CN104334989B - The method carrying out ore dressing for former brown coal moist to ore deposit - Google Patents

The method carrying out ore dressing for former brown coal moist to ore deposit Download PDF

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Publication number
CN104334989B
CN104334989B CN201380026540.0A CN201380026540A CN104334989B CN 104334989 B CN104334989 B CN 104334989B CN 201380026540 A CN201380026540 A CN 201380026540A CN 104334989 B CN104334989 B CN 104334989B
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brown coal
former
dry
fluidized bed
bed dryer
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CN104334989A (en
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H-J·克卢茨
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RWE Power AG
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RWE Power AG
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B1/00Preliminary treatment of solid materials or objects to facilitate drying, e.g. mixing or backmixing the materials to be dried with predominantly dry solids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2201/00Pretreatment of solid fuel
    • F23K2201/20Drying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B3/00Drying solid materials or objects by processes involving the application of heat
    • F26B3/02Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air
    • F26B3/06Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried
    • F26B3/08Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed
    • F26B3/084Drying solid materials or objects by processes involving the application of heat by convection, i.e. heat being conveyed from a heat source to the materials or objects to be dried by a gas or vapour, e.g. air the gas or vapour flowing through the materials or objects to be dried so as to loosen them, e.g. to form a fluidised bed with heat exchange taking place in the fluidised bed, e.g. combined direct and indirect heat exchange

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Drying Of Solid Materials (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The present invention relates to a kind of carry out ore dressing, method in particular for the heat utilization in station boiler for former brown coal moist to ore deposit.First by former brown coal precrushing and then pulverized at least one milling device (2) and flow to follow-up being dried.Described being dried is implemented in the case of the fluidized bed dryer (3) utilizing at least one to be heated indirectly in fluosolids.A part of branch of the former brown coal that will extract from described fluidized bed dryer (3), and mixed described former brown coal before described being dried, that thus improves brown coal can be fluidity.

Description

The method carrying out ore dressing for former brown coal moist to ore deposit
Technical field
The present invention relates to a kind of carry out ore dressing for former brown coal moist to ore deposit, in particular for the heat utilization in station boiler Method, wherein, first by former brown coal precrushing and then it pulverized at least one milling device and flow to Follow-up is dried, and wherein said being dried is implemented in fluid bed at the fluidized bed dryer utilizing at least one to be heated indirectly, Described fluidized bed dryer steam runs as fluidizing agent.
Background technology
A kind of method for aqueous brown coal being dried in fluosolids such as from DE 20 01 723 C2 Know.
The fluid-bed drying described there proposes, and by conveying worm, feed coal is flowed to fluid bed drying Device.
Should be suitable for being dried bulk material, the size of described bulk material from the known in the literature method mentioned before In the scope of such as 0.3cm to 10cm.To this end, the material that need to be dried, such as brown coal become finer and close material in eddy current Such as quartz sand.The method requires: removed together with a part for granular fluidizable material by the solid material being dried, and Solid material and fluidizable material are separated from one another, thus are backed in fluid bed by isolated fluidizable material.The method is Complicated and actually be not easy implement.
For drying brown coal, in particular for applying the another kind of method in station boiler such as from DE 196 20 In 047 A1 known.The method is only run as fluidizing agent as solid and with steam with brown coal.Need to flow to be dried The brown coal of device are milled by opposite fine to fluidize in fluid bed, mean diameter d of the about 1mm that such as mills50
According to the character of brown coal, such fluid bed drying process can be relatively stable and without reason in fixing fluosolids Barrier ground is carried out.
As this explanation in DE 29 01 723 C2, this is substantially dependent on solid at fluid bed drying In device can be fluidity.Extremely complex in the fluid machinery process within fixing fluosolids and only can emulate limitedly.? In the pilot plant run by the applicant, produce the interference of hybrid dynamics every now and then according to the quality stream that need to introduce.Because Such interference, the deposition of former brown coal is preferably formed on the heat exchanger of fluidized bed dryer.Heat transfer is thus made to be deteriorated, dry The power of dry device significantly reduces, and fluosolids caves in worst case.
Confirm with the test of fluidized bed dryer under different handling capacities, former brown coal can fluidity not only with fluidisation The load of machinery systems of bed dryer is correlated with, and relevant to the type of former brown coal and composition.
Summary of the invention
Therefore the present invention based on purpose be to provide a kind of fluid bed drying for utilizing at least one to be heated indirectly The method that device former brown coal moist to ore deposit carry out ore dressing, even if described method is in high handling capacity with at different types of raw material Also ensure that in the case of coal that the most stable and glitch-free fluid bed runs.
Ore dressing is carried out, in particular for station boiler by a kind of for former brown coal moist to ore deposit based on the purpose of the present invention In the method for heat utilization be achieved, wherein, first by former brown coal precrushing and then by it at least one dress of milling Put middle pulverizing and flow to follow-up being dried, wherein, being dried at the fluidized bed dryer utilizing at least one to be heated indirectly In the case of in fluosolids implement, described fluidized bed dryer steam runs as fluidizing agent, wherein, by former brown coal As mean diameter d50Discrete material for maximum 2mm is thrown in fluosolids, and the driest from fluidized bed dryer downstream Brown coal in branch out subflow and by this subflow mix be dried before former brown coal.
Particle size distribution such as can be via affecting turning of one or more mills being connected to fluidized bed dryer upstream Speed guarantees.Such as apply impact mill as mill, described impact mill obtains other according to rotating speed and mills Precision.Particle size distribution is checked by screening and can every day or batch provide sampling for this.Sample is at laboratory In by screening grade monitor.Alternatively, particle size distribution can also be measured via at line method in terms of volume.
In order to the stability of fluosolids the most important thing is, excessive grain part (> 2mm) will not be excessive, otherwise this can damage stream Change the stability of layer.
Particle size distribution alternatively can also be guaranteed by following manner, and sieve classification is at dry brown coal of milling Downstream, wherein, excessive grain part is sized and stands to mill again.
The present invention based on knowledge be: the moist former brown coal in ore deposit have different adhesiveness relatively from its place of production, this glue Characteristic and coal fluidity can be had either large or small impact.
It is known that the natural product that former brown coal obtain as digging is in terms of water content, carbon content and mineralogical composition Different according to the place of production.The specific performance of former brown coal must be considered as given when application.
Applicant experimentally finds, former brown coal can be fluidity closely related with its flowable and former brown The flowable of coal can produce the impact in front by mixing the dry brown coal of identical coal class unexpectedly.
Therefore it is proposed, according to the invention, that be that the former brown coal that need to be dried add the identical of dry brown coal form before the drying process Coal class.
The stability of the beneficiation method according to the present invention, especially in the stability of the fluosolids within fluidized bed dryer Can be improved by following manner unexpectedly: part loopy moving in process of the brown coal being dried, thus Make it difficult in this way or the former brown coal of energy fluidizing also are not able to do at fluid bed while handling capacity is relatively high Dry device is applied and is dried.
Fluosolids can be fluidity problem also relevant to the load of machinery systems of fluidized bed dryer.The interference of fluosolids is especially Can occur in the case of the high load capacity of fluidized bed dryer.
Preferably, the mixture of the dry brown coal of former brown coal and recirculation is in the method according to the invention via impeller gate Enter in the fluidized bed dryer being under slight overpressure, introduce on fluosolids and be distributed on fluosolids.
Particularly preferably proposing, the dry brown coal share mixed to former brown coal accounts for 10 mass % and 30 matter of whole loose material Between amount %, between preferably 10 mass % and 20 mass %.
Propose aptly: regulate the share of the dry brown coal of recirculation according to the amount of the former brown coal flowing to fluosolids.Adjust Joint can be arranged such: sets the quantity ratio of the determination of the most former brown coal of dry brown coal, and correspondingly measures dry brown coal.According to institute Set machine utilization, the dry brown coal amount of recirculation can in the case of proportions constant Auto-matching.
In the sense that the application, regulation is interpreted as the regulation of automatization, is provided with corresponding process for this regulation Control technology.
Former brown coal can have until the water content/moisture content of fluctuation of 65 mass %.Take out from fluidized bed dryer The water content of the dry brown coal taken passes through fluosolids temperature or by solving in moisture absorption scope in the case of system pressure is constant Inhale isothermal change curve to determine.From fluidized bed dryer, the dry brown coal of extraction can have 0.4mm to 0.8mm, excellent Select mean diameter d of 0.1mm to 0.4mm, if desired 0.1mm to 0.2mm50.The moisture content of dry brown coal can be in 10 mass % And between 15 mass %, the most such as between 15 mass % and 18 mass %.Overvoltage within fluidized bed dryer can be straight To 10bar.The moisture content of dry brown coal can also be between 8 mass % and 20 mass %, preferably in 10 mass % and 16 matter Between amount %.
The most like that, fluidized bed dryer is preferably heated indirectly as adding thermal medium with steam.Dry The part of dry device steam or alternatively external steam from the power plant process coupled may be used for fluid bed or at stream The fluidisation of the change former brown coal within bed dryer.
The dry brown coal being branched can introduce fluid bed with former brown coal in the case of utilizing at least one mixing arrangement In internal mix before exsiccator.Such mixing is not or not the most all required, but it significantly improves finely The adhesion on the granule of the moist former brown coal used of the dry brown coal granule.
For example, it is possible to cool down and be subjected to mill again to dry brown coal in fluidized bed dryer downstream, wherein, exist The downstream milled again is by the subflow branch on dry brown coal.
The most also it is possible that directly will need the dry brown coal branch of recirculation in the downstream of fluidized bed dryer, but more Advantageously cool down and mill again, thus such as will have particle mean size d of 0mm to 1mm50Dry brown coal be added to former brown coal. Particle size distribution can be determined by sieve classification equally in terms of volume, thus can in the case of particle size distribution has deviation To mill the most again.
The dry brown coal of recirculation can be milled between level or in the downstream of a upper level of milling mixes former brown coal at two. The most also it is possible that the dry brown coal of recirculation were added to former brown coal before milling for the first time.
In this case, milled together with dry brown coal by former brown coal and ensured internal mix, thus possible Individually mixing arrangement is unnecessary.But in the sense that relative efficiency or energy-conservation method controls it is essential that As few as possible dry brown coal are introduced circulation and the path of that need recirculation or that meeting companion is carried secretly dry brown coal is kept as The shortest.The most also the angle of blast protection protection it is considered as at this.For reasons of the latter suitable and it is of importance that need to follow again The dry brown coal of ring introduce in former brown coal in the downstream of the former brown coal of fine ground, and such as by static or mix dress dynamically Put in the conveying of fluidized bed dryer, implementing the mixing with former brown coal.Mixing also such as is able to via traditional transporter Implement.
Desirably, the share of dry brown coal and the adhesion property of former brown coal and/or the fluidized bed dryer of former brown coal it are mixed into Load condition change relatively.As discussed further below, it has been discovered that the adhesion property of former brown coal and flowing Performance largely depends on the compressibility of former brown coal and then depends on former brown coal discrete material density under compression.
Aptly, it is arranged on the allotter chute of rotation on fluid bed by least one, preferably according to about stream Former brown coal are poured in fluosolids by the distribution preset of the cross section changing bed dryer.
Accompanying drawing explanation
The present invention is illustrated below with reference to appended accompanying drawing.
In accompanying drawing:
Fig. 1 illustrates the schematic diagram of the Method And Principle of the beneficiation method according to the present invention;
Fig. 2 illustrates chart, has the discrete material robustness of material of different flowable with solid shown in this chart Change the dependency of stress.
Detailed description of the invention
With reference first to the Method And Principle shown in Fig. 1, its diagram illustrates the flow chart of fluidized bed dryer, and described fluid bed is done Dry device such as may be coupled on boiler of power plant for combusting brown coal.
From brown coal strip mining equipment, such as, the former brown coal with the precrushing of the particle mean size of 0mm to 80mm are drawn Enter former brown coal coal bunker 1.From former brown coal coal bunker 1 out, for fine ground by former brown coal at two mills set gradually In be ground to the particle mean size (d of such as 0mm to 2mm50).Then in the case of mixing with dry brown coal, as will be explained further below As, former brown coal are introduced fluidized bed dryer 3.Between fluidized bed dryer 3 is such as via corresponding internal heat exchanger Ground connection is heated by steam.Steam feeding for loading to heat exchanger is provided with reference 4 in method sketch (Fig. 1). Fluidized bed dryer 3 is crossed pressure run slight in known manner, wherein, former brown coal via unshowned impeller gate with And be incorporated on fluid bed via the allotter chute in the upper part being arranged on fluidized bed dryer 3.From fluid bed drying The steam 5 of device 3 extraction is fed to other different application in electronic filter after dedusting.Described steam such as can be arranged Go out in air.Can also be alternatively by described moisture condensation, wherein it is possible to by the such as coupling of the low-temperature heat quantity from moisture condensation The boiler feedwater closing power plant's process is hankered in advance.Additionally can alternatively vapour pressure be contractd and in order to heat and flow to stream Change bed dryer 3.Energy from steam can also be coupled in ORC process (organic Rankine bottoming cycle).
The subflow 70 of steam 5 is under any circumstance fed to fluidized bed dryer 3 as fluidizing agent.Do from fluid bed In dry device 3, the dry brown coal 8 of extraction are first cooled in cooler 9, then mill in mill 10 again and are fed to Dry brown coal storehouse 11.The possible position extracting dry brown coal from the brown coal stream being provided for heat utilization identifies with E1 to E4, its In, E1 mark is in fluidized bed dryer 3 downstream and in the extraction position of cooler 9 upstream, and E2 mark is at cooler 9 Downstream and in the extraction position of mill 10 upstream, E3 mark in mill 10 downstream and in upstream, dry brown coal storehouse 11 Extract position.Last E4 mark is the extraction position in downstream, dry brown coal storehouse 11.
Preferably, at E4, extract the subflow needing recirculation of dry brown coal, this is because owing to being arranged on dry brown coal storehouse 11 In storage and guarantee the more preferable accountability of the subflow of recirculation.
Dry brown coal storehouse 11 can be provided with marker impeller in discharge side, and described marker impeller can run with variable rotating speed. Control to measure dry brown coal amount via the rotating speed of marker impeller such that it is able to the cohesion of former brown coal relatively and/or with The load of machinery systems of fluidized bed dryer 3 or load condition are set between the dry brown coal amount of recirculation and former brown coal amount relatively Quantity ratio.Dry brown coal storehouse 11 can have two single dry brown coal draw-out devices, and one of them dry brown coal draw-out device sets It is set to remix for dry brown coal recirculation or dry brown coal, and another dry brown coal draw-out device is provided for extracting conduct The dry brown coal of the available product of drying process.Use two single draw-out devices especially to have the advantage of control technology, make Obtain follow-up transportation route also to be able to for being filled with dry brown coal before activation by fluidized bed dryer 3.At fluidized bed dryer 3 It is necessary that first set up fluosolids, because soft coal is due to it with dry brown coal 8 before introducing former brown coal for the first time when starting running Cohesive characteristic can not fluidize.
Another advantage being arranged so as to is, in the case of soft coal conveying may shut down, dry brown coal recirculation can Compensate the dust in fluosolids to discharge, and all control loops of fluidized bed dryer and fluosolids can continue to normally transport OK.
The station location marker of R1 to R4 is for needing the possible recirculation position of the dry brown coal of recirculation, wherein, recirculation position Putting R1 and be set directly at soft coal coal bunker 1 downstream, recirculation position R2 is arranged between first and second mill, recirculation position R3 is arranged on the second mill downstream and in fluidized bed dryer 3 upstream.Recirculation position R4 is set directly at fluid bed drying Device 3 upstream.
The applicant it was unexpectedly observed that different soft coal flowable with they in fluid bed can fluidity direct phase Close.By being mixed into by dry brown coal, the former brown coal being difficult to fluidize can significantly improve the former brown coal need to being incorporated in drying process Flowable.
In order to prove this dependency, the applicant is to the different former brown coal from different surface mining equipment and divides The dry brown coal not obtained from these soft coals are studied in terms of its mobility.Hereafter in order to simple and by different coal samples Originally it is designated sample 1 to 5, and the dry brown coal obtained the most respectively are designated TBK1 to TBK5 below, to them respectively Standing flowable research, wherein, flowable is tried to achieve as the ratio of solidification internal stress relative compressive strength.Flowable by Following formula draws:
ffc1: σc, wherein ffcRepresent flowable, σ1Represent solidification internal stress and σcRepresent comprcssive strength.Such Flowable both can also can determine by commercially available ring shear apparatus by known uniaxial compressive strength test.Such ring Cut instrument such as to buy from Dr.Dietmat Schulze Schuettgutmesstechnik company (ring shear apparatus ST-XS). Various other type of ring shear apparatus can be used.
The shouldering mobility and can classify as follows at this of discrete material:
Discrete material intensity σcSolidification internal stress σ from the region for having different flowables1Dependency such as exist Shown in Fig. 2.
The sample studied by the applicant grinds at a temperature of about 19 DEG C under the relative air humidity of about 30% Study carefully.For the measurement result of flowable shown in following form 1, wherein σcRepresent discrete material intensity or loose material The comprcssive strength of material, with stress σ1After compression discrete material, ffcRepresent σ1With σcRatio, ρbWith kg/cm3Represent loose material Material density,The numerical value at the internal friction angle of expression discrete material in passive flow,Be denoted as near linear and The angle of climb of linearizing critical localisation (Fliessort), andRepresent the internal friction angle in passive flow.
Form 1:
Obtain for former brown coal sample 1 to 5: the flowable ff in form 1cIt is in for observed solidification internal stress 1.8 to 2.4.Therefore, sample can classify as in the case of not affected by time solidification and adhere to adhere very much.In sample 2 For worst flowable, best flowable obtains for sample 1, discrete material intensity σ of relative sample 1c, sample Originally 2 have 1/3 bigger intensity.
As for dry brown coal, sample 6 to 10, the flowable of dry brown coal is substantially more favourable than former brown coal.
Former brown coal sample 2 shows worst mobile performance.Former brown coal sample 2 be mixed into now weight quota be 5%, 10%, the dry brown coal TBK2 (from the dry brown coal of sample 2) of the different shares of 15% and 20%.The most correspondingly to mixture Flowable is studied, and measurement result illustrates in table 2.
Form 2:
Discrete material density had both determined under unpressed loose condition (of surface) that about 4kPa was (in form 1 the most after solidification Value).The form 3 illustrated below was both remembered also for sample TBK1 to TBK5 for sample 1 to 5 with being also directed to different mixtures Record record in the uncompressed state and discrete material density under sample solid state.
Form 3:
Sample 2 has the lowest discrete material density.This is consistent with the worst flowable of this sample, as its As form 1 is given.If discrete material has disadvantageous flowable, then individual particle is motionless in loose material, Therefore the cavity and the loose thickness that stay are low.Therefore, sample is compressible, thus discrete material density is relevant to load.? Big compressibility equally determines in sample 2.
Dry brown coal are the most significantly different in terms of discrete material density.But not can determine that relevant between former brown coal to dry brown coal Property, the low discrete material density of former brown coal is also not necessarily mean that the low discrete material density of dry brown coal.Dry brown coal are solid Change the compressibility in the observed region of stress the least until can measure.
Along with the increase of the share of dry brown coal, unpressed discrete material density and the pine under the solidification internal stress of about 4kPa Scattered density of material also increases.This can description below being mixed into the more preferable flowable after dry brown coal: advantageous flows Dynamic property is capable of having encapsulating more closely of relatively low cavity rate and then higher loose thickness.
Therefore, it is possible to determine, dry brown coal are such as mixed into sample 2 advantageously affects the flowable of mixture.
Reference numerals list
1 former brown coal coal bunker
2 mills
3 fluidized bed dryers
4 steam feedings
5 steam
6 electronic filters
The subflow of 7 steam
8 dry brown coal
9 coolers
10 mills
11 dry brown coal storehouses
E1 to E4 is for the extraction position of dry brown coal
R1 to R4 is for the recirculation position of dry brown coal

Claims (10)

1. the method carrying out ore dressing for former brown coal moist to ore deposit, wherein, first by former brown coal precrushing and then exists Being pulverized at least one milling device and flow to follow-up being dried, described being dried is utilizing at least one indirectly to be added Implementing in fluosolids in the case of the fluidized bed dryer of heat, described fluidized bed dryer steam is transported as fluidizing agent OK, wherein, using former brown coal as having mean diameter d50Discrete material for maximum 2mm is thrown in fluosolids, and from institute That states before branching out subflow and be dried described in this subflow being incorporated in the brown coal being dried in fluidized bed dryer downstream is former Brown coal, wherein, regulate the share of the dry brown coal of recirculation, and are mixed into former brown according to the amount of the former brown coal flowing to fluosolids The discrete material density under compression of the share of the dry brown coal of the recirculation in coal and described former brown coal and/or adhesiveness Can change relatively.
2. the method for claim 1, it is characterised in that the share of the dry brown coal of the recirculation being mixed into former brown coal accounts for whole Between 10 mass % and 30 mass % of individual loose material.
3. method as claimed in claim 2, it is characterised in that the share of the dry brown coal of the recirculation being mixed into former brown coal accounts for whole Between 10 mass % and 20 mass % of individual loose material.
4. the method as described in one of claims 1 to 3, it is characterised in that the dry brown coal being branched are utilizing at least one mixed Closely mixed with former brown coal before introducing described fluidized bed dryer in the case of locking device.
5. the method as described in one of claims 1 to 3, it is characterised in that dry brown coal are entered in the downstream of fluidized bed dryer Row cooling and be subjected to mill again, and need the subflow of dry brown coal of recirculation in the described downstream branch milled again.
6. the method as described in one of claims 1 to 3, it is characterised in that dry brown coal are milled between level or upper at two The downstream of one level of milling is mixed in former brown coal.
7. the method as described in one of claims 1 to 3, it is characterised in that former brown coal and being blended in of dry brown coal utilize at least Carry out in the conveying of described fluidized bed dryer at discrete material in the case of one static mixing arrangement.
8. the method as described in one of claims 1 to 3, it is characterised in that the rotation being arranged on fluid bed by least one Former brown coal are poured in fluosolids by the allotter chute turned.
9. method as claimed in claim 8, it is characterised in that presetting according to the cross section about described fluidized bed dryer Distribution former brown coal are poured in fluosolids.
10. the method for claim 1, it is characterised in that described method heat utilization in station boiler.
CN201380026540.0A 2012-05-23 2013-05-22 The method carrying out ore dressing for former brown coal moist to ore deposit Expired - Fee Related CN104334989B (en)

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DE102012010078.7 2012-05-23
DE102012010078A DE102012010078A1 (en) 2012-05-23 2012-05-23 Process for the treatment of gruel wet lignite
PCT/EP2013/060437 WO2013174828A1 (en) 2012-05-23 2013-05-22 Method for processing pit-moist raw brown coal

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