
The present invention solves the technical scheme that its technical problem adopts: a kind of anti-attrition lubricant, by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 18%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 54%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 13%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 47%, titanium dioxide 5 ~ 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 8%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10%, graphite 60%, Graphene 10%, MnZnFe 2o 410%, titanium dioxide 10%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 18%, graphite 54%, Graphene 13%, MnZnFe 2o 47%, titanium dioxide 8%.
Further, anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 20%, graphite 50%, Graphene 20%, MnZnFe 2o 45%, titanium dioxide 5%.
Further, the purity of molybdenumdisulphide is greater than 96%, MnZnFe 2o 4for the nanometer MnZnFe of particle diameter 10 ~ 90nm 2o 4.
The invention has the beneficial effects as follows: graphite is filled up, repair coarse metallic surface, plays anti-attrition effect; MnZnFe 20 4nanoparticle can significantly improve the supporting capacity of basic grease, reduces the ditch dug with a plow of wear scar diameter and wear surface; Molybdenumdisulphide at Graphene effect low suspension in grease, mulch film is formed in metallic surface, and there is anti-extreme pressure energy, even if after the film generated is worn, the molybdenumdisulphide suspended constantly can add to wear metal surface again, play anti-attrition lubrication, also serve energy-saving and environmental protection, speedup, anti-extreme pressure wear and the effect such as anti-oxidant simultaneously.
Embodiment
The invention will be further described in conjunction with specific embodiments now, and following examples are intended to the present invention instead of limitation of the invention further are described.
Embodiment one
Anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10%, graphite 60%, Graphene 10%, MnZnFe 2o 410%, titanium dioxide 10%.
Embodiment two
Anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 18%, graphite 54%, Graphene 13%, MnZnFe 2o 47%, titanium dioxide 8%.
Embodiment three
Anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 20%, graphite 50%, Graphene 20%, MnZnFe 2o 45%, titanium dioxide 5%.
Graphite is hexagonal, frictional coefficient is 0.05 ~ 0.19, in flakey, Stability Analysis of Structures, carbon atom combines securely, be not easy to destroy, layer is more weak with inter-layer bonding force, is easy to slippage by shear action, surface of friction has and well fills and repair, easily forming mulch film in metallic surface, is a kind of good solid lubricant.
Graphene is a kind of novel material of the individual layer sheet structure be made up of carbon atom, by individual layer atomic building, is interconnected to hexagonal gridding between carbon atom, and its proportion in grease is lower.
The structure of molybdenumdisulphide is the same with graphite, is hexagonal, and how carefully no matter grind, have laminate structure definitely, under pressure friction, have very strong avidity to metallic surface, bearing pressure is 3.45 × 10 9pa.The parts of coating molybdenumdisulphide can operate in without oily situation, and under certain temperature and pressure, molybdenumdisulphide and metallic surface occur to react instantaneously, generate the solid film that frictional coefficient is extremely low, prevent metallic surface phase mutual friction sintering.
The proportion of the oil of molybdenumdisulphide is 4.7g/cm 3, be easily deposited in the bottom of mechanical grease, can not be contained in mechanical grease and go, cause molybdenumdisulphide skewness.Add appropriate Graphene, after mixing with molybdenumdisulphide, overall proportion is alleviated, the lubrication of molybdenum dioxide can be played better.
MnZnFe 20 4nanoparticle can significantly improve the supporting capacity of basic grease, reduces the ditch dug with a plow of wear scar diameter and wear surface.MnZnFe 20 4can be made into nano magnetic particle, except having similar character with plain metal particle, also because particle has weak magnetic, be conducive to it and adsorb in metallic surface, play better wear-resistant and antifriction effect.
The white pigment of titanium dioxide to be main component be titanium dioxide, its whiteness is high, effectively can hide the black of graphite, and in dispersion system good dispersity, resistance to settling is high, compatibleness good, make antifriction material having in oil or fat distribute more all even stable.
Making processes is: by molybdenumdisulphide, graphite, Graphene, MnZnFe 2o 4with titanium dioxide mixing, deployed raw material carries out stirring, disperse, dry, obtained antifriction material.
Antifriction material adds in oil or fat, form anti-attrition oil or anti-attrition fat, it is except keeping the primary characteristic of base grease grease, and also have energy-conservation, anti-attrition, anti-extreme pressure wear, the function such as anti-oxidant, antifriction material of the present invention is the desirable lubricating oil and grease additive that people use.
We use the cargo truck of different model to do controlled trial, and use the automobile that with the addition of the lubricant of antifriction material than the automobile using traditional lubricant, saving fuel oil 5 ~ 10%, component wear is reduced to 2/3 ~ 3/4, reduces mechanicalness noise 3 ~ 10 decibels.
Utilize the lubricating grease that antifriction material manufactures as additive, in running of an engine, shearing force is utilized antifriction material to be filled into the surface of the parts such as piston ring, piston and cylinder wall, improve the mechanical seal of combustion chamber, inhibit the pressurized air in compression and power stroke and fuel to miss in piston, improve again the efficiency of combustion of fuel simultaneously.So both improve the economy of fuel, decrease exhaust emissions, protection of the environment, owing to filling enough mulch films, prevent friction, wearing and tearing when cold start-up, engine parts can be protected better.
With above-mentioned according to desirable embodiment of the present invention for enlightenment, by above-mentioned description, relevant staff in the scope not departing from this invention technological thought, can carry out various change and amendment completely.The technical scope of this invention is not limited to the content on specification sheets, must determine its technical scope according to right.

Claims (10)

1. an anti-attrition lubricant, is characterized in that: by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
2. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 18%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
3. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 54%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
4. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 13%, MnZnFe 2o 45 ~ 10%, titanium dioxide 5 ~ 10%.
5. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 47%, titanium dioxide 5 ~ 10%.
6. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10 ~ 20%, graphite 50 ~ 60%, Graphene 10 ~ 20%, MnZnFe 2o 45 ~ 10%, titanium dioxide 8%.
7. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 10%, graphite 60%, Graphene 10%, MnZnFe 2o 410%, titanium dioxide 10%.
8. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 18%, graphite 54%, Graphene 13%, MnZnFe 2o 47%, titanium dioxide 8%.
9. a kind of anti-attrition lubricant according to claim 1, is characterized in that: described anti-attrition lubricant by weight percentage, comprises following component: molybdenumdisulphide 20%, graphite 50%, Graphene 20%, MnZnFe 2o 45%, titanium dioxide 5%.
10. a kind of anti-attrition lubricant according to claim 1, is characterized in that: the purity of described molybdenumdisulphide is greater than 96%, MnZnFe 2o 4for the nanometer MnZnFe of particle diameter 10 ~ 90nm 2o 4.
CN201410512999.8A 2014-09-29 2014-09-29 Anti-attrition lubricating material Pending CN104342223A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867630A (en) * 2017-01-03 2017-06-20 温凯环保科技(上海)有限公司 Environment-friendly type high performance antiwear additive
CN114162810A (en) * 2021-11-12 2022-03-11 湖北民族大学 Graphene-lead compound nanocomposite and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199474A (en) * 2011-04-29 2011-09-28 安徽工业大学 Dry film lubricant used for metal parts
CN102796590A (en) * 2012-08-24 2012-11-28 江苏大学 Preparation method for tubular graphene/MoS2 nanocomposite material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199474A (en) * 2011-04-29 2011-09-28 安徽工业大学 Dry film lubricant used for metal parts
CN102796590A (en) * 2012-08-24 2012-11-28 江苏大学 Preparation method for tubular graphene/MoS2 nanocomposite material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106867630A (en) * 2017-01-03 2017-06-20 温凯环保科技(上海)有限公司 Environment-friendly type high performance antiwear additive
CN106867630B (en) * 2017-01-03 2019-08-13 温凯环保科技(上海)有限公司 Environment-friendly type high performance antiwear additive
CN114162810A (en) * 2021-11-12 2022-03-11 湖北民族大学 Graphene-lead compound nanocomposite and preparation method thereof

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